公开(公告)号：WO02068538A3

公开(公告)日：2002-10-31

申请号：PCT/EP0201573

申请日：2002-02-14

Applicant: BASF AG ,  MAX PLANCK GESELLSCHAFT ,  BOEHM ARNO ,  KRIEGER MATTHIAS ,  BECKER STEFAN ,  MUELLEN KLAUS

Inventor： BOEHM ARNO ,  KRIEGER MATTHIAS ,  BECKER STEFAN ,  MUELLEN KLAUS

IPC: C07B61/00 ,  C07D221/18 ,  C09B5/62 ,  C09D5/26 ,  C09D7/12 ,  C09D11/02 ,  C09D201/00 ,  C09K9/02 ,  C08K5/3437 ,  C09D11/00

CPC classification number: C09B5/62 ,  C07D221/18

Abstract: The invention relates to rylene dyes of general formula (I), in which: R represents hydrogen or optionally substituted C1-C30 alkyl, aryl or heteroaryl; R' represents optionally substituted C2-C30 alkyl or C5-C8 cycloalkyl, or substituted methyl; n represents 0 or 1. The invention also relates to the production of said dyes, to the use thereof for colouring highly molecular organic and inorganic materials and to aminorylene-3,4-dicarboxylic acid imides IV as their intermediate products.

Abstract translation: 通式（I）的Rylene染料具有以下变量的含义：R是氢; 任选取代的C 1 -C 30烷基，芳基或杂芳基; R'是任选取代的C 2 -C 30 - 烷基或C 5 -C 8 - 环烷基，取代的甲基; n为0或1，它们的制备和用于高分子量有机和无机材料和氨基萘-3,4-二甲酰亚胺IV作为其中间体的Einfarbüng。

公开(公告)号：WO2006021307A8

公开(公告)日：2007-02-08

申请号：PCT/EP2005008443

申请日：2005-08-04

Applicant: BASF AG ,  KOENEMANN MARTIN ,  BOEHM ARNO ,  BIDLINGMAIER HERMANN ,  RIEGER REINHOLD ,  BLASCHKA PETER ,  REICHELT HELMUT ,  KRIEGER MATTHIAS

Inventor： KOENEMANN MARTIN ,  BOEHM ARNO ,  BIDLINGMAIER HERMANN ,  RIEGER REINHOLD ,  BLASCHKA PETER ,  REICHELT HELMUT ,  KRIEGER MATTHIAS

IPC: C07D471/06 ,  C09B5/62

CPC classification number: C07D471/06 ,  C09B5/62

Abstract: The invention relates to a method for producing the quaterrylene-3,4:13,14-tetracarboxy diimides of general formula (I), wherein R, R' independently represent hydrogen or optionally substituted C 1 -C 30 alkyl, C 3 -C 8 cycloalkyl or aryl or hetaryl. The inventive method is characterized by reacting the perylene-3,4-dicarboximide of the general formula (IIa) in the presence of a base resistant, high-boiling, organic solvent and an alkali-containing or alkaline earth-containing base with the perylene-3,4-dicarboximide of the general formula (IIb), wherein X represents hydrogen, bromine or chlorine.

Abstract translation: 一种制备四萘-3,4-过程：通式（I）其中R，R“独立地是氢或任选取代的C _{的13,14-四羧酸二酰亚胺1 -C 30 8 烷基，C 3 -C 的环烷基，或芳基或杂芳基，其特征在于，（通式IIA的苝-3,4-二甲酰亚胺 ）中，在碱稳定的，高沸点有机溶剂的存在下，并用通式（IIb）中，其中X是氢，溴或氯的苝-3,4-二甲酰亚胺的碱金属或碱土金属碱，进行反应。}

公开(公告)号：WO02076988A3

公开(公告)日：2003-02-13

申请号：PCT/EP0203279

申请日：2002-03-20

Applicant: BASF AG ,  BOEHM ARNO ,  HELFER WILLI ,  BECK GEORG ,  KRIEGER MATTHIAS ,  ERK PETER

Inventor： BOEHM ARNO ,  HELFER WILLI ,  BECK GEORG ,  KRIEGER MATTHIAS ,  ERK PETER

IPC: C07D221/18 ,  A61K8/18 ,  A61K8/49 ,  A61K8/58 ,  A61Q1/00 ,  A61Q1/02 ,  C07D209/56 ,  C07D211/08 ,  C07D241/38 ,  C07D471/06 ,  C07D487/06 ,  C07D487/22 ,  C08K5/00 ,  C09B3/44 ,  C09B5/62 ,  C09B47/18 ,  C09B69/00 ,  C09B69/10 ,  C09D5/36 ,  C09D7/12 ,  C09D11/00 ,  C09D11/02 ,  C09D201/00

CPC classification number: C07D241/38 ,  C07D209/56 ,  C07D211/08 ,  C07D471/06 ,  C07D487/06 ,  C08K5/0041 ,  C09B3/44 ,  C09B5/62 ,  C09B47/18 ,  C09B69/00 ,  C09D5/36 ,  C09D11/037

Abstract: Tert. alkylphenoxy substituted polycyclic compounds of general formula (I), in which the variables have the following meanings: P = a conjugated polycyclic group, optionally aryl substituted, stable to base and acid and not containing residues from the group -CO-NH-CO-, -COOH and -CO-O-CO-; R = C1-C8 alkyl, the carbon chain of which may be interrupted by one or several groups of -O-, -S-, -NR -, -CO- and/or -SO2- and which may be mono- or serially-substituted by C1-C6 alkoxy or a 5- to 7-membered heterocyclic group, bonded by means of a nitrogen atom, which can contain further heteroatoms and can be aromatic, C5-C8 cycloalkyl, the carbon skeleton of which may be interrupted by one or several groups of -O-, -S-, -NR -, -CO- and/or -SO2- and may optionally be substituted with C1-C6 alkyl; R = H or C1-C6 alkyl; Hal = chlorine and/or bromine; m = a number from 0 to 15; n = a number from 1 to 16, whereby the sum m + n

Abstract translation: 叔alkylphenoxysubstituierte通式（I），其中各变量具有以下含义的多环化合物：P a到碱和亲核试剂stabilier，任选的芳基取代基的苯基，共轭多环基团，其不含有选自基团-CO-NH-CO- ，-COOH和-CO-O-CO-包含; [R C1-C8烷基，其碳链被一个或多个-O - ， - S - ， - NR <1> - 可以被中断， - CO-和/或-SO 2和由C 1 -C 6 - 烷氧基或 通过氮原子键合的5至7元杂环基团，其可包含其它杂原子，并且可以是芳族的，可以是单或多取代的; C5-C8环烷基，其碳骨架由一个或多个-O - ， - S - ， - NR <1> - 可以被中断， - CO-和/或-SO 2 - 和其任选地单 - 或C1取代 -C 6烷基可以被取代; [R <1>是氢或C1-C6烷基; Hal是氯和/或溴; m是从0至15的数; n是一个从1到16，m + n的

公开(公告)号：DE50203504D1

公开(公告)日：2005-08-04

申请号：DE50203504

申请日：2002-03-20

Applicant: BASF AG

Inventor： BOEHM ARNO ,  HELFER WILLI ,  BECK GEORG ,  KRIEGER MATTHIAS ,  ERK PETER

IPC: C07D221/18 ,  A61K8/18 ,  A61K8/49 ,  A61K8/58 ,  A61Q1/00 ,  A61Q1/02 ,  C07D209/56 ,  C07D211/08 ,  C07D241/38 ,  C07D471/06 ,  C07D487/06 ,  C07D487/22 ,  C08K5/00 ,  C09B3/44 ,  C09B5/62 ,  C09B47/18 ,  C09B69/00 ,  C09B69/10 ,  C09D5/36 ,  C09D7/12 ,  C09D11/00 ,  C09D11/02 ,  C09D201/00

Abstract: Tert-alkylphenoxy-substituted polycyclic compounds of the general formula I where P is a conjugated polycyclic radical which is stable to bases and nucleophiles, optionally bears aryl substituents and contains no group from the group consisting of -CO-NH-CO-, -COOH and -CO-O-CO-; R is C 1 -C 8 -alkyl, whose carbon chain may be interrupted by one or more groups selected from the group consisting of -O-, -S-, -NR 1 -, -CO- and/or -SO 2 - and which may be monosubstituted or polysubstituted by C 1 -C 6 -alkoxy or by a 5- to 7-membered heterocyclic radical which is attached via a nitrogen atom and may contain further heteroatoms and be aromatic; C 5 -C 8 -cycloalkyl whose carbon chain may be interrupted by one or more groups selected from the group consisting of -O-, -S-, -NR 1 -, -CO- and/or -SO 2 - and which may be monosubstituted or polysubstituted by C 1 -C 6 -alkyl; R 1 is hydrogen or C 1 -C 6 -alkyl; Hal is chlorine and/or bromine; m is from 0 to 15; n is from 1 to 16, subject to the proviso that the sum m+n is

公开(公告)号：AU2003238211A1

公开(公告)日：2003-12-22

申请号：AU2003238211

申请日：2003-06-04

Applicant: BASF AG

Inventor： REUTHER ERIK ,  MULLEN KLAUS ,  BOHM ARNO ,  KRIEGER MATTHIAS

IPC: C07D471/06 ,  C09B5/62 ,  C09K11/06

Abstract: New 1,6,9,14-tetra-substituted terrylenetetracarbodiimides (I) are claimed, in which the 1,6-positions and 9,14-positions independently are substituted by bromo, cyano, (het)aryloxy, (het)arylthio, optionally substituted (hetero)-alk(en)yl or -alkynyl, N-heterocyclyleth(en)yl, N-heterocyclylethynyl or (substituted) amino. 1,6,9,14-Tetra-substituted terrylenetetracarbodiimides of formula (I) are new X, Y = Br, CN, (het)aryloxy or (het)arylthio (optionally mono- or poly-substituted by 1-12C alkyl, 1-12C alkoxy, -COOR1, -SO3R1, halogen, COOH, carboxy, CN, -CONHR2 and/or -NHCOR2), -L-R3, -N(R2)2; R, R' = H, 1-30C alkyl (optionally with -O-, -S-, -NR1-, -CO- and/or -SO2- group(s) in the chain and optionally mono- or poly-substituted by CN, 1-6 C alkoxy, aryl (optionally substituted by 1-18 C alkyl or 1-6 C alkoxy) and/or a 5-7-N-heterocyclic group, which may contain other hetero-atoms and may be aromatic), 5-8 C cycloalkyl (optionally with -O-, -S- and/or -NR1- group(s) in the C skeleton and/or mono- or poly-substituted by 1-6 C alkyl), (het)aryl (optionally mono- or poly-substituted by 1-18 C alkyl, 1-6 C alkoxy, CN, -CONHR2, -NHCOR2 and/or (het)arylazo, which may be substituted by 1-10 C alkyl, 1-6 C alkoxy or CN); L = 1,2-ethylene, 1,2-ethenylene or 1,2-ethynylene; R1 = H or 1-6C alkyl; R2 = H, 1-18C alkyl or (het)aryl, optionally substituted by 1-6 C alkyl, 1-6 C alkoxy, halogen, OH, carboxy or CN); R3 = 1-18C alkyl (optionally with -O-, -S-, -NR1-, -CO- and/or -SO2- group(s) in the chain and optionally substituted by -COOR1, -SO3R1, OH, CN, 1-6C alkoxy, aryl (optionally substituted by 1-18 C alkyl or 1-6 C alkoxy) and/or a 5-7-N-heterocyclic group, which may contain other hetero-atoms and may be aromatic). Independent claims are also included for methods of preparing (I).

公开(公告)号：DE10102647A1

公开(公告)日：2002-07-25

申请号：DE10102647

申请日：2001-01-20

Applicant: BASF AG

Inventor： BUETHE INGOLF ,  WALTER HANS-MICHAEL ,  DEHNICKE KURT ,  GREINER ANDREAS ,  KRIEGER MATTHIAS ,  MAST CHRIASTIAN OLIVER ,  SCHROERS MICHAEL

IPC: B01J23/755 ,  B01J31/14 ,  B01J31/18 ,  B01J31/28 ,  C08F4/606 ,  C08F132/08 ,  C08F255/00 ,  C08F297/06 ,  C08F297/08 ,  C08F232/00

Abstract: Catalysts containing a nickel-phosphoraniminato complex and a borane or borate. Catalyst comprises: (a) a nickel-phosphoraniminato complex of formula (I); and (b) a borane or borate. (NiX(NPR3))4 (I) X = a covalently-bonded or weakly-coordinating ligand; and R = 1-20C alkyl, 6-20C aralkyl or 1-20C alkyl-phosphacyclopentanyl. Independent claims are included for: (1) a method for the polymerisation of cyclo-olefins in presence of catalyst (I); (2) polycyclo-olefins with a glass transition point (Tg) of 100 deg C or above, a weight average molecular weight of 50000-2 million and a heterogeneity (Mw/Mn) of 1.3 or less; and (3) block copolymers or graft copolymers containing a polycyclo-olefin block as above.

公开(公告)号：DE102004041604A1

公开(公告)日：2006-03-02

申请号：DE102004041604

申请日：2004-08-26

Applicant: BASF AG

Inventor： KOENEMANN MARTIN ,  BOEHM ARNO ,  BIDLINGMAIER HERMANN ,  RIEGER REINHOLD ,  BLASCHKA PETER ,  REICHELT HELMUT ,  KRIEGER MATTHIAS

IPC: C07D471/06 ,  C09B5/62

Abstract: A process for preparing quaterrylene-3,4:13,14-tetracarboximides of the general formula I in which R, R′ are each independently hydrogen or optionally substituted C1-C30-alkyl, C5-C8-cycloalkyl or aryl or hetaryl; which comprises reacting a perylene-3,4-dicarboximide of the general formula IIa in the presence of a base-stable, high-boiling, organic solvent and of an alkali metal base or alkaline earth metal base, with a perylene-3,4-dicarboximide of the general formula IIb in which X is hydrogen, bromine or chlorine.

公开(公告)号：ES2244777T3

公开(公告)日：2005-12-16

申请号：ES02735166

申请日：2002-03-20

Applicant: BASF AG

Inventor： BOHM ARNO ,  HELFER WILLI ,  BECK GEORG ,  KRIEGER MATTHIAS ,  ERK PETER

IPC: C07D221/18 ,  A61K8/18 ,  A61K8/49 ,  A61K8/58 ,  A61Q1/00 ,  A61Q1/02 ,  C07D209/56 ,  C07D211/08 ,  C07D241/38 ,  C07D471/06 ,  C07D487/06 ,  C07D487/22 ,  C08K5/00 ,  C09B3/44 ,  C09B5/62 ,  C09B47/18 ,  C09B69/00 ,  C09B69/10 ,  C09D5/36 ,  C09D7/12 ,  C09D11/00 ,  C09D11/02 ,  C09D201/00

Abstract: Compuestos policíclicos substituidos por terc.- alquilfenoxi de la fórmula general I en las que las variables tienen el significado siguiente: P significa un resto policíclico conjugado, que porta en caso dado substituyentes de arilo, estable frente a las bases y a los nucleófilos, que no contiene agrupamientos contenidos en el grupo formado por -CO- NH-CO-, -COOH y -CO-O-CO-, quedando excluidos las metalftalocianinas y, en el caso en que n signifique 4, la dimida del ácido perilen-3, 4:9, 10- tetracarboxílico N, N¿-disubstituida; R significa alquilo con 1 a 8 átomos de carbono, cuya cadena carbonada puede estar interrumpida por uno o varios agrupamientos -O-, -S-, -NR1-, -CO- y/o -SO2- y que puede estar substituido una o varias veces por alcoxi con 1 a 6 átomos de carbono o por un resto heterocíclico con 5 hasta 7 miembros, enlazado a través de un átomo de nitrógeno, que puede contener otros heteroátomos y que puede ser aromático; cicloalquilo con 5 a 8 átomos de carbono, cuya estructuracarbonada puede estar interrumpida por uno o varios agrupamientos -O-, -S-, -NR1-, -CO- y/o -SO2- y que puede estar substituido, en caso dado, una o varias veces por alquilo con 1 a 6 átomos de carbono; R1 significa hidrógeno o alquilo con 1 a 6 átomos de carbono; Hal significa cloro y/o bromo; m significa un número desde 0 hasta 15; n significa un número desde 1 hasta 16, siendo la suma m + n 16.

公开(公告)号：DE10238994A1

公开(公告)日：2004-02-26

申请号：DE10238994

申请日：2002-08-20

Applicant: BASF AG

Inventor： KRIEGER MATTHIAS ,  BOEHM ARNO ,  SIGGEL LORENZ ,  BECKER STEFAN ,  MUELLEN KLAUS ,  KOHL CHRISTOPHER

IPC: G03G5/06 ,  C07D487/06 ,  C07D487/22 ,  C09B5/24 ,  C09B5/62 ,  C09C3/08 ,  C09D7/12 ,  C09D11/00 ,  C09B3/68

Abstract: New mono- and bis-rylenedicarbimidyl-anthraquinone dyes (I) are claimed. New mono- and bis-rylenedicarbimidyl-anthraquinone dyes are of formula (I). R = H or (substituted) 1-30 C alkyl, 5-8 C cycloalkyl or (het)aryl; R' = Br, CN, -NR32 or (substituted) (het)aryloxy, (het)arylthio or 3-18 C alk-1-ynyl; R3 = H, 1-18 C alkyl or (substituted) (het)aryl; or NR32 = a 5-7-membered heterocyclic group; X, Y = H or together a 6-membered ring attached to a rylene ring system (Ia), in which X corresponds to the -NH- group and Y to the other free bond; n = 2, 3, 4 or may also be 1 if X and Y are a (Ia) group; and m = 0-6. The full definitions are given in the DEFINITIONS (Full Definitions) Field. Independent claims are also included for methods of preparing asymmetric (I; where X, Y = H) and symmetric and asymmetric (I, where X, Y = a 6-membered ring attached to arylene ring system).

公开(公告)号：AU2003238211A8

公开(公告)日：2003-12-22

申请号：AU2003238211

申请日：2003-06-04

Applicant: MAX PLANCK GESELLSCHAFT ,  BASF AG

Inventor： REUTHER ERIK ,  MULLEN KLAUS ,  BOHM ARNO ,  KRIEGER MATTHIAS

IPC: C07D471/06 ,  C09B5/62 ,  C09K11/06

Abstract: New 1,6,9,14-tetra-substituted terrylenetetracarbodiimides (I) are claimed, in which the 1,6-positions and 9,14-positions independently are substituted by bromo, cyano, (het)aryloxy, (het)arylthio, optionally substituted (hetero)-alk(en)yl or -alkynyl, N-heterocyclyleth(en)yl, N-heterocyclylethynyl or (substituted) amino. 1,6,9,14-Tetra-substituted terrylenetetracarbodiimides of formula (I) are new X, Y = Br, CN, (het)aryloxy or (het)arylthio (optionally mono- or poly-substituted by 1-12C alkyl, 1-12C alkoxy, -COOR1, -SO3R1, halogen, COOH, carboxy, CN, -CONHR2 and/or -NHCOR2), -L-R3, -N(R2)2; R, R' = H, 1-30C alkyl (optionally with -O-, -S-, -NR1-, -CO- and/or -SO2- group(s) in the chain and optionally mono- or poly-substituted by CN, 1-6 C alkoxy, aryl (optionally substituted by 1-18 C alkyl or 1-6 C alkoxy) and/or a 5-7-N-heterocyclic group, which may contain other hetero-atoms and may be aromatic), 5-8 C cycloalkyl (optionally with -O-, -S- and/or -NR1- group(s) in the C skeleton and/or mono- or poly-substituted by 1-6 C alkyl), (het)aryl (optionally mono- or poly-substituted by 1-18 C alkyl, 1-6 C alkoxy, CN, -CONHR2, -NHCOR2 and/or (het)arylazo, which may be substituted by 1-10 C alkyl, 1-6 C alkoxy or CN); L = 1,2-ethylene, 1,2-ethenylene or 1,2-ethynylene; R1 = H or 1-6C alkyl; R2 = H, 1-18C alkyl or (het)aryl, optionally substituted by 1-6 C alkyl, 1-6 C alkoxy, halogen, OH, carboxy or CN); R3 = 1-18C alkyl (optionally with -O-, -S-, -NR1-, -CO- and/or -SO2- group(s) in the chain and optionally substituted by -COOR1, -SO3R1, OH, CN, 1-6C alkoxy, aryl (optionally substituted by 1-18 C alkyl or 1-6 C alkoxy) and/or a 5-7-N-heterocyclic group, which may contain other hetero-atoms and may be aromatic). Independent claims are also included for methods of preparing (I).