Polymer dispersion for contact adhesives, obtained by radical polymerization from the polymer dispersion of a monomer mixture containing a Redox initiator useful as contact adhesive tapes for sealing cartons

    公开(公告)号:DE10128512A1

    公开(公告)日:2002-12-19

    申请号:DE10128512

    申请日:2001-06-13

    Applicant: BASF AG

    Abstract: Packaging contact adhesive tapes obtained by production of a polymer dispersion containing a contact adhesive by radical polymerization at 80 deg C of a monomer mixture in the presence of a Redox initiator, where at least 50 wt.% of the oxidation component is in the polymerisation vessel and the reduction component and the bulk of the monomer is added continuously. Process for preparation of an aqueous polymer dispersion by radical polymerization of a monomer mixture containing (wt.%): (a) 4-12C alkyl acrylates (80-99); (b) at least one monomer different from (a) of glass transition temperature of at least 0 deg C selected from: 1-20C alkyl (meth)acrylates, vinyl esters of 1-20C carboxylic acids, vinyl aromatic, ethylenically unsaturated nitriles, vinyl halogenides, vinylidene halogenides, and their mixtures (0-20); (c) at least one ethylenically unsaturated mono- or dicarboxylic acid or its anhydride (0-10); and (d) at least one different from (a) and (b) ethylenically unsaturated monomers (0-20), in the presence of at least one Redox initiator, including an oxidation component and at least one reduction component, in a polymerization vessel, where most of the monomer undergoing polymerization is added continuously to the polymerization vessel and the maximum polymerization temperature is 80 deg C. Independent claims are included for: (1) a polymer dispersion obtainable by the above process; (2) a contact adhesive containing at least one aqueous polymer dispersion as described above; (3) an adhesive tape or label including a carrier and a coating and at least one contract adhesive.

    4.
    发明专利
    未知

    公开(公告)号:DE59809053D1

    公开(公告)日:2003-08-28

    申请号:DE59809053

    申请日:1998-05-22

    Applicant: BASF AG

    Abstract: Adhesives (I), containing (a) 5-95 wt% adhesive dispersion with a viscosity of 2000-10,000 mPa.s which contains (a1) an aqueous polymer dispersion obtained by radical polymerisation of a mixture (M) containing ethylenically unsaturated monomer(s) (A) to a polymer (P) in presence of a protective colloid based on a water-soluble prepolymer of at least one water-soluble monomer (B) selected from alpha . beta -unsaturated 3-6C mono- or di-carboxylic acids, their anhydrides and half-esters and mixtures thereof, (a2) optionally a base, i.e. alkali metal hydroxide, ammonia or volatile amine, (a3) optionally a completely water-miscible organic solvent, and optionally other additives, (b) 0-90 wt% polysaccharide and/or protein and/or protein degradation product, (c) 0-95 wt% filler(s), (d) 0-10 wt% emulsifier(s), (e) 0-30 wt% other additives, and water to 100 wt%.

    6.
    发明专利
    未知

    公开(公告)号:DE19721691A1

    公开(公告)日:1998-11-26

    申请号:DE19721691

    申请日:1997-05-23

    Applicant: BASF AG

    Abstract: Adhesives (I), containing (a) 5-95 wt% adhesive dispersion with a viscosity of 2000-10,000 mPa.s which contains (a1) an aqueous polymer dispersion obtained by radical polymerisation of a mixture (M) containing ethylenically unsaturated monomer(s) (A) to a polymer (P) in presence of a protective colloid based on a water-soluble prepolymer of at least one water-soluble monomer (B) selected from alpha . beta -unsaturated 3-6C mono- or di-carboxylic acids, their anhydrides and half-esters and mixtures thereof, (a2) optionally a base, i.e. alkali metal hydroxide, ammonia or volatile amine, (a3) optionally a completely water-miscible organic solvent, and optionally other additives, (b) 0-90 wt% polysaccharide and/or protein and/or protein degradation product, (c) 0-95 wt% filler(s), (d) 0-10 wt% emulsifier(s), (e) 0-30 wt% other additives, and water to 100 wt%.

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