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    Method for producing polymer aqueous dispersion
    1.
    发明专利
    Method for producing polymer aqueous dispersion 审中-公开
    生产聚合物水性分散体的方法

    公开(公告)号：JP2003048906A

    公开(公告)日：2003-02-21

    申请号：JP2002147950

    申请日：2002-05-22

    Applicant: Basf Ag ,  ビーエーエスエフ アクチェンゲゼルシャフト

    Inventor： GERST MATTHIAS ,  LAUBENDER MATTHIAS ,  RECK BERND DR

    IPC: C08L33/02 ,  C08F2/16 ,  C08F2/22 ,  C08F2/26 ,  C08F2/44 ,  C08F220/18 ,  C08F265/02 ,  C08K5/5415 ,  C08L35/00 ,  D04H1/58

    CPC classification number: C08F265/02 ,  C08F2/26 ,  C08F2/44 ,  C08F220/18 ,  C08K5/5415

    Abstract: PROBLEM TO BE SOLVED: To more improve various performance characteristics of a thermoplastic binder, particularly the strength of a molded product produced therefrom as compared with that of the conventional corresponding products thereof. SOLUTION: A method for producing a polymer aqueous dispersion is provided. The polymer aqueous dispersion comprises an emulsion polymer, a polymer composed of at least 5 mass% of an ethylenically unsaturated monocarboxylic acid, dicarboxylic acid or dicarboxylic acid anhydride (abbreviated to an acid polymer SP) and an alkoxysilane represented by the formula SiR R R R [wherein, groups R to R denote each mutually independently an organic group and at least one of the groups denotes an alkoxy group]. The method for production is characterized by producing the emulsion polymer in the presence of at least a small amount of the alkoxysilane by an emulsion polymerization.

    Abstract translation: 要解决的问题：为了更好地改善热塑性粘合剂的各种性能特征，特别是与其生产的模制产品的强度相比，与常规相应的产品相比。 解决方案：提供一种制备聚合物水分散体的方法。 聚合物水性分散体包含乳液聚合物，由至少5质量％的烯属不饱和一元羧酸，二羧酸或二羧酸酐（缩写为酸性聚合物SP）和由式SiR 1表示的烷氧基硅烷组成的聚合物， R 2 R 3 R 4 [其中，基团R 1至R 4各自独立地表示有机基团，并且至少一个基团表示烷氧基]。 生产方法的特征在于通过乳液聚合在至少少量的烷氧基硅烷存在下制备乳液聚合物。

    MESOPOROUS SILICA AND ITS PRODUCTION
    2.
    发明专利
    MESOPOROUS SILICA AND ITS PRODUCTION 失效

    公开(公告)号：JPH10152316A

    公开(公告)日：1998-06-09

    申请号：JP25677097

    申请日：1997-09-22

    Applicant: BASF AG

    Inventor： MUELLER ULRICH DR ,  RECK BERND DR ,  ROSER JOACHIM DR

    IPC: C12N11/14 ,  A61K47/02 ,  A61K47/04 ,  B01J21/08 ,  B01J35/10 ,  C01B33/12 ,  C01B37/02 ,  C09C1/30

    Abstract: PROBLEM TO BE SOLVED: To obtain a new mesoporous silica having respectively specific surface area and volume of the mesopores and useful as a molded article, a catalyst or a catalyst carrier by converting a silica precursor in a water-containing reaction medium containing a polymer dispersion liquid. SOLUTION: The mesopore of this mesoporous silica has a specific surface area of >=500m /g and a volume of >=1.0mL/g. The maximum size of the pare diameter distribution of the mesopore is preferably >=3nm. The obtained silica is preferably baked. The polymer dispersion liquid is preferably a cationic aqueous polymer dispersion liquid stabilized with a cationic emulsifier and/or a cationic comonomer (emulsifying agent or α,β-ethylenic unsaturated monomer having quaternary amine or ammonium structure). These emulsified polymers can be produced preferably by using a free-radical polymerization initiator having a cationic group.

    4.
    发明专利
    未知

    公开(公告)号：DE19749731A1

    公开(公告)日：1999-05-12

    申请号：DE19749731

    申请日：1997-11-11

    Applicant: BASF AG

    Inventor： JAHNS EKKEHARD DR ,  RECK BERND DR

    IPC: B01J13/14 ,  B01J13/18 ,  C04B16/08 ,  C04B20/10 ,  C04B24/00 ,  C04B24/02 ,  C04B24/08 ,  C04B24/12 ,  C09D7/12 ,  C09K5/06 ,  B01J13/02 ,  C08J5/10 ,  C08J7/16

    Abstract: The invention relates to the application of microcapsules I with one or more lipophilic substances as core material. Said lipophilic substances have a solid/liquid phase transition at a temperature ranging from -20 to 120 DEG C and a polymer which is used as a shell and can be obtained by means of radical polymerization of a monomer mixture containing 30 to 100 wt.%, referring to the total weight of the monomers, one or more C1-C24-alkyl esters of the acrylic acid and/or methylacrylic acid (monomer I), 0 to 80 wt.%, referring to the total weight of the monomers, one bi- or polyfuntional monomer (monomer II) which is insoluble or poorly soluble in water, and 0 to 40 wt.%, referring to the total weight of the monomers, and other monomers (monomer III). The microcapsules can be used as latent heat accumulators. The invention also relates to novel microcapsules Ia, spray-dried microcapsules Ia', methods for the production thereof, and to shaped bodies and coating masses containing said microcapsules.

    5.
    发明专利
    未知

    公开(公告)号：DE59600081D1

    公开(公告)日：1998-02-26

    申请号：DE59600081

    申请日：1996-03-20

    Applicant: BASF AG

    Inventor： RECK BERND DR ,  BECKERLE WILHELM FRIEDRICH ,  PORTUGALL MICHAEL DR ,  WISTUBA ECKEHART DR ,  MEISTER MARTIN DR

    IPC: C04B26/04 ,  C04B26/06 ,  C08F212/08 ,  C08F220/12 ,  C08L25/14 ,  C08L33/04 ,  C08L33/06 ,  C08K5/17 ,  C09J125/14 ,  C09J133/06 ,  C09K23/16

    Abstract: A method is claimed for using cationically stabilised aq. polymer dispersions (PD) as binders for moulded prods. based on finely divided materials with a negative surface charge (M). These dispersions contain (A) a dispersed copolymer (A) with a static Tg of 40-110 deg. C, based on (a) 30-80 pts. wt. styrene, (b) 20-70 pts. wt. (1-8C alkyl) (meth)acrylate(s) and (c) 0-10 pts. wt. other radically copolymerisable monomers, and (B) as dispersant, a mixt. of prim., sec. and/or tert. organic mono-amine(s) with at least 8 C atoms and acid addn. salts thereof. Also claimed are (i) polymer dispersions (PD) as above; (ii) moulded prods. based on materials (M) and binders (PD); (iii) rectangular moulded sheets based on (M) and (PD), with a length and breadth of 30-70 cm and a thickness of 1-20 mm; (iv) a process for the prodn. of mouldings (ii), by suspending material (M) in water, adding dispersion (PD), precipitating copolymer (A) onto material (M) by adding bases or salts of multivalent anions, placing the mixt. obtd. in a mould, removing water, and drying; (v) moulded prods. obtd. by this process.

    7.
    发明专利
    未知

    公开(公告)号：DE19734183A1

    公开(公告)日：1999-02-11

    申请号：DE19734183

    申请日：1997-08-07

    Applicant: BASF AG

    Inventor： SCHERZER DIETRICH DR ,  TREULING ULRICH DR ,  RIEBEL LOTHAR ,  RECK BERND DR

    IPC: C08G18/18 ,  C08G18/62

    Abstract: Mixtures containing (a) organic amine(s) and (b) organic polyacid(s) of formula -ÄCH(Z)-C(X)(COOY)Ün- (I) are new, in which n = 2-2600; X = H or 1-6C alkyl, preferably H, methyl or ethyl; Y = H or a cation; and Z = H or -COOY. Also claimed are (i) a process for the production of polyisocyanate-polyaddition products (optionally in the form of foam) by reacting isocyanates with NCO-reactive compounds in the presence of catalysts, blowing agents, additives etc. and mixtures of (a) and (b); and (ii) polyisocyanate polyaddition products containing polyacids as above, their salts and/or reaction products thereof with polyisocyanates, as obtained by the above process.

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