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公开(公告)号:DE19802094A1
公开(公告)日:1999-07-22
申请号:DE19802094
申请日:1998-01-21
Applicant: BASF AG
Inventor: MC KEE GRAHAM EDMUND DR , GOERRISSEN HEINER DR , KOCH JUERGEN DR , KASTENHUBER WALTER
IPC: C08F2/18 , C08F255/08 , C08F265/04 , C08F220/18 , C08F291/02 , C08L51/04 , C14C11/00 , D06M15/21 , D21H17/37
Abstract: Production of an elastomeric (graft)polymer micro-suspension comprises dispersion of a mixture comprising ethylenically unsaturated monomers, crosslinking monomers and aliphatic hydrocarbon polymer; polymerisation of the droplets using a radical polymerisation initiator; and optionally graft polymerisation of the resulting mixture in the presence of ethylenically unsaturated monomers. Production of an elastomeric (graft)polymer micro-suspension (A) comprises (a) dispersion of a mixture comprising (A11) 30-99.9 wt.% ethylenically unsaturated monomers, (A12) 0-20 wt.% crosslinking monomers and (A13) 0.1-50 wt.% aliphatic hydrocarbon polymer having a Tg of less than 0degreesC, (b) polymerisation of the droplets using a radical polymerisation initiator, and optionally (c) graft polymerisation of the resulting mixture in the presence of ethylenically unsaturated monomers. Independent claims are included for (i) the elastomeric (graft) polymer micro-suspension (A); (ii) a molding composition comprising (A) 1-85 wt.% graft polymer, (B)15-99 wt.% of a polymer matrix consisting of polymers of styrene, alpha -methylstyrene, acrylonitrile, methacrylonitrile and/or (meth)acrylic acid ester, (C) 0-50 wt.% fibrous and/or particulate fillers, and (D) 0-40 wt.% other additives; and (iii) fibers, film or molded articles prepared from the molding composition.
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公开(公告)号:ES2124353T3
公开(公告)日:1999-02-01
申请号:ES94114215
申请日:1994-09-09
Applicant: BASF AG
Inventor: FISCHER WOLFGANG DR , GUNTHERBERG NORBERT DR , MC KEE GRAHAM EDMUND DR
IPC: C08F2/22 , C08F212/00 , C08F212/04 , C08F212/06 , C08F220/10 , C08F220/12 , C08L25/00 , C08F220/42 , C08L25/08 , C08L25/12 , C08L25/14 , C08L33/06 , C08L33/18
Abstract: Particulate polymer A, having a mean particle size of below 1000 nm, comprising a1: up to 99.8 % by weight of at least one vinylaromatic monomer a1, a2: up to 99.8 % by weight of at least one alkyl methacrylate a2 having 1 to 8 carbon atoms in the alkyl radical, a3: up to 50 % by weight of at least one polar, copolymerisable, ethylenically unsaturated monomer a3, a4: from 0.1 to 10 % by weight of at least one polyfunctional, crosslinking monomer a4, a5: from 0.1 to 15 % by weight, preferably from 0.5 to 10 % by weight, of at least one monomer a5 containing one or more acidic, basic or epoxy groups, where the total amount of constituents a1, a2 and a3 is from 75 % by weight to 99.8 % by weight, based on A, and the total amount of a1, a2, a3, a4 and a5 is 100 % by weight, based on A.
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公开(公告)号:DE19728629A1
公开(公告)日:1999-01-07
申请号:DE19728629
申请日:1997-07-04
Applicant: BASF AG
Inventor: GUENTHERBERG NORBERT DR , KOCH JUERGEN DR , ITTEMANN PETER DR , SEIBRING JOACHIM DR , GRABOWSKI SVEN DR , MC KEE GRAHAM EDMUND DR , MOSBACH NORBERT
Abstract: The invention relates to thermoplastic molding material containing the constituents A) to F), 5 to 80 wt. % of a graft polymer A) with a bimodal particle size distribution, 20 to 95 wt. % of a thermoplastic polymer B) with a viscosity VZ of 50 to 120 ml/g and optionally other thermoplastic polymers C), D) and/or E) based on at least one vinyl-aromatic monomer, and optionally additives F). The inventive material can be obtained by 1) producing the graft polymers A) according to the emulsion polymerization method, 2) mixing the graft polymer A) with polymer B) and, insofar as they are available, the other constituents C), D), E) and/or F) in a mixing device, whereby a substantially molten polymer mixture arises and 3) rapidly cooling the substantially molten polymer mixture.
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公开(公告)号:DE19719061A1
公开(公告)日:1998-11-12
申请号:DE19719061
申请日:1997-05-06
Applicant: BASF AG
Inventor: RIEF URSULA DR , MC KEE GRAHAM EDMUND DR
IPC: C08F2/38 , C08F14/06 , C08F114/06
Abstract: A process for the polymerisation of vinyl chloride (VC) at 20-100 deg C and 5-30 bar, in which polymerisation is stopped by the addition of 1,1-diphenyl-ethylene (DPE) or a derivative of DPE.
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公开(公告)号:DE19651299A1
公开(公告)日:1998-06-18
申请号:DE19651299
申请日:1996-12-10
Applicant: BASF AG
Inventor: JUENGLING STEPHAN DR , MC KEE GRAHAM EDMUND DR , WARZELHAN VOLKER DR , GAUSEPOHL HERRMANN DR , FISCHER MICHAEL DR
IPC: C08L55/00 , C08F2/00 , C08F20/00 , C08F20/12 , C08F287/00 , C08F297/02 , C08L53/00 , C08F220/18 , C08L33/04 , C08J5/00 , C08J5/18 , D01F6/36
Abstract: A process is disclosed for producing reaction mixtures including homopolymers, copolymers or block copolymers, and for producing homopolymers, copolymers and block copolymers containing acrylates and/or methacrylates. The process is characterised in that olefinically unsaturated compounds which are not derived from acrylate or methacrylate are used as solvents or as solvent components.
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公开(公告)号:DE19630135A1
公开(公告)日:1998-01-29
申请号:DE19630135
申请日:1996-07-25
Applicant: BASF AG
Inventor: NAARMANN HERBERT DR , MC KEE GRAHAM EDMUND DR , PIRKER ALFRED , STERZEL HANS-JOSEF DR , BRANDSTETTER FRANZ PROF DR , BERNSTORFF BERND-STEFFEN VON D , ROSENAU BERNHARD DR , ENDEMANN ULRICH DR , STRAUBE BURKHARD
IPC: C08F255/02 , C08F265/04 , C08F283/12 , C08L25/12 , C08L51/00 , C08L51/04 , A63H17/00 , C08L25/02 , C08L33/06 , C08L33/20 , C08L51/08 , C08L69/00
Abstract: The invention concerns the use of thermoplastic moulding materials which are different from ABS and which, in relation to the sum of the quantities of components A and B and optionally C and/or D resulting in a total of 100 wt %, contain a) 1-99 wt %, preferably 15-60 wt %, in particular 25-50 wt % of a particulate emulsion polymer with a glass transition temperature of less than 0 DEG C and a mean particle size of 50-1000 nm, preferably 50-500 nm as component A, b) 1-99 wt %, preferably 40-85 wt %, in particular 50-75 wt % of at least one amorphous or semi-crystalline polymer as component B, c) 0-50 wt % polycarbonates as component C and d) 0-50 wt % fibre or particle-shaped filling materials or their mixtures as component D, for producing toy vehicles for children and parts of the toy vehicles.
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公开(公告)号:DE19540312A1
公开(公告)日:1997-04-30
申请号:DE19540312
申请日:1995-10-28
Applicant: BASF AG
Inventor: WEBER MARTIN DR , WEIS ROBERT DR , HECKMANN WALTER DR , HINGMANN ROLAND DR , MC KEE GRAHAM EDMUND DR
Abstract: Moulding materials (MM), containing (A) 1-96.5 wt% halogen- free polycarbonate(s), (B) 1-96.5 wt% halogen-free graft copolymer consisting of (b1) 40-80 wt% rubber-elastic grafting base with a Tg of below 0 deg C and (b2) 20-60 wt% grafted shell derived from (b21) 50-95 wt% vinylaromatic monomers of formula (I), in which R = H or 1-8C alkyl; R = 1-8C alkyl; n = 0, 1, 2 or 3; and/or MMA, and (b22) 5-50 wt% (meth)acrylonitrile, MMA and/or maleic anhydride, (C) 1-96.5 wt% halogen-free thermoplastic copolymer with an average mol. wt. (Mw) of less than 400,000, derived from (c1) 50-95 wt% monomer (I) and/or MMA and (c2) 5-50 wt% comonomer(s) as in (b22), (D) 0.5-30 wt% halogen-free thermoplastic copolymer with a Mw of at least 800,000 and a wide mol. wt. distribution, derived from (d1) 50-95 wt% monomer(s) (I), (d2) 5-50 wt% comonomers as in (b22) and (d3) 0-15 wt% mono-unsaturated comonomers with at least one polar functional group, (E) 1-25 wt% halogen-free phosphorus compound(s) and (F) 0-50 wt% additives. Also claimed are mouldings, film and fibres containing MM.
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公开(公告)号:DE19524585A1
公开(公告)日:1997-01-09
申请号:DE19524585
申请日:1995-07-06
Applicant: BASF AG
Inventor: WEBER MARTIN DR , HOFMANN JUERGEN , WEIS ROBERT DR , HECKMANN WALTER DR , HINGMANN ROLAND DR , WUENSCH JOSEF DR , MC KEE GRAHAM EDMUND DR
IPC: C08F2/14 , C08F12/00 , C08F12/06 , C08L25/00 , C08L25/06 , C08L71/12 , C08L101/00 , D01F6/46 , D01F6/66 , D01F6/94 , C08L53/02 , C08L21/00 , C08K5/49 , D01F1/07
Abstract: Halogen-free antidrip agents for thermoplastic molding compounds contain polymers based on vinyl aromatic monomers with molecular weights (Mw) of at least 800 000 g/mol and a narrow molecular weight distribution.
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公开(公告)号:DE4328004A1
公开(公告)日:1995-02-23
申请号:DE4328004
申请日:1993-08-20
Applicant: BASF AG
Inventor: NIESSNER NORBERT DR , KNOLL KONRAD DR , GOTTSCHALK AXEL DR , MC KEE GRAHAM EDMUND DR
IPC: C08F293/00 , C08G81/02 , C08L53/00
Abstract: A thermoplastic block copolymer whose branches are arranged in a radial star manner, where the branches each comprise at least two monomer sequences (blocks), characterised in that at least two types of blocks A and B participate in the construction of a branch (where block A essentially comprises polymethacrylate and block B essentially comprises polyacrylate), as obtained by group-transfer polymerisation followed by coupling with a difunctional or polyfunctional coupling agent.
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公开(公告)号:DE3911828A1
公开(公告)日:1990-10-18
申请号:DE3911828
申请日:1989-04-11
Applicant: BASF AG
Inventor: MC KEE GRAHAM EDMUND DR , KNOLL MANFRED , KOLM PETER , LAUSBERG DIETRICH DR
Abstract: Thermoplastic moulding compositions based on a mixture of polybutylene terephthalate and polyethylene terephthalate (a1), graft polymers containing acrylate rubbers as the graft base (a2), copolymers of vinyl aromatic monomers and acrylonitrile or methacrylonitrile (a3) and glass fibres (B) have a balanced property profile.
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