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公开(公告)号:DE59807759D1
公开(公告)日:2003-05-08
申请号:DE59807759
申请日:1998-09-17
Applicant: BASF AG
Inventor: RUPANER ROBERT , LAWRENZ SVEN , DOBBELAAR JOHANNES , BAUER GERHARD , MUESELER FRANZ-JOSEF , KIRCHNER WERNER , MORRISON RONALD , NAHSTOLL JUERGEN , MEISTER MARTIN , BAECHER REINHARD , HUEBINGER WOLFGANG , SCHUMACHER GERHARD
IPC: C08F6/00
Abstract: A process is described for reducing the residual monomer content in a liquid solution, mixture, melt, suspension or dispersion of a polymer by postpolymerization with addition of a redox initiator system at a reaction temperature appropriate to it and with an extremely short mixing time of the liquid system in the production reactor by metering-gradually, in portions or continuously-at least one of the redox initiator components required to initiate polymerization of the residual monomers over a period (metering time) which is from about 10 to 250 times the mixing time of the liquid system in said reactor.
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公开(公告)号:DE19842482A1
公开(公告)日:2000-03-23
申请号:DE19842482
申请日:1998-09-16
Applicant: BASF AG
Inventor: FULL JOACHIM , ARMBRUSTER HARALD , REHMER GERD , NAHSTOLL JUERGEN
IPC: G05B15/02 , G05B19/418 , G06Q50/00 , B01J19/00
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公开(公告)号:DE59903724D1
公开(公告)日:2003-01-23
申请号:DE59903724
申请日:1999-09-14
Applicant: BASF AG
Inventor: FULL JOACHIM , REHMER GERD , ARMBRUSTER HARALD , NAHSTOLL JUERGEN
IPC: G05B15/02 , G05B19/418 , G06Q50/00
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公开(公告)号:BR9812087A
公开(公告)日:2000-09-26
申请号:BR9812087
申请日:1998-09-17
Applicant: BASF AG
Inventor: RUPANER ROBERT , LAWRENZ SVEN , DOBBELAAR JOHANNES , BAUER GERHARD , MUESELER FRANZ-JOSEF , KIRCHNER WERNER , MORRISON BRADLEY RONALD , NAHSTOLL JUERGEN , MEISTER MARTIN , BOCHER REINHARD , HUEBINGER WOLFGANG H , SCHUMACHER GERHARD
IPC: C08F6/00
Abstract: A process is described for reducing the residual monomer content in a liquid solution, mixture, melt, suspension or dispersion of a polymer by postpolymerization with addition of a redox initiator system at a reaction temperature appropriate to it and with an extremely short mixing time of the liquid system in the production reactor by metering-gradually, in portions or continuously-at least one of the redox initiator components required to initiate polymerization of the residual monomers over a period (metering time) which is from about 10 to 250 times the mixing time of the liquid system in said reactor.
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公开(公告)号:DE19856590A1
公开(公告)日:2000-06-15
申请号:DE19856590
申请日:1998-12-08
Applicant: BASF AG
Inventor: DOBBELAAR JOHANNES , RUPANER ROBERT , GERBERDING KARL , NEUTZNER JOSEF , VISSEREN MARINUS , SCHWAB RUDOLF , NAHSTOLL JUERGEN , MUESELER FRANZ-JOSEF , BAUER GERHARD , HARTMANN JUERGEN , MEISTER MARTIN , LAWRENZ SVEN
Abstract: A process for the emulsion polymerization of olefinically saturated monomers comprises heating the reaction mixture by the addition of heated water or steam. A process to reduce the wall coating and coagulate formation during the radically initiated polymerization of olefinically unsaturated monomers in aqueous emulsions at a polymerization temperature of 35-120 deg C comprises heating the reaction mixture to at least the polymerization temperature by the addition of heated water and/or steam.
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