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公开(公告)号：WO2008034836A2
公开(公告)日：2008-03-27
申请号：PCT/EP2007059870
申请日：2007-09-19
Applicant: BASF AG , SEIDEMANN LOTHAR , KARCHES MARTIN , STUETZER DIETER , SESING MARTIN , SCHUBERT OLGA , URTEL HEIKO
Inventor： SEIDEMANN LOTHAR , KARCHES MARTIN , STUETZER DIETER , SESING MARTIN , SCHUBERT OLGA , URTEL HEIKO
CPC classification number: C01B7/04 , B01J8/1836 , B01J8/1872 , B01J8/34 , B01J19/32 , B01J23/462 , B01J23/868 , B01J2208/00132 , B01J2208/00212 , B01J2219/3221 , B01J2219/32217 , B01J2219/3222 , B01J2219/32227 , B01J2219/32262 , B01J2219/32408 , B01J2219/32425 , B01J2219/32441 , B01J2219/32475 , B01J2219/32483 , Y02P20/228
Abstract: The invention relates to a method for producing chlorine in a fluidized bed reactor, a gaseous reaction mixture containing hydrogen chloride and oxygen flowing from the bottom to the top of a heterogeneous particulate catalyst that forms a fluidized bed. The invention is characterized in that said fluidized bed comprises insertion elements which divide the fluidized bed into a plurality of horizontal and vertical cells arranged in the fluidized bed reactor, the walls of said cells being permeable to gas and having openings for ensuring the exchange of particles of the heterogeneous particulate catalyst in the vertical direction in the range of between 1 and 100 liter(s)/hour per liter of reactor volume.
Abstract translation: 公开了用于在一个流化床反应器，制备氯的方法，其中含有氯化氢和氧气，异构微粒，从底部流过顶部的流化床成形催化剂，其特征在于：折流板设置在流化床的气态反应混合物 划分流化床成多个水平和多个垂直布置在所述流化床反应器中的细胞，与细胞壁可渗透的气体，并且具有开口，其非均相，颗粒催化剂在1至100升每/小时的范围内的垂直方向的交换数 确保升反应器体积。
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公开(公告)号：DE502004004897D1
公开(公告)日：2007-10-18
申请号：DE502004004897
申请日：2004-08-06
Applicant: BASF AG
Inventor： WALSDORFF CHRISTIAN , FIENE MARTIN , SESING MARTIN , METELKINA OLGA , SEIDEMANN LOTHAR , STROEFER ECKHARD , HARTH KLAUS
IPC: C01B7/04
Abstract: The invention relates to a process for preparing chlorine by catalytic gas-phase oxidation of hydrogen chloride, which comprises the steps: a) providing a feed gas stream I comprising hydrogen chloride and a feed gas stream II comprising oxygen; b) in a first oxidation stage, feeding the feed gas stream I, the feed gas stream II, if desired a recycle stream la comprising hydrogen chloride and if desired an oxygen-containing recycle stream IIa into a first oxidation zone and bringing them into contact with a first oxidation catalyst so that a first partial amount of the hydrogen chloride is oxidized to chlorine and a gas stream III comprising chlorine, unreacted oxygen, unreacted hydrogen chloride and water vapor is obtained; c) in a second oxidation stage, feeding the gas stream III into a second oxidation zone and bringing it into contact with at least one further oxidation catalyst so that a second partial amount of the hydrogen chloride is oxidized to chlorine and a product gas stream IV comprising chlorine, unreacted oxygen, unreacted hydrogen chloride and water vapor is obtained; d) isolating chloride, if desired the recycle stream Ia and if desired the recycle stream IIa from the product gas stream IV, wherein the first oxidization catalyst in the first oxidation zone is present in a fluidized bed and the further oxidation catalyst or catalysts in the second oxidation zone is/are present in a fixed bed.
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公开(公告)号：DE102004006610A1
公开(公告)日：2005-09-01
申请号：DE102004006610
申请日：2004-02-11
Applicant: BASF AG
Inventor： SEIDEMANN LOTHAR , SCHUBERT OLGA , SESING MARTIN , STROEFER ECKHARD , FIENE MARTIN , WALSDORFF CHRISTIAN , HARTH KLAUS
Abstract: The invention relates to a reactor and a process for preparing chlorine from hydrogen chloride by gas-phase oxidation by means of oxygen in the presence of a heterogeneous catalyst in a fluidized bed, with gas-permeable plates being located in the fluidized bed. The gas-permeable plates are connected in a thermally conductive manner to a heat exchanger located in the fluidized bed.
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公开(公告)号：ES2290748T3
公开(公告)日：2008-02-16
申请号：ES04763900
申请日：2004-08-06
Applicant: BASF AG
Inventor： WALSDORFF CHRISTIAN , FIENE MARTIN , SESING MARTIN , METELKINA OLGA , SEIDEMANN LOTHAR , STROEFER ECKHARD
IPC: C01B7/04
Abstract: Procedimiento para la obtención de cloro mediante oxidación catalítica en fase gaseosa de cloruro de hidrógeno, con los pasos: a) se pone a disposición una corriente gaseosa de alimentación I que contiene cloruro de hidrógeno, y una corriente gaseosa de alimentación II que contiene oxígeno; b) en una primera etapa de oxidación se alimentan la corriente gaseosa de alimentación I, la corriente gaseosa de alimentación II, en caso dado una recirculación Ia que contiene cloruro de hidrógeno, y en caso dado una recirculación IIa que contiene oxígeno, en una primera zona de oxidación, y se ponen en contacto con un primer catalizador de oxidación, oxidándose una primera cantidad parcial de cloruro de hidrógeno para dar cloro, y obteniéndose una corriente gaseosa III que contiene cloro, oxígeno no transformado, cloruro de hidrógeno no transformado y vapor de agua; c) en una segunda etapa de oxidación se alimenta la corriente gaseosa III a una segunda zona de oxidación, y se pone en contacto con al menos otro catalizador de oxidación, oxidándose una segunda cantidad parcial de cloruro de hidrógeno para dar cloro, y obteniéndose una corriente gaseosa de producto IV, que contiene cloro, oxígeno no transformado, cloruro de hidrógeno no transformado y vapor de agua; d) a partir de la corriente gaseosa de producto IV se obtiene cloro, en caso dado la recirculación Ia, y en caso dado la recirculación IIa, caracterizado porque el primer catalizador de oxidación se presenta en la primera zona de oxidación como lecho fluidizado, y el catalizador o catalizadores de oxidación adicionales se presentan en la segunda zona de oxidación en una carga de lecho fijo.
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公开(公告)号：AT372299T
公开(公告)日：2007-09-15
申请号：AT04763900
申请日：2004-08-06
Applicant: BASF AG
Inventor： WALSDORFF CHRISTIAN , FIENE MARTIN , SESING MARTIN , METELKINA OLGA , SEIDEMANN LOTHAR , STROEFER ECKHARD , HARTH KLAUS
IPC: C01B7/04
Abstract: The invention relates to a process for preparing chlorine by catalytic gas-phase oxidation of hydrogen chloride, which comprises the steps: a) providing a feed gas stream I comprising hydrogen chloride and a feed gas stream II comprising oxygen; b) in a first oxidation stage, feeding the feed gas stream I, the feed gas stream II, if desired a recycle stream la comprising hydrogen chloride and if desired an oxygen-containing recycle stream IIa into a first oxidation zone and bringing them into contact with a first oxidation catalyst so that a first partial amount of the hydrogen chloride is oxidized to chlorine and a gas stream III comprising chlorine, unreacted oxygen, unreacted hydrogen chloride and water vapor is obtained; c) in a second oxidation stage, feeding the gas stream III into a second oxidation zone and bringing it into contact with at least one further oxidation catalyst so that a second partial amount of the hydrogen chloride is oxidized to chlorine and a product gas stream IV comprising chlorine, unreacted oxygen, unreacted hydrogen chloride and water vapor is obtained; d) isolating chloride, if desired the recycle stream Ia and if desired the recycle stream IIa from the product gas stream IV, wherein the first oxidization catalyst in the first oxidation zone is present in a fluidized bed and the further oxidation catalyst or catalysts in the second oxidation zone is/are present in a fixed bed.
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Patent Agency Ranking
公开(公告)号：DE102005008612A1
公开(公告)日：2006-08-24
申请号：DE102005008612
申请日：2005-02-23
Applicant: BASF AG
Inventor： SESING MARTIN , DIEFENBACHER ARMIN , VOS HARTWIG , SCHUBERT OLGA , SEIDEMANN LOTHAR , KARCHES MARTIN , GRASLER THOMAS , STROEFER ECKHARD
IPC: C01B7/04
Abstract: The stream containing hydrogen chloride (I) and the stream containing oxygen (II) are fed into an oxidation zone. The hydrogen chloride is oxidized to chlorine. A gas and a water-free gas streams are remained through the cooling and drying. The stream reversal contains chlorine-rich, chlorine, oxygen and carbon dioxide, and the liquefaction is carried out by compression and cooling (6). The gas and the water-free gas streams contain chlorine, water, oxygen, carbon dioxide and inert gases. The Gas/liquid stream is separated into a gas stream containing chlorine, oxygen, carbon dioxide and inert gases and into a fluid stream containing chlorine, oxygen and carbon dioxide. The gas stream is fed into a membrane separation unit (9) and separated into the stream reversal and chlorine-poor, chlorine, oxygen and carbon dioxide containing gas by membrane separation. The liquid stream is separated into a chlorine stream and a stream containing oxygen and carbon dioxide by distillation. The chlorine-poor and the gas stream are led into the oxidation zone, and the chlorine poor is removed.
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7.发明专利
公开(公告)号：SG175661A1
公开(公告)日：2011-11-28
申请号：SG2011076726
申请日：2005-03-21
Applicant: BASF AG
Inventor： SOHN MARTIN , STROEFER ECKHARD , SCHUBERT OLGA , GRASSLER THOMAS , FIENE MARTIN , SESING MARTIN , SEIDEMANN LOTHAR , WALSDORFF CHRISTIAN
Abstract: FLUIDIZED BED METHOD AND REACTOR FOR CARRYING OUT EXOTHERMIC CHEMICAL EQUILIBRIUM REACTIONSAbstractThe invention relates to a process for carrying out exothermic chemical equilib rium reactions in a fluidized-bed reactor, wherein there is a temperature distribu tion in the fluidized bed of the fluidized-bed reactor and the temperature differencebetween the lowest temperature and the highest temperature is at least 10 K. The invention further relates to a fluidized-bed reactor for carrying out chemical reac tions In a fluidized bed (5), wherein at least one heat exchanger (12, 28) is located in the fluidized bed (5) to control the temperature distribution.(Figure 1)
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公开(公告)号：DE102005040286A1
公开(公告)日：2007-03-01
申请号：DE102005040286
申请日：2005-08-25
Applicant: BASF AG
Inventor： SCHUBERT OLGA , SESING MARTIN , SEIDEMANN LOTHAR , KARCHES MARTIN , GRASLER THOMAS , SOHN MARTIN
Abstract: An oxidation process employing a mechanically stable catalyst of an active metal or combination of active metals supported on aluminum oxide, which is predominantly alpha-aluminum oxide, is provided. The active metal or metals is optionally one or a mixture of ruthenium, copper, gold, an alkaline earth metal, an alkali metal, palladium, platinum, osmium, iridium, silver, and rhenium. The process is applicable to the oxidation of hydrogen chloride to chlorine in a Deacon process.
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公开(公告)号：DE102004014677A1
公开(公告)日：2005-10-13
申请号：DE102004014677
申请日：2004-03-25
Applicant: BASF AG
Inventor： WALSDORFF CHRISTIAN , SEIDEMANN LOTHAR , SESING MARTIN , FIENE MARTIN , GRASLER THOMAS , METELKINA OLGA , STROEFER ECKHARD , SOHN MARTIN
Abstract: The invention relates to a process for carrying out exothermic chemical equilibrium reactions in a fluidized-bed reactor, wherein there is a temperature distribution in the fluidized bed of the fluidized-bed reactor and the temperature difference between the lowest temperature and the highest temperature is at least 10 K. The invention further relates to a fluidized-bed reactor for carrying out chemical reactions in a fluidized bed ( 5 ), wherein at least one heat exchanger ( 12, 28 ) is located in the fluidized bed ( 5 ) to control the temperature distribution.
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公开(公告)号：DE102006008000A1
公开(公告)日：2006-11-30
申请号：DE102006008000
申请日：2006-02-21
Applicant: BASF AG
Inventor： LANGENSIEPEN HANS-WERNER , SCHWAB EKKEHARD , SEIDEMANN LOTHAR , ORBAND JAN
IPC: C07C209/86 , B01D11/04 , C07B63/00 , C07C209/36 , C07C211/43 , C07C211/46
Abstract: Extraction of an aromatic amine from an aqueous phase trough extraction of the aromatic amine with a corresponding nitroaromatic .
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