Abstract:
The invention relates to a method for producing organic isocyanates, said method consisting of the following steps: (a) a first partial quantity of chlorine containing
Abstract:
The invention relates to a method for producing chlorine by oxidising hydrogen chloride in the presence of a catalyst, whereby hydrogen chloride is not used in a gaseous form, but at least partially in the form of hydrochloric acid. In an especially preferred form of embodiment, the feed gas flow containing hydrogen chloride is obtained from phosgene and primary amines during the isocyanate synthesis, and the product gas flow containing chlorine is used to produce the phosgene which is subsequently reacted with the primary amines to form isocyanates. The invention thus also relates to an integrated method for producing organic isocyanates.
Abstract:
The invention relates to a catalyst for the catalytic oxidation of hydrogen chloride, containing on a support: a) between 0.001 and 30 wt. % gold; b) between 0 and 3 wt. % one or more alkaline-earth metals; c) between 0 and 3 wt % one or more alkaline metals; d) between 0 and 10 wt. % one or more rare-earth metals; e) between 0 and 10 wt % one or more additional metals, selected from the group consisting of ruthenium, palladium, platinum, osmium, iridium, silver, copper and rhenium, whereby each quantity relates to the total weight of the catalyst.
Abstract:
A method for the production of formaldehyde by gas phase oxidation of methanol vapour with a gas flow containing a molecular oxygen in the presence of solid bed catalyst containing iron and molybdenum is carried out in a reactor (1) comprising thermal sheet metal plates (2) which are arranged in the longitudinal direction of the reactor (1) and spaced from each other. A heat transfer medium flows through the gaps between the plates. The heat transfer medium is transferred via inlets and outlets 3, 4 to the thermal sheet steel plates (2), and gaps (5) between the thermal sheet steel metal plates (2) and which are filled with the solid bed catalyst and into which the gas containing the methanol vapour and the molecular oxygen flows.
Abstract:
A process for preparing formaldehyde by gas-phase oxidation of methanol vapor by means of a gas stream comprising molecular oxygen in the presence of a fixed-bed catalyst comprising iron and molybdenum, wherein the process is carried out in a reactor ( 1 ) having heat-exchange plates ( 2 ) which are arranged in the longitudinal direction of the reactor ( 1 ) and have a spacing between them and through which a heat transfer medium flows, inlet and outlet facilities ( 3, 4 ) for the heat transfer medium to the heat-exchange plates ( 2 ) and also gaps ( 5 ) between heat-exchange plates ( 2 ) in which the fixed-bed catalyst is present and into which the methanol vapor and the gas stream comprising molecular oxygen are passed, is described.
Abstract:
A method for the production of polyurethane components, especially isocyanates, involves using a system made up of components used in micro-technology.
Abstract:
Preparation of chlorine involves passing hydrogen chloride and gas stream comprising molecular oxygen in a reactor (1) having parallel catalyst tubes (2) charged with fixed-bed catalyst and at least one deflector plate (6) perpendicular to the reactor. The plates leave passages on opposite sides of the reactor free next to its interior wall. A liquid heat transfer medium circulates between tubes.
Abstract:
The invention relates to a catalyst for the catalytic oxidation of hydrogen chloride, comprising on a support a) from 0.001 to 30% by weight of gold, b) from 0 to 3% by weight of one or more alkaline earth metals, c) from 0 to 3% by weight of one or more alkali metals, d) from 0 to 10% by weight of one or more rare earth metals, e) from 0 to 10% by weight of one or more further metals selected from the group consisting of ruthenium, palladium, platinum, osmium, iridium, silver, copper and rhenium, in each case based on the total weight of the catalyst.
Abstract:
A process for preparing formaldehyde by gas-phase oxidation of methanol vapor by means of a gas stream comprising molecular oxygen in the presence of a fixed-bed catalyst comprising iron and molybdenum, wherein the process is carried out in a reactor ( 1 ) having heat-exchange plates ( 2 ) which are arranged in the longitudinal direction of the reactor ( 1 ) and have a spacing between them and through which a heat transfer medium flows, inlet and outlet facilities ( 3, 4 ) for the heat transfer medium to the heat-exchange plates ( 2 ) and also gaps ( 5 ) between heat-exchange plates ( 2 ) in which the fixed-bed catalyst is present and into which the methanol vapor and the gas stream comprising molecular oxygen are passed, is described.