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    MESOPOROUS METAL-ORGANIC FRAMEWORK
    2.
    发明专利
    MESOPOROUS METAL-ORGANIC FRAMEWORK 未知

    公开(公告)号：CA2618869A1

    公开(公告)日：2007-03-01

    申请号：CA2618869

    申请日：2006-08-16

    Applicant: BASF AG

    Inventor： MATTENHEIMER HENDRICK ,  MUELLER ULRICH ,  SCHUBERT MARKUS ,  TONIGOLD MARKUS

    IPC: C07C51/41 ,  C01B3/00 ,  C07F5/06 ,  C25B3/23

    Abstract: The present invention relates to a porous metal-organic framework comprising AlIII and at least one at least bidentate compound, wherein the at least one at least bidentate organic compound is a six-membered aromatic hydrocarbon ring A in which one or more ring carbons may be replaced by nitrogen and which has three substituents X and optionally one or more substituents selected from the group consisting of R, NRR′, OR, SR, F, Cl and Br, where R, R′ are each, independently of one another, hydrogen, methyl which may optionally be substituted by one or more fluorine atoms or ethyl which may optionally be substituted by one or more fluorine atoms and each X is, independently of the others, C(═O)O−, C(═S)O−, C(═O)S−, C(═S)S− or a protonated form thereof. The invention further provides a process for preparing it and provides for the use of the new porous metal-organic framework.

    3.
    发明专利
    未知

    公开(公告)号：DE102005039654A1

    公开(公告)日：2007-03-01

    申请号：DE102005039654

    申请日：2005-08-22

    Applicant: BASF AG

    Inventor： SCHUBERT MARKUS ,  MUELLER ULRICH ,  MATTENHEIMER HENDRICK ,  TONIGOLD MARKUS

    IPC: C07F5/06 ,  B01J19/00 ,  B01J20/30 ,  C07B61/00 ,  C25B3/23 ,  F17C11/00

    Abstract: The present invention relates to a porous metal-organic framework comprising AlIII and at least one at least bidentate compound, wherein the at least one at least bidentate organic compound is a six-membered aromatic hydrocarbon ring A in which one or more ring carbons may be replaced by nitrogen and which has three substituents X and optionally one or more substituents selected from the group consisting of R, NRR′, OR, SR, F, Cl and Br, where R, R′ are each, independently of one another, hydrogen, methyl which may optionally be substituted by one or more fluorine atoms or ethyl which may optionally be substituted by one or more fluorine atoms and each X is, independently of the others, C(═O)O−, C(═S)O−, C(═O)S−, C(═S)S− or a protonated form thereof. The invention further provides a process for preparing it and provides for the use of the new porous metal-organic framework.

    4.
    发明专利
    未知

    公开(公告)号：DE102005039623A1

    公开(公告)日：2007-03-01

    申请号：DE102005039623

    申请日：2005-08-22

    Applicant: BASF AG

    Inventor： SCHUBERT MARKUS ,  MUELLER ULRICH ,  TONIGOLD MARKUS ,  RUETZ ROGER

    IPC: C07F19/00 ,  B01J20/30 ,  C07B61/00 ,  F17C11/00

    Abstract: The present invention relates to a process for preparing a porous metal-organic framework by reacting at least one metal compound in which the metal is Be, Mg, Ca, Sr, Ba, Al, Ga or In with at least one at least bidentate organic compound and also the use of such porous metal-organic frameworks.

    PROCESS FOR PREPARING COPPER-COMPRISING METAL ORGANIC FRAMEWORKS
    6.
    发明专利
    PROCESS FOR PREPARING COPPER-COMPRISING METAL ORGANIC FRAMEWORKS 未知

    公开(公告)号：CA2658757A1

    公开(公告)日：2008-01-31

    申请号：CA2658757

    申请日：2007-07-13

    Applicant: BASF AG

    Inventor： TONIGOLD MARKUS ,  MULLER ULRICH ,  KIENER CHRISTOPH ,  OZKIRIM FARUK ,  SCHUBERT MARKUS

    IPC: C07F1/00

    Abstract: The present invention relates to methods for producing a porous, organome tallic framework material containing a first and at least one second at leas t bidentate organic compound coordinatively bound to at least one copper ion , including the following steps: (a) Reaction of a reaction mixture in the l iquid phase containing at least one copper compound and the first at least b identate organic compound with formation of a complex intermediate containin g at least one copper ion and the first at least bidentate organic compound, wherein the first at least bidentate organic compound derives from a dicarb oxylic acid and has a hydrocarbon framework, and (b) Reaction of the complex intermediate with the at least second at least bidentate organic compound, wherein the at least second at least bidentate organic compound is an option ally substituted monocyclic, bicyclic or polycyclic saturated or unsaturated hydrocarbon in which at least two ring carbon atoms are replaced by heteroa toms selected from the group consisting of N, O and S, wherein the reaction mixture in step (a) has less than a threefold excess amount of 25 formic aci d based on the copper used in the copper compound.

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