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    METALLIC SALTS OF CYCLOHEXENONOXYMETHERS
    92.
    发明专利
    METALLIC SALTS OF CYCLOHEXENONOXYMETHERS 未知

    公开(公告)号：BG102521A

    公开(公告)日：1999-11-30

    申请号：BG10252198

    申请日：1998-06-09

    Applicant: BASF AG

    Inventor： BRATZ MATTHIAS ,  JAGER KARL-FRIEDRICH ,  BENOIT REMY ,  RANG HARALD ,  MISSLITZ ULF ,  WESTPHALEN KARL-OTTO

    IPC: A01N35/10 ,  A01N43/10 ,  A01N43/14 ,  A01N43/16 ,  A01N43/18 ,  C07C239/20 ,  C07C251/42 ,  C07C251/50 ,  C07C323/47 ,  C07D309/06 ,  C07D335/02

    Abstract: The compounds have improved temperature stability in storageand reduced hydroscopicity. The herbicide acting metal salts ofcyclohexenonoxymethers have the formulawhere Ra is C1-C6-alkyl, Rb is the equivalent of alkaline, alkaliearth or transitory metal, Rc is H, CN, CHO, C1-C6-alkyl,C1-C4-alkoxy-C1-C6-alkyl, C1-C6-alkylthio-C1-C6-alkyl,phenoxy-C1-C6-alkyl-, phenylthio-C1-C6-alkyl,pyridyloxy-C1-C6-alkyl or pyridylthio-C1-C6-alkyl, where thephenyl or the pyridyl rings can be substituted by 1 to 3 of thefollowing residues: NO2, CN, halogen, C1-C4-alkyl,C1-C4-halogenalkyl, C1-C4-alkoxy, C1-C4-halogenalkoxy,C1-C4-alkylthio, C3-C6-alkenyl, C3-C6-alkenylkoxy, C3-C6-alkynyl,C3-C6-alkanyloxy and/or substituted eminogroup, optionallysubstituted C3-C7-cyloalkyl or C5-C7-cycloalkenyl group,optionally substituted 5-member saturated heterocyclic ring with 1or 2 oxygen and/or sulphur atoms, optionally substituted 6- or7-member heterocyclic ring with 1 or 2 oxygen and/or sulphuratoms, optionally substituted 5-member heteroaromatic ring with 1or 2 N-atoms and one oxygen or one sulphur atom, or 1 to 3nitrogen atoms, or 1 oxygen, or 1 sulphur atom, phenyl or pyridylresidue, optionally substituted by 1 to 3 of the followingsubstitutents: NO2, CN, CHO, halogen, C1-C4-alkyl,C1-C4-halogenalkyl, C1-C4-alkoxy, C1-C4-halogenalkoxy,C1-C4-alkylthio, C3-C6-alkenyl, C3-C6-alkenyloxy, C3-C6-alkynyl,C3-C6-alkynyloxy and/or optionally substiuted aminogroup, Rd is H,OH or when Rc means C1-C6-alkyl, then it also means C1-C6-alkyl,Re means H, CN, halogen, (C1-C4-alkoxy)carbonyl or(C1-C4-alkyl)ketoxime, Alk optionally is substitutedC1-C6-alkylene, C3-C6-alkylene or C3-C6-alkynylene chain, 3- to6-member alkylene or 4- to 6-member alkenylene chain which apartfrom methylene or methene units can also contain, bridge bound,one of the following members: O, S, -SO-, -SO2- or -N(Ri)-, whereRi is hydrogen, C1-C4-alkyl, C3-C6-alkenyl or C3-C6-alkynyl, Rf isphenyl group, halogenphenyl or dihalogenphenyl group where thephenyl ring can be substituted by 1 to 3 of the followingsubstitutents: NO2, CN, CHO, halogen, C1-C6-alkyl,C1-C4-halogenalkyl, C1-C4-alkoxy, C1-C4-halogenalkoxy,C3-C6-alkyenyl, C3-C6-alkenyloxy, C3-C6-alkynyl, C3-C6-alkynyloxyand/or optionally substituted aminogroup.10 claims

    93.
    发明专利
    未知

    公开(公告)号：TR199701128T1

    公开(公告)日：1998-02-21

    申请号：TR9701128

    申请日：1996-03-25

    Applicant: BASF AG

    Inventor： MULLER RUTH ,  BENOIT REMY ,  BAYER HERBERT ,  GOTZ NORBERT ,  SAUTER HUBERT

    IPC: C07B61/00 ,  C07D231/12 ,  C07C249/04 ,  C07C249/12 ,  C07C249/14 ,  C07C251/38 ,  C07C251/48 ,  C07C255/62 ,  C07D261/08

    Abstract: PCT No. PCT/EP96/01306 Sec. 371 Date Oct. 7, 1997 Sec. 102(e) Date Oct. 7, 1997 PCT Filed Mar. 25, 1996 PCT Pub. No. WO96/32373 PCT Pub. Date Oct. 17, 1996A process for the preparation of largely isomerically pure alpha -bisoximes of the formula IaR1O-N=CR2-CR3=N-OR4Iawhere the groups R1O- and R2 on the N=C bond are cis to one another and where the radicals have the following meanings: R1 and R4 are hydrogen or a C-organic radical; R2 is hydrogen, cyano, nitro, hydroxyl, amino, halogen or an organic radical which can be bonded to the structure directly or via an oxygen, sulfur or nitrogen atom; R3 is hydrogen, cyano, nitro, hydroxyl, amino, halogen, alkyl, haloalkyl, alkoxy, haloalkoxy, alkylthio, alkylamino, dialkylamino or cycloalkyl, from a mixture of the isomers of the a-bisoximes Ia and Ib is described.

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