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公开(公告)号:ES2063089T3
公开(公告)日:1995-01-01
申请号:ES89115340
申请日:1989-08-19
Applicant: BASF AG
Inventor: BERBNER HEINZ , EBEL KLAUS DR , KUCZATY MICHAEL , SEID BERNHARD , WOERNER FRANK PETER DR , ZETTLER HANS DIETER
IPC: C08G12/32
Abstract: The present invention relates to a process for the continuous preparation of melamine-formaldehyde precondensate solutions, characterised in that melamine, formaldehyde and optionally modifiers and/or additives are metered into a continuous mixture, the homogeneous mixture is passed into a single- or twin-screw extruder, condensed at elevated temperature, cooled and discharged.
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公开(公告)号:DE4230144A1
公开(公告)日:1994-03-17
申请号:DE4230144
申请日:1992-09-11
Applicant: BASF AG
Inventor: GEHRER EUGEN DR , HARDER WOLFGANG DR , EBEL KLAUS DR , MELDER JOHANN-PETER DR , TELES JOAQUIM HENTIQUE DR
IPC: B01J31/02 , C07B61/00 , C07C45/75 , C07C47/19 , C07D233/88 , C07D249/14 , C07D277/42 , C07D285/135 , C07D293/04 , C07D487/04
Abstract: Condensn. prods. of HCHO (or HCHO-precursors) are obtd. using a meso-ionic, heterocyclic catalyst of formula (I); X = N or CR3; Y = S, Se or NR4; R1-R3 = 1-30C aliphatic gp. or opt. substd. aryl, aralkyl and/or heteroaryl gp.; R4 = as for R1-R3 or forms together with R2 a 2-5C alkylene or alkenylene bridge or 6-14C arylene bridge; and R5 = H, -CH2OH or -CH(OH)(CH2OH).
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公开(公告)号:DE4219789A1
公开(公告)日:1993-12-23
申请号:DE4219789
申请日:1992-06-17
Applicant: BASF AG
Inventor: EBEL KLAUS DR , SCHROEDER JUERGEN DR
IPC: C07D239/06 , C07D239/26
Abstract: Pyrimidines of the general formula I in which R denotes C1- to C8-alkyl, C7- to C12-aralkyl or phenyl and R , R and R independently of one another denote hydrogen, C1- to C8-alkyl, C7- to C12-aralkyl or phenyl, are prepared by reacting carbonitriles of the general formula II R -C IDENTICAL N (II> in which the substituent R has the abovementioned meaning, with 1,3-diaminopropanes of the general formula III in which the substituents R to R have the abovementioned meanings, in the presence of copper(II) acetate at temperatures from 150 to 250 DEG C to give the tetrahydropyrimidine of the general formula IV in which the substituents R to R have the abovementioned meanings, and dehydrogenating the tetrahydropyrimidine of the formula IV to the pyrimidine of the formula I using Raney nickel at temperatures from 150 to 300 DEG C.
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公开(公告)号:DE3586232D1
公开(公告)日:1992-07-23
申请号:DE3586232
申请日:1985-10-12
Applicant: BASF AG
Inventor: EBEL KLAUS DR , REUTHER WOLFGANG DR
IPC: C07D251/70
Abstract: N,N',N''-tris(2 -hydroxypropyl)melamine (I) is prepd. by reacting melamine (II) with isopropanolamine (III) in the presence of acid catalysts at a temp. of 120-300 deg. C, using excess (III) such that the molar ratio of free (III) to the sum of free and converted (II) does not fall below 4:1 during the whole reaction period.
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公开(公告)号:DE4015535A1
公开(公告)日:1991-11-21
申请号:DE4015535
申请日:1990-05-15
Applicant: BASF AG
Inventor: EBEL KLAUS DR
IPC: C07D233/54 , C07D233/58 , C07D233/64 , C07D233/68 , C07D521/00
Abstract: Process for the preparation of N-substituted imidazoles of the general formula I … … in which the substituents …… R denotes C1- to C20-alkyl, C2- to C20-alkenyl, C2- to C20-alkynyl, C2- to C20-alkoxyalkyl, C3- to C20-alkenyloxyalkyl, C3- to C12-cycloalkyl, C4- to C20-cycloalkylalkyl, aryl which is unsubstituted or substituted by C1- to C8-alkyl, C1- to C8-alkoxy, halogen, C1- to C4-haloalkyl, C1- to C4-haloalkoxy or phenoxy or denotes C7- to C20-arylalkyl, … the substituents R , R , R , independently of one another, denote hydrogen, C1- to C20-alkyl, C2- to C20-alkoxyalkyl, C3- to C12-cycloalkyl, halogen, aryl which is unsubstituted or substituted by C1- to C8-alkyl, C1- to C8-alkoxy, halogen, C1- to C4-haloalkyl, C1- to C4-haloalkoxy or phenoxy or denote C7- to C20-arylalkyl or R and R together denote a (CH2)n or (CH=CH)m group which is unsubstituted or mono- or disubstituted by C1- to C8-alkyl, C1- to C8-alkoxy and/or halogen and in which n represents 1 to 6 and m represents 1 to 3, … by reaction of imidazoles of the general formula II … … in which R , R and R have the abovementioned meanings, with halides of the general formula III… R -X (III> in which X represents chlorine, bromine or iodine and R has the abovementioned meanings, in aqueous hydroxide solutions at temperatures of 0 to 100 DEG C by carrying out the reaction in the presence of 0.1 to 50 mol % of an N-substituted imidazole, relative to II.
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公开(公告)号:DE3835195A1
公开(公告)日:1990-04-19
申请号:DE3835195
申请日:1988-10-15
Applicant: BASF AG
Inventor: KOEHLER HERMANN DR , EBEL KLAUS DR , KARN HELMUT , TAUBITZ CHRISTOF DR
IPC: C07D233/54 , C07D233/64
Abstract: Process for the preparation of imidazoles substituted in the 2- and/or 4- and/or 5-position by p-nitrophenyl and, if appropriate, additional substituents by reaction of imidazoles substituted in the 2- and/or 4- and/or 5-position by phenyl and, if appropriate, additional substituents with mixtures of sulphuric acid and nitric acid, by carrying out the reaction in the presence of urea.
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公开(公告)号:DE3724868A1
公开(公告)日:1989-02-09
申请号:DE3724868
申请日:1987-07-28
Applicant: BASF AG
Inventor: EBEL KLAUS DR , REUTHER WOLFGANG DR , FIKENTSCHER ROLF DR , LACH DIETRICH DR , STREICHER ROLF , SCHAFFER ORTWIN DR
IPC: C08G12/02 , C08G12/12 , C08G12/32 , C08G12/34 , C08G14/06 , C08G14/10 , C14C3/04 , C14C3/18 , C14C3/28
Abstract: A tanning assistant useful in particular for tanning in combination with aluminum tanning agents is obtained by condensing melamine with glyoxal and/or glyoxylic acid and optionally with an aromatic compound which has a phenolic hydroxyl group or optionally with a condensable nitrogen compound.
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公开(公告)号:DE3564681D1
公开(公告)日:1988-10-06
申请号:DE3564681
申请日:1985-06-11
Applicant: BASF AG
Inventor: EBEL KLAUS DR , REUTHER WOLFGANG DR , WEISS WOLFRAM DR , LELGEMANN LUDWIG
IPC: C07D251/54 , C07D251/70 , C08G12/26 , C08G12/30 , C08G12/34 , C08G12/38
Abstract: N,N',N''-tris-(2-hydroxyethyl)-melamine, if required, as a mixture with N-mono- and N,N'-bis-(2-hydroxyethyl)-melamine, is prepared by reacting melamine with ethanolamine in the presence of an acidic catalyst by a method in which the reaction is carried out at from 120 DEG to 250 DEG C. using an excess of ethanolamine, and the molar ratio of free ethanolamine to the sum of free and converted melamine is not permitted to fall below 4:1 during the entire reaction time, and the stated (2-hydroxyethyl)-melamines are used as modifiers in the prepartion of aminoplast resins which are suitable for laminating surfaces.
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公开(公告)号:DE50211196D1
公开(公告)日:2007-12-27
申请号:DE50211196
申请日:2002-12-03
Applicant: BASF AG
Inventor: GERLACH TILL DR , GOEBBEL HANS-GEORG DR , FUNKE FRANK DR , EBEL KLAUS DR , SCHWAB EKKEHARD DR , UNVERRICHT SIGNE DR , KOERNER REINHARD DR , LOBREE LISA DR
IPC: B01J23/89 , B01J21/18 , B01J33/00 , B01J37/03 , C07B61/00 , C07C29/141 , C07C29/145 , C07C29/17 , C07C33/02 , C07C33/025
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公开(公告)号:DE50209961D1
公开(公告)日:2007-05-31
申请号:DE50209961
申请日:2002-12-03
Applicant: BASF AG
Inventor: GOEBBEL HANS-GEORG DR , GERLACH TILL DR , FUNKE FRANK DR , EBEL KLAUS DR , UNVERRICHT SIGNE DR , KAIBEL GERD DR
IPC: C07C29/141 , C07B61/00 , C07C33/03
Abstract: Selective hydrogenation of alpha , beta -ethylenically unsaturated aldehydes (II) to corresponding unsaturated alcohols (I) comprises performing reaction in a reactor containing a liquid phase, suspended catalyst and optionally a gas phase, The liquid phase and gas phase (if present) are supplied to the reactor through a device (A) with openings or channels having a hydraulic diameter of 0.5-2 mm. Selective hydrogenation of unsaturated aldehydes of formula R R C=CR -CHO (II) to corresponding alcohols of formula R R C=CR -CH2OH (I) comprises performing the reaction in a reactor containing a liquid phase, suspended catalyst and optionally a gas phase. The liquid phase and optionally the gas phase are supplied to the reactor through a device (A) with openings or channels having a hydraulic diameter of 0.5-2 mm. R , R = H, optionally substituted mono- or polyunsaturated 1-20C alkyl (sic; some of the groups exemplified in the disclosure are saturated), optionally substituted aryl or optionally substituted heterocyclyl; R = H or 1-4C alkyl.
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