91.
    发明专利
    未知

    公开(公告)号:ES2063089T3

    公开(公告)日:1995-01-01

    申请号:ES89115340

    申请日:1989-08-19

    Applicant: BASF AG

    Abstract: The present invention relates to a process for the continuous preparation of melamine-formaldehyde precondensate solutions, characterised in that melamine, formaldehyde and optionally modifiers and/or additives are metered into a continuous mixture, the homogeneous mixture is passed into a single- or twin-screw extruder, condensed at elevated temperature, cooled and discharged.

    93.
    发明专利
    未知

    公开(公告)号:DE4219789A1

    公开(公告)日:1993-12-23

    申请号:DE4219789

    申请日:1992-06-17

    Applicant: BASF AG

    Abstract: Pyrimidines of the general formula I in which R denotes C1- to C8-alkyl, C7- to C12-aralkyl or phenyl and R , R and R independently of one another denote hydrogen, C1- to C8-alkyl, C7- to C12-aralkyl or phenyl, are prepared by reacting carbonitriles of the general formula II R -C IDENTICAL N (II> in which the substituent R has the abovementioned meaning, with 1,3-diaminopropanes of the general formula III in which the substituents R to R have the abovementioned meanings, in the presence of copper(II) acetate at temperatures from 150 to 250 DEG C to give the tetrahydropyrimidine of the general formula IV in which the substituents R to R have the abovementioned meanings, and dehydrogenating the tetrahydropyrimidine of the formula IV to the pyrimidine of the formula I using Raney nickel at temperatures from 150 to 300 DEG C.

    94.
    发明专利
    未知

    公开(公告)号:DE3586232D1

    公开(公告)日:1992-07-23

    申请号:DE3586232

    申请日:1985-10-12

    Applicant: BASF AG

    Abstract: N,N',N''-tris(2 -hydroxypropyl)melamine (I) is prepd. by reacting melamine (II) with isopropanolamine (III) in the presence of acid catalysts at a temp. of 120-300 deg. C, using excess (III) such that the molar ratio of free (III) to the sum of free and converted (II) does not fall below 4:1 during the whole reaction period.

    95.
    发明专利
    未知

    公开(公告)号:DE4015535A1

    公开(公告)日:1991-11-21

    申请号:DE4015535

    申请日:1990-05-15

    Applicant: BASF AG

    Inventor: EBEL KLAUS DR

    Abstract: Process for the preparation of N-substituted imidazoles of the general formula I … … in which the substituents …… R denotes C1- to C20-alkyl, C2- to C20-alkenyl, C2- to C20-alkynyl, C2- to C20-alkoxyalkyl, C3- to C20-alkenyloxyalkyl, C3- to C12-cycloalkyl, C4- to C20-cycloalkylalkyl, aryl which is unsubstituted or substituted by C1- to C8-alkyl, C1- to C8-alkoxy, halogen, C1- to C4-haloalkyl, C1- to C4-haloalkoxy or phenoxy or denotes C7- to C20-arylalkyl, … the substituents R , R , R , independently of one another, denote hydrogen, C1- to C20-alkyl, C2- to C20-alkoxyalkyl, C3- to C12-cycloalkyl, halogen, aryl which is unsubstituted or substituted by C1- to C8-alkyl, C1- to C8-alkoxy, halogen, C1- to C4-haloalkyl, C1- to C4-haloalkoxy or phenoxy or denote C7- to C20-arylalkyl or R and R together denote a (CH2)n or (CH=CH)m group which is unsubstituted or mono- or disubstituted by C1- to C8-alkyl, C1- to C8-alkoxy and/or halogen and in which n represents 1 to 6 and m represents 1 to 3, … by reaction of imidazoles of the general formula II … … in which R , R and R have the abovementioned meanings, with halides of the general formula III… R -X (III> in which X represents chlorine, bromine or iodine and R has the abovementioned meanings, in aqueous hydroxide solutions at temperatures of 0 to 100 DEG C by carrying out the reaction in the presence of 0.1 to 50 mol % of an N-substituted imidazole, relative to II.

    96.
    发明专利
    未知

    公开(公告)号:DE3835195A1

    公开(公告)日:1990-04-19

    申请号:DE3835195

    申请日:1988-10-15

    Applicant: BASF AG

    Abstract: Process for the preparation of imidazoles substituted in the 2- and/or 4- and/or 5-position by p-nitrophenyl and, if appropriate, additional substituents by reaction of imidazoles substituted in the 2- and/or 4- and/or 5-position by phenyl and, if appropriate, additional substituents with mixtures of sulphuric acid and nitric acid, by carrying out the reaction in the presence of urea.

    100.
    发明专利
    未知

    公开(公告)号:DE50209961D1

    公开(公告)日:2007-05-31

    申请号:DE50209961

    申请日:2002-12-03

    Applicant: BASF AG

    Abstract: Selective hydrogenation of alpha , beta -ethylenically unsaturated aldehydes (II) to corresponding unsaturated alcohols (I) comprises performing reaction in a reactor containing a liquid phase, suspended catalyst and optionally a gas phase, The liquid phase and gas phase (if present) are supplied to the reactor through a device (A) with openings or channels having a hydraulic diameter of 0.5-2 mm. Selective hydrogenation of unsaturated aldehydes of formula R R C=CR -CHO (II) to corresponding alcohols of formula R R C=CR -CH2OH (I) comprises performing the reaction in a reactor containing a liquid phase, suspended catalyst and optionally a gas phase. The liquid phase and optionally the gas phase are supplied to the reactor through a device (A) with openings or channels having a hydraulic diameter of 0.5-2 mm. R , R = H, optionally substituted mono- or polyunsaturated 1-20C alkyl (sic; some of the groups exemplified in the disclosure are saturated), optionally substituted aryl or optionally substituted heterocyclyl; R = H or 1-4C alkyl.

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