-
91.
公开(公告)号:CA2160912C
公开(公告)日:2007-10-02
申请号:CA2160912
申请日:1994-04-13
Applicant: BASF AG
Inventor: BAUMANN ERNST , RHEINHEIMER JOACHIM , VOGELBACHER UWE JOSEF , BRATZ MATTHIAS , THEOBALD HANS , GERBER MATTHIAS , WESTPHALEN KARL-OTTO , WALTER HELMUT , RADEMACHER WILHELM
IPC: C07D239/24 , C07D251/22 , A01N43/54 , A01N43/64 , A01N43/66 , A01N43/72 , A01P13/00 , A01P21/00 , C07C45/58 , C07C47/198 , C07C47/277 , C07C59/125 , C07C67/31 , C07C69/708 , C07C69/734 , C07C205/28 , C07C323/22 , C07C323/50 , C07D239/26 , C07D239/30 , C07D239/34 , C07D239/38 , C07D239/60 , C07D251/12 , C07D251/24 , C07D251/30 , C07D251/34 , C07D401/12 , C07D403/12 , C07D405/12 , C07D409/12 , C07D411/12 , C07D413/12 , C07D417/12 , C07D477/12 , C07D491/048
Abstract: The invention concerns 3-(hetero)aryl carboxylic acid derivatives of formula (I) in which R is a formyl group, a CO2H group or a group which can be hydrolysed to give a COOH group and the other substituents are as follows: R2 and R3 are halogen, alkyl, haloalkyl, alkoxy, haloalkoxy or alkylthio; X is nitrogen or CR14, R14 being hydrogen or forming together with R3, an alkylene or alkenylene chain in which each methylene group may be replaced by oxygen; R4 is optionally substituted phenyl or naphthyl or an optionally substituted five-membered or six-membered heteroatomic ring containing one to three nitrogen atoms and/or a sulphur or oxygen atom; R5 is hydrogen, alkyl, alkenyl, alkinyl, cycloalkyl, haloalkyl, alkoxyalkyl, alkylthioalkyl or phenyl; R6 is C1C8 alkyl, C3-C6 alkenyl, C3-C6 alkinyl or C3-C8 cycloalkyl, whereby these groups may carry one or more substituents; Y is sulphur, oxygen or a single bound; Z is sulphur or oxygen; with the proviso that R6 be not unsubstituted C1-C4 alkyl if R4 is unsubstituted phenyl, Z is oxygen and at the same time, R5 is methyl or hydrogen. These derivatives are useful for regulating plant growth.
-
公开(公告)号:CA2167291C
公开(公告)日:2006-04-25
申请号:CA2167291
申请日:1994-07-11
Applicant: BASF AG
Inventor: SCHAEFER PETER , HAMPRECHT GERHARD , HEISTRACHER ELISABETH , KOENIG HARTMANN , KLINTZ RALF , MUENSTER PETER , RANG HARALD , WESTPHALEN KARL-OTTO , GERBER MATTHIAS , WALTER HELMUT
IPC: C07D417/12 , A01N43/40 , A01N43/48 , A01N43/64 , A01N43/72 , C07D213/30 , C07D213/61 , C07D213/62 , C07D213/89 , C07D265/36 , C07D405/10 , C07D409/02 , C07D409/12 , C07D411/10 , C07D413/12 , C07F5/02
Abstract: Substituted 2-phenylpyridines have formula (I) wherein R1, R3 = H halogen, alkyl, haloalkyl, alkoxyalkyl, alkoxy, alkoxyalkoxy, OH, haloalkoxy, alkylcarbonyloxy, haloalkylcarbonyloxy, SH, alkylthio, alkylsulfinyl, alkylsulfonyl, haloalkylthio, haloalkylsulfinyl, haloalkyl-sulfonyl, CHO, CN, CO2H, alkoxycarbonyl, alkoxyalkoxycarbonyl, haloalkoxycarbonyl, alkylcarbonyl, haloalkylcarbonyl, alkoxyalkyl-carbonyl, CONH2, alkylaminocarbonyl, dialkylaminocarbonyl, pyrrolidinylcarbonyl, piperidylcarbonyl, morpholinylcarbonyl, NO2, NH2, alkylamino, dialkylamino, pyrrolidinyl, piperidinyl, morpholinyl, alkylcarbonylamino haloalkylcarbonylamino, alkylsulfonylamino; R2 = halogen CN, NO2, alkyl, haloalkyl, alkoxy, haloalkoxy, alkylthio, haloalkylthio; or R1 + R2 or R2 + R3 = trimethylene or tetramethylene chain; R4 = halogen, alkyl, haloalkyl, alkoxyalkyl, alkoxy, alkoxyalkoxy, OH haloalkoxy, alkylcarbonyloxy, haloalkylcarbonyloxy, SH, alkylthio, alkylsulfinyl, alkylsulfonyl, haloalkylthio haloalkylsulfinyl, haloalkylsulfonyl, CHO, CN, CO2H, alkoxycarbonyl, alkoxyalkoxy-carbonyl, haloalkoxycarbonyl, alkylcarbonyl, haloalkylcarbonyl, alkoxyalkylcarbonyl, NO2, NH2, alkylamino, dialkylamino, pyrrolidinyl, piperidinyl, morpholinyl, alkylcarbonylamino, haloalkylcarbonylamino, alkylsulfonylamino; R5 = hydrogen orhalogen R6 = halogen, CN, NO2, OH, CF3, C1-C6-alkyl, C1-C4 alkoxy; R7 = various radicals; and the N- oxides of (I) and the agriculturally utilizable salts of (I) where these exist, excepting those compounds (I) where R2 is C1-C4-alkoxy and R1 and/or R3 is carboxyl or the salt, ester or amide thereof. Use: herbicides; desiccation/defoliation of plants.
-
公开(公告)号:DE69434391D1
公开(公告)日:2005-07-07
申请号:DE69434391
申请日:1994-07-11
Applicant: BASF AG
Inventor: SCHAEFER PETER , HAMPRECHT GERHARD , HEISTRACHER ELISABETH , KOENIG HARTMANN , KLINTZ RALF , MUENSTER PETER , RANG HARALD , WESTPHALEN KARL-OTTO , GERBER MATTHIAS , WALTER HELMUT
IPC: A01N43/40 , A01N43/42 , A01N43/60 , A01N43/647 , A01N43/76 , A01N43/78 , A01N43/84 , A01N47/22 , C07D213/30 , C07D213/61 , C07D213/65 , C07D213/68 , C07D213/70 , C07D213/89 , C07D265/36 , C07D401/04 , C07D405/04 , C07D405/14 , C07D409/04 , C07D409/12 , C07D413/04 , C07D417/04
Abstract: PCT No. PCT/EP94/02264 Sec. 371 Date Jan. 11, 1996 Sec. 102(e) Date Jan. 11, 1996 PCT Filed Jul. 11, 1994 PCT Pub. No. WO95/02590 PCT Pub. Date Jan. 26, 1995A substituted 2-phenylpyridine of the formula I where Ar is and the N-oxides of I and the agriculturally utilizable salts of I where these exist. Use: herbicides; desiccation/defoliation of plants.
-
公开(公告)号:ES2173917T3
公开(公告)日:2002-11-01
申请号:ES94914369
申请日:1994-04-14
Applicant: BASF AG
Inventor: BAUMANN ERNST , RHEINHEIMER JOACHIM , VOGELBACHER UWE JOSEF , BRATZ MATTHIAS , MEYER NORBERT , GERBER MATTHIAS
IPC: C07D251/34 , A01N43/54 , A01N43/60 , A01N43/66 , A01P13/00 , C07C69/22 , C07C69/712 , C07C69/734 , C07D239/26 , C07D239/30 , C07D239/34 , C07D239/38 , C07D239/52 , C07D239/60 , C07D251/30 , C07D307/46 , C07D307/54 , C07D333/24 , C07D405/12 , C07D409/12 , C07D491/048
Abstract: PCT No. PCT/EP94/01156 Sec. 371 Date Oct. 19, 1995 Sec. 102(e) Date Oct. 19, 1995 PCT Filed Apr. 14, 1994 PCT Pub. No. WO94/25443 PCT Pub. Date Nov. 10, 19943-(Het)aryloxy(thio)carboxylic acid derivatives of the formula I I where R1 is hydrogen, COOH or a radical which can be hydrolyzed to give COOH; R2 and R3 are each halogen, alkyl, haloalkyl, alkoxy, haloalkoxy or alkylthio; X is nitrogen or CR14, where R14 is hydrogen or, together with R3, forms a 3-membered or 4-membered alkylene or alkenylene chain, in each of which a methylene group is replaced by oxygen; R4 is alkyl, cycloalkyl, cycloalkenyl, alkenyl or alkynyl, each of which is unsubstituted or substituted; an unsubstituted or substituted five-membered or six-membered heteroaromatic structure containing one to three nitrogen atoms or one sulfur or oxygen atom; unsubstituted or substituted phenyl or naphthyl; R4 and R5, together with the neighboring carbon atom, form a 3-membered to 8-membered ring which may contain an oxygen or sulfur atom and which is unsubstituted or substituted; R5 is hydrogen, alkyl, alkenyl, alkynyl, cycloalkyl, haloalkyl, alkoxyalkyl, alkylthioalkyl or phenyl, each of which is unsubstituted or substituted; R6 is unsubstituted or substituted phenyl or naphthyl or an unsubstituted or substituted five-membered or six-membered heteroaromatic structure containing one to three nitrogen atoms or one sulfur or oxygen atom; Y is sulfur or oxygen or a single bond; and Z is sulfur or oxygen.
-
公开(公告)号:PT695295E
公开(公告)日:2002-08-30
申请号:PT94913588
申请日:1994-04-13
Applicant: BASF AG
Inventor: WESTPHALEN KARL-OTTO , RADEMACHER WILHELM , GERBER MATTHIAS , HANS THEOBALD DR , WALTER HELMUT , BRATZ MATTHIAS , BAUMANN ERNST , RHEINHEIMER JOACHIM , VOGELBACHER UWE JOSEF
IPC: A01N43/54 , A01N43/64 , A01N43/66 , A01N43/72 , A01P13/00 , A01P21/00 , C07C45/58 , C07C47/198 , C07C47/277 , C07C59/125 , C07D251/22 , C07C67/31 , C07C69/708 , C07C69/734 , C07C205/28 , C07C323/22 , C07C323/50 , C07D239/26 , C07D239/30 , C07D239/34 , C07D239/38 , C07D239/60 , C07D251/24 , C07D251/30 , C07D251/34 , C07D401/12 , C07D403/12 , C07D405/12 , C07D409/12 , C07D411/12 , C07D413/12 , C07D477/12 , C07D491/048
Abstract: PCT No. PCT/EP94/01141 Sec. 371 Date Oct. 19, 1995 Sec. 102(e) Date Oct. 19, 1995 PCT Filed Apr. 13, 1994 PCT Pub. No. WO94/25442 PCT Pub. Date Nov. 10, 19943-(Het)arylcarboxylic acid derivatives of the formula I I where R is formyl, CO2H or a radical hydrolyzable to COOH and the other substituents have the following meanings: R2 and R3 are each halogen, alkyl, haloalkyl, alkoxy, haloalkoxy or alkylthio; X is nitrogen or CR14, where R14 is hydrogen or, together with R3, forms an alkylene or alkenylene chain, in each of which a methylene group is replaced by oxygen; R4 is phenyl or naphthyl, each of which is unsubstituted or substituted or an unsubstituted or substituted five-membered or six-membered heteroaromatic structure containing one to three nitrogen atoms or one sulfur or oxygen atom; R5 is hydrogen, alkyl, alkenyl, alkynyl, cycloalkyl, haloalkyl, alkoxyalkyl, alkylthioalkyl or phenyl; R6 is C1-C8-alkyl, C3-C6-alkenyl, C3-C6-alkynyl or C3-C4-cyclo-alkyl, each of which may be mono- or polysubstituted; Y is sulfur, oxygen or a single bond; and Z is sulfur or oxygen; with the proviso that R6 is not unsubstituted C1-C4-alkyl when R4 is unsubstituted phenyl, Z is oxygen and simultaneously R5 is methyl or hydrogen.
-
公开(公告)号:DE59510111D1
公开(公告)日:2002-04-18
申请号:DE59510111
申请日:1995-07-04
Applicant: BASF AG
Inventor: KLINTZ RALF , HAMPRECHT GERHARD , HEISTRACHER ELISABETH , SCHAEFER PETER , VON DEM BUSSCHE-HUENNEFELD CHR , MUENSTER PETER , KIRSTGEN REINHARD , HARREUS ALBRECHT , WESTPHALEN KARL-OTTO , GERBER MATTHIAS , WALTER HELMUT
IPC: C07D239/52 , A01N37/32 , A01N37/50 , A01N43/38 , A01N43/54 , C07C251/40 , C07C259/06 , C07C265/14 , C07C271/28 , C07C271/58 , C07C331/28 , C07D209/48 , C07D239/54 , C07D239/56 , C07D239/58 , C07D413/10
Abstract: PCT No. PCT/EP95/02584 Sec. 371 Date Jun. 30, 1997 Sec. 102(e) Date Jun. 30, 1997 PCT Filed Jul. 4, 1995 PCT Pub. No. WO96/02518 PCT Pub. Date Feb. 1, 1996Substituted cinnamic oxime derivatives I and cinnamic hydroxamide derivatives II (R1=halogen, NO2, CN, CF3; R2=H, halogen; R3=H, halogen, C1-C6-alkyl, C1-C6-haloalkyl, C3-C6-cycloalkyl, C3-C6-alkenyl, C3-C6-alkynyl, hydroxy-C1-C6-alkyl; R4=H, halogen, CN, C1-C6-alkyl, C1-C6-haloalkyl or R3+R4=chemical bond; Y=-O-, -S-, -O-CO-, -O-SO2- or chemical bond; Y'=-O- or -S-; R5=unsubst. or subst. C1-C6-alkyl or C1-C6-haloalkyl; C3-C6-cycloalkyl, C3-C6-alkenyl, C3-C6-alkynyl, unsubst. or subst. phenyl or phenyl-C1-C6-alkyl, or, if Y is -O-, -S- or a chemical bond, is (C1-C6-alkyl)carbonyl or (C1-C6-alkoxy)carbonyl; or, if Y is a chemical bond, is hydrogen or halogen; R5'=R5, H or (C1-C6-haloalkyl)carbonyl; R6=H, C1-C6-alkyl, C1-C6-haloalkyl, C3-C6-cycloalkyl, C3-C6-alkenyl, C3-C6-alkynyl, hydroxy-C1-C6-alkyl, C1-C6-alkoxy-C1-C6-alkyl, C1-C6-alkylthio-C1-C6-alkyl, cyano-C1-C6-alkyl, (C1-C6-alkoxy) carbonyl-C1-C6-alkyl, (C1-C6-alkyl) carbonyl-C1-C6-alkyl, (C1-C6-alkyl)carbonyloxy-C1-C6-alkyl or unsubst. or subst. phenyl-C1-C6-alkyl; or, if Y is oxygen or sulfur, R5+R6 together=unsubst. or subst. C1-C3-alkylene; Cyc=N-(3,4,5,6-tetrahydrophthalimido) or X1, X2=oxygen or sulfur; R7=H, C1-C6-alkyl, C1-C6-haloalkyl, NH2; R8, R9=H, halogen, C1-C6-alkyl, C1-C6-haloalkyl or unsubst. or subst. phenyl); and salts of I and II. Use: herbicides; desiccation/defoliation of plants.
-
公开(公告)号:DE59410072D1
公开(公告)日:2002-04-11
申请号:DE59410072
申请日:1994-04-13
Applicant: BASF AG
Inventor: BAUMANN ERNST , RHEINHEIMER JOACHIM , VOGELBACHER JOSEF , BRATZ MATTHIAS , THEOBALD HANS , GERBER MATTHIAS , WESTPHALEN KARL-OTTO , WALTER HELMUT , RADEMACHER WILHELM
IPC: C07D251/22 , A01N43/54 , A01N43/64 , A01N43/66 , A01N43/72 , A01P13/00 , A01P21/00 , C07C45/58 , C07C47/198 , C07C47/277 , C07C59/125 , C07C67/31 , C07C69/708 , C07C69/734 , C07C205/28 , C07C323/22 , C07C323/50 , C07D239/26 , C07D239/30 , C07D239/34 , C07D239/38 , C07D239/60 , C07D251/24 , C07D251/30 , C07D251/34 , C07D401/12 , C07D403/12 , C07D405/12 , C07D409/12 , C07D411/12 , C07D413/12 , C07D477/12 , C07D491/048
Abstract: PCT No. PCT/EP94/01141 Sec. 371 Date Oct. 19, 1995 Sec. 102(e) Date Oct. 19, 1995 PCT Filed Apr. 13, 1994 PCT Pub. No. WO94/25442 PCT Pub. Date Nov. 10, 19943-(Het)arylcarboxylic acid derivatives of the formula I I where R is formyl, CO2H or a radical hydrolyzable to COOH and the other substituents have the following meanings: R2 and R3 are each halogen, alkyl, haloalkyl, alkoxy, haloalkoxy or alkylthio; X is nitrogen or CR14, where R14 is hydrogen or, together with R3, forms an alkylene or alkenylene chain, in each of which a methylene group is replaced by oxygen; R4 is phenyl or naphthyl, each of which is unsubstituted or substituted or an unsubstituted or substituted five-membered or six-membered heteroaromatic structure containing one to three nitrogen atoms or one sulfur or oxygen atom; R5 is hydrogen, alkyl, alkenyl, alkynyl, cycloalkyl, haloalkyl, alkoxyalkyl, alkylthioalkyl or phenyl; R6 is C1-C8-alkyl, C3-C6-alkenyl, C3-C6-alkynyl or C3-C4-cyclo-alkyl, each of which may be mono- or polysubstituted; Y is sulfur, oxygen or a single bond; and Z is sulfur or oxygen; with the proviso that R6 is not unsubstituted C1-C4-alkyl when R4 is unsubstituted phenyl, Z is oxygen and simultaneously R5 is methyl or hydrogen.
-
公开(公告)号:ES2164775T3
公开(公告)日:2002-03-01
申请号:ES95928489
申请日:1995-07-29
Applicant: BASF AG
Inventor: PLATH PETER , RANG HARALD , WESTPHALEN KARL-OTTO , GERBER MATTHIAS , WALTER HELMUT
IPC: C07D277/68 , A01N43/80 , A01P13/00 , C07B41/08 , C07D275/06
Abstract: PCT No. PCT/EP95/03022 Sec. 371 Date Feb. 3, 1997 Sec. 102(e) Date Feb. 3, 1997 PCT Filed Jul. 29, 1995 PCT Pub. No. WO96/05184 PCT Pub. Date Feb. 22, 1996Saccharincarboxylic acids and -carboxylic acid esters of the formula I I where the substituents have the following meanings: L and M are hydrogen, alkyl, alkoxy, alkylthio, chlorine, cyano, alkylsulfonyl, nitro or trifluoromethyl; Z is hydrogen, alkyl, cycloalkyl, alkyl, aryl or aralkyl; R is H or C1-C6-alkyl, are prepared by reacting corresponding bromo- or iodo-substituted saccharin derivatives of the formula II II where L, M and Z have the abovementioned meanings, or if Z NOTEQUAL H, compounds of the formula III III in the presence of a palladium, nickel, cobalt or rhodium transition metal catalyst and of a base with carbon monoxide and water or a C1-C6-alcohol under elevated pressure.
-
公开(公告)号:DE59509621D1
公开(公告)日:2001-10-25
申请号:DE59509621
申请日:1995-07-29
Applicant: BASF AG
Inventor: PLATH PETER , RANG HARALD , WESTPHALEN KARL-OTTO , GERBER MATTHIAS , WALTER HELMUT
IPC: C07D277/68 , A01N43/80 , A01P13/00 , C07B41/08 , C07D275/06
Abstract: PCT No. PCT/EP95/03022 Sec. 371 Date Feb. 3, 1997 Sec. 102(e) Date Feb. 3, 1997 PCT Filed Jul. 29, 1995 PCT Pub. No. WO96/05184 PCT Pub. Date Feb. 22, 1996Saccharincarboxylic acids and -carboxylic acid esters of the formula I I where the substituents have the following meanings: L and M are hydrogen, alkyl, alkoxy, alkylthio, chlorine, cyano, alkylsulfonyl, nitro or trifluoromethyl; Z is hydrogen, alkyl, cycloalkyl, alkyl, aryl or aralkyl; R is H or C1-C6-alkyl, are prepared by reacting corresponding bromo- or iodo-substituted saccharin derivatives of the formula II II where L, M and Z have the abovementioned meanings, or if Z NOTEQUAL H, compounds of the formula III III in the presence of a palladium, nickel, cobalt or rhodium transition metal catalyst and of a base with carbon monoxide and water or a C1-C6-alcohol under elevated pressure.
-
公开(公告)号:DE59209901D1
公开(公告)日:2001-05-23
申请号:DE59209901
申请日:1992-01-29
Applicant: BASF AG
Inventor: MAYER HORST , HAMPRECHT GERHARD , WESTPHALEN KARL-OTTO , GERBER MATTHIAS , WALTER HELMUT
IPC: A01N47/36 , A01P13/00 , A61K47/36 , C07D239/42 , C07D239/46 , C07D239/47 , C07D239/52 , C07D251/42 , C07D251/46 , C07D251/52 , C07D521/00
Abstract: PCT No. PCT/EP92/00182 Sec. 371 Date Aug. 6, 1993 Sec. 102(e) Date Aug. 6, 1993 PCT Filed Jan. 29, 1992 PCT Pub. No. WO92/14715 PCT Pub. Date Sep. 3, 1992.Sulfonylurea derivatives of the formula I ted alkyl or phenyl; alkenyl or propargyl, alkylamino or dialkylamino; R2 is hydrogen, halogen, unsubstituted or substituted methyl, methoxy or ethoxy, alkylsulfonyl, nitro or cyano; R3 is difluoromethoxy, trifluoromethoxy, bromodifluoromethoxy, chlorodifluoromethoxy or fluorine; R4 is halogen, unsubstituted or halogen-substituted methyl, ethyl, methoxy or ethoxy or is methylamino or dimethylamino; R5 is hydrogen, alkyl or alkenyl or alkynyl, and Z is CH or N, with the proviso that a) when R3 is difluoromethoxy, R1 is not dialkylamino, R2 is not alkylsulfonyl and R4 is not methyl or methoxy and b) when R3 is fluorine and Z is N, R4 is not alkylamino, and salts thereof are suitable as herbicides.
-
-
-
-
-
-
-
-
-