SUBSTITUTED 2-PHENYLPYRIDINES WITH HERBICIDAL ACTION

    公开(公告)号:CA2167291C

    公开(公告)日:2006-04-25

    申请号:CA2167291

    申请日:1994-07-11

    Applicant: BASF AG

    Abstract: Substituted 2-phenylpyridines have formula (I) wherein R1, R3 = H halogen, alkyl, haloalkyl, alkoxyalkyl, alkoxy, alkoxyalkoxy, OH, haloalkoxy, alkylcarbonyloxy, haloalkylcarbonyloxy, SH, alkylthio, alkylsulfinyl, alkylsulfonyl, haloalkylthio, haloalkylsulfinyl, haloalkyl-sulfonyl, CHO, CN, CO2H, alkoxycarbonyl, alkoxyalkoxycarbonyl, haloalkoxycarbonyl, alkylcarbonyl, haloalkylcarbonyl, alkoxyalkyl-carbonyl, CONH2, alkylaminocarbonyl, dialkylaminocarbonyl, pyrrolidinylcarbonyl, piperidylcarbonyl, morpholinylcarbonyl, NO2, NH2, alkylamino, dialkylamino, pyrrolidinyl, piperidinyl, morpholinyl, alkylcarbonylamino haloalkylcarbonylamino, alkylsulfonylamino; R2 = halogen CN, NO2, alkyl, haloalkyl, alkoxy, haloalkoxy, alkylthio, haloalkylthio; or R1 + R2 or R2 + R3 = trimethylene or tetramethylene chain; R4 = halogen, alkyl, haloalkyl, alkoxyalkyl, alkoxy, alkoxyalkoxy, OH haloalkoxy, alkylcarbonyloxy, haloalkylcarbonyloxy, SH, alkylthio, alkylsulfinyl, alkylsulfonyl, haloalkylthio haloalkylsulfinyl, haloalkylsulfonyl, CHO, CN, CO2H, alkoxycarbonyl, alkoxyalkoxy-carbonyl, haloalkoxycarbonyl, alkylcarbonyl, haloalkylcarbonyl, alkoxyalkylcarbonyl, NO2, NH2, alkylamino, dialkylamino, pyrrolidinyl, piperidinyl, morpholinyl, alkylcarbonylamino, haloalkylcarbonylamino, alkylsulfonylamino; R5 = hydrogen orhalogen R6 = halogen, CN, NO2, OH, CF3, C1-C6-alkyl, C1-C4 alkoxy; R7 = various radicals; and the N- oxides of (I) and the agriculturally utilizable salts of (I) where these exist, excepting those compounds (I) where R2 is C1-C4-alkoxy and R1 and/or R3 is carboxyl or the salt, ester or amide thereof. Use: herbicides; desiccation/defoliation of plants.

    94.
    发明专利
    未知

    公开(公告)号:ES2173917T3

    公开(公告)日:2002-11-01

    申请号:ES94914369

    申请日:1994-04-14

    Applicant: BASF AG

    Abstract: PCT No. PCT/EP94/01156 Sec. 371 Date Oct. 19, 1995 Sec. 102(e) Date Oct. 19, 1995 PCT Filed Apr. 14, 1994 PCT Pub. No. WO94/25443 PCT Pub. Date Nov. 10, 19943-(Het)aryloxy(thio)carboxylic acid derivatives of the formula I I where R1 is hydrogen, COOH or a radical which can be hydrolyzed to give COOH; R2 and R3 are each halogen, alkyl, haloalkyl, alkoxy, haloalkoxy or alkylthio; X is nitrogen or CR14, where R14 is hydrogen or, together with R3, forms a 3-membered or 4-membered alkylene or alkenylene chain, in each of which a methylene group is replaced by oxygen; R4 is alkyl, cycloalkyl, cycloalkenyl, alkenyl or alkynyl, each of which is unsubstituted or substituted; an unsubstituted or substituted five-membered or six-membered heteroaromatic structure containing one to three nitrogen atoms or one sulfur or oxygen atom; unsubstituted or substituted phenyl or naphthyl; R4 and R5, together with the neighboring carbon atom, form a 3-membered to 8-membered ring which may contain an oxygen or sulfur atom and which is unsubstituted or substituted; R5 is hydrogen, alkyl, alkenyl, alkynyl, cycloalkyl, haloalkyl, alkoxyalkyl, alkylthioalkyl or phenyl, each of which is unsubstituted or substituted; R6 is unsubstituted or substituted phenyl or naphthyl or an unsubstituted or substituted five-membered or six-membered heteroaromatic structure containing one to three nitrogen atoms or one sulfur or oxygen atom; Y is sulfur or oxygen or a single bond; and Z is sulfur or oxygen.

    96.
    发明专利
    未知

    公开(公告)号:DE59510111D1

    公开(公告)日:2002-04-18

    申请号:DE59510111

    申请日:1995-07-04

    Applicant: BASF AG

    Abstract: PCT No. PCT/EP95/02584 Sec. 371 Date Jun. 30, 1997 Sec. 102(e) Date Jun. 30, 1997 PCT Filed Jul. 4, 1995 PCT Pub. No. WO96/02518 PCT Pub. Date Feb. 1, 1996Substituted cinnamic oxime derivatives I and cinnamic hydroxamide derivatives II (R1=halogen, NO2, CN, CF3; R2=H, halogen; R3=H, halogen, C1-C6-alkyl, C1-C6-haloalkyl, C3-C6-cycloalkyl, C3-C6-alkenyl, C3-C6-alkynyl, hydroxy-C1-C6-alkyl; R4=H, halogen, CN, C1-C6-alkyl, C1-C6-haloalkyl or R3+R4=chemical bond; Y=-O-, -S-, -O-CO-, -O-SO2- or chemical bond; Y'=-O- or -S-; R5=unsubst. or subst. C1-C6-alkyl or C1-C6-haloalkyl; C3-C6-cycloalkyl, C3-C6-alkenyl, C3-C6-alkynyl, unsubst. or subst. phenyl or phenyl-C1-C6-alkyl, or, if Y is -O-, -S- or a chemical bond, is (C1-C6-alkyl)carbonyl or (C1-C6-alkoxy)carbonyl; or, if Y is a chemical bond, is hydrogen or halogen; R5'=R5, H or (C1-C6-haloalkyl)carbonyl; R6=H, C1-C6-alkyl, C1-C6-haloalkyl, C3-C6-cycloalkyl, C3-C6-alkenyl, C3-C6-alkynyl, hydroxy-C1-C6-alkyl, C1-C6-alkoxy-C1-C6-alkyl, C1-C6-alkylthio-C1-C6-alkyl, cyano-C1-C6-alkyl, (C1-C6-alkoxy) carbonyl-C1-C6-alkyl, (C1-C6-alkyl) carbonyl-C1-C6-alkyl, (C1-C6-alkyl)carbonyloxy-C1-C6-alkyl or unsubst. or subst. phenyl-C1-C6-alkyl; or, if Y is oxygen or sulfur, R5+R6 together=unsubst. or subst. C1-C3-alkylene; Cyc=N-(3,4,5,6-tetrahydrophthalimido) or X1, X2=oxygen or sulfur; R7=H, C1-C6-alkyl, C1-C6-haloalkyl, NH2; R8, R9=H, halogen, C1-C6-alkyl, C1-C6-haloalkyl or unsubst. or subst. phenyl); and salts of I and II. Use: herbicides; desiccation/defoliation of plants.

    98.
    发明专利
    未知

    公开(公告)号:ES2164775T3

    公开(公告)日:2002-03-01

    申请号:ES95928489

    申请日:1995-07-29

    Applicant: BASF AG

    Abstract: PCT No. PCT/EP95/03022 Sec. 371 Date Feb. 3, 1997 Sec. 102(e) Date Feb. 3, 1997 PCT Filed Jul. 29, 1995 PCT Pub. No. WO96/05184 PCT Pub. Date Feb. 22, 1996Saccharincarboxylic acids and -carboxylic acid esters of the formula I I where the substituents have the following meanings: L and M are hydrogen, alkyl, alkoxy, alkylthio, chlorine, cyano, alkylsulfonyl, nitro or trifluoromethyl; Z is hydrogen, alkyl, cycloalkyl, alkyl, aryl or aralkyl; R is H or C1-C6-alkyl, are prepared by reacting corresponding bromo- or iodo-substituted saccharin derivatives of the formula II II where L, M and Z have the abovementioned meanings, or if Z NOTEQUAL H, compounds of the formula III III in the presence of a palladium, nickel, cobalt or rhodium transition metal catalyst and of a base with carbon monoxide and water or a C1-C6-alcohol under elevated pressure.

    99.
    发明专利
    未知

    公开(公告)号:DE59509621D1

    公开(公告)日:2001-10-25

    申请号:DE59509621

    申请日:1995-07-29

    Applicant: BASF AG

    Abstract: PCT No. PCT/EP95/03022 Sec. 371 Date Feb. 3, 1997 Sec. 102(e) Date Feb. 3, 1997 PCT Filed Jul. 29, 1995 PCT Pub. No. WO96/05184 PCT Pub. Date Feb. 22, 1996Saccharincarboxylic acids and -carboxylic acid esters of the formula I I where the substituents have the following meanings: L and M are hydrogen, alkyl, alkoxy, alkylthio, chlorine, cyano, alkylsulfonyl, nitro or trifluoromethyl; Z is hydrogen, alkyl, cycloalkyl, alkyl, aryl or aralkyl; R is H or C1-C6-alkyl, are prepared by reacting corresponding bromo- or iodo-substituted saccharin derivatives of the formula II II where L, M and Z have the abovementioned meanings, or if Z NOTEQUAL H, compounds of the formula III III in the presence of a palladium, nickel, cobalt or rhodium transition metal catalyst and of a base with carbon monoxide and water or a C1-C6-alcohol under elevated pressure.

    100.
    发明专利
    未知

    公开(公告)号:DE59209901D1

    公开(公告)日:2001-05-23

    申请号:DE59209901

    申请日:1992-01-29

    Applicant: BASF AG

    Abstract: PCT No. PCT/EP92/00182 Sec. 371 Date Aug. 6, 1993 Sec. 102(e) Date Aug. 6, 1993 PCT Filed Jan. 29, 1992 PCT Pub. No. WO92/14715 PCT Pub. Date Sep. 3, 1992.Sulfonylurea derivatives of the formula I ted alkyl or phenyl; alkenyl or propargyl, alkylamino or dialkylamino; R2 is hydrogen, halogen, unsubstituted or substituted methyl, methoxy or ethoxy, alkylsulfonyl, nitro or cyano; R3 is difluoromethoxy, trifluoromethoxy, bromodifluoromethoxy, chlorodifluoromethoxy or fluorine; R4 is halogen, unsubstituted or halogen-substituted methyl, ethyl, methoxy or ethoxy or is methylamino or dimethylamino; R5 is hydrogen, alkyl or alkenyl or alkynyl, and Z is CH or N, with the proviso that a) when R3 is difluoromethoxy, R1 is not dialkylamino, R2 is not alkylsulfonyl and R4 is not methyl or methoxy and b) when R3 is fluorine and Z is N, R4 is not alkylamino, and salts thereof are suitable as herbicides.

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