92.
    发明专利
    未知

    公开(公告)号:DE59007620D1

    公开(公告)日:1994-12-08

    申请号:DE59007620

    申请日:1990-08-29

    Applicant: BASF AG

    Abstract: Process for the preparation of 3-methylquinoline-8-carboxylic acid I and its derivatives by reacting o-toluidine II or its derivatives with methacrolein III in the presence of iodine or an iodine compound, in 70-90% by weight sulphuric acid, and oxidation of the resulting 3,8-dimethylquinoline IV or its derivatives with nitric acid in a solution of sulphuric acid in the presence of vanadium ions, characterised in that, in a first step, the by-products of the reaction are decomposed by oxidation in the reaction solution of 3,8-dimethylquinoline IV in sulphuric acid, the resulting 3,8-dimethylquinoline solution is concentrated by distillation, and subsequently the 3,8-dimethylquinoline is oxidised in situ with nitric acid to give 3-methylquinolinecarboxylic acid.

    93.
    发明专利
    未知

    公开(公告)号:DE59102149D1

    公开(公告)日:1994-08-18

    申请号:DE59102149

    申请日:1991-04-30

    Applicant: BASF AG

    Abstract: Herbicidal agent containing a naphthalene derivative I (R = alkyl, alkylthio, haloalkyl, alkoxy, halogen, OH, NO2 and/or benzyl; m = 0, 1, 2 or 3; R = -CN, -C(NH2)NOH, -C(Z)TR , R = halogen, -NR R , -N=CH-R , -NR -SO2R , COOR , OH, Z = O, S; T = O, -NR ; R = H, optionally substituted alkyl, phenyl or benzyl; R = optionally substituted phenyl; R = H, optionally substituted alkyl or phenyl; R = H or optionally substituted alkyl; R = optionally substituted alkyl, phenyl or an optionally substituted heteroaromatic ring; R = optionally substituted alkyl or phenyl, or the R radicals together are an optionally substituted alkylene or alkenylene chain, or an optionally substituted fused benzene ring; R and R = alkyl or, together with the joint carbon atom, cycloalkyl; B = H, optionally substituted alkyl, alkoxycarbonyl, phenyl or -NR R -) as an antidote, and at least one herbicidal active substance from the group of the cyclohexenone derivatives.

    94.
    发明专利
    未知

    公开(公告)号:AT108793T

    公开(公告)日:1994-08-15

    申请号:AT90109552

    申请日:1990-05-19

    Applicant: BASF AG

    Abstract: The invention relates to quinoline derivatives which are fused to five-membered heterocyclic rings, of the formula in which R represents hydrogen, halogen, carboxyl or optionally substituted alkyl, Y represents nitrogen or a C-R group in which R represents hydrogen, halogen, hydroxyl, alkoxy, alkylthio, optionally substituted alkyl, optionally substituted cycloalkyl, an optionally substituted benzyl, phenethyl, phenyl or naphthyl radical or an optionally substituted 5- or 6-membered heterocyclic ring having one or two hetero atoms selected from amongst the group comprising oxygen, sulphur and nitrogen, X represents oxygen or the radical H-R , where R represents hydrogen, optionally substituted alkyl, alkenyl, alkynyl, cycloalkyl or optionally substituted benzyl, to processes for their preparation, and to their use for controlling undesirable plant growth.

    98.
    发明专利
    未知

    公开(公告)号:DE3775657D1

    公开(公告)日:1992-02-13

    申请号:DE3775657

    申请日:1987-08-18

    Applicant: BASF AG

    Abstract: Quinoline-8-carboxylic acid derivs. of formula (I) are new, where R1 = H, 1-4C alkyl, 2-4C alkenyl, or one equivalent of an alkali or alkaline earth metal cation; R2 = F, Cl or Br, R3 = -CHX-R4, -CY-R5, F, Br, I, -SCN, NO2, amino, hydrazino, -N2+Z-, -NHCHO, -NHCOOR6, -NHCONHR5, -NHCOCOR6, -NHCOCH2COR6, -NHCOCH2COOR6, -NH-CH=C(COOR6)2, -N=CH-NR7R8, -NHCOR5, -NHCONHCOR6, -NHSO2R6 or -NHSO2NHR6; X = Cl, Br, I, -SCN, -OR5, -SR5, -SO2R6; Y = O, =NR5, =NOH, =NNH2, =NOR4, =N-OCHO, =NOCOR5, =NO-CO2R4, =NO-CO-NHR6, =N-NHR5, =N-NH-COR5, =N-NH-CO2R4, =N-NHCONH2, =N-NH-CS-NH2 or =N-NH-SO2R6; Z = Br, BF4, PF6 or SbF6; R4 = 1-4C alkyl, 2-4C alkenyl, 1-4C haloalkyl or 2-4C haloalkenyl; R5 = H (provided that Y is other than 0), 1-4C alkyl, 1-4C hydroxyalkyl, 1-4C halo-alkyl, phenyl (opt. substd. by halogen or 1-4C alkyl), 2-5C carboxyalkyl, or 3-8C alkoxycarbonylalkyl; R6 = 1-4C alkyl, 1-4C haloalkyl, 2-5C alkylcarbonyl, 2-5C haloalkylcarbonyl, or phenyl (opt. substd. by halogen or 1-4C alkyl); R7, R8 = 1-4C alkyl.

    New and known heterocyclo-quinoline derivs.

    公开(公告)号:DE4003587A1

    公开(公告)日:1991-08-08

    申请号:DE4003587

    申请日:1990-02-07

    Applicant: BASF AG

    Abstract: (A) Heterocycloquinoline derivs. of formula (I) are new: R1 = H, halogen, COOH, or 1-6C alkyl opt. substd. by 1-4C alkoxy, 1-4C alkylthio or halogen; Y = N or CR2; R2 = (a) H, halogen, OH, 1-4C alkoxy or 1-4C alkylthio, (b) 1-6C alkyl opt. substd. by halogen, OH, acetoxy, CN, 1-4C alkoxy or 1-4C alkylthio, (c) 3-6C cycloalkyl opt. substd. by 1-4C alkyl, (d) benzyl, phenethyl, phenyl or naphthyl, opt. substd. by NO2, NH2, halogen, 1-4C alkyl, 1-4C alkoxy, 1-4C alkylthio, 1-4C haloalkyl, acylamino or acyloxy, or (e) 5- or 6-membered heterocyclyl contg. 1 or 2 heteroatoms (O, S and/or N), opt. substd. by NO2, 1-4C alkyl or halogen; X = O or NR3; R3 = (a) H, 2-6C alkenyl or 2-6C alkynyl, (b) 1-6C alkyl opt. substd. by halogen, NH2, mono- or di-alkylamino, OH, 1-4C alkoxy or 1-4C acyloxy, (c) 3-6C cycloalkyl opt. substd. by 1-4C alkyl, or (d) benzyl opt. substd. by halogen, 1-4C alkyl, 1-4C haloalkyl or 1-4C alkoxy.

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