2.
    发明专利
    未知

    公开(公告)号:BR9305881A

    公开(公告)日:1997-08-19

    申请号:BR9305881

    申请日:1993-01-30

    Applicant: BASF AG

    Abstract: PCT No. PCT/EP93/00215 Sec. 371 Date Aug. 11, 1994 Sec. 102(e) Date Aug. 11, 1994 PCT Filed Jan. 30, 1993 PCT Pub. No. WO93/16063 PCT Pub. Date Aug. 19, 1993.Cyclohexenone oxime ethers I I R1=C1-C6-alkyl; W=unsubstituted or C1-C3-alkyl-substituted C2-C4-alkylene chain; X=NO2, CN, halogen, C1-C4-alkyl, C1-C4-haloalkyl; n=0-3 or 1-5 if all X's are halogen; R2 =C1-C4-alkoxy-C1-C6-alkyl, C1-C4-alkylthio-C1-C6-alkyl, substituted or unsubstituted C3-C7-cycloalkyl, substituted or unsubstituted C5-C7-cycloalkenyl, a substituted or unsubstituted 5-membered saturated heterocycle containing 1 or 2 oxygen and/or sulfur atoms, substituted or unsubstituted 6- or 7-membered heterocycle having 1 or 2 non-adjacent oxygen and/or sulfur atoms and which is saturated or mono- or diunsaturated, substituted or unsubstituted 5-membered heteroaromatic containing 1 or 2N atoms and one O or S atom, phenyl or pyridyl, both of which are unsubstituted or bear 1-3 halogen, NO2, CN, alkyl, alkoxy, alkyl-thio, haloalkyl, alkenyloxy, alkynyloxy and/or -NRaRb substituents; Ra=H, alkyl, alkenyl or alkynyl and Rb=H, alkyl, alkenyl, alkynyl, acyl or substituted or unsubstituted benzoyl; and agriculturally utilizable salts and esters of compounds I with C1-C10-carboxylic acids and inorganic acids.

    4.
    发明专利
    未知

    公开(公告)号:ES2062245T3

    公开(公告)日:1994-12-16

    申请号:ES90118944

    申请日:1990-10-04

    Applicant: BASF AG

    Abstract: Preparation of cyclohexanetrionecarboxylic acid thiol esters of the formula I in which R and R represent optionally substituted alkyl, alkenyl, alkynyl, cycloalkyl, benzyl or phenyl, and R additionally denotes hydrogen, by reacting a cyclohexanetrione compound II with hydroxylamine or hydroxylamine O-sulphonic acid in an inert solvent at temperatures from 0 to 150 DEG C to give cyclohexanetrione compounds III subsequently reacting the compounds III with a mercaptan IV R -SH IV in the presence of an anhydrous acid HX to give cyclohexanetrione imidothioester salts V where X represents the acid radical, and hydrolysing the compounds V to give the cyclohexanetrione carboxylic acid thiol esters I.

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