-
公开(公告)号:AU2003273863A1
公开(公告)日:2004-04-19
申请号:AU2003273863
申请日:2003-09-12
Applicant: BASF AG
Inventor: MERTEN ANNE-KATHRIN , WINKLER JURGEN , HARRE KATHRIN , LORENZ REINHARD , RUPPEL RAIMUND , OSTROWSKI THOMAS , BOHRES EDWARD , HOPPNER GERD , HOPPE ANDREAS
Abstract: The invention relates to a method for producing polyether alcohols by means of catalytic polymerisation of alkylene oxides. Said method is characterised in that the alkylene oxide contains propylene oxide, at least one multimetal cyanide compound is used as a catalyst, and the free alkylene oxide content in the reactor is lower than or equal to 8 wt. %, in relation to the total amount of educts and reaction products in the reactor.
-
公开(公告)号:AT260880T
公开(公告)日:2004-03-15
申请号:AT99968663
申请日:1999-09-06
Applicant: BASF AG
-
公开(公告)号:DE10210125A1
公开(公告)日:2003-09-25
申请号:DE10210125
申请日:2002-03-08
Applicant: BASF AG
Inventor: BAUM EVA , RUPPEL RAIMUND , TISCHER GERLINDE , HARRE KATHRIN , BOHRES EDWARD
IPC: C08G18/48 , C08G63/668 , C08G65/26 , C08G65/28 , C08G18/08
Abstract: The invention relates to a method for producing polyether alcohols with a functionality of more than 2, comprising the following steps: a) a polyester alcohol having a functionality of more than 2, preferably at least 3, is produced by reacting at least one multifunctional alcohol with at least one multifunctional carboxylic acid; b) said polyester alcohol is reacted with alkylene oxides by using at least one DMC catalyst.
-
公开(公告)号:AU2003210406A1
公开(公告)日:2003-09-22
申请号:AU2003210406
申请日:2003-03-04
Applicant: BASF AG
Inventor: BAUM EVA , RUPPEL RAIMUND , TISCHER GERLINDE , HARRE KATHRIN , BOHRES EDWARD
Abstract: The invention relates to a method for producing polyether alcohols with a functionality of more than 2, comprising the following steps: a) a polyester alcohol having a functionality of more than 2, preferably at least 3, is produced by reacting at least one multifunctional alcohol with at least one multifunctional carboxylic acid; b) said polyester alcohol is reacted with alkylene oxides by using at least one DMC catalyst.
-
公开(公告)号:ES2186649T3
公开(公告)日:2003-05-16
申请号:ES00926868
申请日:2000-04-11
Applicant: BASF AG
Inventor: LORENZ REINHARD , BAUER STEPHAN , JUNGE DIETER , BAUM EVA , HARRE KATHRIN , ERBES JORG
Abstract: In a process for producing polyurethanes by reacting at least one polyisocyanate with at least one compound containing at least two hydrogen atoms which are reactive toward isocyanate groups, the compound having at least two active hydrogen atoms which is used is at least one polyether alcohol prepared by addition of alkylene oxides onto H-functional initiator substances by means of multimetal cyanide catalysis and the reaction is carried out in the presence of at least one metal salt.
-
公开(公告)号:HU0300001A2
公开(公告)日:2003-04-28
申请号:HU0300001
申请日:2001-02-20
Applicant: BASF AG
Inventor: BAUM EVA , FRANKE DIRK , GROSCH GEORG HEINRICH , HARRE KATHRIN , MUNZINGER MANFRED , STOESSER MICHAEL
Abstract: A process for preparing polyether polyols includes a precipitation step, a recrystallization step, and a reaction step. In the precipitation step, a multimetal cyanide compound is precipitated by reaction of a metal salt with a cyanometalate compound. In the recrystallization step, the multimetal cyanide compound precipitated above is recrystallized by adding further metal salt and/or further cyanometalate compound. The recrystallization forms a multimetal cyanide catalyst compound. In the reaction step, an initiator and one or more alkylene oxide are reacted in the presence of the multimetal cyanide catalyst compound.
-
97.
公开(公告)号:HU0204462A2
公开(公告)日:2003-04-28
申请号:HU0204462
申请日:2001-02-16
Applicant: BASF AG
Inventor: GROSCH GEORG HEINRICH , HARRE KATHRIN , OSTROWSKI THOMAS , WINKLER JUERGEN
Abstract: Production of polyether polyols by reaction of diols or polyols with a 2-4C alkylene oxide in the presence of a multi-metal cyanide complex catalyst comprises use of a tall vertical cylindrical reactor with a central stirrer and heat exchange plates arranged in the longitudinal direction of the reactor at an angle, alpha , of 0-70 [deg] in the direction of rotation of the stirrer to the reactor radius. A process for the production of polyether polyols (I) by reaction of diols or polyols with ethylene oxide, propylene oxide and/or butylene oxide in the presence of a multi-metal cyanide complex catalyst (II) comprises carrying out the reaction in a tall vertical cylindrical reactor with a central stirrer and heat exchanger plates, through which a heat exchange medium flows and which are arranged essentially in the longitudinal direction of the reactor at an angle alpha , of 0-70 [deg] in the direction of rotation of the stirrer to the reactor radius.
-
公开(公告)号:ES2178469T3
公开(公告)日:2002-12-16
申请号:ES99944507
申请日:1999-08-25
Applicant: BASF AG
Inventor: GROSCH GEORG HEINRICH , LARBIG HARALD , LORENZ REINHARD , JUNGE DIETER , HARRE KATHRIN
IPC: C08G65/10 , B01J23/00 , B01J27/232 , B01J27/236 , B01J27/26 , C08G18/48 , C08G65/26 , C08G65/28
Abstract: A process for preparing polyetherols by ring-opening polymerization of alkylene oxides onto H-functional initiator molecules, which comprises at least one process step a) in which a compound of the formula (I) M'aM''b(OH)cOd*Ac*Lf (I), applied to a solid inert support or incorporated in the latter or molded to form a shaped body is used as catalyst, and at least one process step b) in which a multimetal cyanide compound of the formula (II) M1a[M2(CN)b(A)c]d.fM1gXn.h(H2O).eL (II) applied to a solid, inert support or incorporated in the latter or molded to form a shaped body or in powder or paste form is used as catalyst.
-
公开(公告)号:AU3163802A
公开(公告)日:2002-06-03
申请号:AU3163802
申请日:2001-11-22
Applicant: BASF AG
Inventor: BOHRES EDWARD , GROSCH GEORG HEINRICH , VOSS HARTWIG , HOPPNER GERD , HARRE KATHRIN , PAREDIS ELS , WINKLER JURGEN , STOSSER MICHAEL , SAGER WILFRIED
-
公开(公告)号:DE10057891A1
公开(公告)日:2002-05-23
申请号:DE10057891
申请日:2000-11-22
Applicant: BASF AG
Inventor: HEIDER WOLFGANG , BOHRES EDWARD , GROSCH GEORG HEINRICH , VOS HARTWIG , HOEPPNER GERD , HARRE KATHRIN , PAREDIS ELS , WINKLER JUERGEN
Abstract: A method for working up polyether-polyols (I) obtained by ring-opening polymerization of epoxides with hydroxy-functional starters in presence of heterogeneous catalysts involves separating the catalyst from the product (I) by a membrane separation process. An Independent claim is also included for a method for the production of (I) by ring-opening polymerization of epoxides followed by a work-up process using a separation step as above.
-
-
-
-
-
-
-
-
-