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    91.
    发明专利
    未知

    公开(公告)号：DE59407708D1

    公开(公告)日：1999-03-04

    申请号：DE59407708

    申请日：1994-06-23

    Applicant: BASF AG

    Inventor： ROHDE WOLFGANG ,  SAIVE ROLAND ,  GOERTZ HANS-HELMUT ,  SCHWEIER GUENTHER

    IPC: C08F4/02 ,  C08F4/639 ,  C08F4/6392 ,  C08F4/69 ,  C08F10/00

    Abstract: Polyalk-1-enes are prepared by polymerization of alk-1-enes with the aid of the compound bis(cyclopentadienyl)-chromium(II)in which the cyclopentadienyl rings may carry inert organic radicals, said compound being adsorbed on an inorganic oxide carrier, by a process in which the polymerization is carried out in the presence of an organometallic compound of a metal of main groups I to III or of a metal hydride, in particular of n-butyl-lithium.

    Catalyst systems of the ziegler-nappa type
    93.
    发明专利
    Catalyst systems of the ziegler-nappa type 未知

    公开(公告)号：ZA975101B

    公开(公告)日：1998-12-10

    申请号：ZA975101

    申请日：1997-06-10

    Applicant: BASF AG

    Inventor： HUEFFER STEPHAN ,  BIDELL WOLFGANG ,  MUELLER PATRIK ,  MOLL ULRICH ,  HINGMAN ROLAND ,  SCHWEIER GUENTHER

    IPC: C08F4/654 ,  C08F4/02 ,  C08F4/646 ,  C08F4/658 ,  C08F10/00 ,  C08F110/06 ,  C08F

    Abstract: Ziegler-Natta type catalyst system (ZNC), containing (a) a titanium-based solid component containing compounds of Ti and magnesium, a halogen, an inorganic oxide support (IOS) and a carboxylate ester as electron donor, (b) an aluminium compound and (c) optionally another electron donor, in which the oxide (IOS) has a pH of 1-6, an average particle diameter of 5-200 microns and an average primary particle diameter of 1-20 mu m, and contains pores or channels with an average diameter of 0.1-20 mu m in amounts of 5-30 vol%. Also claimed is (i) a process for the production of ZNC by interacting components (a), (b) and (c) together at 0-150 degrees C and 1-100 bar; (ii) a process for the production of polymers of 2-20C alk-1-enes by polymerisation of the alkene (preferably propylene) and optionally other comonomers at 20-150 degrees C and 1-100 bar in presence of (ZNC); (iii) polymers of propylene obtained by this process.

    95.
    发明专利
    未知

    公开(公告)号：ES2112543T3

    公开(公告)日：1998-04-01

    申请号：ES94916969

    申请日：1994-05-17

    Applicant: BASF AG

    Inventor： LANGHAUSER FRANZ ,  KERTH JUERGEN ,  MUELLER PATRIK ,  KERSTING MEINOLF ,  SCHWEIER GUENTHER

    IPC: C08F2/34 ,  C08F4/642 ,  C08F4/646 ,  C08F4/68 ,  C08F297/08

    Abstract: PCT No. PCT/EP94/01591 Sec. 371 Date Nov. 9, 1995 Sec. 102(e) Date Nov. 9, 1995 PCT Filed May 17, 1994 PCT Pub. No. WO94/28042 PCT Pub. Date Dec. 8, 1994Multiphase block copolymers of propylene comprising a) a polymer of propylene with from 0 to 5% by weight of further C2-C10 1-alkenes, b) a copolymer of propylene with from 5 to 98% by weight of further C2-C10 1-alkenes, the multiphase block copolymers having a melting point of less than 155 DEG C. and a stiffness (shear modulus G) conforming to the following condition (I): (I) where Ma) denotes the amount of propylene polymer a) and Mco denotes the amount of the multiphase block copolymer. are obtainable in particular by polymerization by means of metallocene-containing catalyst systems.\!

    PROCESS FOR PRODUCING POLYMERS OF ALKENES BY SUSPENSION POLYMERISATION
    96.
    发明专利
    PROCESS FOR PRODUCING POLYMERS OF ALKENES BY SUSPENSION POLYMERISATION 未知

    公开(公告)号：CA2246389A1

    公开(公告)日：1997-08-28

    申请号：CA2246389

    申请日：1997-02-19

    Applicant: BASF AG

    Inventor： LYNCH JOHN ,  G RTZ HANS-HELMUT ,  SCHWEIER GUENTHER ,  FISCHER DAVID

    IPC: C08F2/14 ,  C08F2/18 ,  C08F4/02 ,  C08F4/60 ,  C08F4/642 ,  C08F4/646 ,  C08F4/659 ,  C08F4/6592 ,  C08F4/68 ,  C08F10/00 ,  C08F110/02 ,  C08F4/62

    Abstract: A process for producing polymers of alkenes by suspension polymerisation in the presence of catalyst systems where use is made of supported catalyst systems obtainable by A) reacting an inorganic support material with a metal compound of the general formula (I): M1(R1)r(R2)s(R3)t(R4)u, in which M1 is an alkaline or alkaline earth metal or a metal from main group III or IV of the periodic system; R1 is hydrogen, C1-C10 alkyl, C6-C15 aryl, alkyl aryl or aryl alkyl with 1 to 10 C atoms in the alkyl radical and 6 to 20 C atoms in the aryl radical; R2 to R4 are hydrogen, C1-C10 alkyl, C6-C15 aryl, alkyl aryl or aryl alkyl, alkoxy or dialkylamino with 1 to 10 C atoms in the alkyl radical and 6 to 20 C atoms in the aryl radical; r is a whole number from 1 to 4; and s, t and u are whole numbers from 0 to 3, where the sum r+s+t+u corresponds to the valency of M1; B) reacting the material obtained from A) with a metallocene complex in its metal dihalogenide form and a metallocenium ionforming compound; and C) subsequent reaction with a metal compound of the general formula (II): M2(R5)o(R6)p(R7)q, in which M2 is an alkaline or alkaline earth metal or a metal of main group III of the periodic system; R5 is hydrogen, C1-C10 alkyl, C6-C15 aryl, alkyl aryl or aryl alkyl with 1 to 10 C atoms in the alkyl radical and 6 to 20 C atoms in the aryl radical; R6 and R7 are hydrogen, halogen, C1-C10 alkyl, C6-C15 aryl, alkyl aryl, aryl alkyl, or alkoxy with 1 to 10 C atoms in the alkyl radical and 6 to 20 C atoms in the aryl radical, o is a whole number from 1 to 3; and p and q are whole numbers from 0 to 2 where the sum o+p+q corresponds to the valency of M2.

    PROCESS FOR PRODUCING ALKENE POLYMERS BY GAS PHASE POLYMERISATION
    97.
    发明专利
    PROCESS FOR PRODUCING ALKENE POLYMERS BY GAS PHASE POLYMERISATION 未知

    公开(公告)号：CA2246307A1

    公开(公告)日：1997-08-27

    申请号：CA2246307

    申请日：1997-02-19

    Applicant: BASF AG

    Inventor： G RTZ HANS-HELMUT ,  LYNCH JOHN ,  SCHWEIER GUENTHER ,  FISCHER DAVID

    IPC: C08F2/34 ,  C08F4/619 ,  C08F4/6192 ,  C08F4/646 ,  C08F4/68 ,  C08F10/00 ,  C08F110/02 ,  C08F4/02 ,  C08F4/62

    Abstract: A process for producing polymers of alkenes by gas phase polymerisation in the presence of catalyst systems where use is made of supported catalyst systems obtainable by A) reacting an inorganic support material with a metal compound of the general formula (I) M1(R1)r(R2)s(R3)t(R4)u in which M1 is an alkaline or alkaline earth metal or a metal from main group III or IV of the periodic system, R1 is hydrogen, C1-C10 alkyl, C6-C15 aryl, alkyl or aryl alkyl with 1 to 10 C atoms in the alkyl radical and 6 to 20 C atoms in the aryl radical, R2 to R4 are hydrogen, C1-C10 alkyl, C6-C15 aryl, alkyl aryl or aryl alkyl, alkoxy or dialkylamino with 1 to 10 C atoms in the alkyl radical and 6 to 20 C atoms in the aryl radical, r is a whole number from 1 to 4 and s, t, and u are whole numbers from 0 to 3, where the sum r+s+t+u corresponds to the valency of M1, B) reacting the material obtained from A) with a metallocene complex in its metal dihalogenide from and a metallocenium ion-forming compound and C) subsequent reaction with a metal compound of the general formula (II) M2(R5)o(R6)p(R7)q in which M2 is a metal of main group III of the periodic system, R5 is hydrogen, C1-C10 alkyl, C6-C15 aryl, alkyl aryl or aryl alkyl with 1 to 10 C atoms in the alkyl radical and 6 to 20 C atoms in the aryl radical, R6 and R7 are hydrogen, halogen, C1-C10 alkyl, C6-C15 aryl, alkyl aryl, aryl alkyl or alkoxy with 1 to 10 C atoms in the alkyl radical and 6 to 20 C atoms in the aryl radical, o is a whole number from 1 to 3 and p and q are whole numbers from 0 to 2 where the sum o+p+q corresponds to the valency of M2.

    100.
    发明专利
    未知

    公开(公告)号：NO960089D0

    公开(公告)日：1996-01-09

    申请号：NO960089

    申请日：1996-01-09

    Applicant: BASF AG

    Inventor： ROHDE WOLFGANG ,  SAIVE ROLAND ,  GOERTZ HANS-HELMUT ,  SCHWEIER GUENTHER

    IPC: C08F4/02 ,  C08F4/639 ,  C08F4/6392 ,  C08F4/69 ,  C08F10/00

    Abstract: Polyalk-1-enes are prepared by polymerization of alk-1-enes with the aid of the compound bis(cyclopentadienyl)-chromium(II)in which the cyclopentadienyl rings may carry inert organic radicals, said compound being adsorbed on an inorganic oxide carrier, by a process in which the polymerization is carried out in the presence of an organometallic compound of a metal of main groups I to III or of a metal hydride, in particular of n-butyl-lithium.

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