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公开(公告)号:CA2211436A1
公开(公告)日:1996-08-29
申请号:CA2211436
申请日:1996-02-14
Applicant: BASF AG
Inventor: WESTPHALEN KARL-OTTO , HILL REGINA LUISE , WALTER HELMUT , OTTEN MARTINA , ENGEL STEFAN , KARDORFF UWE , VOSSEN MARCUS , HARREUS ALBRECHT , RANG HARALD , KOENIG HARTMANN , PLATH PETER , VON DEYN WOLFGANG , MISSLITZ ULF
IPC: A01N43/78 , A01N43/80 , C07D207/32 , C07D207/327 , C07D207/33 , C07D213/57 , C07D213/64 , C07D213/647 , C07D213/70 , C07D213/74 , C07D215/12 , C07D215/14 , C07D231/12 , C07D231/14 , C07D235/18 , C07D239/26 , C07D239/38 , C07D249/08 , C07D261/04 , C07D261/08 , C07D261/18 , C07D263/32 , C07D271/06 , C07D271/10 , C07D271/107 , C07D275/02 , C07D277/20 , C07D277/22 , C07D277/30 , C07D277/32 , C07D277/34 , C07D277/36 , C07D277/66 , C07D279/06 , C07D285/00 , C07D285/08 , C07D285/12 , C07D285/125 , C07D307/46 , C07D307/54 , C07D317/30 , C07D317/36 , C07D317/44 , C07D319/06 , C07D333/24 , C07D333/28 , C07D333/34 , C07D339/06 , C07D339/08 , A01N41/10 , A01N43/04 , A01N43/34 , A01N43/48 , A01N43/653 , A01N43/72 , C07C317/44 , C07D207/337 , C07D213/62 , C07D235/08
Abstract: Phenyldiketone derivatives have the formula (I), in which the substituents have the following meanings: L, M are hydrogen, C1-C6 alkyl, C2-C6 alkenyl, C2C6 alkinyl, C1-C4 alkoxy optionally substituted by 1 to 5 halogen atoms or C1C4 alkoxy, halogen, cyano, nitro, a group -(Y)n-S(O)mR7 or a group -(Y)n-CO-R8; Z is a 5 or 6 membered saturated or unsaturated heterocyclic rest that contains 1 to 3 heteroatoms selected from the group that includes oxygen, sulphur or nitrogen, optionally substituted by halogen, cyano, nitro, a group CO-R8, C1-C4 alkyl, C1-C4 halogen alkyl, C3-C8 cycloalkyl, C1-C4 alkoxy, C1-C4 halogen alkoxy, C1-C4 alkylthio, C1-C4 halogen alkylthio, di-C1-C4-alkylamino or an optionally substituted phenyl ring, and that forms a bicyclic system together with a condensed carbon cycle or a second condensed heterocycle; Y is O, NR9; n equals 0 or 1; m equals 0, 1 or 2; R7 is C1-C4 alkyl, C1-C4 halogen alkyl or NR9R10; R8 is C1-C4 alkyl, C1-C4 halogen alkyl, C1-C4 alkoxy or NR9R10; R9 is hydrogen or C1-C4 alkyl; R10 is C1-C4 alkyl; and R1 is cyclopropyl, 1-methylcyclopropyl, 1-methylthiocyclopropyl or tertiary butyl. Also disclosed are the salts of compounds (I) usually utilized in agriculture.
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公开(公告)号:AU3568995A
公开(公告)日:1996-04-26
申请号:AU3568995
申请日:1995-09-19
Applicant: BASF AG
Inventor: KAST JURGEN , VOSSEN MARCUS , DEYN WOLFGANG VON , ENGEL STEFAN , HILL REGINA LUISE , KARDORFF UWE , OTTEN MARTINA , PLATH PETER , WALTER HELMUT , WESTPHALEN KARL-OTTO , MISSLITZ ULF
IPC: C07D317/26 , A01N33/18 , A01N33/26 , A01N35/02 , A01N35/06 , A01N41/10 , A01N43/28 , A01N43/32 , C07C49/84 , C07C69/757 , C07C69/76 , C07C201/12 , C07C205/45 , C07C245/08 , C07C255/66 , C07C309/04 , C07C311/02 , C07C317/24 , C07C323/22 , C07D317/14 , C07D319/06 , C07D339/06 , C07D339/08
Abstract: PCT No. PCT/EP95/03685 Sec. 371 Date Mar. 18, 1997 Sec. 102(e) Date Mar. 18, 1997 PCT Filed Sep. 19, 1995 PCT Pub. No. WO96/10561 PCT Pub. Date Apr. 11, 19962- Aroylcyclohexanediones I where X, Y=O or S; Ar=phenyl or heteroaryl in each case having 1-4 substituents: halogen, cyano, nitro, -N=N-Ph, C1-C4-alkoxycarbonyl, -N(R9)-COR10, -N(R9)-SO2-R11, -SO2-N(R9)R10, -S(O)m-R8 or opt. subst. C1-C4-alkyl, C1-C4-alkoxy, C1-C4-haloalkyl or C1-C4-haloalkoxy; two adjacent C atoms of the phenyl or heteroaryl ring can also be bridged by means of a chain -C(R12)=C(R13)-C(R14)=C(R15)-, -Z1-C(R12)=N-, -Z1-N=C(R12)-, -Z1-C(R12)=C(R13)-, -Z1-C(R12)=C(R13)-C(R14,R15)-, -Z1-C (R12,R13)-C(R14,R15)-, -Z1-C(R12,R13)-C(R14R15)-Z2-, -C(R12,R13)-Z1-C(R14,R15)-C(R16,R17)-, -Z1-N(R20)-Z2-, -Z1-Z2-N(R20)-, -Z1-C(R12,R13)-Z2-N(R20)-, -Z1-N(R20)-Z2-N(R21)-, -N(R21)-Z1-Z2-, -N(R20)-Z1-N=C(R12)-, -Z1-C(R12,R13)-C(=NOR22)-, -Z1-C(R12,R13)-C(R14,R15)-C(=NOR22)- or Z1-Z2-Z1; (Z1, Z2=-O-, -S-, -SO-, -SO2-, -CO-, -C(R18,R19)- or -N(R20)-; R12, R19=H, OH, halogen, C1-C4alkyl, C1-C4-alkoxy, C1-C4-alkylthio, C1-C4-alkylamino, di-(C1-C4-alkyl)amino or phenyl; R20, R21=H, C1-C4-alkyl, C1-C4-alkoxy, C1-C4-alkylcarbonyl, phenyl or benzoyl; R22=H, C1-C4-alkyl, allyl or phenyl; Ph=phenyl, which can carry 1-3 substituents: halogen, cyano, nitro, -S(O)n-R23, C1-C4-alkoxycarbonyl, -SO2-N(R24)R25, -N(R24)-COR25, -N(R24)-SO2R26 or opt. subst. C1-C4-alkyl, C1-C4-alkoxy, C1-C4-haloalkyl or C1-C4-haloalkoxy; m, n=0-2; R8, R23=opt. subst. C1-C4-alkyl or C1-C4-haloalkyl; R9,R10,R24,R25=H, C1-C4-alkyl, C1-C4-haloalkyl or opt. subst. phenyl; R11, R26=opt. subst. C1-C4-alkyl or C1-C4-haloalkyl) R1,R2,R3,R4=hydrogen or C1-C4-alkyl; R5=H, C1-C4-alkyl or C1-C4-alkoxycarbonyl; R6, R7=C1-C4-alkyl, benzyl or together are an opt. subst. ethylene or propylene chain; excluding 2-(4-chloro-2-nitrobenzoyl)-5-dimethoxymethyl-5-methylcyclohexane-1,3-dione, and the salts of I and esters of I with acids. Use: herbicides; growth regulators.
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93.
公开(公告)号:CA2200497A1
公开(公告)日:1996-04-11
申请号:CA2200497
申请日:1995-09-19
Applicant: BASF AG
Inventor: KAST JUERGEN , VOSSEN MARCUS , VON DEYN WOLFGANG , ENGEL STEFAN , HILL REGINA LUISE , KARDORFF UWE , OTTEN MARTINA , PLATH PETER , WALTER HELMUT , WESTPHALEN KARL-OTTO , MIBETALITZ ULF
IPC: C07D317/26 , A01N33/18 , A01N33/26 , A01N35/02 , A01N35/06 , A01N41/10 , A01N43/28 , A01N43/32 , C07C49/84 , C07C69/757 , C07C69/76 , C07C201/12 , C07C205/45 , C07C245/08 , C07C255/66 , C07C309/04 , C07C311/02 , C07C317/24 , C07C323/22 , C07D317/14 , C07D319/06 , C07D339/06 , C07D339/08 , C07D339/00 , A01N43/00 , A01N41/02 , A01N35/04 , C07C311/08 , C07C311/29 , C07F9/40 , C07C323/64 , C07C309/73
Abstract: 2-aroylcyclohexandiones have general formula (I), in which X, Y stand for O or S; Ar stands for phenyl or heteroaryl with 1 to 4 substituents; or two adjacent carbon atoms of the phenyl or heteroaryl ring may also be bridged by a chain; R1, R2, R3, R4 stand for hydrogen or C1-C4-alkyl; R5 stands for H, C1C4-alkyl or C1-C4-alkoxycarbonyl; R6, R7 stand for C1-C4-alkyl, benzyl or stand together for an optionally substituted ethylene or propylene chain. Also disclosed are the salts and esters of these compounds with acids, except for 2 (4-chloro-2-nitrobenzoyl)-5-dimethoxymethyl-5-methyl-cyclohexan-1,3-dione, and their use as herbicides and growth regulators.
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公开(公告)号:ES2255073T3
公开(公告)日:2006-06-16
申请号:ES96902274
申请日:1996-02-14
Applicant: BASF AG
Inventor: VON DEYN WOLFGANG , HILL REGINA LUISE , KARDORFF UWE , ENGEL STEFAN , OTTEN MARTINA , VOSSEN MARCUS
IPC: C07D231/20 , A01N43/56 , A01N43/74 , A01N43/76 , A01N43/78 , A01N43/80 , C07D231/24 , C07D277/22 , C07D401/10 , C07D403/10 , C07D405/10 , C07D409/10 , C07D411/10 , C07D413/10 , C07D417/10
Abstract: DERIVADOS DE PIRAZOL EN LA QUE LOS SUSTITUYENTES TIENEN EL SIGUIENTE SIGNIFICADO: L Y M SON HIDROGENO, C{SUB,1} {SUB,6} ALQUENILO, C{SUB,2} C{SUB,4} ALCOXI, PUDIENDO SER SUSTITUIDOS OPCIONALMENTE ESTOS GRUPOS POR UNO HASTA CINCO ATOMOS DE HALOGENO O C{SUB,1} UB,4} ALCOXI, HALOGENO, CIANO, NITRO, UN GRUPO O){SUB,M}R{SUP,7} O UN GRUPO ADO, QUE CONTIENE DE UNO HASTA TRES HETEROATOMOS Y SELECCIONADO DEL GRUPO DEL OXIGENO, AZUFRE O NITROGENO, QUE PUEDE SER OPCIONALMENTE SUSTITUIDO POR HALOGENO, CIANO, NITRO, UN GRUPO HALOGENALQUILO, C{SUB,3} C{SUB,4} DI SUSTITUIDO POR HALOGENO, CIANO, NITRO, C{SUB,1} LQUILO, C{SUB,1} OBLE ENLACE, QUE PUEDE PRESENTARSE OPCIONALMENTE TAMBIEN EN LA FORMA TAUTOMERA COMO GRUPO HIDROXI, O QUE FORMA UN SISTEMA BICICLICO CON UN ANILLO FENILO CONDENSADO, OPCIONALMENTE SUSTITUIDO POR HALOGENO, CIANO, NITRO, C{SUB,1} C{SUB,1} UN SEGUNDO HETEROCICLO CONDENSADO, OPCIONALMENTE SUSTITUIDO POR HALOGENO, CIANO, NITRO, C{SUB,1} {SUB,1} C{SUB,1} - C{SUB,4} HALOGENALCOXI O C{SUB,1}GENALQUILO; Y ES O, NR{SUP,9}; N ES CERO O UNO; M ES CERO, UNO O DOS; R{SUP,7} ES C{SUB,1} {SUB,4} HALOGENALQUILO O NR{SUP,9}R{SUP,10 SUB,1} C{SUB,4} O, C{SUB,1} ,9} ES HIDROGENO O C{SUB,1} C{SUB,1} ULADO EN LA POSICION 4 Y DE FORMULA (II), EN DONDE R{SUP,1} ES C{SUB,1} UB,4} (I) QUE SE UTILIZAN NORMALMENTE EN AGRICULTURA.
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公开(公告)号:CA2247167C
公开(公告)日:2005-07-12
申请号:CA2247167
申请日:1997-02-20
Applicant: BASF AG
Inventor: WESTPHALEN KARL-OTTO , HILL REGINA LUISE , MISSLITZ ULF , KARDORFF UWE , WALTER HELMUT , ENGEL STEFAN , VOSSEN MARCUS , PLATH PETER , VON DEYN WOLFGANG , OTTEN MARTINA
IPC: A01N43/32 , C07D327/06 , C07D339/08 , C07D407/08 , C07D411/08 , C07D409/08
Abstract: The invention concerns hetaroyl derivatives of formula (I) in which the substituents have the following meanings: L, M are hydrogen, C1-C6 alkyl, C2-C6 alkenyl, C2-C6 alkinyl, C1-C4 alkoxy, wherein these groups can optionally be substituted by between one and five halogen atoms or C1-C4 alkoxy; halogen, cyano, nitro; X is oxygen or sulphur which can be substituted by one or two oxygens; n is zero, one, two; and Q, R1, R2, R3, R4 have the meanings given in claim 1. The invention further concerns a process for preparing the hetaroyl derivatives, agents containing the latter , and the use of these derivatives or agents containing them for weed control.
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公开(公告)号:CA2211534C
公开(公告)日:2004-10-26
申请号:CA2211534
申请日:1996-02-13
Applicant: BASF AG
Inventor: KARDORFF UWE , ENGEL STEFAN , ROHL FRANZ , HARREUS ALBRECHT , PLATH PETER , RANG HARALD , WALTER HELMUT , VOSSEN MARCUS , HILL REGINA LUISE , OTTEN MARTINA , VON DEYN WOLFGANG , MISSLITZ ULF , WESTPHALEN KARL-OTTO
IPC: A01N43/80 , C07D261/08 , C07D413/10 , C07D417/10 , A01N43/72 , C07D261/18
Abstract: The invention concerns isoxazol-4-yl-benzoyl derivatives of formula (I) in which the substituents have the following meanings: L and M represent hydrogen, C1-C6 alkyl, C2-C6 alkenyl, C2-C6 alkinyl, C1-C4 alkoxy (these groups being optionally substituted by one to five halogen atoms or C1-C4 alkoxy), halogen, cyano, nitro, a -(Y)n-S(O)m R7 or - (Y)n-CO-R8 group; Z represents a five to six-membered heterocyclic saturated or unsaturated group which contains one to three heteroatoms selected from the group comprising oxygen, sulphur or nitrogen and can optionally be substituted by halogen, cyano, nitro, an -CO- R8 group, C1-C4 alkyl, C1-C4 alkyl halide, C3-C8 cycloalkyl, C1-C4 alkoxy, C1-C4 alkoxy halide, C1-C4 alkyl thio, C1-C4 alkyl thio halide, di-C1-C4 alkyl amino, phenyl optionally substituted by halogen, cyano, nitro, C1-C4 alkyl or C1-C4 alkyl halide, or an oxo group which can b e present in the tautomeric form as a hydroxy group, is substituted or, together with a condensation-bound phenyl ring which is optionally substituted by halogen, cyano, nitro, C1-C4 alkyl or C1-C4 alkyl halide, with a condensation-bound carbocycle or with a condensation-bound second heterocycle which can optionally be substituted by halogen, cyano, nitro, C1-C4 alkyl, d i- C1-C4 alkyl amino, C1-C4 alkoxy, C1-C4 alkoxy halide, or a C1-C4 alkyl halide, form a bicyclic system; Y represents O or NR9; n is 0 or 1; m is 0, 1 or 2; R7 represents C1-C4 alkyl, C1-C4 alkyl halide or NR9R10; R8 represents C1-C4 alkyl, C1-C4 alkyl halide, C1-C4 alkoxy or NR9R1 0; R9 represents hydrogen or C1-C4 alkyl; R10 represents C1-C4 alkyl; Q represents an isoxazole ring connected at position 4 and of formula (II) in which R1 represents hydrogen or -CO2R3, R2 represents hydrogen, C1-C4 alkyl or C3-C6 cycloalkyl which can optionally be substituted by one or more halogen atoms or C1-C4 alkyl, R3 representing a C1-C4 alkyl; J represents a carbonyl group CO or a -CHR4 group, R4 representing an OH group, a hydroxyl group optionally acylated with C2-C4 acyl, or a chlorine atom. The invention also concerns salts of compounds of formula (I) usually utilized in agriculture.
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公开(公告)号:CA2421995A1
公开(公告)日:2003-03-12
申请号:CA2421995
申请日:2001-09-12
Applicant: BASF AG
Inventor: OBERDORF KLAUS , HARREUS ALBRECHT , GOTZ NORBERT , MAYWALD VOLKER , KOBER REINER , HEIMANN FRANK , VOSSEN MARCUS
IPC: A01N43/14 , A01N43/18 , C07D335/02
Abstract: The invention relates to a method for producing 2-{1-[2-(4-chlorophenoxy)- propoxyimino]-butyl}-3-hydroxy-5-(tetrahydrothiopyrane-3-yl)-cyclohex-2-enon e lithium salt by reacting the corresponding acid 2-{1-[2-(4-chlorophenoxy)- propoxyimino]-butyl}-3-hydroxy-5-(tetrahydrothiopyrane-3-yl)-cyclohex-2-enon e with lithium hydroxide, and for extracting the lithium salt. It is advantageous to use a solvent mixture containing methanol and at least one aromatic hydrocarbon, and to remove part of the solvent before extraction. I t is especially preferable to dissolve the acid in an aromatic hydrocarbon, preferably toluol, and to use a methanolic lithium hydroxide solution. The product obtained efficiently according to the inventive method also has considerable advantages in terms of formulation techniques.
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公开(公告)号:AT218564T
公开(公告)日:2002-06-15
申请号:AT97903334
申请日:1997-02-20
Applicant: BASF AG
Inventor: OTTEN MARTINA , VON DEYN WOLFGANG , ENGEL STEFAN , HILL REGINA LUISE , KARDORFF UWE , VOSSEN MARCUS , PLATH PETER , GOETZ NORBERT , WESTPHALEN KARL-OTTO , WALTER HELMUT , MISSLITZ ULF
IPC: A01N43/56 , C07D409/06 , C07D411/06
Abstract: PCT No. PCT/EP97/00803 Sec. 371 Date Aug. 24, 1998 Sec. 102(e) Date Aug. 24, 1998 PCT Filed Feb. 20, 1997 PCT Pub. No. WO97/30993 PCT Pub. Date Aug. 28, 1997Pyrazolylhetaroyl derivatives of the formula I where the substituents have the following meanings: L and M are hydrogen, C1-C6-alkyl, C2-C6-alkenyl, C2-C6-alkynyl, C1-C4-alkoxy, it being possible for these groups to be unsubstituted or substituted by one to five halogen atoms or C1-C4-alkoxy; halogen, cyano, nitro; X is oxygen or sulfur which can be substituted by one or two oxygens; n is zero, one or two; and Q, R1, R2, R3 and R4 have the meanings given in claim 1, processes for the preparation of the pyrazol-4-yl-hetaroyl derivatives, compositions comprising them, and the use of these derivatives or of the compositions comprising them for controlling weeds.
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公开(公告)号:DK0961774T3
公开(公告)日:2002-04-02
申请号:DK96930126
申请日:1996-08-29
Applicant: BASF AG
Inventor: OTTEN MARTINA , VON DEYN WOLFGANG , ENGEL STEFAN , HILL REGINA LUISE , KARDORFF UWE , VOSSEN MARCUS , PLATH PETER , GOETZ NORBERT , WALTER HELMUT , WESTPHALEN KARL-OTTO , MISSLITZ ULF
IPC: A01N43/18 , A01N43/56 , C07D333/64 , C07D335/06 , C07D409/06 , C07D411/06 , C07D417/06
Abstract: Pyrazol-4-ylbenzoyl derivativeswhere the substituents L, M, X, Y and n have the meanings given in claim 1 andQ is a pyrazole ring, linked in the 4-position, of the formula IIwhereR15 is C1-C4-alkyl,R16 is hydrogen, C1-C4-alkyl or C1-C4-haloalkyl andR17 is hydrogen, C1-C4-alkylsulfonyl, phenylsulfonyl or alkylphenylsulfonyl,where, in the event that Y=C=O, X is other than NR23,agriculturally useful salts, a process for their preparation, and their use as herbicides.
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公开(公告)号:BG63503B1
公开(公告)日:2002-03-29
申请号:BG10182597
申请日:1997-08-08
Applicant: BASF AG
Inventor: VON DEYN WOLFGANG , HILL REGINA L , KARDORFF UWE , ENGEL STEFAN , OTTEN MARTINA , VOSSEN MARCUS , PLATH PETER , RANG HARALD , HARREUS ALBRECHT , KOENIG HARTMANN , WALTER HELMUT , WESTPHALEN KARL-OTTO , MISSLITZ ULF
IPC: C07D231/20 , A01N43/56 , A01N43/74 , A01N43/76 , A01N43/78 , A01N43/80 , C07D231/24 , C07D277/22 , C07D401/10 , C07D403/10 , C07D405/10 , C07D409/10 , C07D411/10 , C07D413/10 , C07D417/10
Abstract: Pyrazol-4-yl-benzoyl derivatives have the formula in which the substituents have the following meanings: L, M are hydrogen, C1-C6 alkyl, C2-C6 alkenyl, C2-C6 alkinyl, C1-C4 alkoxy, these groups being optionally substituted by 1 to 5 halogen atoms or C1-C4 alkoxy, halogen, cyano, nitro, a group -(Y)n-S(O)mR7 or a group -(Y)n,-CO-R8; Z is a 5 or 6-membered saturated or unsaturated heterocyclic rest, that contains 1 to 3 heteroatoms selected from the group that includes oxygen, sulphur or nitrogen, optionally substituted by halogen, cyano, nitro, a group -CO-R8, C1-C4 alkyl, C1-C4 halogen alkyl, C3-C8 cycloalkyl, C1-C4 alkoxy, C1-C4 halogen alkoxy, C1-C4 alkylthio, C1-C4 halogen alkylthio, di-C1-C4-alkylamino, a phenyl optionally substituted by halogen, cyano, nitro C1-C4 alkyl or C1-C4 halogen alkyl or a twice bound oxygen that optionally in the tautomer form may also be a hydroxy group, or that forms a bicyclic system together with a condensed phenyl ring optionally substituted by halogen, cyano, nitro, C1-C4 alkyl or C1-C4 halogen alkyl, with a condensed carbon cycle or with a second condensed heterocycle optionally substituted by halogen, cyano, nitro, C1-C4 alkyl, di-C1-C4-alkylamino, C1-C4 alkoxy, C1-C4 halogen alkoxy or C1-C4 halogen alkyl; Y is 0, NR9; n equals 0 or 1; m equals 0, 1 or 2; R7 is C1-C4 alkyl, C1-C4 halogen alkyl or NR9R10; R8 is C1-C4 alkyl, C1-C4 halogen alkyl, C1-C4 alkoxy or NR9R10; R9 is hydrogen or C1-C4 alkyl; R10 is C1-C4 alkyl; Q is a pyrazol ring linked at position 4 having the formula in which R1 is C1-C4 alkyl; R2 is hydrogen or C1-C4 alkyl; and R3 is hydrogen, C1-C4 alkyl sulphonyl, phenyl sulphonyl or alkyl phenyl sulphonyl. Also disclosed are the salts of compounds (I) usually utilized in agriculture. 8 claims
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