2-aroylcyclohexandiones, process for preparing the same and their use as herbicides or plant growth regulators

    公开(公告)号:AU3568995A

    公开(公告)日:1996-04-26

    申请号:AU3568995

    申请日:1995-09-19

    Applicant: BASF AG

    Abstract: PCT No. PCT/EP95/03685 Sec. 371 Date Mar. 18, 1997 Sec. 102(e) Date Mar. 18, 1997 PCT Filed Sep. 19, 1995 PCT Pub. No. WO96/10561 PCT Pub. Date Apr. 11, 19962- Aroylcyclohexanediones I where X, Y=O or S; Ar=phenyl or heteroaryl in each case having 1-4 substituents: halogen, cyano, nitro, -N=N-Ph, C1-C4-alkoxycarbonyl, -N(R9)-COR10, -N(R9)-SO2-R11, -SO2-N(R9)R10, -S(O)m-R8 or opt. subst. C1-C4-alkyl, C1-C4-alkoxy, C1-C4-haloalkyl or C1-C4-haloalkoxy; two adjacent C atoms of the phenyl or heteroaryl ring can also be bridged by means of a chain -C(R12)=C(R13)-C(R14)=C(R15)-, -Z1-C(R12)=N-, -Z1-N=C(R12)-, -Z1-C(R12)=C(R13)-, -Z1-C(R12)=C(R13)-C(R14,R15)-, -Z1-C (R12,R13)-C(R14,R15)-, -Z1-C(R12,R13)-C(R14R15)-Z2-, -C(R12,R13)-Z1-C(R14,R15)-C(R16,R17)-, -Z1-N(R20)-Z2-, -Z1-Z2-N(R20)-, -Z1-C(R12,R13)-Z2-N(R20)-, -Z1-N(R20)-Z2-N(R21)-, -N(R21)-Z1-Z2-, -N(R20)-Z1-N=C(R12)-, -Z1-C(R12,R13)-C(=NOR22)-, -Z1-C(R12,R13)-C(R14,R15)-C(=NOR22)- or Z1-Z2-Z1; (Z1, Z2=-O-, -S-, -SO-, -SO2-, -CO-, -C(R18,R19)- or -N(R20)-; R12, R19=H, OH, halogen, C1-C4alkyl, C1-C4-alkoxy, C1-C4-alkylthio, C1-C4-alkylamino, di-(C1-C4-alkyl)amino or phenyl; R20, R21=H, C1-C4-alkyl, C1-C4-alkoxy, C1-C4-alkylcarbonyl, phenyl or benzoyl; R22=H, C1-C4-alkyl, allyl or phenyl; Ph=phenyl, which can carry 1-3 substituents: halogen, cyano, nitro, -S(O)n-R23, C1-C4-alkoxycarbonyl, -SO2-N(R24)R25, -N(R24)-COR25, -N(R24)-SO2R26 or opt. subst. C1-C4-alkyl, C1-C4-alkoxy, C1-C4-haloalkyl or C1-C4-haloalkoxy; m, n=0-2; R8, R23=opt. subst. C1-C4-alkyl or C1-C4-haloalkyl; R9,R10,R24,R25=H, C1-C4-alkyl, C1-C4-haloalkyl or opt. subst. phenyl; R11, R26=opt. subst. C1-C4-alkyl or C1-C4-haloalkyl) R1,R2,R3,R4=hydrogen or C1-C4-alkyl; R5=H, C1-C4-alkyl or C1-C4-alkoxycarbonyl; R6, R7=C1-C4-alkyl, benzyl or together are an opt. subst. ethylene or propylene chain; excluding 2-(4-chloro-2-nitrobenzoyl)-5-dimethoxymethyl-5-methylcyclohexane-1,3-dione, and the salts of I and esters of I with acids. Use: herbicides; growth regulators.

    DERIVADOS DE PIRAZOL-4-IL-BENZOILO Y SU EMPLEO COMO HERBICIDAS.

    公开(公告)号:ES2255073T3

    公开(公告)日:2006-06-16

    申请号:ES96902274

    申请日:1996-02-14

    Applicant: BASF AG

    Abstract: DERIVADOS DE PIRAZOL EN LA QUE LOS SUSTITUYENTES TIENEN EL SIGUIENTE SIGNIFICADO: L Y M SON HIDROGENO, C{SUB,1} {SUB,6} ALQUENILO, C{SUB,2} C{SUB,4} ALCOXI, PUDIENDO SER SUSTITUIDOS OPCIONALMENTE ESTOS GRUPOS POR UNO HASTA CINCO ATOMOS DE HALOGENO O C{SUB,1} UB,4} ALCOXI, HALOGENO, CIANO, NITRO, UN GRUPO O){SUB,M}R{SUP,7} O UN GRUPO ADO, QUE CONTIENE DE UNO HASTA TRES HETEROATOMOS Y SELECCIONADO DEL GRUPO DEL OXIGENO, AZUFRE O NITROGENO, QUE PUEDE SER OPCIONALMENTE SUSTITUIDO POR HALOGENO, CIANO, NITRO, UN GRUPO HALOGENALQUILO, C{SUB,3} C{SUB,4} DI SUSTITUIDO POR HALOGENO, CIANO, NITRO, C{SUB,1} LQUILO, C{SUB,1} OBLE ENLACE, QUE PUEDE PRESENTARSE OPCIONALMENTE TAMBIEN EN LA FORMA TAUTOMERA COMO GRUPO HIDROXI, O QUE FORMA UN SISTEMA BICICLICO CON UN ANILLO FENILO CONDENSADO, OPCIONALMENTE SUSTITUIDO POR HALOGENO, CIANO, NITRO, C{SUB,1} C{SUB,1} UN SEGUNDO HETEROCICLO CONDENSADO, OPCIONALMENTE SUSTITUIDO POR HALOGENO, CIANO, NITRO, C{SUB,1} {SUB,1} C{SUB,1} - C{SUB,4} HALOGENALCOXI O C{SUB,1}GENALQUILO; Y ES O, NR{SUP,9}; N ES CERO O UNO; M ES CERO, UNO O DOS; R{SUP,7} ES C{SUB,1} {SUB,4} HALOGENALQUILO O NR{SUP,9}R{SUP,10 SUB,1} C{SUB,4} O, C{SUB,1} ,9} ES HIDROGENO O C{SUB,1} C{SUB,1} ULADO EN LA POSICION 4 Y DE FORMULA (II), EN DONDE R{SUP,1} ES C{SUB,1} UB,4} (I) QUE SE UTILIZAN NORMALMENTE EN AGRICULTURA.

    ISOXAZOLYL-BENZOYL DERIVATIVES
    96.
    发明专利

    公开(公告)号:CA2211534C

    公开(公告)日:2004-10-26

    申请号:CA2211534

    申请日:1996-02-13

    Applicant: BASF AG

    Abstract: The invention concerns isoxazol-4-yl-benzoyl derivatives of formula (I) in which the substituents have the following meanings: L and M represent hydrogen, C1-C6 alkyl, C2-C6 alkenyl, C2-C6 alkinyl, C1-C4 alkoxy (these groups being optionally substituted by one to five halogen atoms or C1-C4 alkoxy), halogen, cyano, nitro, a -(Y)n-S(O)m R7 or - (Y)n-CO-R8 group; Z represents a five to six-membered heterocyclic saturated or unsaturated group which contains one to three heteroatoms selected from the group comprising oxygen, sulphur or nitrogen and can optionally be substituted by halogen, cyano, nitro, an -CO- R8 group, C1-C4 alkyl, C1-C4 alkyl halide, C3-C8 cycloalkyl, C1-C4 alkoxy, C1-C4 alkoxy halide, C1-C4 alkyl thio, C1-C4 alkyl thio halide, di-C1-C4 alkyl amino, phenyl optionally substituted by halogen, cyano, nitro, C1-C4 alkyl or C1-C4 alkyl halide, or an oxo group which can b e present in the tautomeric form as a hydroxy group, is substituted or, together with a condensation-bound phenyl ring which is optionally substituted by halogen, cyano, nitro, C1-C4 alkyl or C1-C4 alkyl halide, with a condensation-bound carbocycle or with a condensation-bound second heterocycle which can optionally be substituted by halogen, cyano, nitro, C1-C4 alkyl, d i- C1-C4 alkyl amino, C1-C4 alkoxy, C1-C4 alkoxy halide, or a C1-C4 alkyl halide, form a bicyclic system; Y represents O or NR9; n is 0 or 1; m is 0, 1 or 2; R7 represents C1-C4 alkyl, C1-C4 alkyl halide or NR9R10; R8 represents C1-C4 alkyl, C1-C4 alkyl halide, C1-C4 alkoxy or NR9R1 0; R9 represents hydrogen or C1-C4 alkyl; R10 represents C1-C4 alkyl; Q represents an isoxazole ring connected at position 4 and of formula (II) in which R1 represents hydrogen or -CO2R3, R2 represents hydrogen, C1-C4 alkyl or C3-C6 cycloalkyl which can optionally be substituted by one or more halogen atoms or C1-C4 alkyl, R3 representing a C1-C4 alkyl; J represents a carbonyl group CO or a -CHR4 group, R4 representing an OH group, a hydroxyl group optionally acylated with C2-C4 acyl, or a chlorine atom. The invention also concerns salts of compounds of formula (I) usually utilized in agriculture.

    98.
    发明专利
    未知

    公开(公告)号:AT218564T

    公开(公告)日:2002-06-15

    申请号:AT97903334

    申请日:1997-02-20

    Applicant: BASF AG

    Abstract: PCT No. PCT/EP97/00803 Sec. 371 Date Aug. 24, 1998 Sec. 102(e) Date Aug. 24, 1998 PCT Filed Feb. 20, 1997 PCT Pub. No. WO97/30993 PCT Pub. Date Aug. 28, 1997Pyrazolylhetaroyl derivatives of the formula I where the substituents have the following meanings: L and M are hydrogen, C1-C6-alkyl, C2-C6-alkenyl, C2-C6-alkynyl, C1-C4-alkoxy, it being possible for these groups to be unsubstituted or substituted by one to five halogen atoms or C1-C4-alkoxy; halogen, cyano, nitro; X is oxygen or sulfur which can be substituted by one or two oxygens; n is zero, one or two; and Q, R1, R2, R3 and R4 have the meanings given in claim 1, processes for the preparation of the pyrazol-4-yl-hetaroyl derivatives, compositions comprising them, and the use of these derivatives or of the compositions comprising them for controlling weeds.

    PYRAZOL-4-YL-BENZOYL DERIVATIVES AND THEIR USE AS HERBICIDES

    公开(公告)号:BG63503B1

    公开(公告)日:2002-03-29

    申请号:BG10182597

    申请日:1997-08-08

    Applicant: BASF AG

    Abstract: Pyrazol-4-yl-benzoyl derivatives have the formula in which the substituents have the following meanings: L, M are hydrogen, C1-C6 alkyl, C2-C6 alkenyl, C2-C6 alkinyl, C1-C4 alkoxy, these groups being optionally substituted by 1 to 5 halogen atoms or C1-C4 alkoxy, halogen, cyano, nitro, a group -(Y)n-S(O)mR7 or a group -(Y)n,-CO-R8; Z is a 5 or 6-membered saturated or unsaturated heterocyclic rest, that contains 1 to 3 heteroatoms selected from the group that includes oxygen, sulphur or nitrogen, optionally substituted by halogen, cyano, nitro, a group -CO-R8, C1-C4 alkyl, C1-C4 halogen alkyl, C3-C8 cycloalkyl, C1-C4 alkoxy, C1-C4 halogen alkoxy, C1-C4 alkylthio, C1-C4 halogen alkylthio, di-C1-C4-alkylamino, a phenyl optionally substituted by halogen, cyano, nitro C1-C4 alkyl or C1-C4 halogen alkyl or a twice bound oxygen that optionally in the tautomer form may also be a hydroxy group, or that forms a bicyclic system together with a condensed phenyl ring optionally substituted by halogen, cyano, nitro, C1-C4 alkyl or C1-C4 halogen alkyl, with a condensed carbon cycle or with a second condensed heterocycle optionally substituted by halogen, cyano, nitro, C1-C4 alkyl, di-C1-C4-alkylamino, C1-C4 alkoxy, C1-C4 halogen alkoxy or C1-C4 halogen alkyl; Y is 0, NR9; n equals 0 or 1; m equals 0, 1 or 2; R7 is C1-C4 alkyl, C1-C4 halogen alkyl or NR9R10; R8 is C1-C4 alkyl, C1-C4 halogen alkyl, C1-C4 alkoxy or NR9R10; R9 is hydrogen or C1-C4 alkyl; R10 is C1-C4 alkyl; Q is a pyrazol ring linked at position 4 having the formula in which R1 is C1-C4 alkyl; R2 is hydrogen or C1-C4 alkyl; and R3 is hydrogen, C1-C4 alkyl sulphonyl, phenyl sulphonyl or alkyl phenyl sulphonyl. Also disclosed are the salts of compounds (I) usually utilized in agriculture. 8 claims

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