公开(公告)号：JP2002155049A

公开(公告)日：2002-05-28

申请号：JP2000345823

申请日：2000-11-13

Applicant: DAICEL CHEM

Inventor： ISHII YASUTAKA ,  NAKANO TATSUYA ,  TATSUMI JUNRO

IPC: C07D223/10 ,  B01J31/02 ,  C07B61/00 ,  C07D201/00

Abstract: PROBLEM TO BE SOLVED: To provide a method for producing a lactam, by which the corresponding lactam can be produced from a cycloalkane, a cycloalkanol or a cycloalkanote in one step. SOLUTION: This method for producing the lactam, comprising reacting at least one compound selected from the cycloalkane, the cycloalkanol or the cycloalkanone with ammonia and oxygen in the presence of an imide compound catalyst having an N-hydroxy(or N-oxo)cyclic imide skeleton to obtain the corresponding lactam. The imide compound catalyst includes a compound represented by formula (1) (R1 and R2 are each H, a halogen atom, an alkyl, an aryl, a cycloalkyl, or the like, or R1 R2 may be bound to each other to form a double bond, or an aromatic or non-aromatic ring; X is O or HO).

公开(公告)号：JP2002145877A

公开(公告)日：2002-05-22

申请号：JP2000336767

申请日：2000-11-02

Applicant: DAICEL CHEM

Inventor： ISHII YASUTAKA ,  NAKANO TATSUYA

IPC: C07D323/06 ,  C07B61/00

Abstract: PROBLEM TO BE SOLVED: To provide a method for efficiently producing a corresponding trioxane compound even from an aldehyde having large carbon atoms or branched chain. SOLUTION: The trioxane compound expressed by formula (2) (R is H or an organic group having a carbon atom at the site bonding with the adjacent carbonyl carbon atom) is produced by contacting an aldehyde of formula RHO (1) with a zirconium catalyst.

公开(公告)号：JP2001253838A

公开(公告)日：2001-09-18

申请号：JP2000067682

申请日：2000-03-10

Applicant: DAICEL CHEM

Inventor： ISHII YASUTAKA ,  NAKANO TATSUYA ,  HIRAI NARIHISA

IPC: C07D333/38 ,  B01J31/04 ,  C07B41/08 ,  C07B61/00 ,  C07C51/235 ,  C07C51/265 ,  C07C59/305 ,  C07C63/26 ,  C07C67/29 ,  C07C69/157 ,  C07C201/12 ,  C07C205/57 ,  C07D213/79 ,  C07D213/80 ,  C07D213/803 ,  C07D307/89

Abstract: PROBLEM TO BE SOLVED: To obtain a carboxylic acid in high selectivity and yield by efficiently oxidizing a corresponding organic substrate with molecular oxygen. SOLUTION: An organic substrate bearing a group that can be converted into carboxyl group by oxidation is allowed to react with molecular oxygen at 110-200 deg.C in the presence of a catalyst comprising an imide represented by formula (1) [wherein R1 and R2 are each H, a halogen atom, an alkyl, an aryl, or the like; R1 and R2 may bond to each other to form a double bond or an aromatic or a nonaromatic ring; X is oxygen atom or hydroxyl group; the above R1 and R2, the double bond and the aromatic or non-aromatic ring may be substituted with one or two N-substituted cyclic imides shown in formula (1)].

公开(公告)号：JP2001181259A

公开(公告)日：2001-07-03

申请号：JP37217799

申请日：1999-12-28

Applicant: DAICEL CHEM

Inventor： ISHII YASUTAKA ,  NAKANO TATSUYA

IPC: C07D201/02

Abstract: PROBLEM TO BE SOLVED: To provide a method for producing a corresponding amide or lactam from hydrocarbons having methylene groups by one step. SOLUTION: A linear or cyclic compound having the methylene group is reacted with a nitrogen oxide in the presence of an imide compound represented by formula (1) [wherein, R1 and R2 are the same as or different from each other and each a hydrogen atom, a halogen atom, an alkyl group, an aryl group, a cycloalkyl group, a hydroxy group, an alkoxy group, a carboxy group, an alkoxycarbonyl group or an acyl group, or may form a double bond or an aromatic or nonaromatic ring by bonding to each other; X is an oxygen atom or a hydroxy group; The R1, R2, or the double bond or the aromatic or nonaromatic ring formed by bonding to each other may further have one or two N-substituted cyclic imide groups of formula (1)], and a halogen or a Beckmann's rearrangement catalyst to provide the objective corresponding amide or lactam.

公开(公告)号：JP2001026562A

公开(公告)日：2001-01-30

申请号：JP2000172040

申请日：2000-06-08

Applicant: DAICEL CHEM

Inventor： ISHII YASUTAKA ,  NAKANO TATSUYA

IPC: B01J31/02 ,  C07B61/00 ,  C07C29/50 ,  C07C35/08 ,  C07C45/33 ,  C07C49/403 ,  C07C51/215 ,  C07C55/14

Abstract: PROBLEM TO BE SOLVED: To provide a method for efficiently oxidizing a cycloalkane under mild conditions in the absence of a specific reducing agent, or the like, by oxidizing the cycloalkane as a substrate with molecular oxygen in the presence of a specific compound and a cobalt compound. SOLUTION: This method comprises oxidizing (A) a cycloalkane as a substrate with (B) molecular oxygen in the presence of (C) 0.001-1 mol, pref. around 0.05 to 0.25 mol, per mol of the component A, of an imide compound of the formula [R1 and R2 are each H, a halogen, a (cyclo)alkyl, an aryl, OH, an alkoxy(carboxyl), COOH or an acyl, or bound together to form a double bond or a (non)aromatic ring; X is O or OH; (n) is 1-3] as an oxidation catalyst (e.g. N-hydroxyphthalimide) and (D) a cobalt compound as a cooxidizing agent, in a molar ratio of the compound C to the compound D of (95:5) to (5:95), pref. (85:15) to (50):(50).

公开(公告)号：JP2000290312A

公开(公告)日：2000-10-17

申请号：JP10344299

申请日：1999-04-12

Applicant: DAICEL CHEM

Inventor： ISHII YASUTAKA ,  FUNAKI KATSUNORI ,  NAKANO TATSUYA

IPC: C08F8/36 ,  C08F8/00 ,  C08F8/06 ,  C08F8/10 ,  C08F8/30

Abstract: PROBLEM TO BE SOLVED: To provide a method for modifying a polymer of high general-purpose properties wherein a polar group can be readily introduced into a polymer, particularly, a hydrophobic polymer. SOLUTION: A polymer is treated with an oxygen atom-containing gas, such as oxygen, carbon monoxide, nitrogen oxide, sulfur oxide or the like, in the presence of an imide compound represented by the formula, such as an N-hydroxyphthalimide or the like, (wherein R1 and R2 may be the same or different and independently represent a hydrogen atom, a halogen atom, an alkyl group, an aryl group, a cycloalkyl group, an alkoxycarbonyl group or an acyl group provided that R1 and R2 may join together to form a double bond, or an aromatic or non-aromatic ring; and X represents an oxygen atom or a hydroxyl group). The oxygen atom-containing gas should preferably be made of at least one member selected from oxygen, carbon monoxide, nitrogen oxide and sulfur oxide.

公开(公告)号：JPH11189578A

公开(公告)日：1999-07-13

申请号：JP35986097

申请日：1997-12-26

Applicant: DAICEL CHEM ,  ISHII YASUTAKA

Inventor： ISHII YASUTAKA ,  NAKANO TATSUYA

IPC: B01J27/135 ,  B01J31/22 ,  C07B61/00 ,  C07C227/18 ,  C07C227/20 ,  C07C229/28 ,  C07C229/48 ,  C07C253/08 ,  C07C255/46 ,  C07C255/64

Abstract: PROBLEM TO BE SOLVED: To obtain at high yield the subject compound useful for the production of an amino acid by reacting a specified oxime ester compound with a cyanogenation agent in the presence of a metal catalyst. SOLUTION: This compound of formula II (R is a residue resulted from the elimination of a cyano group from the cyanogenation agent, or the like) (e.g. 1-acetyloxyamino-1-cyanocyclohexane) is obtained by reacting in the presence of (A) a metal catalyst such as di(η -pentamethylcyclopentadienyl)samarium (B) an oxime ester compound (e.g. acetyloxyiminocyclohexane) of formula I R to R are each a nonreactive atom or the like) with (C) preferably a cyanogenation agent such as hydrogen cyanide, a metal cyanide or a cyanhydrin (e.g. acetone cyanhydrin) usually in a solvent such as toluene, using preferably about 0.9-1.5 mol per mol component C per mol component B, preferably at about 10-40 deg.C.

公开(公告)号：JPH10316625A

公开(公告)日：1998-12-02

申请号：JP12947197

申请日：1997-05-20

Applicant: DAICEL CHEM

Inventor： ISHII YASUTAKA ,  NAKANO TATSUYA

IPC: B01J31/02 ,  C07B41/08 ,  C07B61/00 ,  C07C67/39 ,  C07C69/86

Abstract: PROBLEM TO BE SOLVED: To produce the subject compound without forming metals salts as a by-product by protecting phenolic hydroxyl group of a cresol with a protective group and carrying out an oxidizing reaction of the protected cresol with oxygen in the presence of an imide compound. SOLUTION: A methyl group-containing aromatic compound in which phenolic hydroxyl group is protected by a protective group (e.g. o-, m- or p-cresol, methylnaphthol, xylenol, dimethylnaphthol, dihydroxytoluene or dihydroxyxylene) is brought into contact with oxygen in the presence of an imide compound represented by the formula [R and R are each H, a halogen, an alkyl, an aryl, a cycloalkyl, etc., and R and R may be combined with each other to form a double bond or a ring; X is oxygen or hydroxyl; (n) is 1 to 3] (an alicyclic polyvalent caboxylic acid anhydride such as N-hydroxyphthalimide is cited as an especially preferred one) at 0 to 300 deg.C, preferably 30 to 250 deg.C for 30 min to 48 hr to thereby afford the objective compound.

公开(公告)号：JPH10316601A

公开(公告)日：1998-12-02

申请号：JP12947297

申请日：1997-05-20

Applicant: DAICEL CHEM ,  ISHII YASUTAKA

Inventor： NAKANO TATSUYA ,  ISHII YASUTAKA ,  HIRAI NARIHISA

IPC: C07B41/00 ,  C07B41/02 ,  C07B41/06 ,  C07B61/00 ,  C07C27/12 ,  C07C35/44 ,  C07C45/28 ,  C07C49/417 ,  C07C49/453

Abstract: PROBLEM TO BE SOLVED: To carry out oxidation reaction effectively at high conversion rate on an industrial scale while suppressing the adhesion of a sublimable polycyclic hydrocarbon on a reactor and on the internal walls of tubes by using a specific mixed solvent as a reaction solvent on the oxidation of the polycyclic hydrocarbon. SOLUTION: A sublimable polycyclic hydrocarbon (e.g. a bridged cyclic hydrocarbon having a methylidyne group, especially an adamantane) is oxidized in the presence of an oxidizing catalyst consisting of an imide compound expressed by the formula [R and R are each H, a halogen, an alkyl, etc., and they may be bonded to each other to form a double bond or a ring; X is oxygen or hydroxyl; (n)=1-3] in a mixed solvent consisting of (A) a non- sublimable aromatic compound (e.g. a benzene derivative) and (B) at least one compound (e.g. an organic compound such as a 1-4C aliphatic hydrocarbon) selected from acidic compounds and non-aromatic nitrile compounds [the component A/the component B=(25/75) to (95/5) by weight] under contact with oxygen to produce a polycyclic hydrocarbon which has a hydroxyl or oxo group.

公开(公告)号：JPH10286467A

公开(公告)日：1998-10-27

申请号：JP35339697

申请日：1997-12-22

Applicant: DAICEL CHEM ,  ISHII YASUTAKA

Inventor： NAKANO TATSUYA ,  ISHII YASUTAKA

IPC: B01J21/06 ,  B01J23/16 ,  B01J23/38 ,  B01J23/70 ,  B01J27/053 ,  B01J27/06 ,  B01J27/25 ,  B01J31/02 ,  B01J31/18 ,  B01J31/22 ,  C07B33/00 ,  C07B41/00 ,  C07B61/00 ,  C07C27/00 ,  C07C35/08 ,  C07C35/37 ,  C07C35/38 ,  C07C45/33 ,  C07C45/34 ,  C07C45/36 ,  C07C47/453 ,  C07C47/542 ,  C07C49/385 ,  C07C49/675 ,  C07C51/265 ,  C07C51/31 ,  C07C55/14 ,  C07C63/04

Abstract: PROBLEM TO BE SOLVED: To obtain an oxide corresponding to a substrate at a high conversion and selectivity by oxidizing the substrate with molecular state oxygen under a mild condition. SOLUTION: An oxide (ketone, alcohol, carboxylic acid or the like) is obtained by oxidizing a substrate (cycloalkanes, polycyclic hydrocarbons, aromatic compounds having methyl group) with oxygen in the presence of the oxide catalyst system, which is composed of an imide compound (N-hydroxy phthal imide or the like) expressed by a formula and of a co-catalyst containing an element selected from groups III-XII in the periodic table (particularly groups IV-XI in the periodic table) and in which the co-catalyst is composed of a compound containing plural elements (where, hetro poly acid and the combination of a group VII element with a group VIII element are excluded). In the formula, R and R each expresses a substituent group such as hydrogen atom and a halogen atom and can form a double bond or an aromatic or non-aromatic 5 to 12 ring by coupling each other. X expresses O or OH and n=1-3.