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101.
公开(公告)号:AU2671095A
公开(公告)日:1996-01-05
申请号:AU2671095
申请日:1995-05-26
Applicant: BASF AG
Inventor: BAYER HERBERT , ISAK HEINZ , WINGERT HORST , SAUTER HUBERT , KEIL MICHAEL , NETT MARKUS , BENOIT REMY , MULLER RUTH
IPC: C07C67/22 , C07C69/716 , C07C69/738 , C07C235/78 , C07C249/08 , C07C249/12 , C07C251/48 , C07C251/60 , C07C255/41 , C07C255/62 , C07D249/12 , C07D521/00
Abstract: A process and intermediates for preparing alpha -methoxyiminocarboxylic acid methylamides (I) by Pinner reaction of a cyanoketone (II) with an alcohol and subsequent reaction of the resulting ester (IV) with hydroxylamine to give the oxime (V), methylation of (V) to give the oxime ether (VI) and subsequent reaction of (VI) with methylamine: +TR X = nitro, trifluoromethyl, halogen, alkyl or alkoxy; n = 0, 1, 2, 3 or 4; Y = a C-organic radical.
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102.
公开(公告)号:NZ248522A
公开(公告)日:1995-07-26
申请号:NZ24852293
申请日:1993-08-27
Applicant: BASF AG
Inventor: BAYER HERBERT , WINGERT HORST , SAUTER HUBERT , BENOIT REMY , OBERDORF KLAUS , ROEHL FRANZ , AMMERMANN EBERHARD , LORENZ GISELA
IPC: A01N37/50 , C07C249/08 , C07C249/12 , C07C251/38 , C07C251/48 , C07C251/58 , C07C251/60 , C07C255/61 , C07C255/62 , C07C255/64 , C07C259/18 , C07C271/28 , C07C317/32 , C07C323/45 , C07C323/47 , C07C327/48 , C07C255/63 , A01N41/10
Abstract: N-methylamides of the formula I in which R denotes alkyl or cyclopropyl, the radicals A denote hydrogen, halogen, cyano, nitro, alkyl, cycloalkyl, OR , cycloalkyloxy, haloalkyl, haloalkyloxy, alkenyl, alkenyloxy, alkynyl, alkoxyalkyl, cyanoalkyl, nitroalkyl, phenyl, phenoxy, C(O)R , CO2R , C(O)NR R , C(S)NR R , NR R , NR C(O)R , NR CO2R , OC(O)R , SR , S(O)R , S(O)2R , the groups -C(R )=NR , -N=CR R , where the radicals R , R and R denote hydrogen or C1-C6-alkyl or X denotes S, O and NR and n denotes the numbers 0 or 1, or two of the groups Am in adjacent positions together denote the group -CH=CH-CH=CH and m represents the numbers 1, 2 or 3, and fungicides containing these compounds.
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公开(公告)号:AU658280B2
公开(公告)日:1995-04-06
申请号:AU3564993
申请日:1993-04-02
Applicant: BASF AG
Inventor: BENOIT REMY , SAUTER HUBERT
IPC: C07C253/30 , C07C249/12 , C07C251/60 , C07C255/17 , C07C255/57 , C07C255/61 , C07C259/04 , C07C259/12 , C07C259/14 , C07C259/18 , C07C317/24 , C07C323/47 , C07C323/63 , C07D209/14 , C07D209/48 , C07D213/53 , C07D213/57 , C07D239/26 , C07D277/20 , C07D277/38 , C07D333/24 , C07D333/36 , C07D333/22
Abstract: Process for the preparation of an o-iminooxymethylbenzoic acid of the general formula I in which m denotes an integer from 0 to 3, X denotes alkyl, alkoxy, nitro, cyano, or halogen, R1 and R2 denote hydrogen, cyano, hydroxyl, alkyl, cycloalkyl, alkenyl, cycloalkenyl, alkynyl, alkoxy, alkylthio, benzylthio, benzylamino, alkylcarbonyl, optionally substituted phenylcarbonyl, optionally substituted benzylcarbonyl, alkoxycarbonyl, optionally substituted phenoxycarbonyl, optionally substituted benzyloxycarbonyl, optionally substituted aryl, optionally substituted aryloxy, optionally substituted arylthio, optionally substituted arylalkyl, optionally substituted arylalkenyl, optionally substituted aryloxyalkyl, optionally substituted arylthioalkyl, optionally substituted hetaryl, optionally substituted hetaryloxy, optionally substituted hetarylthio, optionally substituted heteroarylalkyl, optionally substituted hetarylalkenyl, optionally substituted hetaryloxyalkyl, hetarylthioalkyl, optionally substituted heterocyclyl, optionally substituted heterocyclyloxy, or denote N(R )2, where R denotes H, alkyl or phenyl, or denote -CO-N(R )2, where R denotes H, alkyl or phenyl, or R and R together with the C atom which they substitute can form a carbo- or heterocyclic ring, or R or R denotes halogen or the group denotes the radical where n denotes the integers 1 to 4 and the radicals R denote H, halogen, cyano, nitro; alkyl, alkoxy, aryl, aryloxy, benzyloxy, hetaryl and hetaryloxy, by reacting an oxime of the general formula II in which R1 and R2 have the abovementioned meanings, with a lactone of the general formula III in which X and m have the abovementioned meaning, if appropriate in the presence of a base or of a diluent, and o-iminooxymethylbenzoic acids of the abovementioned formula.
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104.
公开(公告)号:ZA9306299B
公开(公告)日:1995-02-27
申请号:ZA9306299
申请日:1993-08-27
Applicant: BASF AG
Inventor: BAYER HERBERT , WINGERT HORST , SAUTER HUBERT , BENOIT REMY , OBERDORF KLAUS , ROEHL FRANZ , AMMERMANN EBERHARD , LORENZ GISELA
IPC: A01N37/50 , C07C249/08 , C07C249/12 , C07C251/38 , C07C251/48 , C07C251/58 , C07C251/60 , C07C255/61 , C07C255/62 , C07C255/64 , C07C259/18 , C07C271/28 , C07C317/32 , C07C323/45 , C07C323/47 , C07C327/48 , C07C , A01N
CPC classification number: C07C255/61 , A01N37/50 , C07C251/48 , C07C251/60 , C07C323/47 , C07C327/48 , C07C2601/02 , C07C2601/14
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公开(公告)号:AU648142B2
公开(公告)日:1994-04-14
申请号:AU1074292
申请日:1992-02-06
Applicant: BASF AG
Inventor: BENOIT REMY , SAUTER HUBERT , KIRSTGEN REINHARD , LORENZ GISELA , AMMERMANN EBERHARD
IPC: A01N35/10 , A01N37/12 , A01N37/34 , A01N37/50 , A01N43/10 , A01N53/10 , C07C251/48 , C07C251/50 , C07C251/58 , C07C251/60 , C07C251/80 , C07C255/61 , C07C255/62 , C07D239/52 , C07C255/64 , C07C251/38 , C07D241/12 , C07D239/26 , C07D213/53 , C07D307/52 , C07D333/22 , C07D213/643 , C07D239/34 , C07D307/33 , C07D307/46 , C07D333/16
Abstract: alpha -Imino oxime cpds, described as oxime ethers, of formula (I) are new: R = CR2R3R4 or opt. substd. 3-8C cycloalkyl, 2-8C alkenyl, 2-8C alkynyl, phenyl or heteroaryl; R1 = H or 1-8C alkyl; R2 = H, 1-8C alkyl, aralkyl, heteroarylalkyl, alkoxyalkyl, aryloxyalkyl, aryl or heteroaryl; R3 = H, Me, CN, COOH or 2-9C alkoxycarbonyl; R4 = a gp. as defined for R2; or CR2R3 is a 5- to 8-membered lactone ring or CR2R4 is a 3-8C cycloalkane ring; R5 = H, 1-8C alkyl, aralkyl, 3-6C cycloalkyl, OH, 1-4C alkoxy, NH2, 1-4C alkylamino or dialkylamino; Y = a gp. stated to be an opt. substd. 1-8C alkyl, opt. substd. 2-8C alkenyl, 2-8C alkynyl, O, S(O)m (m = 0-2), N substd. by opt. substd. 1-8C alkyl, oxycarbonyl, carbonyloxy, oxycarbonyl (1-8C) alkyl, carbonyloxy (1-8C) alkyl, 2-8C oxyalkyloxy, 2-8C oxyalkenyl, 1-8C alkoxy, 1-4C oxyalkyl, 1-8C thioalkyl, azo, opt. 1-8C alkyl-substd. -carbonylamino, -aminocarbonyl or -aminocarbonyloxy, oxyimino or opt. substd. imino oxyalkyl; Z = (a) 1-18C alkyl, 2-18C alkenyl, 3-18C alkynyl, aryl, aryl (1-10C) alkyl, aryl (2-10C) alkenyl, aryloxy (1-10C) alkyl, (1-4C) alkoxy (1-10C) alkyl, 1-10C haloalkyl, 2-5C alkoxycarbonyl or heteroaryl; (b) aryloxy, aryloxy (1-10C) alkoxy, aryl (1-10C) alkoxy, 1-10C alkoxy or heteroaryloxy when Y is not oxyalkyl, oxyalkyloxy, thialkyl (sic), -O-N=C- (sic), -N=N-, oxycarbonyl, oxycarbonyloxy, O or S; or (c) 1-18C alkylthio or arylthio when Y is not oxyalkyl, oxyalkyloxy, -O-N=C- (sic), -N=N-, oxycarbonyl, oxycarbonyloxy or O, and Z is opt. substd. by halogen, CN, NO2, 1-4C alkyl, 2-4C alkenyl, 1-4C alkoxy, 1-4C haloalkyl, (1-4C) alkoxy (1-4C) alkyl, di(1-4C) alkoxy (1-4C) alkyl, opt. substd. 1-10C alkoxyimino, opt. substd. 2-10C alkenyloxyimino, opt. substd. aralkoxyimino, opt. substd. 2-10C alkanoyl, opt. substd. formyl, 2-4C haloalkenyl, 2-5C alkoxycarbonyl, opt. substd. phenyl, or opt. substd. 5-membered heterocyclyl which contains 1-4 heteroatoms (N, O and/or S) and is opt. fused with an opt. substd. aromatic or heteroaromatic ring; X = H, halogen, NO2 and/or opt. substd. 1-4C alkyl, 1-4C alkoxy and/or 1-4C haloalkyl; m = 1-4.
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106.
公开(公告)号:PL300213A1
公开(公告)日:1994-04-05
申请号:PL30021393
申请日:1993-08-26
Applicant: BASF AG
Inventor: BAYER HERBERT , WINGERT HORST , SAUTER HUBERT , BENOIT REMY , OBERDORF KLAUS , ROEHL FRANZ , AMMERMANN EBERHARD , LORENZ GISELA
IPC: A01N37/50 , C07C249/08 , C07C249/12 , C07C251/38 , C07C251/48 , C07C251/58 , C07C251/60 , C07C255/61 , C07C255/62 , C07C255/64 , C07C259/18 , C07C271/28 , C07C317/32 , C07C323/45 , C07C323/47 , C07C327/48 , C07C251/00
Abstract: N-methylamides of the formula I in which R denotes alkyl or cyclopropyl, the radicals A denote hydrogen, halogen, cyano, nitro, alkyl, cycloalkyl, OR , cycloalkyloxy, haloalkyl, haloalkyloxy, alkenyl, alkenyloxy, alkynyl, alkoxyalkyl, cyanoalkyl, nitroalkyl, phenyl, phenoxy, C(O)R , CO2R , C(O)NR R , C(S)NR R , NR R , NR C(O)R , NR CO2R , OC(O)R , SR , S(O)R , S(O)2R , the groups -C(R )=NR , -N=CR R , where the radicals R , R and R denote hydrogen or C1-C6-alkyl or X denotes S, O and NR and n denotes the numbers 0 or 1, or two of the groups Am in adjacent positions together denote the group -CH=CH-CH=CH and m represents the numbers 1, 2 or 3, and fungicides containing these compounds.
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107.
公开(公告)号:AU4491893A
公开(公告)日:1994-03-03
申请号:AU4491893
申请日:1993-08-27
Applicant: BASF AG
Inventor: BAYER HERBERT , WINGERT HORST , SAUTER HUBERT , BENOIT REMY , OBERDORF KLAUS , ROEHL FRANZ , AMMERMANN EBERHARD , LORENZ GISELA
IPC: A01N37/50 , C07C249/08 , C07C249/12 , C07C251/38 , C07C251/48 , C07C251/58 , C07C251/60 , C07C255/61 , C07C255/62 , C07C255/64 , C07C259/18 , C07C271/28 , C07C317/32 , C07C323/45 , C07C323/47 , C07C327/48 , C07C255/13 , A01N53/00 , A01N47/08
Abstract: N-methylamides of the formula I in which R denotes alkyl or cyclopropyl, the radicals A denote hydrogen, halogen, cyano, nitro, alkyl, cycloalkyl, OR , cycloalkyloxy, haloalkyl, haloalkyloxy, alkenyl, alkenyloxy, alkynyl, alkoxyalkyl, cyanoalkyl, nitroalkyl, phenyl, phenoxy, C(O)R , CO2R , C(O)NR R , C(S)NR R , NR R , NR C(O)R , NR CO2R , OC(O)R , SR , S(O)R , S(O)2R , the groups -C(R )=NR , -N=CR R , where the radicals R , R and R denote hydrogen or C1-C6-alkyl or X denotes S, O and NR and n denotes the numbers 0 or 1, or two of the groups Am in adjacent positions together denote the group -CH=CH-CH=CH and m represents the numbers 1, 2 or 3, and fungicides containing these compounds.
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公开(公告)号:AU9008291A
公开(公告)日:1992-07-02
申请号:AU9008291
申请日:1991-12-24
Applicant: BASF AG
Inventor: WINGERT HORST , WOLF BERND , BENOIT REMY , SAUTER HUBERT , HEPP MICHAEL , GRAMMENOS WASSILIOS , KUEKENHOEHNER THOMAS
IPC: C07C69/736 , C07C20060101 , C07C51/09 , C07C51/367 , C07C59/68 , C07C65/21 , C07C65/24 , C07C67/22 , C07C69/738 , C07C69/76 , C07C235/34 , C07C235/78 , C07C249/08 , C07C251/48 , C07C253/14 , C07C255/17 , C07C255/40 , C07C317/24
Abstract: Prepn. of 2-phenoxymethyl benzoic acid derivs. of formula (I) comprises (a) converting a phenol of formula (II) to the phenolate in the presence of a basic diluent; (b) mixing the mixt. with a lactone of formula (III); (c) distilling off the diluent; (d) reacting the mixt. at 50-250 degrees C in the melt; and (e) dissolving the liq. melt with water and acidifying. X, Y = halogen, 1-4C alkyl, 1-4C alkoxy or CF3; m = 0-4; n = 0-3.
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109.
公开(公告)号:HU9200372D0
公开(公告)日:1992-05-28
申请号:HU9200372
申请日:1992-02-06
Applicant: BASF AG
Inventor: BENOIT REMY , SAUTER HUBERT , KIRSTGEN REINHARD , LORENZ GISELA , AMMERMANN EBERHARD
IPC: A01N35/10 , A01N37/12 , A01N37/34 , A01N37/50 , A01N43/10 , A01N53/10 , C07C251/48 , C07C251/50 , C07C251/58 , C07C251/60 , C07C251/80 , C07C255/61 , C07C255/62 , C07D239/52
Abstract: alpha -Imino oxime cpds, described as oxime ethers, of formula (I) are new: R = CR2R3R4 or opt. substd. 3-8C cycloalkyl, 2-8C alkenyl, 2-8C alkynyl, phenyl or heteroaryl; R1 = H or 1-8C alkyl; R2 = H, 1-8C alkyl, aralkyl, heteroarylalkyl, alkoxyalkyl, aryloxyalkyl, aryl or heteroaryl; R3 = H, Me, CN, COOH or 2-9C alkoxycarbonyl; R4 = a gp. as defined for R2; or CR2R3 is a 5- to 8-membered lactone ring or CR2R4 is a 3-8C cycloalkane ring; R5 = H, 1-8C alkyl, aralkyl, 3-6C cycloalkyl, OH, 1-4C alkoxy, NH2, 1-4C alkylamino or dialkylamino; Y = a gp. stated to be an opt. substd. 1-8C alkyl, opt. substd. 2-8C alkenyl, 2-8C alkynyl, O, S(O)m (m = 0-2), N substd. by opt. substd. 1-8C alkyl, oxycarbonyl, carbonyloxy, oxycarbonyl (1-8C) alkyl, carbonyloxy (1-8C) alkyl, 2-8C oxyalkyloxy, 2-8C oxyalkenyl, 1-8C alkoxy, 1-4C oxyalkyl, 1-8C thioalkyl, azo, opt. 1-8C alkyl-substd. -carbonylamino, -aminocarbonyl or -aminocarbonyloxy, oxyimino or opt. substd. imino oxyalkyl; Z = (a) 1-18C alkyl, 2-18C alkenyl, 3-18C alkynyl, aryl, aryl (1-10C) alkyl, aryl (2-10C) alkenyl, aryloxy (1-10C) alkyl, (1-4C) alkoxy (1-10C) alkyl, 1-10C haloalkyl, 2-5C alkoxycarbonyl or heteroaryl; (b) aryloxy, aryloxy (1-10C) alkoxy, aryl (1-10C) alkoxy, 1-10C alkoxy or heteroaryloxy when Y is not oxyalkyl, oxyalkyloxy, thialkyl (sic), -O-N=C- (sic), -N=N-, oxycarbonyl, oxycarbonyloxy, O or S; or (c) 1-18C alkylthio or arylthio when Y is not oxyalkyl, oxyalkyloxy, -O-N=C- (sic), -N=N-, oxycarbonyl, oxycarbonyloxy or O, and Z is opt. substd. by halogen, CN, NO2, 1-4C alkyl, 2-4C alkenyl, 1-4C alkoxy, 1-4C haloalkyl, (1-4C) alkoxy (1-4C) alkyl, di(1-4C) alkoxy (1-4C) alkyl, opt. substd. 1-10C alkoxyimino, opt. substd. 2-10C alkenyloxyimino, opt. substd. aralkoxyimino, opt. substd. 2-10C alkanoyl, opt. substd. formyl, 2-4C haloalkenyl, 2-5C alkoxycarbonyl, opt. substd. phenyl, or opt. substd. 5-membered heterocyclyl which contains 1-4 heteroatoms (N, O and/or S) and is opt. fused with an opt. substd. aromatic or heteroaromatic ring; X = H, halogen, NO2 and/or opt. substd. 1-4C alkyl, 1-4C alkoxy and/or 1-4C haloalkyl; m = 1-4.
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公开(公告)号:HU914162D0
公开(公告)日:1992-03-30
申请号:HU416291
申请日:1991-12-30
Applicant: BASF AG
Inventor: WINGERT HORST , WOLF BERND , BENOIT REMY , SAUTER HUBERT , HEPP MICHAEL , GRAMMENOS WASSILIOS , KUEKENHOEHNER THOMAS
IPC: C07C69/736 , C07C20060101 , C07C51/09 , C07C51/367 , C07C59/68 , C07C65/21 , C07C65/24 , C07C67/22 , C07C69/738 , C07C69/76 , C07C235/34 , C07C235/78 , C07C249/08 , C07C251/48 , C07C253/14 , C07C255/17 , C07C255/40 , C07C317/24
Abstract: Prepn. of 2-phenoxymethyl benzoic acid derivs. of formula (I) comprises (a) converting a phenol of formula (II) to the phenolate in the presence of a basic diluent; (b) mixing the mixt. with a lactone of formula (III); (c) distilling off the diluent; (d) reacting the mixt. at 50-250 degrees C in the melt; and (e) dissolving the liq. melt with water and acidifying. X, Y = halogen, 1-4C alkyl, 1-4C alkoxy or CF3; m = 0-4; n = 0-3.
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