公开(公告)号：JP2002356468A

公开(公告)日：2002-12-13

申请号：JP2002116019

申请日：2002-04-18

Applicant: BASF AG

Inventor： WINGERT HORST ,  WOLF BERND ,  BENOIT REMY ,  SAUTER HUBERT DR ,  HEPP MICHAEL ,  GRAMMENOS WASSILIOS ,  KUEKENHOEHNER THOMAS

IPC: C07C69/736 ,  C07C20060101 ,  C07C51/09 ,  C07C51/367 ,  C07C59/68 ,  C07C65/21 ,  C07C65/24 ,  C07C67/22 ,  C07C69/738 ,  C07C69/76 ,  C07C235/34 ,  C07C235/78 ,  C07C249/08 ,  C07C251/48 ,  C07C253/14 ,  C07C255/17 ,  C07C255/40 ,  C07C317/24

Abstract: PROBLEM TO BE SOLVED: To provide 2-phenoxymethylbenzoyl isocyanide and a method for production of the same which is an intermediate for production of E-oxime ether of a phenyl glyoxylic acid ester useful as a plant protective. SOLUTION: This method produces the 2-phenoxymethylbenzoyl isocyanide of formula (VI) by producing a 2-phenoxymethyl benzoic acid of formula (IV) from a phenolic compound of formula (II) and a lactone of formula (II), reacting the product with phosgene or the like to obtain corresponding benzoyl chloride and then subjecting to a cyanization. (X and Y are each a halogen atom, a 1-4C alkyl group or the like, m is an integer of 0 to 4 and n is an integer of 0 to 3).

公开(公告)号：JP2000256273A

公开(公告)日：2000-09-19

申请号：JP2000100964

申请日：2000-04-03

Applicant: BASF AG

Inventor： WINGERT HORST ,  WOLF BERND ,  BENOIT REMY ,  SAUTER HUBERT DR ,  HEPP MICHAEL ,  GRAMMENOS WASSILIOS ,  KUEKENHOEHNER THOMAS

IPC: C07C69/736 ,  C07C20060101 ,  C07C51/09 ,  C07C51/367 ,  C07C59/68 ,  C07C65/21 ,  C07C65/24 ,  C07C67/22 ,  C07C69/738 ,  C07C69/76 ,  C07C235/34 ,  C07C235/78 ,  C07C249/08 ,  C07C251/48 ,  C07C253/14 ,  C07C255/17 ,  C07C255/40 ,  C07C317/24

Abstract: PROBLEM TO BE SOLVED: To obtain the subject new compound being an intermediate useful for producing E-oxime ether of phenylglyoxylic acid ester, comprising a specific ketocarboxylic acid ester-dimethyl ketal. SOLUTION: This compound is shown by formula (X and Y are each a halogen, a 1-4C alkyl or the like; (m) is 0-4; and (n) is 0-3). The compound of formula I is obtained by treating a phenol of formula II with a base in the presence of a diluent into a phenolate, mixing the phenolate with a lactone of formula III, volatilizing the diluent, melting the mixture into a melt at 50-250 deg.C, dissolving the melt in a flow state in water, acidifying the solution to give a 2- phenoxymethylbenzoic acid of formula IV, reacting the compound with phosgene, etc., to give a 2-phenoxymethylbenzoyl chloride of formula V, reacting the compound with an alkali metal cyanide in the presence of prussic acid to give a 2-phenoxymethylbenzoyl cyanide of formula VI and reacting the compound with methanol in the presence of an acid.

公开(公告)号：JPH0352871A

公开(公告)日：1991-03-07

申请号：JP17040490

申请日：1990-06-29

Applicant: BASF AG

Inventor： SCHUETZ FRANZ ,  BRAND SIEGBERT ,  WILD JOCHEN ,  KUEKENHOEHNER THOMAS ,  HOFMEISTER PETER ,  KUENAST CHRISTOPH

IPC: C07D239/34 ,  A01N43/54 ,  C07D239/32 ,  C07D239/38

公开(公告)号：LV10361A

公开(公告)日：1995-02-20

申请号：LV930433

申请日：1993-05-27

Applicant: BASF AG

Inventor： MISSLITZ ULF ,  MEYER NORBERT ,  KAST JUERGEN ,  GOETZ NORBERT ,  HARREUS ALBRECHT ,  KUEKENHOEHNER THOMAS ,  WUERZER BRUNO ,  WALTER HELMUT ,  WESTPHALEN KARL-OTTO ,  GERBER MATTHIAS

IPC: C07D213/30 ,  A01N43/08 ,  A01N43/10 ,  A01N43/16 ,  A01N43/18 ,  A01N43/36 ,  A01N43/40 ,  A01P13/00 ,  C07D207/32 ,  C07D207/333 ,  C07D307/38 ,  C07D307/42 ,  C07D333/16 ,  C07D333/28 ,  C07D405/08 ,  C07D405/12 ,  C07D407/08 ,  C07D407/12 ,  C07D409/08 ,  C07D409/12 ,  A01N33/24 ,  A01N35/10 ,  C07C251/32

Abstract: Cyclohexenone oxime ethers of the formula I (I) (R1=C1-C6-alkyl; A=substituted or unsubstituted alkylene or alkenylene; Z=a 5-membered or 6-membered heteroaromatic structure; X=substituted or unsubstituted amino, nitro, cyano, halogen, alkyl, C1-C4-alkoxy, C1-C4-alkylthio, C1-C4-haloalkyl, C1-C4-haloalkoxy, carboxyl, C1-C4-alkoxycarbonyl, substituted or unsubstituted benzyloxycarbonyl and phenyl; n=0 to 3, or 1 to 4 where Z is halogen-substituted pyridyl; and R2=alkoxyalkyl or alkylthioalkyl; substituted or unsubstituted cycloalkyl or cycloalkenyl; a substituted or unsubstituted 5-membered saturated heterocyclic structure which contains one or two hetero atoms; a substituted or unsubstituted 6-membered or 7-membered saturated or mono- or diunsaturated heterocyclic structure containing one or two hereto atoms; a substituted or unsubstituted 5-membered heteroaromatic structure containing one to three hereto atoms; substituted or unsubstituted phenyl or pyridyl) and their agriculturally useful salts and esters of C1-C10-carboxylic acids and inorganic acids. The compounds are suitable as herbicides.

公开(公告)号：CA1330998C

公开(公告)日：1994-07-26

申请号：CA614143

申请日：1989-09-28

Applicant: BASF AG

Inventor： FRICKEL FRITZ-FRIEDER ,  KUEKENHOEHNER THOMAS ,  RENDENBACH-MUELLER BEATRICE ,  WEIFENBACH HARALD ,  TESCHENDORF HANS-JUERGEN

IPC: A61K31/335 ,  A61K31/35 ,  A61K31/40 ,  A61K31/41 ,  A61K31/44 ,  A61K31/443 ,  A61K31/4433 ,  A61K31/445 ,  A61K31/47 ,  A61P25/00 ,  C07D405/12 ,  C07D407/12 ,  C07D409/12 ,  C07D413/12 ,  C07D417/12 ,  C07D419/12

Abstract: An alkoxycoumarin substituted by a heterocyclic radical, of the formula I R1 and R2 independently of one another are each hydrogen, C1-C5-alkyl, trifluoromethyl, phenyl or halogen, or together form a C3-C5-alkylene chain, R3 is C1-C5-alkyl or halogen, n is an integer of from 0 to 3, R4 is hydrogen or C1-C4-alkyl and Het is one of the following heterocyclic radicals: where X is oxygen or sulfur, R5 is unsubstituted or C1C4-alkoxy-substituted C1-C10-alkyl, 5-membered or 6membered oxacycloalkyl, C3-C7-cycloalkyl, benzyl, phenyl which is unsubstituted or substituted by halogen or NO2, a pyridine ring, C1-C5-alkoxycarbonyl or perfluoro-C1-C2-alkyl, R6 is C1-C5-alkyl or C1-C5-alkoxy, R7 is C1-C5-alkyl, unsubstituted or halogen-substituted benzyl or halogen, m is from 0 to 2, R8 is C1-C5-alkyl, C3-C8-cycloalkyl, benzyl or phenyl, R9 is hydrogen or C1-C5-alkyl, R10 is C1C5-alkyl or C1-C8 cycloalkyl, R11 is C1-C5-alkyl, R12 is hydrogen, C1-C5-alkyl or C3-C6-cycloalkyl, R13 is C1-C5-alkyl or halogen, p is from 0 to 2, R14 is C1-C5-alkyl, q is 0 or 1, R15 and R16 are each hydrogen, C1-C5-alkyl or benzyl, R17 is hydrogen or C1-C5-alkyl and R18 is C1-C5-alkyl, with the proviso that R5 is not phenyl when X is oxygen, R1 is methyl and R2 to R4 are each hydrogen, processes for their preparation and drugs prepared therefrom.

公开(公告)号：HUT63402A

公开(公告)日：1993-08-30

申请号：HU9203947

申请日：1992-12-11

Applicant: BASF AG

Inventor： HENKELMANN JOCHEM ,  RUEHL THOMAS ,  ZIMMERMANN HORST ,  GOETZ NORBERT ,  SPIEGLER WOLFGANG ,  KUEKENHOEHNER THOMAS

IPC: B01J23/656 ,  B01J23/62 ,  B01J23/72 ,  B01J23/86 ,  B01J23/88 ,  C07B61/00 ,  C07D309/06

Abstract: Method for the preparation of 4-hydroxymethyltetrahydropyrans of the general formula I in which R , R , R and R denote hydrogen, C1- to C12-alkyl, C3- to C8-cycloalkyl, aryl or C7- to C20-aralkyl, by reacting tetrahydropyrancarboxylic esters of the general formula II in which R1, R2, R3 and R4 have the abovementioned meanings and R5 denotes hydrogen or C1- to C12-alkyl, at temperatures of 50 to 400 DEG C and pressures of 1 to 400 bar in the presence of hydrogen and hydrogenation catalysts.

公开(公告)号：HU207645B

公开(公告)日：1993-05-28

申请号：HU506690

申请日：1990-08-17

Applicant: BASF AG

Inventor： RHEINHEIMER JOACHIM ,  EICKEN KARL ,  VOGELBACHER UWE JOSEF ,  ROHR WOLFGANG ,  KUEKENHOEHNER THOMAS ,  WESTPHALEN KARL-OTTO ,  WUERZER BRUNO

IPC: C07D251/30 ,  A01N43/54 ,  A01N43/64 ,  A01N43/66 ,  A01N43/80 ,  A01N43/82 ,  A01N43/836 ,  C07D239/52 ,  C07D239/60 ,  C07D251/22 ,  C07D251/34 ,  C07D251/38 ,  C07D401/12 ,  C07D401/14 ,  C07D413/12 ,  C07D413/14 ,  C07D417/12 ,  C07D417/14 ,  C07D239/28

Abstract: Carboxylic acid derivatives of the general formula I I where R1 and R2 are each C1-C4-alkyl, C1-C4-haloalkyl, C1-C4-alkoxy, C1-C4-haloalkoxy and/or C1-C4-alkylthio; R3 is hydrogen, hydroxyl, cyano, nitro, formyl, halogen, unsubstituted or substituted amino, C1-C4-alkyl, C1-C4-alkoxy, C3-C6-alkenyl, C3-C6-alkenyloxy, C3-C6-alkynyl or C3-C6-alkynyloxy; R4 is hydrogen or C1-C4-alkyl; R5 is unsubstituted or substituted five-membered hetaryl or isoxazolinyl or -CR6=NOR7; R6 is hydrogen or unsubstituted or substituted C1-C4-alkyl, C3-C8-cycloalkyl or phenyl; R7 is unsubstituted or substituted C1-C4-alkyl, C3-C6-alkenyl, C3-C8-cycloalkyl or phenyl; A is oxygen or sulfur; X is nitrogen or methine =CR8-; R8 is one of the radicals R3, or R8 and R3 together form unsubstituted or substituted 1,3-butadiene-1,4-yl or aza-1,3-butadiene-1,4-yl, and Y and Z are each nitrogen or methine =CH-, their preparation and agents containing them.

公开(公告)号：ZA913481B

公开(公告)日：1993-01-27

申请号：ZA913481

申请日：1991-05-08

Applicant: BASF AG

Inventor： MISSLITZ ULF ,  ULF MISSLITZ ,  MEYER NORBERT ,  NORBERT MEYER ,  KAST JUERGEN ,  JUERGEN KAST ,  GOETZ NORBERT ,  NORBERT GOETZ ,  HARREUS ALBRECHT ,  ALBRECHT HARREUS ,  KUEKENHOEHNER THOMAS ,  THOMAS KUEKENHOEHNER ,  WUERZER BRUNO ,  BRUNO WUERZER ,  WALTER HELMUT ,  HELMUT WALTER ,  WESTPHALEN KARL-OTTO ,  KARL-OTTO WESTPHALEN ,  GERBER MATTHIAS ,  MATTHIAS GERBER

IPC: C07D213/30 ,  A01N43/08 ,  A01N43/10 ,  A01N43/16 ,  A01N43/18 ,  A01N43/36 ,  A01N43/40 ,  A01P13/00 ,  C07D207/32 ,  C07D207/333 ,  C07D307/38 ,  C07D307/42 ,  C07D333/16 ,  C07D333/28 ,  C07D405/08 ,  C07D405/12 ,  C07D407/08 ,  C07D407/12 ,  C07D409/08 ,  C07D409/12 ,  C07D ,  A01N

Abstract: Cyclohexenone oxime ethers of the formula I (I) (R1=C1-C6-alkyl; A=substituted or unsubstituted alkylene or alkenylene; Z=a 5-membered or 6-membered heteroaromatic structure; X=substituted or unsubstituted amino, nitro, cyano, halogen, alkyl, C1-C4-alkoxy, C1-C4-alkylthio, C1-C4-haloalkyl, C1-C4-haloalkoxy, carboxyl, C1-C4-alkoxycarbonyl, substituted or unsubstituted benzyloxycarbonyl and phenyl; n=0 to 3, or 1 to 4 where Z is halogen-substituted pyridyl; and R2=alkoxyalkyl or alkylthioalkyl; substituted or unsubstituted cycloalkyl or cycloalkenyl; a substituted or unsubstituted 5-membered saturated heterocyclic structure which contains one or two hetero atoms; a substituted or unsubstituted 6-membered or 7-membered saturated or mono- or diunsaturated heterocyclic structure containing one or two hereto atoms; a substituted or unsubstituted 5-membered heteroaromatic structure containing one to three hereto atoms; substituted or unsubstituted phenyl or pyridyl) and their agriculturally useful salts and esters of C1-C10-carboxylic acids and inorganic acids. The compounds are suitable as herbicides.

公开(公告)号：ZA9103487B

公开(公告)日：1993-01-27

申请号：ZA9103487

申请日：1991-05-08

Applicant: BASF AG

Inventor： KAST JUERGEN ,  JUERGEN KAST ,  MEYER NORBERT ,  NORBERT MEYER ,  MISSLITZ ULF ,  ULF MISSLITZ ,  HARREUS ALBRECHT ,  ALBRECHT HARREUS ,  KUEKENHOEHNER THOMAS ,  THOMAS KUEKENHOEHNER ,  RANG HARALD ,  HARALD RANG ,  GERBER MATTHIAS ,  MATTHIAS GERBER ,  WESTPHALEN KARL-OTTO ,  KARL-OTTO WESTPHALEN ,  WALTER HELMUT ,  HELMUT WALTER

IPC: A01N35/10 ,  A01N37/22 ,  A01N37/34 ,  A01N43/08 ,  A01N43/10 ,  A01N43/14 ,  A01N43/16 ,  A01N43/28 ,  A01N43/80 ,  A01P13/00 ,  C07C239/20 ,  C07C249/08 ,  C07C251/42 ,  C07C251/52 ,  C07C251/54 ,  C07C251/58 ,  C07C251/60 ,  C07C255/62 ,  C07C323/47 ,  C07D213/30 ,  C07D261/08 ,  C07D275/02 ,  C07D307/10 ,  C07D309/06 ,  C07D309/08 ,  C07D309/20 ,  C07D317/14 ,  C07D333/06 ,  C07D335/02 ,  C07D339/06 ,  C07D ,  A01N

CPC classification number: C07D213/30 ,  A01N35/10 ,  A01N43/14 ,  C07C239/20 ,  C07C251/42 ,  C07C251/52 ,  C07C2601/12 ,  C07C2601/14 ,  C07D261/08 ,  C07D309/06 ,  C07D309/08 ,  C07D335/02

公开(公告)号：ZA911021B

公开(公告)日：1992-10-28

申请号：ZA911021

申请日：1991-02-12

Applicant: BASF AG

Inventor： ZIERKE THOMAS ,  THOMAS ZIERKE ,  KUEKENHOEHNER THOMAS ,  THOMAS KUEKENHOEHNER ,  AMMERMAN EBERHARD ,  EBERHARD AMMERMAN ,  LORENZ GISELA ,  GISELA LORENZ

IPC: A01N43/40 ,  C07D213/30 ,  C07D213/42 ,  C07D213/57 ,  C07D213/89 ,  C07D ,  A01N ,  A01G

Abstract: Compounds of the formula 1 1 where R is unsubstituted or substituted cycloalkyl or cycloalkenyl, X, Y and Z are hydrogen, halogen, alkyl, alkoxy, alkoximino, haloalkyl, cyano, nitro or unsubstituted or substituted phenyl or phenoxy, W is -CH2- or -CH2CH2- and n is 0 or 1, and the plant-tolerated acid-addition salts thereof, and fungicides containing these compounds are described.