公开(公告)号：JPS62158269A

公开(公告)日：1987-07-14

申请号：JP29907986

申请日：1986-12-17

Applicant: BASF AG

Inventor： WOLF BERND ,  THEOBALD HANS ,  BECKER RAINER ,  GOETZ NORBERT ,  HIMMELE WALTER ,  KROPP RUDOLF

IPC: A01N43/08 ,  A01N43/10 ,  A01N53/00 ,  A01N53/04 ,  A01N53/08 ,  C07C249/00 ,  C07D261/04 ,  C07D307/40 ,  C07D307/42 ,  C07D307/45 ,  C07D307/46 ,  C07D307/54 ,  C07D409/12

公开(公告)号：JP2002356468A

公开(公告)日：2002-12-13

申请号：JP2002116019

申请日：2002-04-18

Applicant: BASF AG

Inventor： WINGERT HORST ,  WOLF BERND ,  BENOIT REMY ,  SAUTER HUBERT DR ,  HEPP MICHAEL ,  GRAMMENOS WASSILIOS ,  KUEKENHOEHNER THOMAS

IPC: C07C69/736 ,  C07C20060101 ,  C07C51/09 ,  C07C51/367 ,  C07C59/68 ,  C07C65/21 ,  C07C65/24 ,  C07C67/22 ,  C07C69/738 ,  C07C69/76 ,  C07C235/34 ,  C07C235/78 ,  C07C249/08 ,  C07C251/48 ,  C07C253/14 ,  C07C255/17 ,  C07C255/40 ,  C07C317/24

Abstract: PROBLEM TO BE SOLVED: To provide 2-phenoxymethylbenzoyl isocyanide and a method for production of the same which is an intermediate for production of E-oxime ether of a phenyl glyoxylic acid ester useful as a plant protective. SOLUTION: This method produces the 2-phenoxymethylbenzoyl isocyanide of formula (VI) by producing a 2-phenoxymethyl benzoic acid of formula (IV) from a phenolic compound of formula (II) and a lactone of formula (II), reacting the product with phosgene or the like to obtain corresponding benzoyl chloride and then subjecting to a cyanization. (X and Y are each a halogen atom, a 1-4C alkyl group or the like, m is an integer of 0 to 4 and n is an integer of 0 to 3).

公开(公告)号：JP2003002867A

公开(公告)日：2003-01-08

申请号：JP2002143979

申请日：2002-05-20

Applicant: Basf Ag ,  ビーエーエスエフ アクチェンゲゼルシャフト

Inventor： ISAK HEINZ ,  KEIL MICHAEL ,  WOLF BERND ,  WINGERT HORST

IPC: C07C67/313 ,  C07B61/00 ,  C07C59/68 ,  C07C59/84 ,  C07C67/31 ,  C07C69/708 ,  C07C69/716 ,  C07C249/04 ,  C07C249/08 ,  C07C249/12 ,  C07C251/48

CPC classification number: C07C251/48

Abstract: PROBLEM TO BE SOLVED: To provide a method for easily producing an E-oxime ether isomer of a phenylglyoxylic ester.
SOLUTION: The method for producing the E-oxime ether represented by formula (I) (wherein, X and Y are each a halogen, a 1-4C alkyl, a 1-4C alkoxy, trifluoromethyl, and a 1-1-5C alkyl-(2-5C alkenyl)-hydroxyimino-1-5C alkyl-(2-5C alkenyl)-hydroxyimino; (m) is an integer of 0-54; (n) is an integer of 0-53) is characterized by converting the E-oxime ether represented by formula (IIa) (wherein, substituents are the same as defined above) to a salt by using a base in the presence of an organic diluent and reacting the product with a methylation agent of CH
3 (wherein, X is Cl, Br, or the like).
COPYRIGHT: (C)2003,JPO

Abstract translation: 要解决的问题：提供一种容易地生产苯基乙醛酸酯的肟基醚异构体的方法。 解决方案：制备由式（I）表示的E-肟醚的方法（其中X和Y各自为卤素，1-4C烷基，1-4C烷氧基，三氟甲基和1-1-5C烷基 - （2-5C烯基） - 羟基亚氨基-1C-C 1-5烷基 - （2-5C烯基） - 羟基亚氨基;（m）是0-54的整数;（n）是0-53的整数） 由式（IIa）表示的E-肟醚（其中取代基与上述定义相同）与盐在有机稀释剂存在下使用碱反应，并使产物与甲基化试剂CH3（其中X， 是Cl，Br等）。

公开(公告)号：JP2000256273A

公开(公告)日：2000-09-19

申请号：JP2000100964

申请日：2000-04-03

Applicant: BASF AG

Inventor： WINGERT HORST ,  WOLF BERND ,  BENOIT REMY ,  SAUTER HUBERT DR ,  HEPP MICHAEL ,  GRAMMENOS WASSILIOS ,  KUEKENHOEHNER THOMAS

IPC: C07C69/736 ,  C07C20060101 ,  C07C51/09 ,  C07C51/367 ,  C07C59/68 ,  C07C65/21 ,  C07C65/24 ,  C07C67/22 ,  C07C69/738 ,  C07C69/76 ,  C07C235/34 ,  C07C235/78 ,  C07C249/08 ,  C07C251/48 ,  C07C253/14 ,  C07C255/17 ,  C07C255/40 ,  C07C317/24

Abstract: PROBLEM TO BE SOLVED: To obtain the subject new compound being an intermediate useful for producing E-oxime ether of phenylglyoxylic acid ester, comprising a specific ketocarboxylic acid ester-dimethyl ketal. SOLUTION: This compound is shown by formula (X and Y are each a halogen, a 1-4C alkyl or the like; (m) is 0-4; and (n) is 0-3). The compound of formula I is obtained by treating a phenol of formula II with a base in the presence of a diluent into a phenolate, mixing the phenolate with a lactone of formula III, volatilizing the diluent, melting the mixture into a melt at 50-250 deg.C, dissolving the melt in a flow state in water, acidifying the solution to give a 2- phenoxymethylbenzoic acid of formula IV, reacting the compound with phosgene, etc., to give a 2-phenoxymethylbenzoyl chloride of formula V, reacting the compound with an alkali metal cyanide in the presence of prussic acid to give a 2-phenoxymethylbenzoyl cyanide of formula VI and reacting the compound with methanol in the presence of an acid.

公开(公告)号：JP2006188531A

公开(公告)日：2006-07-20

申请号：JP2006052375

申请日：2006-02-28

Applicant: Basf Ag ,  ビーエーエスエフ アクチェンゲゼルシャフトBASF Aktiengesellschaft

Inventor： ISAK HEINZ ,  WETTLING THOMAS ,  KEIL MICHAEL ,  WOLF BERND ,  DOETZER REINHARD

IPC: C07C255/40 ,  C07C253/14 ,  C07C255/32

CPC classification number: C07C255/40 ,  C07C253/14

Abstract: PROBLEM TO BE SOLVED: To provide a new halomethylbenzoyl cyanide industrially useful as an important intermediate product for the synthesis of a plant protection agent. SOLUTION: The halomethylbenzoyl cyanide expressed by formula I' is produced by the reaction of a halomethylbenzoyl chloride with an alkali metal cyanide or a transition metal cyanide. In the formula, X is a halogen atom, a 1-4C alkyl, a 1-4C alkoxy, trifluoromethyl, -C(1-5C alkyl)=N-O-(1-5C alkyl) or -C(1-5C alkyl)=N-O-(2-5C alkenyl); m is 0-4; and Y is chloromethyl or bromomethyl. COPYRIGHT: (C)2006,JPO&NCIPI

Abstract translation: 要解决的问题：提供工业上可用作合成植物保护剂的重要中间产物的新的卤代甲基苯甲酰氰。 解决方案：由式I'表示的卤代甲基苯甲酰氰由卤代甲基苯甲酰氯与碱金属氰化物或过渡金属氰化物的反应产生。 在该式中，X是卤素原子，1-4C烷基，1-4C烷氧基，三氟甲基，-C（1-5C烷基）= NO-（1-5C烷基）或-C（1-5C烷基） = NO-（2-5C烯基）; m为0-4; Y是氯甲基或溴甲基。 版权所有（C）2006，JPO＆NCIPI

公开(公告)号：WO0142183A2

公开(公告)日：2001-06-14

申请号：PCT/EP0011814

申请日：2000-11-27

Applicant: BASF AG ,  STAMM ARMIN ,  GOETZ ROLAND ,  GOETZ NORBERT ,  HENKELMANN JOCHEM ,  KNEUPER HEINZ JOSEF ,  WOLF BERND

Inventor： STAMM ARMIN ,  GOETZ ROLAND ,  GOETZ NORBERT ,  HENKELMANN JOCHEM ,  KNEUPER HEINZ-JOSEF ,  WOLF BERND

IPC: C07C51/58 ,  C07B61/00 ,  C07C51/09 ,  C07C57/76 ,  C07C51/00

CPC classification number: C07C51/09 ,  C07C63/04

Abstract: The invention relates to a method for producing o-chloromethyl benzenecarbonyl chlorides of formula (I), wherein R -R can be the same or different and stand for hydrogen, C1-C4-alkyl, halogen or trifluoromethyl, by converting benzocondensed lactones of formula (II), wherein R -R have the aforementioned meaning, with gaseous or liquid phosgene and the dimers or trimers thereof. The inventive method is characterised in that the conversion is carried out in the presence of catalytical amounts of a Lewis acid and catalytical amounts of a phosgenation catalyst.

Abstract translation: 本发明涉及一种用于制备式（I），其中R <1> -R <4>相同或不同，并代表氢，C1-C4烷基，卤素或三氟甲基，由反应的邻 - 氯甲基苯甲酰氯 苯并稠合的式（II）的内酯，其中R <1> -R <4>具有上述含义，与gesförmigem或液体光气，其二聚体或三聚体，其特征在于，在催化量的路易斯的存在下的反应 进行酸和催化量的光气化催化剂。

公开(公告)号：WO2008043835A2

公开(公告)日：2008-04-17

申请号：PCT/EP2007060879

申请日：2007-10-12

Applicant: BASF AG ,  SCHMIDT THOMAS ,  GEBHARDT JOACHIM ,  LOEHR SANDRA ,  KEIL MICHAEL ,  WEVERS JAN HENDRIK ,  ERK PETER ,  SAXELL HEIDI EMILIA ,  HAMPRECHT GERHARD ,  SEITZ WERNER ,  MAYER GUIDO ,  WOLF BERND ,  COX GERHARD ,  MICHEL ALFRED ,  ZAGAR CYRILL ,  REINHARD ROBERT ,  SIEVERNICH BERND

Inventor： SCHMIDT THOMAS ,  GEBHARDT JOACHIM ,  LOEHR SANDRA ,  KEIL MICHAEL ,  WEVERS JAN HENDRIK ,  ERK PETER ,  SAXELL HEIDI EMILIA ,  HAMPRECHT GERHARD ,  SEITZ WERNER ,  MAYER GUIDO ,  WOLF BERND ,  COX GERHARD ,  MICHEL ALFRED ,  ZAGAR CYRILL ,  REINHARD ROBERT ,  SIEVERNICH BERND

CPC classification number: C07D239/54

Abstract: The present invention relates to a crystalline form of 2-chloro-5-[3,6-dihydro-3-methyl-2,6-dioxo-4-(trifluoromethyl)-1-(2H)-pyrimidinyl]-4-fluoro-N-[[methyl-(1-methylethyl)amino]sulphonyl]benzamide. The invention also relates to a method for preparing this crystalline form and to formulations for crop protection which comprise this crystalline form of the phenyluracil.

Abstract translation: 本发明涉及2-氯-5- [3,6-二氢-3-甲基-2,6-二氧-4-（三氟甲基）-1（2H） - 嘧啶基] -4-氟的结晶形式 N - [[甲基 - （1-甲基乙基）氨基]磺酰基]苯甲酰胺。 本发明还涉及一种用于该结晶形式的制备以及制剂，其包含苯基尿嘧啶的该晶形的作物保护的方法。

公开(公告)号：WO0142185A3

公开(公告)日：2002-05-02

申请号：PCT/EP0011817

申请日：2000-11-27

Applicant: BASF AG ,  GOETZ ROLAND ,  GOETZ NORBERT ,  KEIL MICHAEL ,  WOLF BERND ,  STEINMETZ ADRIAN ,  STAMM ARMIN ,  HENKELMANN JOCHEM

Inventor： GOETZ ROLAND ,  GOETZ NORBERT ,  KEIL MICHAEL ,  WOLF BERND ,  STEINMETZ ADRIAN ,  STAMM ARMIN ,  HENKELMANN JOCHEM

IPC: C07C51/58 ,  C07B61/00 ,  C07C51/60 ,  C07C57/76 ,  C07C63/10

CPC classification number: C07C51/60 ,  C07C63/10

Abstract: The invention relates to a method for producing o-chloromethyl benzoic acid chlorides of formula (I), in which R to R can be the same or different and represent hydrogen C1-C4 alkyl, halogen or trifluoromethyl, by reacting benzo-condensed lactones of formula (II), in which R to R have the above-mentioned meaning, with thionyl chloride. The inventive method is characterized in that the reaction is carried out in the presence of catalytic quantities of a Lewis acid and in the presence of catalytic quantities of a phosphine derivative.

Abstract translation: 本发明涉及一种用于制备式（I），其中R <1> -R <4>相同或不同，并代表氢，C1-C4烷基，卤素或三氟甲基，由反应的邻 - 氯甲基苯甲酰氯 苯并稠合的式（II）的内酯，其中R <1> -R <4>具有上述含义，与亚硫酰氯，其特征在于，一个执行在路易斯酸催化量和催化量的膦的存在下进行反应。

公开(公告)号：WO0142182A3

公开(公告)日：2001-12-06

申请号：PCT/EP0011810

申请日：2000-11-27

Applicant: BASF AG ,  GOETZ ROLAND ,  GOETZ NORBERT ,  KEIL MICHAEL ,  WOLF BERND ,  STEINMETZ ADRIAN ,  STAMM ARMIN ,  HENKELMANN JOCHEM

Inventor： GOETZ ROLAND ,  GOETZ NORBERT ,  KEIL MICHAEL ,  WOLF BERND ,  STEINMETZ ADRIAN ,  STAMM ARMIN ,  HENKELMANN JOCHEM

IPC: C07C51/60 ,  C07C63/04 ,  C07C63/10

CPC classification number: C07C51/60 ,  C07C63/04 ,  C07C63/10

Abstract: The invention relates to a method for producing o-chloromethyl benzoic acid chlorides of formula (I), in which R to R can be the same or different and represent hydrogen C1-C4 alkyl, halogen or trifluoromethyl, by reacting benzo-condensed lactones of formula (II), in which R to R have the above-mentioned meaning, with thionyl chloride. The inventive method is characterized in that the reaction is carried out in the presence of catalytic quantities of a boric acid, boric acid anhydride, borate, boronic acid or boronic acid ester and in the presence of catalytic quantities of a quaternary ammonia salt.

Abstract translation: 本发明涉及一种用于制备式（I）的邻 - 氯甲基苯甲酰氯，于R的处理<4>可以<1>是相同的或R不同，并代表氢，C1-C4烷基，卤素或三氟甲基，通过使 苯并稠合的式内酯（II），至R <4>具有R <1>如上所定义，与亚硫酰氯，其特征在于gekennzeichet，在催化量的硼酸，的存在下进行反应硼酸酐，硼酸盐，硼酸或Boronsäureester一个和 催化量的季铵盐。

公开(公告)号：CA2574406C

公开(公告)日：2013-02-19

申请号：CA2574406

申请日：2005-07-13

Applicant: BASF AG

Inventor： LOEHR SANDRA ,  GEBHARDT JOACHIM ,  MAYER GUIDO ,  KEIL MICHAEL ,  SCHMIDT THOMAS ,  WOLF BERND

IPC: C07D239/54 ,  C07C307/06

Abstract: The invention relates to a method for the production of 3-phenyl(thio)uracils and dithiouracils of formula I, wherein the variables have the meanings cited in the description, characterized in that carbamates of formula II, wherein variables X1, X3, Ar and A have the above-mentioned meanings and L1 represents a nucleophilically displaceable nucleofuge, can be reacted with enamines of formula III, wherein variables X2, R1, R2 and R3 have the above-mentioned meanings and L2 represents a nucleophilically displaceable nucleofuge. The invention also relates to intermediate products for the production thereof.