Abstract:
Hindered tert-butylphenolic antioxidant compositions characterized by a low level of volatile and undesirable single-ring tert-butylphenolic antioxidants and a high level of non-volatile multi-ring (or methylene bridged) tert-butylphenolic antioxidants are obtained by reacting a specific mixture of ultra pure ortho-tert-butylphenol (OTBP), ultra pure 2,6-di-tert-butylphenol (DTBP) and formaldehyde in a solvent in the presence of catalyst. These antioxidants are further characterized by having a low level of 2,6-di-tert-butylphenol, low levels of ortho-tert-butylphenol, and trace levels of 2,4,6-tri-tert-butylphenol.
Abstract:
A cyclic compound comprising m units of the formula Ia. 1 and n units of the formula (Ib) 2 joined together to form a ring, wherein Y and Y2 are divalent bridging groups which may be the same or different in each unit; R0 is H or (C1-C6) alkyl or is a metal or ammonium cation; R5 is H or (C1-C60) alkyl or OH group; j is 1 or 2; R3 is hydrogen, a hydrocarbyl or a hetero-substituted hydrocarbyl group; each of R1, R2 and R4, which may be the same or different, is hydroxyl, hydrogen, hydrocarbyl or hetero-substituted hydrocarbyl, with the provisos that i) at least one of R1, R2, R4 is hydroxyl, and mnulln is 4 to 20, m is 1-8 and n is at least 3, and ii) in formula Ia at least one OH group is in the meta or para position to the COOR0 group and/or at least one R5 group is OH.
Abstract translation:包含m个式Ia化合物的环状化合物。 和式(Ib)的n个单元连接在一起形成环,其中Y和Y2是每个单元可以相同或不同的二价桥连基团; R 0是H或(C 1 -C 6)烷基或是金属或铵阳离子; R5是H或(C1-C60)烷基或OH基; j为1或2; R3是氢,烃基或杂取代的烃基; R 1,R 2和R 4各自可以相同或不同,是羟基,氢,烃基或杂取代的烃基,条件是i)R 1,R 2,R 4中的至少一个是羟基,m + n 为4至20,m为1-8且n为至少3,和ii)在式Ia中,至少一个OH基位于COOR0基团的间位或对位,和/或至少一个R 5基团为OH。
Abstract:
There are disclosed fuel compositions containing an additive formed by admixture of (i) at least one ethylene polymer, (ii) the product of the condensation reaction between an aldehyde or ketone or reactive equivalent thereof and at least one compound comprising one or more aromatic moieties having at least one substituent of the formula XR1 and one further substituent R2 wherein X is oxygen of sulfur, R1 is hydrogen or a moiety bearing at least one hydrocarbyl group and R2 represents a hydrocarbyl group and (iii) at least one oil soluble polar nitrogen compound different from the condensation product and having one or more substituents of the formula NR13 where R13 represents a hydrocarbyl group containing 8 to 40 carbon atoms.
Abstract:
The present invention relates to a synergistic mixture comprising, as asphaltene dispersant, from 5 to 95% by weight of a compound A of the formula I or II defined in the description, and from 5 to 95% by weight of a compound B of the formula (III) defined in the description, the substituents being defined as described in the description. The mixture is an excellent asphaltene dispersant in crude oils and products derived therefrom.
Abstract:
The present invention relates to crude oils and products derived therefrom comprising, as asphaltene dispersant, ethercarboxylic acids of the formulaRO(CH.sub.2 CHR.sub.1 O).sub.x (CH.sub.2 CHR.sub.2 O).sub.y CH.sub.2 --CO.sub.2 Hwhere the substituents have the meaning defined in the description.
Abstract:
This invention relates to metal salts of the general formulaA.sup.y- M.sup.y+ (I)wherein M represents one or more metal ions, y is the total valence of all M and A represents one or more anion containing groups having a total of about y individual anionic moieties and each antion containing group is a group of the formula ##STR1## wherein each group in (II) is as described in the specification. These salts find utility in lubricants and fuels other than 2-cycle engine lubricants and fuels.
Abstract:
A fuel composition for internal combustion engines, and more particularly, a fuel composition for internal combustion engines containing less than about 0.5 gram of lead per liter of fuel is described. The fuel composition comprises a major amount of a liquid hydrocarbon fuel and a minor, property improving amount of(A) at least one hydrocarbon-soluble alkali or alkaline earth metal-containing composition, and(B) at least one hydrocarbon-soluble ashless dispersant.When a mixture of the metal-containing composition (A) and the ashless dispersant (B) are incorporated into gasolines containing less than about 0.5 gram of lead per liter of fuel, the treated fuel exhibits improved stability and water tolerance, and when the unleaded or low lead-containing fuels of the present invention are utilized in internal combustion engines, there is a significant reduction in valve seat recession. Methods of reducing valve seat recession in internal combustion engines utilizing lead free or low lead-containing fuels also are described.
Abstract:
A composition comprising:(A) a first component selected from the group consisting of:(i) an oil-soluble ethylene backbone polymer having a number average molecular weight in the range of about 500 to about 50,000;(ii) a hydrocarbyl-substituted phenol of the formula(R*).sub.a --AR--(OH).sub.b I wherein R* is a hydrocarbyl group selected from the group consisting of hydrocarbyl groups of from about 8 to about 30 carbon atoms and polymers of at least 30 carbon atoms, Ar is an aromatic moiety having 0 to 4 optional substituents selected from the group consisting of lower alkyl, lower alkoxyl, nitro, halo or combinations of two or more of said optional substituents, and a and b are each independently an integer of 1 up to 5 times the number of aromatic nuclei present in Ar with the proviso that the sum of a and b does not exceed the unsatisfied valences of Ar;(iii) mixtures of (i) and (ii); and(B) as a second component, the reaction product of (B)(I) a hydrocarbyl-substituted carboxylic acylating agent with (B)(II) one or more amines, one or more alcohols, or a mixture of one or more amines and/or one or more alcohols, the hydrocarbyl substituent of said agent (B)(I) being selected from the group consisting of(i') one or more mono-olefins of from about 8 to about 30 carbon atoms;(ii') mixtures of one or more mono-olefins of from about 8 to about 30 carbon atoms with one or more olefin polymers of at least 30 carbon atoms selected from the group consisting of polymers of mono-1-olefins of from 2 to 8 carbon atoms, or the chlorinated or brominated analogs of such polymers; and(iii') one or more olefin polymers of at least 30 carbon atoms selected from the group consisting of(a) polymers of mono-olefins of from about 8 to about 30 carbon atoms;(b) interpolymers of mono-1-olefins of from 2 to 8 carbon atoms with mono-olefins of from about 8 to about 30 carbon atoms;(c) one or more mixtures of homopolymers and/or interpolymers of mono-1-olefins of from 2 to 8 carbon atoms with homopolymers and/or interpolymers of mono-olefins of from about 8 to about 30 carbon atoms; and(d) chlorinated or brominated analogs of (a), (b), or (c).
Abstract:
A composition comprising at least one fuel that is a diesel fuel, a biodiesel fuel, or combinations thereof and less than 100 ppm, less than 50 ppm (or less than 25 ppm, less than 10 ppm, 1 to 7 ppm, or 5 to 7 ppm) of an alkylene-coupled C10 to C60 (or C10 to C40, C14 to C32 or C24 to C28) alkylphenol; 25 to 500 ppm (or 50 to 500 ppm, or 150 to 450 ppm or 250 to 450 ppm, or 250 to 400 ppm) of a terpolymer; and 5 to 90 ppm, (or 10 to 70 ppm, to 60 ppm, or 10 to 55 ppm) of hydrocarbyl-substituted amine detergent having at least one tertiary amino group. Methods of reducing the cold filter plugging point (“CFPP”) of a fuel, said method comprising adding the following components: less than 100 ppm, less than 50 ppm (or less than 25 ppm; less than 10 ppm, 1 to 7 ppm, or 5 to 7 ppm) of an alkylene-coupled C10 to C60 (or C10 to C40, C14 to C32 or C24 to C28) alkylphenol; 25 to 500 ppm (or 50 to 500 ppm, or 150 to 450 ppm or 250 to 450 ppm, or 250 to 400 ppm) of a terpolymer; and 5 to 90 ppm, (or 10 to 70 ppm, to 60 ppm, or 10 to 55 ppm) of hydrocarbyl-substituted amine detergent having at least one tertiary amino group. Uses of a fuel additive composition to reduce the cold filter plugging point (“CFPP”) of a fuel, wherein the fuel additive composition comprises: 0.2 to 3 wt % of an alkylene-coupled C10 to C60 (or C10 to C40, C14 to C32 or C24 to C28) alkylphenol; 10 to 50 wt % of a terpolymer; and 2 to 10 wt % of hydrocarbyl-substituted amine detergent having at least one tertiary amino group; and an optional solvent.
Abstract:
An additive composition for a fuel comprises: (i) a metal compound selected from an iron compound, a manganese compound, a calcium compound, a cerium compound and mixtures thereof; (ii) an organic compound selected from a bicyclic monoterpene, substituted bicyclic monoterpene, adamantane, propylene carbonate and mixtures thereof; and (iii) a stabilizer. The additive composition allows fuels which are prone to separation, for example blended fuels or fuels having a high content of asphaltenes, to be used successfully.