Aqueous film forming preparations based on copolymers of methacrylic acid alkyl esters

    公开(公告)号:DE19810050A1

    公开(公告)日:1999-09-16

    申请号:DE19810050

    申请日:1998-03-09

    Applicant: BASF AG

    Abstract: Surprisingly aqueous preparations containing a copolymer P as completely or largely cross linked constituent comprising methacrylic acid alkyl esters, in which the bulk of methyl methacrylate monomer varies give coatings of gloss with increased stability over time. The coatings show good adhesions to mineral substrates and guarantee good protection against efflorescence. The use of an aqueous film forming preparation, for coating a mineral molded body, containing at least one copolymer P as film forming component dispersed in the preparation and ethylenically unsaturated monomers M is new. The monomer M comprises (wt. %): (i) 70-99 of at least one methacrylic acid ester with a 1-10C alkanol and (ii) 0.1-30 of at least one of different ethylenically unsaturated monomers, in which at least 50 wt. % of monomer M comprises methacrylic acid methyl ester, and at most 1 wt. % of monomer M contains two or more ethylenically unsaturated double bonds. Independent claims are included for: (1) A process for coating a mineral molded body with at least one aqueous film forming preparation; (2) a mineral molded body.

    113.
    发明专利
    未知

    公开(公告)号:BR9707573A

    公开(公告)日:1999-07-27

    申请号:BR9707573

    申请日:1997-02-19

    Applicant: BASF AG

    Abstract: PCT No. PCT/EP97/00768 Sec. 371 Date Aug. 21, 1998 Sec. 102(e) Date Aug. 21, 1998 PCT Filed Feb. 19, 1997 PCT Pub. No. WO97/31059 PCT Pub. Date Aug. 28, 1997A method for forming shaped products by mixing a formaldehyde-free aqueous binder comprising A) a free-radically polymerized polymer containing from 5 to 100% by weight of units derived from an ethylenically unsaturated acid anhydride or from an ethylenically unsaturated dicarboxylic acid whose carboxyl group can form an anhydride group, and B) an alkanolamine having at least two hydroxyl groups, with fibers or chips to form a shaped article, wherein said binder has a property of drying at 50 DEG C. in 72 hours to a film from 0.3 to 1 mm in thickness and, following a subsequent 15 minute cure at 130 DEG C. in air, has a gel content of above 50% by weight, wherein the binder includes less than 0.1% by weight, based on A)+B), of a phosphorus-containing reaction accelerant with fibers or chips.

    USING MICROCAPSULES AS LATENT HEAT STORAGE MEDIA

    公开(公告)号:CA2304476A1

    公开(公告)日:1999-05-20

    申请号:CA2304476

    申请日:1998-10-16

    Applicant: BASF AG

    Abstract: The invention relates to the application of microcapsules I with one or more lipophilic substances as core material. Said lipophilic substances have a solid/liquid phase transition at a temperature ranging from -20 to 120 ~C and a polymer which is used as a shell and can be obtained by means of radical polymerization of a monomer mixture containing 30 to 100 wt.%, referring to the total weight of the monomers, one or more C1-C24-alkyl esters of the acrylic acid and/or methylacrylic acid (monomer I), 0 to 80 wt.%, referring to the total weight of the monomers, one bi- or polyfuntional monomer (monomer II) which is insoluble or poorly soluble in water, and 0 to 40 wt.%, referring to the total weight of the monomers, and other monomers (monomer III). The microcapsules can be used as latent heat accumulators. The invention also relates to novel microcapsules Ia, spray-dried microcapsules Ia', methods for the production thereof, and to shaped bodies and coating masses containing said microcapsules.

    Formaldehyde-free binder for mouldings

    公开(公告)号:AU1874597A

    公开(公告)日:1997-09-10

    申请号:AU1874597

    申请日:1997-02-19

    Applicant: BASF AG

    Abstract: PCT No. PCT/EP97/00768 Sec. 371 Date Aug. 21, 1998 Sec. 102(e) Date Aug. 21, 1998 PCT Filed Feb. 19, 1997 PCT Pub. No. WO97/31059 PCT Pub. Date Aug. 28, 1997A method for forming shaped products by mixing a formaldehyde-free aqueous binder comprising A) a free-radically polymerized polymer containing from 5 to 100% by weight of units derived from an ethylenically unsaturated acid anhydride or from an ethylenically unsaturated dicarboxylic acid whose carboxyl group can form an anhydride group, and B) an alkanolamine having at least two hydroxyl groups, with fibers or chips to form a shaped article, wherein said binder has a property of drying at 50 DEG C. in 72 hours to a film from 0.3 to 1 mm in thickness and, following a subsequent 15 minute cure at 130 DEG C. in air, has a gel content of above 50% by weight, wherein the binder includes less than 0.1% by weight, based on A)+B), of a phosphorus-containing reaction accelerant with fibers or chips.

    120.
    发明专利
    未知

    公开(公告)号:DE3585248D1

    公开(公告)日:1992-03-05

    申请号:DE3585248

    申请日:1985-08-12

    Applicant: BASF AG

    Abstract: Polymers contg. mesogenic gps. are made up of polymer chairs contg. mesogenic gps., to which are bound side chains which each contain a mesogenic gp.. Pref. the mesogenic gps. in the polymer chain are bonded together via aliphatic or araliphatic gps. contg. hetero atoms in the chain, or by aromatic gps., and the side chains contg. mesogenic gps. are bound to the aliphatic, araliphatic or aromatic gps. in the polymer chain or to the mesogenic gps. in the polymer chain, pref. where the mesogenic gps. in the side chains are each bound to the polymer chain via an aliphatic gp. with hetero atoms in the chain with up to 12 chain members.

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