Abstract:
PROBLEM TO BE SOLVED: To provide novel polymers containing carboxyl groups and polyalkylene ether side-chains. SOLUTION: The water-soluble or water-dispersible polymers containing carboxyl groups and the side-chains represented by formula (I) is obtained by radically copolymerizing the polymer having carboxyl groups on the monomers to be polymerized, 3 to 50 wt.% of an ethylenic unsaturated monomers A selected from the group consisting of ethylenic unsaturated 3-6C mono-carboxylic acids and their salts, 50 to 97 wt.% of an ethylenic unsaturated monomers B bearing the side-chains of formula I in the presence of 0.1 to 50 wt.% of a phosphorus-containing compounds such as phosphinic acid or phosphonic acid. The resultant polymer has a weight average molecular (Mw) of 5000 to 150000 dalton. The polymer has favorite property as an additive for mineral building materials. COPYRIGHT: (C)2008,JPO&INPIT
Abstract:
The invention relates to cleaner formulations and to the use of said cleaner formulations for preventing plastic articles from discoloring when cleaned in a dishwasher. The cleaner formulations comprise the following components: a) copolymers containing a1) 10 to 60 % by weight of at least one monomer component (A) from the group of the monoethylenically unsaturated C3-C10 mono- or dicarboxylic acids or the anhydrides thereof; a2) 40 to 90 % by weight of at least one monomer component (B) of the general formula (I), wherein R , R and R independently represent H, CH3, C2H5, C3H7, COOH or OH, Y represents -C(=O)-, -C(=O)-O-, -O-, -O-C(=O)-, -O-C(=O)-O- or -C(=O)-NH-, n equals 0 or 1, R is a linear or branched, cyclic or acyclic aliphatic group with 7 to 100 carbon atoms; and a3) 0 to 30 % by weight of at least one further monomer component (C) that can be copolymerized with the monomer components (A) and (B) and that is selected from the group consisting of C1-C6 (meth)acrylic esters, C1-C6 vinylethers, C2-C8 olefins, styrenes, acrylnitriles, acrylamides, vinylformamides, allylalcohols, vinylphosphonates, vinyl-substituted heterocycles and unsaturated organosulfonic acids; b) a bleaching system that comprises at least one component of the group consisting of bleaching agents, bleaching activators and bleaching catalysts.
Abstract:
The present invention relates to the use of water soluble or water dispersible polymers containing carboxyl groups, optionally in latent form, and side-chains of general formula (I): -X-Y-[-O-(-Alk-O)n-R]k as additives in mineral building materials, wherein X, Y, Alk, R, n and k have the meanings cited in Claim 1. Said polymers can be obtained by polymerizing ethylenically unsaturated monomers in the presence of compounds containing phosphorus and, optionally, by additional polymer-analogous transformation. The invention further relates to the production of said polymers and the use thereof. Also described are polymers, which can be obtained by polymerizing aromatic vinyl compounds, olefins, cycloolefins and/or dienes, as D monomers and anhydrides of ethylenically unsaturated dicarboxylic acids as E monomers, and which can be used both as parent compounds for the above-mentioned polymers and as additives for mineral building materials.00000
Abstract:
The present invention relates to the use of water soluble or water dispersible polymers containing carboxyl groups, optionally in latent form, and side-chains of general formula (I) -X-Y-[-O-(-Alk-O) n -R] k as additives in mineral building materials, wherein X, Y, Alk, R, n and k have the meanings cited in claim 1. Said polymers can be obtained by polymerizing ethylenically unsaturated monomers in the presence of compounds containing phosphorus and, optionally, by additional polymer-analogous transformation. The invention further relates to the production of said polymers and the use thereof. Also described are polymers, which can be obtained by polymerizing aromatic vinyl compounds, olefins, cycloolefins and/or dienes, as D monomers and anhydrides of ethylenically unsaturated dicarboxylic acids as E monomers and which can be used both as parent compounds for the above-mentioned polymers and as additives for mineral building materials.
Abstract:
In a process for producing self-releasing, compact or cellular moldings which comprise polyisocyanate polyaddition products and may contain reinforcing material by reactinga) organic and/or modified organic polyisocyanates withb) at least one compound containing at least two reactive hydrogen atoms and having a molecular weight of from 62 to 10,000 and, if desired,c) chain extenders and/or crosslinkers in the presence ofd) internal mold release agents and in the presence of or absence ofe) catalysts,f) blowing agents,g) reinforcing materials andh) auxiliariesin an open or closed mold, the internal mold release agents (d) used are diesters and/or monoesters of alkylsuccinic acids and/or diesters and/or monoesters of alkenylsuccinic acids.
Abstract:
Aqueous solutions or dispersions of copolymers obtainable by free-radical copolymerization of(a) from 20 to 90% by weight of at least one monoethylenically unsaturated C4-6-dicarboxylic acid or the anhydride thereof, as component A,(b) from 5 to 50% by weight of at least one olefin having 2 to 6 carbon atoms, as component B,(c) from 5 to 50% by weight of at least one hydrophobic comonomer from the group consisting of long-chain olefins, esters of long-chain alcohols with acrylic acid or methacrylic acid, long-chain amides of acrylic acid or methacrylic acid, and long-chain alkyl vinyl ethers, as component C,(d) from 0 to 40% by weight of further comonomers which can be copolymerized with the above monomers, as component D,where the sum of the amounts of components A, B, C and, if used, D is 100% by weight, followed by at least partial esterification or hydrolysis and neutralization and/or reaction of the carboxyl groups formed during the hydrolysis with bases, for treating leather and/or fur skins.
Abstract:
PCT No. PCT/EP97/00773 Sec. 371 Date Aug. 19, 1998 Sec. 102(e) Date Aug. 19, 1998 PCT Filed Feb. 19, 1997 PCT Pub. No. WO97/31060 PCT Pub. Date Aug. 28, 1997The use of a formaldehyde-free aqueous binder comprising A) a polymer obtained by free-radical polymerization comprising 5-100% by weight of an ethylenically unsaturated acid anhydride or of an ethylenically unsaturated dicarboxylic acid whose carboxyl groups may form an anhydride group, and B) an alkanolamine having at least two hydroxyl groups as a coating composition for shaped articles.
Abstract:
PCT No. PCT/EP97/00768 Sec. 371 Date Aug. 21, 1998 Sec. 102(e) Date Aug. 21, 1998 PCT Filed Feb. 19, 1997 PCT Pub. No. WO97/31059 PCT Pub. Date Aug. 28, 1997A method for forming shaped products by mixing a formaldehyde-free aqueous binder comprising A) a free-radically polymerized polymer containing from 5 to 100% by weight of units derived from an ethylenically unsaturated acid anhydride or from an ethylenically unsaturated dicarboxylic acid whose carboxyl group can form an anhydride group, and B) an alkanolamine having at least two hydroxyl groups, with fibers or chips to form a shaped article, wherein said binder has a property of drying at 50 DEG C. in 72 hours to a film from 0.3 to 1 mm in thickness and, following a subsequent 15 minute cure at 130 DEG C. in air, has a gel content of above 50% by weight, wherein the binder includes less than 0.1% by weight, based on A)+B), of a phosphorus-containing reaction accelerant with fibers or chips.
Abstract:
PCT No. PCT/EP97/00770 Sec. 371 Date Aug. 18, 1998 Sec. 102(e) Date Aug. 18, 1998 PCT Filed Feb. 19, 1997 PCT Pub. No. WO97/31036 PCT Pub. Date Aug. 28, 1997Formaldehyde-free aqueous binders comprise A) a polymer containing from 5 to [lacuna]% by weight of units derived from an ethylenically unsaturated acid anhydride or from an ethylenically unsaturated dicarboxylic acid whose carboxyl groups can form an anhydride group, and B) an alkanolamine having at least two hydroxyl groups.
Abstract:
PCT No. PCT/EP97/00768 Sec. 371 Date Aug. 21, 1998 Sec. 102(e) Date Aug. 21, 1998 PCT Filed Feb. 19, 1997 PCT Pub. No. WO97/31059 PCT Pub. Date Aug. 28, 1997A method for forming shaped products by mixing a formaldehyde-free aqueous binder comprising A) a free-radically polymerized polymer containing from 5 to 100% by weight of units derived from an ethylenically unsaturated acid anhydride or from an ethylenically unsaturated dicarboxylic acid whose carboxyl group can form an anhydride group, and B) an alkanolamine having at least two hydroxyl groups, with fibers or chips to form a shaped article, wherein said binder has a property of drying at 50 DEG C. in 72 hours to a film from 0.3 to 1 mm in thickness and, following a subsequent 15 minute cure at 130 DEG C. in air, has a gel content of above 50% by weight, wherein the binder includes less than 0.1% by weight, based on A)+B), of a phosphorus-containing reaction accelerant with fibers or chips.