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111.
公开(公告)号:CA2049312A1
公开(公告)日:1990-09-23
申请号:CA2049312
申请日:1990-03-21
Applicant: HOECHST AG
Inventor: ESCHER CLAUS , DUEBAL HANS-ROLF , HARADA TAKAMASA , HEMMERLING WOLFGANG , ILLIAN GERHARD , MUELLER INGRID , MURAKAMI MIKIO , OHLENDORF DIETER , WINGEN RAINER
Abstract: HOE 89/F 094 of the disclosure Ferroelectric liquid-crystal systems having high spontaneous polarization and good orientation properties Ferroelectric liquid-crystal system having high spontaneous polarization, in particular > 35 nC cm-2, and good orientation properties in the ferroelectric phase, in particular the Sc* phase, contain at least three different optically active compounds, preferably as dopes in a base mixture which is not itself optically active and has a nematic phase above the smectic phase. The optically active compounds are selected so that they do not all induce a helix of the same rotation sense in the nematic phase. Their relative concentrations are selected so that the total resultant pitch of the helix throughout the cholesteric phase is not less than 10 .mu.m.
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公开(公告)号:NO902795D0
公开(公告)日:1990-06-22
申请号:NO902795
申请日:1990-06-22
Applicant: HOECHST AG
Inventor: ESCHER CLAUS , HEMMERLING WOLFGANG , ILLIAN GERHARD , HARADA TAKAMASA , MURAKAMI MIKIO
Abstract: Liquid-crystalline materials are becoming increasingly important in electrooptical switching and display devices. Recently, ferroelectric liquid-crystalline mixtures have also been investigated widely and employed in displays. A particularly important physical parameter for describing FLC mixtures is the spontaneous polarisation (Ps). On the one hand, a high spontaneous polarisation results in short response times, but on the other hand, high Ps values result in optical hysteresis, which causes, inter alia, so-called "ghost images". The use of FLC mixtures of high spontaneous polarisation (Ps 20 nC/cm ) and a natural helical pitch of less than half the layer thickness in an SSFLC display having a layer thickness of from 1 to 10 mu m allows the problem of optical hysteresis to be circumvented, in spite of the high spontaneous polarisation. FLC mixtures in which Ps is > 40 nC/cm can also be switched under these conditions.
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公开(公告)号:DE69128625D1
公开(公告)日:1998-02-12
申请号:DE69128625
申请日:1991-07-17
Applicant: HOECHST AG
Inventor: MURAKAMI MIKIO , HARADA TAKAMASA
IPC: C08G63/60 , C09K19/02 , C09K19/56 , G02F1/1337
Abstract: PCT No. PCT/EP91/01339 Sec. 371 Date Jan. 12, 1993 Sec. 102(e) Date Jan. 12, 1993 PCT Filed Jul. 17, 1991 PCT Pub. No. WO92/01728 PCT Pub. Date Feb. 6, 1992.A liquid-crystal display device having a liquid-crystal layer held between a pair of substrates each having a transparent electrode and an alignment film formed successively on the inner surface, characterized in that the material of the alignment film on at least one of the opposing faces between the substrates is a polymer having recurring units (I, II and III), the recurring unit (I) being represented by formula (A), (A) recurring unit II being a dioxyaryl portion represented by the formula -O-Ar-O- (where Ar is a divalent group having at least one aromatic ring which may contain at least one substituent selected from a C1-4 alkyl group, a C1-4 alkoxy group, a halogen, a phenyl and a substituted phenyl), and recurring unit (III) being a dicarboxyaryl portion represented by formula (B) (B) (where Ar' may be the same as or different from Ar and has the same meaning as Ar).
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公开(公告)号:DE59009244D1
公开(公告)日:1995-07-20
申请号:DE59009244
申请日:1990-03-21
Applicant: HOECHST AG
Inventor: DUEBAL HANS-ROLF , ESCHER CLAUS , HARADA TAKAMASA , HEMMERLING WOLFGANG , ILLIAN GERHARD , MUELLER INGRID , MURAKAMI MIKIO NEW TOWN BLG , OHLENDORF DIETER , WINGEN RAINER
Abstract: PCT No. PCT/EP90/00457 Sec. 371 Date Oct. 28, 1991 Sec. 102(e) Date Oct. 28, 1991 PCT Filed Mar. 21, 1990 PCT Pub. No. WO90/11335 PCT Pub. Date Oct. 4, 1990.The novel ferroelectric liquid-crystalline mixtures are based on at least two mixture components of the general formula (I) (I) but additionally contain at least one optically active dope from one or more of the following groups a) optically active esters of tetrahydrofuran-2-carboxylic acid b) optically active aryl 2,3-epoxyalkyl ethers c) optically active 1,3-dioxolan-4-yl ethers. The ferroelectric LC mixtures have a high spontaneous polarization and facilitate substantial compensation of the pitch of the helix in a nematic phase.
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公开(公告)号:NO924808A
公开(公告)日:1993-02-01
申请号:NO924808
申请日:1992-12-11
Applicant: HOECHST AG
Inventor: HARADA TAKAMASA , ESCHER CLAUS , ILLIAN GERHARD , OHLENDORF DIETER , RIEGER HEINZ , ROESCH NORBERT
IPC: C09K19/52 , G02F20060101 , G02F1/1341
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公开(公告)号:NO930157L
公开(公告)日:1993-01-18
申请号:NO930157
申请日:1993-01-18
Applicant: HOECHST AG
Inventor: BLATTER KARSTEN , ESCHER CLAUS , HARADA TAKAMASA , HARNISCHFEGER PETER , HEMMERLING WOLFGANG
IPC: C07D20060101 , C07D405/12 , C09K19/34 , C09K19/58
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公开(公告)号:NO930157A
公开(公告)日:1993-01-18
申请号:NO930157
申请日:1993-01-18
Applicant: HOECHST AG
Inventor: BLATTER KARSTEN , ESCHER CLAUS , HARADA TAKAMASA , HARNISCHFEGER PETER , HEMMERLING WOLFGANG
IPC: C07D20060101 , C07D405/12 , C09K19/34 , C09K19/58
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公开(公告)号:NO924720L
公开(公告)日:1992-12-07
申请号:NO924720
申请日:1992-12-07
Applicant: HOECHST AG
Inventor: HARADA TAKAMASA , ESCHER CLAUS , ILLIAN GERHARD , OHLENDORF DIETER , RIEGLER HEINZ , ROESCH NORBERT
IPC: G02F20060101 , G02F1/1341
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公开(公告)号:HU9201418D0
公开(公告)日:1992-09-28
申请号:HUP9201418
申请日:1990-11-26
Applicant: HOECHST AG
Inventor: ESCHER CLAUS , HARADA TAKAMASA , ROESCH NORBERT , ILLIAN GERHARD , WINGER RAINER
IPC: C09K20060101 , C09K19/02 , C09K19/34 , C09K19/52 , C09K19/58
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公开(公告)号:NO922978D0
公开(公告)日:1992-07-28
申请号:NO922978
申请日:1992-07-28
Applicant: HOECHST AG
Inventor: ILLIAN GERHARD , MUELLER INGRID , HARADA TAKAMASA
IPC: C07C13/16 , C07C69/86 , C07C15/02 , C07C43/20 , C07C69/92 , C07C69/94 , C07C69/96 , C07D20060101 , C07D213/30 , C07D239/26 , C07D239/34 , C07D239/38 , C07D285/12 , C07D405/12 , C07D417/12 , C07F7/08 , C09K19/08 , C09K19/20 , C09K19/34 , C09K19/42 , C09K19/46 , G02F1/13 , C07D
Abstract: PCT No. PCT/EP91/00129 Sec. 371 Date Jul. 24, 1992 Sec. 102(e) Date Jul. 24, 1992 PCT Filed Jan. 24, 1991 PCT Pub. No. WO91/11441 PCT Pub. Date Aug. 8, 1991.Geminal dimethylalkyl compounds, process for their preparation and their use in liquid-crystalline mixtures Geminal dimethylalkyl compounds of the formula (I) (I) in which: R1 is, for example, straight-chain or branched (with or without an asymmetric carbon atom) alkyl or alkenyl having 2 to 16 carbon atoms, A1, A2 and A3 are, for example, identical or different 1,4-phenylene, 1,4-cyclohexylene or pyrimidine-2,5-diyl, M1 and M2 are, for example, identical or different CO-O or O-CO, G is for example, identical or different straight-chain or branched alkylene having 1 to 16 carbon atoms, k, l, m and n are zero or 1, and R6 is straight-cain alkyl having 1 to 10 carbon atoms, can advantageously be employed in liquid-crystalline mixtures. In liquid-crystalline mixtures, said compounds result in a melting point depression, in a shift in the temperature limit of the Sc phase in ferroelectric mixtures and in other improvements of important electrooptical characteristic values.
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