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公开(公告)号:JPH04230735A
公开(公告)日:1992-08-19
申请号:JP19977591
申请日:1991-04-22
Applicant: HOECHST AG
Inventor: HANSUURORUFU DEYUBARU , HARADA TAKAMASA , HAINTSU RIIGAA , NORUBERUTO REESHIYU , PEETAA BUEEGENAA
IPC: C09K19/00 , G02F1/13 , G02F1/133 , G02F1/1337
Abstract: PURPOSE: To make it possible to improve the contrast and brightness of images by using a compd. having hydrophilicity and lipophilic in combination as oriented layers. CONSTITUTION: This liquid crystal display has a transparent outer plate, electrodes, polarizers, ferroelectric liquid crystal media and the oriented layers. The oriented layers contain components having the hydrophilicity and lipophilicity. Namely, the oriented layers which are originally hydrophilic and lipophilic are subjected to a treatment to make these components to amphoteric compds. or the amphoteric compds. are chemically bonded to the oriented layers, by which these layers are made amphoteric. The amphoteric compds. have surfactant-like properties and the oriented layers made amphoteric improve the contrast of the display, thereby brightening the images.
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公开(公告)号:JPH04225090A
公开(公告)日:1992-08-14
申请号:JP8023391
申请日:1991-04-12
Applicant: HOECHST AG
Inventor: HARADA TAKAMASA , NORUBERUTO REESHIYU , PEETAA BUEEGENAA
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公开(公告)号:JP2511607B2
公开(公告)日:1996-07-03
申请号:JP51274191
申请日:1991-07-19
Applicant: HOECHST AG
Inventor: BURATSUTAA KARUSUTEN , ETSUSHAA KURAUSU , HARADA TAKAMASA , HARUNISHUFUEGAA PEETAA , HEMAARINKU UORUFUGANGU
IPC: C07D405/12 , C09K19/34 , C09K19/58 , G02F1/13
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公开(公告)号:JPH03296021A
公开(公告)日:1991-12-26
申请号:JP15660090
申请日:1990-06-14
Applicant: HOECHST AG
Inventor: KURAUSU ETSUSHIYAA , GEEAHARUTO IRIAN , NORUBERUTO REESHIYU , HARADA TAKAMASA
IPC: G02F1/133 , C07D225/02 , C07D273/08 , C07D323/00 , C07D405/12 , C07D498/08 , C09K19/54 , C09K19/56 , G02F1/13 , G02F1/1337 , G02F1/137 , G02F1/141 , G09F9/35
Abstract: PURPOSE: To inexpensively obtain a shock-resistant liquid crystal switching element and a display device by using a ferroelectric liquid crystal mixture containing an olephilic compd. for a liquid crystal material and applying continuous and periodical voltage till the liquid crystal layer shows bookshelf orientation or quasi-bookshelf orientation before starting the operation. CONSTITUTION: This switching element consists of two supporting plates having at least one orienting layer, at least one polarizer attached to the supporting plate, and a liquid crystal material injected into the space between the two supporting plates. The liquid crystal material to be used here consists of a ferroelectric liquid crystal mixture containing at least one kind of a liquid crystal basic component and at least one kind of an olephilic compd. added to the component. Before starting up the element, continuous and periodical voltage is applied on electrodes of the switching element or a display device till the liquid crystal layer shows bookshelf or quasi-bookshelf orientation. Thereby, the obtd. liquid crystal switching element and the display device have excellent shock resistance and can be produced at a low cost.
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公开(公告)号:JPH0338623A
公开(公告)日:1991-02-19
申请号:JP16654390
申请日:1990-06-25
Applicant: HOECHST AG
Inventor: KURAUSU ETSUSHIYAA , BUORUFUGANGU HEMAARINKU , GEEAHARUTO IRIAN , HARADA TAKAMASA , MURAKAMI MIKIO
Abstract: PURPOSE: To provide a ferroelectric liquid crystal(FLC) display which does not exhibit an optical hysteresis even if the value of spontaneous polarization is high by using an FLC mixture having the high spontaneous polarization and the natural spiral pitch smaller than half the thickness of the layer. CONSTITUTION: The FLC display, which can be operated by using a surface stabilized ferroelectric liquid crystal SSFLC technique, is of 1 to 10μm and more particularly 1.2 to 3μm in the thickness of the layer. The ferroelectric liquid crystal(FLC) mixture which exhibits the high spontaneous polarization PS>20nC.cm (measured at 25 deg.C) and of which the natural spiral pitch is below half the thickness of the layer of the SSFLC display is utilized for the FLC display. The characteristics exhibiting the high spontaneous polarization, the first assigned spiral pitch at a smectic phase and the second assigned spiral pitch as a cholesteric phase are satisfied by an asymmetrical liquid crystal base mixture added with a slight amt. of symmetrical additive impurities. The preferable compds. in this asymmetrical liquid crystal base mixture are expressed by formulas (I) and (II).
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公开(公告)号:JPH04227685A
公开(公告)日:1992-08-17
申请号:JP33702490
申请日:1990-11-30
Applicant: HOECHST AG
Inventor: KURAUSU ETSUSHIYAA , HARADA TAKAMASA , GEEAHARUTO IRIAN , MURAKAMI MIKIO , NORUBERUTO REESHIYU , PEETAA BUEEGENAA , RAINAA BUINGEN
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公开(公告)号:JPH03115241A
公开(公告)日:1991-05-16
申请号:JP12396090
申请日:1990-05-14
Applicant: HOECHST AG
Inventor: ARUMIIN DE MAIIERE , HANSUURORUFU DEYUUBARU , KURAUSU ETSUSHIYAA , HARADA TAKAMASA , BUORUFUGANGU HEMAARINKU , GEEAHARUTO IRIAN , INGURITSUTO MIYUURAA , MURAKAMI MIKIO , DEIITAA OORENDORUFU , RAINAA BUINGEN
IPC: G02F1/13 , C07C13/04 , C07C13/28 , C07C22/00 , C07C25/00 , C07C43/184 , C07C43/205 , C07C43/21 , C07C69/92 , C07C255/45 , C07D213/30 , C07D237/08 , C07D237/14 , C07D237/16 , C07D237/18 , C07D239/26 , C07D239/34 , C07D239/38 , C07D241/12 , C07D241/18 , C07D285/12 , C07D285/125 , C07D285/13 , C07D405/12 , C09K19/20 , C09K19/30 , C09K19/34
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公开(公告)号:JPH03180815A
公开(公告)日:1991-08-06
申请号:JP15659990
申请日:1990-06-14
Applicant: HOECHST AG
Inventor: HANSUURORUFU DEYUUBARU , KURAUSU ETSUSHIYAA , HARADA TAKAMASA , GEEAHARUTO IRIAN , MURAKAMI MIKIO , HAINTSU RIIGAA , NORUBERUTO REESHIYU , PEETAA BUEEGENAA , RAINAA BUINGEN
IPC: G02F1/1337
Abstract: PURPOSE: To improve the lightness, contrast and switching of a liq. crystal display by incorporating a lipophilic compd., a lipophilic property imparting compd. or its mixture into at least one of the constituent elements of the liq. crystal display. CONSTITUTION: In order to improve the max. lightness, max. contrast and display speed of a liq. crystal display, an orienting layer of polyimide or polyamide as one of the constituent elements of the display is composed of 50-99.99wt.% polyimide or polyamide and 0.01-50wt.% one or more kinds of lipophilic compds. or lipophilic property imparting compds. The compds. may be incorporated into an insulating layer, an electrode, a transparent substrate or a polarizing plate. The lipophilic compds. may be monomer, oligomer or polymer compds. and have low polarity and high lipophilic characteristics.
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公开(公告)号:JPH03149289A
公开(公告)日:1991-06-25
申请号:JP20906490
申请日:1990-08-06
Applicant: HOECHST AG
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公开(公告)号:JPH0369921A
公开(公告)日:1991-03-26
申请号:JP20748890
申请日:1990-08-04
Applicant: HOECHST AG
Inventor: KURAUSU ETSUSHIYAA , HANSUURORUFU DEYUUBARU , MIHAERU FUERUTOFUESU , HARADA TAKAMASA , GEEAHARUTO IRIAN , TOMASU MEKURENBURUKU , MURAKAMI MIKIO , DEIITAA OORENDORUFU , KARURU PANPUSU
IPC: C08G61/12 , G02F1/1337 , G02F1/141 , G09F9/35
Abstract: PURPOSE: To effectively suppress optical hysteresis by using a specified liq. crystal switch and a specified display element in a ferroelectric liq. crystal medium display. CONSTITUTION: The liq. crystal switch and display element are used in a display. The display element consists of a ferroelectric liq. crystal medium(FLC), two electrodes, one polarizer, two transparent carrier plates and one orienting layer. This orienting layer has direct electric connection with the electrodes and contains an electrically conductive polymer having repeating untis represented by formula I, wherein each of R and R is H, 1-16C alkyl, 1-16C alkoxy or halogen, X is S or NH, Y is BF4 , PF5 , PO4 , etc., (n) is an integer of 4-100 and (m) is an integer of 1-30. Optical hysteresis phenomenon in the FLC is suppressed.
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