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公开(公告)号:JPS6391387A
公开(公告)日:1988-04-22
申请号:JP25005087
申请日:1987-10-05
Applicant: HOECHST AG
Inventor: HEMMERLING WOLFGANG , DUEBAL HANS-ROLF , MUELLER INGRID , OHLENDORF DIETER , WINGEN RAINER
IPC: C07D405/12 , C07D409/12 , C09K19/34 , C09K19/58 , G02F1/13
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公开(公告)号:NO172985C
公开(公告)日:1993-10-06
申请号:NO892983
申请日:1989-07-20
Applicant: HOECHST AG
Inventor: SCHEROWSKY GUENTER , GAY JUERGEN , WINGEN RAINER , DUEBAL HANS ROLF , ESCHER CLAUS , HEMMERLING WOLFGANG , INOGUSCHI YOSHIO , MUELLER INGRID , OHLENDORF DIETER
IPC: G02F1/13 , C07D317/22 , C07D317/24 , C07D317/36 , C07D317/72 , C07D405/12 , C07D405/14 , C07D407/12 , C07D409/12 , C07D409/14 , C07D417/12 , C07D417/14 , C09K19/34 , C09K19/54 , C09K19/58 , G02F1/137 , G02F1/33 , C07D317/34
Abstract: Optically active 1,3-dioxolane derivates of the general formula which carry a mesogenic radical in the 4-position are suitable as dopes in - in particular ferroelectric - liquid-crystal mixtures. The symbols in the general formula have the following meanings: R has a structure analogous to the moiety of the general formula on the right of X or is an alkyl or alkylene radical, which may be substituted, R , R and R are H or alkyl (R is alternatively alkenyl), which may also be substituted [R and R , together with the C(2) of the dioxolane ring, may alternatively be cycloaliphatic or keto groups], j, l and n are zero, 1 or 2, and k and m are zero or 1, with the proviso that n is zero if k is zero, m is zero if n is zero, and 1 , -A and -A are an aromatic, heterocyclic or aliphatic ring system, -M and -M are -CO-O, -O-CO, -CH2CH2, -CH=CH, -CH2O, -OCH2 or -C IDENTICAL C and X is O, S or O-CO-O. The particular advantage of the compounds of the general formula (I) is that they are able to induce a high twisting power in the cholesteric phase, but without significantly affecting the magnitude of the spontaneous polarisation already present in the mixture in the smectic C phase. They are therefore suitable for pitch compensation, in particular for ferroelectric liquid-crystal mixtures.
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公开(公告)号:NO930027D0
公开(公告)日:1993-01-06
申请号:NO930027
申请日:1993-01-06
Applicant: HOECHST AG
Inventor: TETZLAFF HERIBERT , MUELLER INGRID , RITTNER SIEGBERT , WINGEN RAINER
IPC: C07D20060101 , C07D
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公开(公告)号:NO170801C
公开(公告)日:1992-12-09
申请号:NO872266
申请日:1987-05-29
Applicant: HOECHST AG
Inventor: HEPPKE GERD , BAHR CHRISTIAN , MUELLER INGRID , OHLENDORF DIETER , WINGEN RAINER
IPC: C07D239/26 , C07D239/34 , C07D239/38 , C09K19/20 , C09K19/22 , C09K19/34 , C07D319/06 , C07D339/08 , C09K19/58 , G02F1/13 , G09F9/35
Abstract: The novel compounds are chiral esters formed from alpha -substituted carboxylic acids and mesogenic hydroxyl compounds of the general formula (I) (I) in which the symbols have the following meaning: MO=molecular radical of a mesoganic hydroxyl compound MOH after removing an H, the radial MO being expressed by the general formula (II): R2-(A1)n1-(B-)(n2(A2)(n3-O(II) where the meaning of R2 is a straight-chain or branched (C1-C12)alkyl or alkenyl, it being possible for one or two nonadjacent CH2 groups to be replaced by O and/or S atoms, or if n1=1, also F, Cl, Br or CN, A1, A2 are, independently of each other, 1,4-phenylene, pyrimidine-2,5-diyl, 1,4-cyclohexylene, 1,3-dioxane-2,5-diyl, 1,3-dithiane-2,5-diyl, or 1,4-bicyclo(2,2,2)octylene, it being possible for said groups to be substituted at least singly by F, Cl, Br, CN and/or (C1-C12)alkyl (optionally, one or two nonadjacent CH2 groups are replaced by O and/or S atoms), B is CO-O, O-CO, CH2-CH2, OCH2, CH2O, CH=N, N=CH, N=N N(O)=N, n1, n2, n3 are, independently of each other, 0, 1 or 2, n1 and n3 not being simultaneously 0, Y is F, Cl, Br, CN or CF3, and R1 is branched, (C3-C9)alkyl, benzyl or phenyl, the compounds having R1=branched (C3-C7)alkyl, benzyl or phenyl, Y=F, Cl or Br, R2=(C1-C11)alkoxy, A1, A2= n1, n3=1 and n2=0 being excluded. The compounds preferably find application in tilted smectic liquid-crystalline phases which they transform into ferroelectric liquid-crystalline phases; they have high values of spontaneous polarization.
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公开(公告)号:NO170416C
公开(公告)日:1992-10-14
申请号:NO874177
申请日:1987-10-05
Applicant: HOECHST AG
Inventor: HEMMERLING WOLFGANG , DUEBAL HANS-ROLF , MUELLER INGRID , OHLENDORF DIETER , WINGEN RAINER
IPC: C07D405/12 , C07D409/12 , C09K19/34 , C09K19/58 , G02F1/13
Abstract: The novel compounds are aryl-2,3-epoxyalkyl ethers or thioethers or the corresponding thiirane compounds having a mesogenic aromatic component and a chiral component having a three-membered heterocyclic ring, wherein, in the general formula (1), (I) the symbols have the following meaning: R1=straight-chain or branched (C1-C12) alkyl, where one or two non-neighboring CH2 groups may be replaced by O or S atoms. A=diazine-2,5-diyl or diazine-3,6-diyl, X and Y=O and/or S, and R2, R3 and R4, independently of one another=H, straight-chain (C1-C10) alkyl or branched (C3-C10) alkyl, where R2, R3 and R4 are not simultaneously H. The compounds are preferably employed in tilted smectic liquid-crystal phases which they convert into ferroelectric liquid-crystal phases; they have high values for spontaneous polarization or they induce high values for spontaneous polarization.
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公开(公告)号:DE3775934D1
公开(公告)日:1992-02-20
申请号:DE3775934
申请日:1987-11-02
Applicant: HOECHST AG
Inventor: WINGEN RAINER , DUEBAL HANS-ROLF , HEMMERLING WOLFGANG , MUELLER INGRID , OHLENDORF DIETER
IPC: C04B35/64 , B22F3/14 , B22F3/15 , B23B27/14 , C04B35/10 , C04B35/56 , C04B35/58 , C04B35/645 , C04B35/80 , C04B35/81 , C04B41/50 , C04B41/52 , C04B41/87 , C04B41/89 , C07C20060101 , C07C69/712 , C07C69/773 , C07C69/92 , C07D239/26 , C07D239/34 , C07D405/12 , C09K19/20 , C09K19/54 , C09K19/58 , G02F1/13
Abstract: New chiral aryloxypropionate esters are of formula (I), where R1 = linear 1-16C alkyl or alkoxy or branched 4-16C alkyl or alkoxy, in which one or 2 non-adjacent CH2 gps. can be replaced by S and/or O; A = 1, 2 or 3 (hetero)aromatic rings, joined directly or through one or 2 COO gps.; B = a chemical bond or 1 or 2 (hetero)aromatic rings, joined directly; (a) if B = a chemical bond, R2 = linear 1-15C alkyl, in which one or 2 non-adjacent CH2 gps. can be replaced by O and/or S, or 2-10C alkyl contg. an asymmetrical C atom, which, is substd. with CH3, halogen or -COOC2H5, or 3-10C alkyl contg. 2 adjacent asymmetrical C atoms, one of which is substd. with halogen and the other with CH3, or which together with an O atom form an oxirane ring; or (b) if B = (hetero)aromatic ring(s), R2 = alkyl or alkoxy as in (a).
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公开(公告)号:NO913696A
公开(公告)日:1991-09-19
申请号:NO913696
申请日:1991-09-19
Applicant: HOECHST AG
Inventor: ESCHER CLAUS , DUEBAL HANS-ROLF , HARADA TAKAMASA , HEMMERLING WOLFGANG , ILLIAN GERHARD , MUELLER INGRID , MURAKAMI MIKIO , OHLENDORF DIETER , WINGEN RAINER
IPC: C09K19/34 , G02F20060101 , G02F1/137
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公开(公告)号:NO913463L
公开(公告)日:1991-09-03
申请号:NO913463
申请日:1991-09-03
Applicant: HOECHST AG
Inventor: MUELLER INGRID , DUEBAL HANS-ROLF , ESCHER KLAUS , HEMMERLING WOLFGANG , ILLIAN GERHARD , MURAKAMI MIKIO , OHLENDORF DIETER , WINGEN RAINER
IPC: C07D317/72 , C07D405/00 , C07D405/12 , C09K19/34 , G02F1/13
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公开(公告)号:NO902111L
公开(公告)日:1990-11-14
申请号:NO902111
申请日:1990-05-11
Applicant: HOECHST AG
Inventor: MEIJERE ARMIN DE , DUEBAL HANS-ROLF , ESCHER CLAUS , HARADA TAKAMASA , HEMMERLING WOLFGANG , ILLIAN GERHARD , MUELLER INGRID , MURAKAMI MIKIO , OHLENDORF DIETER , WINGEN RAINER
IPC: G02F1/13 , C07C13/04 , C07C13/28 , C07C22/00 , C07C25/00 , C07C43/184 , C07C43/205 , C07C43/21 , C07C69/92 , C07C255/45 , C07D213/30 , C07D237/08 , C07D237/14 , C07D237/16 , C07D237/18 , C07D239/26 , C07D239/34 , C07D239/38 , C07D241/12 , C07D241/18 , C07D285/12 , C07D285/125 , C07D285/13 , C07D405/12 , C09K19/20 , C09K19/30 , C09K19/34
Abstract: The novel cyclopropylalkyl or -alkenyl compounds have the general formula In this formula, the symbols A , A , A denote unsubstituted and in particular substituted (by halogen or CN) aromatic or heteroaromatic molecular building blocks, such as 1,4-phenylene or pyrimidine-2,5- diyl, which are linked via a single bond or via functional groups M , M , such as CO-O or CH2-O; H and m are zero or 1; j, l, n are zero, 1 or 2. The radicals are R , R , R are H or alkyl/alkenyl, R is alkyl/alkenyl or a substituent known from LC chemistry, such as an alpha - haloalkanoic acid radical. G denotes alkylene or alkenylene.
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公开(公告)号:BR8806184A
公开(公告)日:1989-08-15
申请号:BR8806184
申请日:1988-11-24
Applicant: HOECHST AG
Inventor: MEIJERE ARMIN DE , DUEBAL HANS-ROLF , ESCHER CLAUS , HEMMERLING WOLFGANG , MUELLER INGRID , OHLENDORF DIETER , WINGEN RAINER
IPC: C07D20060101 , C07D213/30 , C07D237/08 , C07D237/10 , C07D237/14 , C07D239/26 , C07D239/32 , C07D239/34 , C07D239/38 , C07D241/12 , C07D285/12 , C07D303/48 , C07D317/10 , C07D405/12 , C09K19/34 , C09K19/42 , C09K19/46 , G02F1/13 , G02F1/137 , G02F1/141
Abstract: The liquid crystalline cyclopropylalkyl or -alkenyl heterocycles have the formula in which the symbols A , A , A are aromatic or heteroaromatic molecular building blocks, such as 1,4-phenylene or pyrimidin-2,5-diyl which are linked via a single bond (if k,m are zero) or via functional groups M , M , such as CO-O or CH2-O; j, k, l, m, n are zero or 1 (j+l+n = 2 or 3). The radicals R , R , R are H or alkyl/alkenyl, R is alkyl/alkenyl or one of the substituents known from LC chemistry, such as an alpha -haloalkanoic radical. In addition, at least one of the building blocks A , A , A must be heteroaromatic and G denotes alkylene or alkenylene.
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