Abstract:
PROBLEM TO BE SOLVED: To obtain an alkylfluorenediamine as a novel compound having a long-chain alkyl group, as well as a polyamic acid and an imidated polymer obtained by using the same, and in addition, a liquid crystal oriented film whose orientation direction cuts the rubbing direction at right angles and which has a pretilt angle of 0 deg., good sticking and a high voltage retention, to provide its manufacturing method, and a liquid crystal display element having the liquid crystal oriented film. SOLUTION: The alkylfluorenediamine is represented by formula (A) (wherein (n) is an integer of 6-20), and the polyamic acid and the imidated polymer can be obtained by using this compound as the diamine component. The liquid crystal orienting agent is composed of these polymers, and the liquid crystal oriented film and its manufacturing method are disclosed. The liquid crystal display element has this liquid crystal oriented film.
Abstract:
PROBLEM TO BE SOLVED: To provide a method of alignment treatment of liquid crystal realizing high alignment controllability of the liquid crystal on an alignment layer which is essential for a liquid crystal display element with not performing a rubbing treatment for aligning the liquid crystal in non-contact manner and to provide a liquid crystal display element having the obtained liquid crystal alignment layer equipped on its substrate with neither defective display quality nor destruction of TFT(thin film transistor) element when the display is turned on. SOLUTION: In the method of alignment treatment of liquid crystal, the liquid crystal alignment layer formed on the substrate is irradiated with light so as to impart liquid crystal alignment properties to the liquid crystal alignment layer. The liquid crystal alignment layer contains a polymer with a chalcone structure and the polymer molecules with the chalcone structure is in a state capable of moving so as to impart the liquid crystal alignment properties to the liquid crystal alignment layer on the irradiation with the light. The liquid crystal display element equipped with the liquid crystal alignment layer obtained by this method on the substrate is also provided.
Abstract:
PROBLEM TO BE SOLVED: To provide a method for producing an organic solvent-soluble silicon polymer which can form a uniform coating film from an organic solvent solution and can further be converted into silicon by subjecting the formed coating film to a heating treatment or the like. SOLUTION: This method for producing an organic solvent-soluble silicon polymer comprises (1) reacting a silicon tetrahalide and a compound of the formula: RQXn [R is a monovalent organic group; Q is silicon atom or magnesium atom; X is a halogen atom; (n) is 3, when Q is silicon atom, or (n) is 1, when Q is magnesium atom] with metal lithium and/or magnesium magnesium, and then (2) reducing the reaction product obtained in the process (1) with MgH2.
Abstract:
PROBLEM TO BE SOLVED: To make it possible to orient the molecules of the surfaces of oriented layer by a non-rubbing treatment by irradiating org. films with polarizer pulse lasers to orient the molecules of the surfaces of the org. films. SOLUTION: The org. films are irradiated with the pulse energy much lower than the min. threshold pulse energy to induce the decomposition of the high polymer by the photoirradiation with the polarized pulse lasers, by which the molecules of the surfaces of the org. films are oriented. The blank of the org. films for forming the liquid crystal oriented layers of this case consists of an org. polymer. The org. polymer includes, for example, polyimide, polysulfone, polyamide, poly(meth)acrylate, polycarbonate, polyphenylene sulfide, polyphenylene oxide, norbornane resins, etc. The org. films are irradiated with the polarized pulse laser, by which the molecules on the surfaces of the org. films are oriented and the liquid crystal oriented layers are formed.
Abstract:
PROBLEM TO BE SOLVED: To provide a liquid crystal orienting agent which gives a liquid crystal orienting film having good liquid crystal orienting property, which hardly produces scratches by rubbing treatment on the surface of the film, and which has excellent durability against cleaning with isopropylalcohol after the rubbing treatment. SOLUTION: This orienting agent contains at least one kind of polymer selected from polymers having a polyamic acid structure and polymers having an imide structure produced by dehydration and ring-closing reaction of the polyamic acid, and an epoxy compd. containing nitrogen atoms. In this method, the average imidization rate of the polymers included in the orienting agent is >=45%.
Abstract:
PROBLEM TO BE SOLVED: To obtain a liquid crystal-orienting agent enabling to form liquid crystal-orienting films good in liquid crystal orientation, excellent in the long period stability of pre-tilt angles, and giving liquid crystal display elements, etc., which are useful for liquid crystal televisions, etc., by including a specific imide polymer, etc. SOLUTION: This liquid crystal-orienting agent comprises at least either of a polyamic acid obtained by reacting (A) a tetracarboxylic acid dianhydride of formula I (R is a tetravalent organic group), such as butane tetracarboxylic acid dianhydride, with (B) a diamine compound of formula II (R is a divalent to hexavalent organic group having a larger length than the longest diameter of 6Å; R is F, a fluoroalkyl, etc.; (n) is 1-5], such as a compound of formula III, and an imide polymer obtained by subjecting the polyamic acid to a dehydrative ring-closing reaction.
Abstract:
PROBLEM TO BE SOLVED: To obtain the subject orientating agent capable of preparing a liquid crystal display element which is short in a time from releasing of applied voltage to erasing of after image by including plural specific polymers. SOLUTION: This orientating agent comprises (A) a polyamic acid obtained by reacting (i) tetracarboxylic acid dianhydride represented by formula I [R is methyl or ethyl; R is H, methyl or ethyl; (a) is 1-4] with (ii) a diamine compound and/or its imidated polymer and (B) a polyamic acid obtained by reacting (iii) a tetracarboxylic acid dianhydride represented by formula II with (iv) a diamine compound and/or its imidated polymer. Furthermore, 1,3,3a, 4,5,9b- hexahydro-7-methyl-5-(tetrahydro-2,5-dioxo-3-furanyl)naphtho[1,2-c]-fu ran-1,3-dione, etc., is preferably used as the component (i).
Abstract:
PROBLEM TO BE SOLVED: To obtain a liquid crystal orientation agent that contains a specific polymer and tertiary alcohol and renders sure orientation to liquid crystal molecules and can provide excellent liquid crystal display devices by rubbing treatment. SOLUTION: This liquid crystal orientation agent comprises a solution that contains (A) at least one polymer selected from polyamic acids obtained by reaction of a tetracarboxylic dianhydride (for example, butanetetracarboxylic dianhydride, etc.) with a diamine compound, and imidated polymers having a structure obtained by ring-opening dehydration of a polyamic acid, and (B) a tertiary alcohol selected from a group consisting of compounds of formulae I to V (X to X , X to X , and X to X are each monovalent hydrocarbon; X , X and X are each divalent hydrocarbon; (a), (b), (c), and (d) are each 0-3; total of X to X is 5 or more).
Abstract:
PROBLEM TO BE SOLVED: To provide a binder composition for a negative electrode, capable of providing a power storage device high in charge/discharge capacity and less in the degree of capacity deterioration due to the repetition of charge/discharge cycles.SOLUTION: The binder composition for a negative electrode is a binder composition for a negative electrode of a power storage device, containing at least a polymer (A), water (B) and a liquid medium (C). The polymer (A) is at least one selected from the group consisting of a polyamic acid and an imidized polymer thereof, the polyamic acid being obtained by the reaction between (a) mol of tetracarboxylic dianhydride and b mol of diamine while a ratio a/b is more than 0.95 and 0.99 or less.
Abstract:
PROBLEM TO BE SOLVED: To provide a composition capable of forming a cured product excellent in at least water-absorbing properties, oxygen-absorbing properties, and heat resistance; a cured product formed from the composition; and an electronic device including the cured product. SOLUTION: The composition contains: (A) an organometallic compound represented by general formula (1): (R 1 )nM; and (B) a polymer including a repeating unit represented by general formula (2) and having a weight-average molecular weight (Mw) of 10,000-1,000,000. COPYRIGHT: (C)2011,JPO&INPIT