124.
    发明专利
    未知

    公开(公告)号:DE3869335D1

    公开(公告)日:1992-04-23

    申请号:DE3869335

    申请日:1988-11-11

    Applicant: BASF AG

    Abstract: Prodn. of heteroaromatic aldehydes or ketones of formula R-CO-R1 (I) is effected by oxidising the corresp. 1-hydroxyalkyl cpds. of formula R-C(OH)H-R1 (II) with an (in)organic hypochlorite or hypobromite in the presence of an oxidised tetraalkyl cyclic amine (III): R=5 or 6-membered heteroaryl contg. N atom R1=H or 1-20C alkyl. (III) is of formula (III): A1-A4=1-4C alkyl; Q=a gp. of formula Q1-Q3= X=an anion; n=0 or 1; Y=O, CO or CR2R3; R2 and R3=H, OH, or C- or O-bonded organic gps. opt. linked to form a 5- or 6-membered ring. Pref. R=opt. substd. isoxazolyl, pyridyl or pyrimidinyl.

    127.
    发明专利
    未知

    公开(公告)号:DE3280354D1

    公开(公告)日:1991-10-10

    申请号:DE3280354

    申请日:1982-03-24

    Applicant: BASF AG

    Abstract: New fungicidal agents contain a triazole deriv. (I) or salt or metal complex thereof: (where R1 and R2 are H, 1-5C alkyl, or phenyl opt. substd. by F, Cl, Br, NO2, CF3 or 1-3C alkyl, alkoxy or alkenyl; Ar is furyl, thienyl, biphenylyl, naphthyl, phenyl, or phenyl substd. by F, Cl, Br, I, NO2, CF3, 1-5C alkyl, alkoxy or alkenyl, or phenoxy; Z-Y is CH:C or CH2-CH4; and X is -CO-, -CH(OH)- or -CH(OR3)-, R3 being 1-8C alkyl, opt. chloro-substd. 2-5C alkenyl, 3-4C alkynyl, benzyl, benzyl substd. by F, Cl, Br, NO2, CF3, 1-3C alkyl or 1-3C alkoxy, or a group -CO-R4 in which R4 is an aromatic residue, 1-5C alkyl, or 1-5C alkyl substd. by halogen, alkoxy, oxo or carboxyalkyl). The cpds. (I) (which are stated to be new) have good activity against injurious fungi, esp. Ascomycetes and Basidiomycetes, and are very well tolerated by plants. Some of the cpds. are systemically active and can be used as foliar and soil fungicides. The cpds. can also be used in materials protection, e.g. for combatting timber-destroying fungi such as Coniophora puteane and Polystictus versicolor.

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