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公开(公告)号:AT81682T
公开(公告)日:1992-11-15
申请号:AT89110558
申请日:1989-06-10
Applicant: BASF AG
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公开(公告)号:DE58902239D1
公开(公告)日:1992-10-15
申请号:DE58902239
申请日:1989-06-10
Applicant: BASF AG
Inventor: WOLF BERND DR , THEOBAL HANS DR , GOETZ NORBERT DR
IPC: C07C29/136 , C07C25/02 , C07C25/18 , C07C25/22 , C07C25/24 , C07C27/00 , C07C29/00 , C07C29/16 , C07C33/20 , C07C33/22 , C07C33/30 , C07C33/34 , C07C33/46 , C07C33/50 , C07C35/21 , C07C35/50 , C07C45/00 , C07C45/44 , C07C47/542 , C07C47/546 , C07C47/548 , C07C47/55 , C07C67/00 , C07C253/14 , C07C255/50
Abstract: Benzonitriles, benzaldehydes and benzyl alcohols of the formula I in which R denotes methyl or ethyl, R denotes alkyl, alkenyl, cycloalkyl, cycloalkenyl, bicycloalkyl, bicycloalkenyl or C1-C5-alkyl-substituted cycloalkyl, cycloakenyl, bicycloalkyl or bicycloalkenyl, X denotes hydrogen, chlorine or fluorine and Z denotes the group -CN, CHO or where R stands for hydrogen, cyano, C2-C4-alkynyl, C2-C4-alkenyl or C1-C4-alkyl, with the proviso that R does not represent the -CH2-CH=CH-B radical if B stands for hydrogen, alkyl or alkenyl and at the same time R has the meaning methyl and Z has the meaning and with the proviso that R does not denote methyl or ethyl if at the same time R stands for methyl and Z stands for and finally with the proviso that R does not denote methyl if at the same time R stands for methyl or ethyl and Z stands for the -CN or -CHO group, and processes for their production.
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123.
公开(公告)号:AT80375T
公开(公告)日:1992-09-15
申请号:AT89110561
申请日:1989-06-10
Applicant: BASF AG
Inventor: WOLF BERND DR , THEOBAL HANS DR , GOETZ NORBERT DR
IPC: C07C29/136 , C07C25/02 , C07C25/18 , C07C25/22 , C07C25/24 , C07C27/00 , C07C29/00 , C07C29/16 , C07C33/20 , C07C33/22 , C07C33/30 , C07C33/34 , C07C33/46 , C07C33/50 , C07C35/21 , C07C35/50 , C07C45/00 , C07C45/44 , C07C47/542 , C07C47/546 , C07C47/548 , C07C47/55 , C07C67/00 , C07C253/14 , C07C255/50
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公开(公告)号:DE3869335D1
公开(公告)日:1992-04-23
申请号:DE3869335
申请日:1988-11-11
Applicant: BASF AG
Inventor: KUEKENHOEHNER THOMAS DR , GOETZ NORBERT DR , THEOBALD HANS DR , KNAUS GUENTER H DR
IPC: C07D213/48 , C07D213/50 , C07D239/26 , C07D261/08
Abstract: Prodn. of heteroaromatic aldehydes or ketones of formula R-CO-R1 (I) is effected by oxidising the corresp. 1-hydroxyalkyl cpds. of formula R-C(OH)H-R1 (II) with an (in)organic hypochlorite or hypobromite in the presence of an oxidised tetraalkyl cyclic amine (III): R=5 or 6-membered heteroaryl contg. N atom R1=H or 1-20C alkyl. (III) is of formula (III): A1-A4=1-4C alkyl; Q=a gp. of formula Q1-Q3= X=an anion; n=0 or 1; Y=O, CO or CR2R3; R2 and R3=H, OH, or C- or O-bonded organic gps. opt. linked to form a 5- or 6-membered ring. Pref. R=opt. substd. isoxazolyl, pyridyl or pyrimidinyl.
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公开(公告)号:DE3869280D1
公开(公告)日:1992-04-23
申请号:DE3869280
申请日:1988-08-26
Applicant: BASF AG
Inventor: GOETZ NORBERT DR , RECKER HANS-GERT DR , SMUDA HUBERT DR
IPC: C07C33/46 , C07C27/00 , C07C29/136 , C07C29/143 , C07C67/00 , C07D301/26 , C07D303/02 , C07D303/04 , C07D303/08 , C07D303/22 , C07D303/34
Abstract: Prodn. of styrene oxides of formula (I) is effected by (a) reducing a haloacetophenone of formula (II) with an alkali(ne earth) metal or quat. ammonium borohydride, and (b) reacting the resulting halohydrin (III) with an alkali(ne earth) metal hydroxide. R1 and R2 = H, 1-4C alkyl, 2-4C alkenyl, phenyl, halogen, NO2, 1-4C alkoxy, 1-4C haloalkyl, phenoxy or phenylsulphonyl; X = halogen. Steps (a) and (b) are effected in a mixt. of H2O, a water-miscible organic solvent and opt. a water-immiscible organic solvent.
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公开(公告)号:DE4017488A1
公开(公告)日:1991-12-05
申请号:DE4017488
申请日:1990-05-31
Applicant: BASF AG
Inventor: SCHUETZ FRANZ DR , SAUTER HUBERT DR , GOETZ NORBERT DR , WILD JOCHEN DR , WOLF HANS-JOSEF DR , DOETZER REINHARD DR , LORENZ GISELA DR , AMMERMANN EBERHARD DR
IPC: A01N37/36 , A01N37/50 , A01N53/00 , A01N53/06 , C07C69/74 , C07C69/743 , C07C251/48
Abstract: Substd. benzyl cyclopropane carboxylate esters of formula (I) are new: Where X = CH or N; A = a gp. (i)-(iv) R1 = CN, 2-8C alkyl, CF3, 3-8C alkenyl, Me3Si, 1-4C alkoxycarbonyl, phenyl (1-6C) alkyl or phenyl (3-6C) alkenyl (in which the aromatic rings can be substd. by 1-5 halo or 1-3 of 1-6C alkyl (opt. partially or fully halogenated) or 1-6C alkoxy); or R1 is phenyl substd. by EtO; 2- or 3- Br; 2- or 4- CF3; 2,4- or 2,6-F2; 2-F-6-Cl; 2,4- or 2,6-Me2, or 2,3,6-Cl3; R2 = H or halo; R3 = phenyl (opt. substd. by 1-5 halo or 1-3 of 1-6C alkyl (opt. partially or fully halogenated) or 1-6C alkoxy); R4 = Me or halogen; Proviso: X = CH if R1 = CF3 or Me3Si. More specifically A = A' with R1 = CN, 2-4C alkyl, CF3, 3-4C alkenyl, Me3Si, 1-2C alkoxycarbonyl, phenyl (1-4C) alkyl or phenyl (3-4C) alkenyl (opt. ring substd. by halo or Me); or phenyl substd. by 2-Br; 2,4- or 2,6-F2; 2-F-6-Cl or 2,3,6-Cl3.
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公开(公告)号:DE3280354D1
公开(公告)日:1991-10-10
申请号:DE3280354
申请日:1982-03-24
Applicant: BASF AG
Inventor: RENTZEA COSTIN DR , FEUERHERD KARL-HEINZ DR , MEYER NORBERT DR , GOETZ NORBERT DR , POMMER ERNST-HEINRICH DR
IPC: A01N43/64 , A01N43/653 , C07D249/08 , C07D319/06 , C07D405/06 , C07D521/00
Abstract: New fungicidal agents contain a triazole deriv. (I) or salt or metal complex thereof: (where R1 and R2 are H, 1-5C alkyl, or phenyl opt. substd. by F, Cl, Br, NO2, CF3 or 1-3C alkyl, alkoxy or alkenyl; Ar is furyl, thienyl, biphenylyl, naphthyl, phenyl, or phenyl substd. by F, Cl, Br, I, NO2, CF3, 1-5C alkyl, alkoxy or alkenyl, or phenoxy; Z-Y is CH:C or CH2-CH4; and X is -CO-, -CH(OH)- or -CH(OR3)-, R3 being 1-8C alkyl, opt. chloro-substd. 2-5C alkenyl, 3-4C alkynyl, benzyl, benzyl substd. by F, Cl, Br, NO2, CF3, 1-3C alkyl or 1-3C alkoxy, or a group -CO-R4 in which R4 is an aromatic residue, 1-5C alkyl, or 1-5C alkyl substd. by halogen, alkoxy, oxo or carboxyalkyl). The cpds. (I) (which are stated to be new) have good activity against injurious fungi, esp. Ascomycetes and Basidiomycetes, and are very well tolerated by plants. Some of the cpds. are systemically active and can be used as foliar and soil fungicides. The cpds. can also be used in materials protection, e.g. for combatting timber-destroying fungi such as Coniophora puteane and Polystictus versicolor.
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公开(公告)号:AT66921T
公开(公告)日:1991-09-15
申请号:AT82102446
申请日:1982-03-24
Applicant: BASF AG
Inventor: RENTZEA COSTIN DR , FEUERHERD KARL-HEINZ DR , MEYER NORBERT DR , GOETZ NORBERT DR , POMMER ERNST-HEINRICH DR
IPC: A01N43/64 , A01N43/653 , C07D249/08 , C07D319/06 , C07D405/06 , C07D521/00
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公开(公告)号:DE3941593A1
公开(公告)日:1991-06-20
申请号:DE3941593
申请日:1989-12-16
Applicant: BASF AG
Inventor: SEELE RAINER DR , ZIPPERER BERNHARD DR , KEIL MICHAEL DR , GOETZ NORBERT DR , AMMERMANN EBERHARD DR , LORENZ GISELA DR , KOBER REINER DR
IPC: A01N43/50 , A01N43/653 , C07D233/60 , C07D249/08 , C07D303/04 , C07D303/08 , C07D303/22 , C07D303/34 , C07D405/06 , C07D405/08 , C07D407/04 , C07D407/06 , C07D493/10 , C07D521/00
Abstract: Azolylmethylcycloalkanol deriv. of formula (I), their acid addn. salts, and metal complexes tolerated by plants are new. In (I), Y = =C=CH- or =CHZ-; Z = O, S, SO, SO2, or NR1, R1 = 1-8C alkyl, phenyl, biphenyl, naphthyl, heteroaryl, benzyl or 3-8C cycloalkyl each of these gps. being opt. mono- di or tri-substd. by halogen, NO2, PhO, amino, 1-4C alkyl, 1-4C alkoxy, or 1-4C haloalkyl) or tetrahydropyranyl; or if Y = =CHZ-, R1 can be H; R2 and R3 = each H or 1-4C alkyl or if Y = =C=CH- R2 and R3 can together form =CHR1; n = 2-5; and X = CH or N. USE/ADVANTAGE - (I) are fungicides with a broad spectrum of active against phytopathogenic fungi, effective against e.g. trysiphe graninis in cereals, Venturia inaequalis or apple, Botytis cinerea on strawberries and vines and pyriculoria oryzae on rice. Suitable dose are 0.02-3kg (I)/ha. (I) can also be used as plant growth regulators. For leaf and soil treatment, suitable doses are 0.01-10 kg/(I)/ha.
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公开(公告)号:DE3768689D1
公开(公告)日:1991-04-25
申请号:DE3768689
申请日:1987-02-02
Applicant: BASF AG
Inventor: PLATH PETER DR , EICKEN KARL DR , GOETZ NORBERT DR , WILD JOCHEN DR , MEYER NORBERT DR , WUERZER BRUNO DR
IPC: A01N37/10 , A01N37/18 , A01N37/32 , A01N37/46 , A01N43/36 , A01N43/38 , C07C201/12 , C07C205/07 , C07C205/44 , C07C205/56 , C07C227/04 , C07C229/36 , C07C229/40 , C07C231/12 , C07C233/05 , C07C233/65 , C07C237/30 , C07C255/32 , C07C255/34 , C07C255/41 , C07D209/48
Abstract: The N-substituted 3,4,5,6-tetrahydrophthalimides and their precursors have the general formula I … … in which the substituents have the following meaning:… A is -NO2, -NH2 or … … corresponding to the compounds Ia, Ib and Ic,… A is -NO2, -NH2 or … … corresponding to the compounds Ia, Ib and Ic,… B is -CH2-, -CH2-CHR -, -CH2-CHR -CH2-, -CH=, -CH=CR - or -CH=CR -CH=, where the radical R is -H, -Cl, -Br or -CH3,… D, depending on the terminal group of B, is -CH or =C ,… X is -H, -Cl or -Br,… Y is -H, C1-C7-alkyl, -Cl, -Br, -CN, CONH2 or -CO2R , in which the radical R is H, C1-C6-alkyl, C5-C6-cycloalkyl, C1-C4-alkoxy- C2-C4-alkyl, C1-C4-alkylmercapto-C2-C4-alkyl, propargyl, benzyl, alpha -phenylethyl, alpha -phenylpropyl, C2-C4-alkyl which is up to trisubstituted by F or Cl, or allyl which is substituted by -CH3 or -Cl,… Z is -COOR , -CONR R , … … or -COR ,… in which the radicals R and R are H or C1-C4-alkyl or together form a cycloaliphatic 5- or 6-membered ring whose carbon chain may be interrupted by an oxygen atom.
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