公开(公告)号：JPH02115164A

公开(公告)日：1990-04-27

申请号：JP23180689

申请日：1989-09-08

Applicant: BASF AG

Inventor： PLATH PETER DR ,  EICKEN KARL DR ,  RUEB LOTHAR DR ,  SCHWALGE BARBARA DR ,  WESTPHALEN KARL-OTTO DR ,  WUERZER BRUNO DR

IPC: A01N37/46 ,  A01N43/38 ,  C07D209/48

公开(公告)号：JPH11322732A

公开(公告)日：1999-11-24

申请号：JP8217999

申请日：1999-03-25

Applicant: BASF AG

Inventor： PLATH PETER DR ,  VON DEYN WOLFGANG ,  RACK MICHAEL DR ,  MISSLITZ ULF DR

IPC: C07C303/40 ,  C07C311/16 ,  C07D275/06

Abstract: PROBLEM TO BE SOLVED: To provide a method for selectively producing a saccharinecarbonyl halide useful as a herbicide from readily available starting materials while avoiding the formation of a byproduct by reacting a specific amide with an inorganic acid halide. SOLUTION: This method for producing a compound of formula I (X is a halogen; R and R are each H, a 1-6C alkyl, a 3-6C cycloalkyl or the like; R is H, a 1-6C alkyl, a 3-8C cycloalkyl or the like) comprises reacting (A) isophthalylsulfonamide of formula II with (B) an inorganic acid halide. Preferably, the reaction is carried out by using tionyl chloride, phosphorus oxychloride, oxalyl chloride or the like as the component B, in an organic solvent such as toluene within the temp. range of 25-130 deg.C.

公开(公告)号：JP2755718B2

公开(公告)日：1998-05-25

申请号：JP23180689

申请日：1989-09-08

Applicant: BASF AG

Inventor： PLATH PETER DR ,  EICKEN KARL DR ,  RUEB LOTHAR DR ,  SCHWALGE BARBARA DR ,  WESTPHALEN KARL-OTTO DR ,  WUERZER BRUNO DR

IPC: A01N37/46 ,  A01N43/38 ,  C07D209/48

公开(公告)号：DE59310185D1

公开(公告)日：2001-08-02

申请号：DE59310185

申请日：1993-04-20

Applicant: BASF AG

Inventor： KLINTZ RALF DR ,  HEISTRACHER ELISABETH DR ,  SCHAEFER PETER DR ,  HAMPRECHT GERHARD DR ,  PLATH PETER DR ,  KARDORFF UWE DR ,  GERBER MATTHIAS DR ,  WESTPHALEN KARL-OTTO DR ,  WALTER HELMUT DR

IPC: C07D317/30 ,  A01N37/30 ,  A01N37/32 ,  A01N37/34 ,  A01N37/46 ,  A01N43/08 ,  A01N43/12 ,  A01N43/16 ,  A01N43/18 ,  A01N43/28 ,  A01N43/32 ,  A01N43/38 ,  A01N43/40 ,  A01N43/74 ,  A01N43/78 ,  C07C233/57 ,  C07C233/60 ,  C07C233/61 ,  C07C233/62 ,  C07C233/63 ,  C07C237/42 ,  C07C251/48 ,  C07C251/60 ,  C07C255/13 ,  C07C255/24 ,  C07C255/42 ,  C07C255/46 ,  C07C255/58 ,  C07C271/62 ,  C07D209/48 ,  C07D295/185 ,  C07D307/12 ,  C07D307/90 ,  C07D309/06 ,  C07D335/02 ,  C07D339/06 ,  C07D339/08 ,  C07D401/10 ,  C07D413/06 ,  C07D413/10 ,  C07D417/06 ,  C07D417/10

Abstract: Substd. cyclohexene-1,2-dicarboxylic acid derivs. of formula (I), and their salts are new. Where T = CONR1R2 or CN; R1, R2 = H; R, 3-6C alkenyl, or 3-6C alkynyl, all opt. substd. by 1-3 halo, CN, NH2, SH, OH, OR, RSO, RSO2, RCO, COOH, ROCO, RNH, (R)2N, RNHCO, (R)2NCO, (RO)(HO)PO, (RO)2PO, or Ar); or Ar' when R1 is H or R, R2 may also be OH, RO, 3-6C alkenyloxy, 3-6C alkynyloxy, 3-7C cycloalkoxy 5-7 cycloalkenyloxy, 1-6C haloalkoxy, 3-6C halo alkenyloxy, 3-7C cycloalkyl-1-6C alkoxy, RCOO, 1-6C cyanoalkoxy, etc.; NR1R2 = a 3-8 membered non-aromatic heterocycle contg. 1-3N atoms and/or one O or S atom and opt. 1-2 CO gps., the ring being opt. substd. by 1-3R; Ar = phenyl or a 3-8 membered heterocycle (contg. 1-4 heteroatoms selected from 1-4N, 1O or 1S) both opt. substd. on every substitutable atom by OH, halo, CN, NO2, CF3, R or RO; Ar' as Ar except that the heterocycle contains 1-4 heteroatoms selected from 1-4N, 1-20 and 1-2S, and only C-atoms may be substd. R = 1-6C alkyl; R3 = H or R; R4 = H or halo; R5 = H, halo, NO2, CN or CF3; R6 = a 3-8 membered heterocycle (contg. 1-4 heteroatoms selected from 1-4N, 1-2O and 1-2S, and in which 1-2 CH2 gps. are opt. replaced by CO), opt. C-substd. by R, 2-6C alkenyl, 2-6C alkynyl, RO, RS, 3-6C alkenyloxy, 3-6C alkynyloxy, 3-6C alkenylthio, 3-6C alkynylthio, ROCO, NO2, NH2, halo, 1-4C alkylamino, di(1-4C)alkylamino, CN, 1-6C cyanoalkyl, 1-6C haloalkyl or 1-6C haloalkyloxy; ACN, ACOB, OR9, C(O)R10, C(S)R10, C(NR16)R10, A = straight chain 2-4C alkenylene or 2-4C alkynylene, both opt. substd. by 1-2 halo, CN, R, 1-6C haloalkyl, OH, RO, RCOO, ROCO or RCO; B = H, R, 3-6C alkenyl, 3-6C alkynyl, 1-6C haloalkyl, 3-7C cycloalkyl, OR17, SR17, phenyl (opt. substd. by 1-3R, 2-6C alkenyl, halo, CN, NO2, 1-6C haloalkyl, RO or ROCO), 1-6C alkoxy-1-6C alkyl, di(1-6C alkoxy)-1-6C alkyl, 1-6C alkylthio-1-6C alkyl or NR18R19; R17 = H, R, 3-6C alkenyl, 3-6C alkynyl, 3-6C cycloalkyl, 1-6C haloalkyl, 1-6C cyanoalkyl, 3-6C haloalkenyl, ROCO, 1-6C alkoxy(1-6C)alkyl, 1-6C alkoxycarbonyl (1-6C) alkyl, 1-6C alkoxyimino(1-6C)alkyl, or phenyl (opt. substd. by 1-3 R, 2-6C alkenyl, halo, CN, NO2, 1-6C haloalkyl, RO or ROCO); R18, R19 = H, R, 3-6C alkenyl, 3-6C alkynyl, 3-6C cycloalkyl, 1-6C haloalkyl, RCO, ROCO, 1-6C alkoxy (1-6C)alkyl, or phenyl (opt. substd. by 1-3R, 3-6C alkenyl, halo, CN, NO2, RO or ROCO); R9 = 1-6C cyanoalkyl RQ, 1-6C haloalkyl, 3-6C haloalkenyl, 3-6C alkynyl, 3-6C haloalkynyl, 1-6 alkoxycarbonyl-2-6C alkyl, ROQOCOQ, 1-6C alkoxyimino (1-6C)alkyl, or phenyl, phenyl-Q, 3-8 membered heterocyclyl or heterocyclyl-Q (where the heterocycles contain 1-4 heteroatoms, etc.; R10 = H, CN, R, 3-6C alkenyl, 3-6C alkynyl, 1-6C haloalkyl, 3-7C cycloalkyl, ROCO, ROCOQ, or phenyl (opt. substd. by 1-3 halo, CN, NO2, R, 3-6C alkenyl, 1-6C haloalkyl, RO or ROCO); R16 = H, R, 3-6C alkenyl, 3-6C alkynyl, 3-7C cycloalkyl, 1-6C haloalkyl, phenyl (opt. substd. by 1-3R, halo, CN, 2-6C alkenyl, NO2, 1-6C haloalkyl, 1-6C alkoxy, or ROCO), ROQ, OH, RO, 3-6C alkenyloxy, 3-6C alkynyloxy, 5-7C cycloalkoxy, 5-7C cycloalkenyloxy, etc.; R5+R6 = an opt. unsatd. 3-5 membered carbon chain which opt. contains 1-2O, S, N, CO or 1-6C alkoximino gps. and which is opt. substd. by 1-2 CN, NO2, NH2, halo, R, 1-6C haloalkyl, 2-6C alkenyl, 2-6C alkynyl, 1-6C cyanoalkyl, RCOQ, phenyl-Q or 3-8 membered heterocyclyl-1-6C alkyl, where the heterocycle is opt. unsatd. and contains 1-4 heteroatoms selected from 1-4N, 1-20 and 1-2S; provided that when T is CONR1R2 then R9 is not 3-6C alkynyl and R16 is not 1-6C alkoxy, and when T is CN then R9 is not 1-6C haloalkoxy.

公开(公告)号：CZ60298A3

公开(公告)日：1998-08-12

申请号：CZ60298

申请日：1996-08-29

Applicant: BASF AG

Inventor： OTTEN MARTINA DR ,  VON DEYN WOLFGANG DR ,  ENGEL STEFAN DR ,  HILL REGINA LUISE DR ,  KARDORFF UWE DR ,  VOSSEN MARCUS DR ,  PLATH PETER DR ,  GOTZ NORBERT DR ,  WALTER HELMUT DR ,  WESTPHALEN KARL-OTTO DR ,  MISSLITZ ULF DR

IPC: A01N43/18 ,  A01N43/56 ,  C07D333/64 ,  C07D335/06 ,  C07D409/06 ,  C07D411/06 ,  C07D417/06 ,  C07D333/60 ,  C07D231/12 ,  A01N43/12

Abstract: Pyrazol-4-ylbenzoyl derivativeswhere the substituents L, M, X, Y and n have the meanings given in claim 1 andQ is a pyrazole ring, linked in the 4-position, of the formula IIwhereR15 is C1-C4-alkyl,R16 is hydrogen, C1-C4-alkyl or C1-C4-haloalkyl andR17 is hydrogen, C1-C4-alkylsulfonyl, phenylsulfonyl or alkylphenylsulfonyl,where, in the event that Y=C=O, X is other than NR23,agriculturally useful salts, a process for their preparation, and their use as herbicides.

公开(公告)号：DE19638484A1

公开(公告)日：1998-03-26

申请号：DE19638484

申请日：1996-09-20

Applicant: BASF AG

Inventor： OTTEN MARTINA DR ,  GOETZ NORBERT DR ,  DEYN WOLFGANG VON DR ,  ENGEL STEFAN DR ,  KARDORFF UWE DR ,  RACK MICHAEL DR ,  HILL REGINA LUISE DR ,  PLATH PETER DR ,  WITSCHEL MATTHIAS DR ,  WESTPHALEN KARL-OTTO DR ,  WALTER HELMUT DR ,  MISLITZ ULF DR

IPC: A01N43/42 ,  A01N43/56 ,  C07D401/06 ,  C07D215/48 ,  C07D217/12

Abstract: Hetaroyl derivatives having the formula (I) are disclosed, as well as their salts useful in agriculture. In the formula, the variables have the following meanings: R , R are hydrogen, nitro, halogen, cyano, rhodano, hydroxy, mercapto, optionally substituted and/or functionalised C1-C6 alkyl, C1-C6 alkoxy, C1-C6 alkylthio, C1-C6 alkylsulfinyl, C1-C6 alkylsulfonyl, C1-C6 alkoxysulfonyl, or optionally substituted phenyl, phenoxy, phenylthio, phenylsulfinyl or phenylsulfonyl; Z is an optionally substituted, 4-membered, unsaturated, partially or completely saturated chain with three carbon atoms and one nitrogen atom; and Q is optionally substituted hydroxypyrazol linked at position 4. Also disclosed is a process for preparing the hetaroyl derivatives, agents containing the same, as well as the use of these derivatives or the agents containing the same for controlling undesirable plants.

公开(公告)号：DE19614856A1

公开(公告)日：1997-10-23

申请号：DE19614856

申请日：1996-04-16

Applicant: BASF AG

Inventor： ENGEL STEFAN DR ,  DEYN WOLFGANG VON DR ,  HILL REGINA LUISE DR ,  KARDORFF UWE DR ,  OTTEN MARTINA DR ,  PLATH PETER DR ,  VOSSEN MARCUS DR ,  MISLITZ ULF DR ,  WALTER HELMUT DR ,  WESTPHALEN KARL-OTTO DR

IPC: A01N43/80 ,  C07D275/06 ,  C07D417/06

Abstract: 4-benzoylisothiazoles have the general formula (1), in which the substituents have the following meanings: X stands for oxygen or sulphur; R stands for hydrogen, alkyl, alkenyl, alkinyl, optionally substituted alkoxycarbonyl, aryl, heterocyclyl or hetaryl; R stands for hydrogen, alkyl, alkenyl, alkinyl, cycloalkyl or cyclalkenyl, aryl, hetaryl or heterocyclyl; and R stands for a radical of general formulas (2a-d), in which n, A, B and the R , R and R substituents have the meanings given in claim 1. Also disclosed are the salts commonly used in agriculture of the 4-benzoylisothiazoles of general formula (1), a process for preparing the same and their use as herbicides.

公开(公告)号：DE19532311A1

公开(公告)日：1997-03-06

申请号：DE19532311

申请日：1995-09-01

Applicant: BASF AG

Inventor： OTTEN MARTINA DR ,  DEYN WOLFGANG VON DR ,  ENGEL STEFAN DR ,  HILL REGINA LUISE DR ,  KARDORFF UWE DR ,  VOSSEN MARCUS DR ,  PLATH PETER DR ,  WALTER HELMUT DR ,  WESTPHALEN KARL-OTTO DR ,  MISLITZ ULF DR

IPC: C07D333/62 ,  A01N43/12 ,  A01N43/18 ,  A01N43/30 ,  A01N43/32 ,  C07D275/04 ,  C07D275/06 ,  C07D279/16 ,  C07D327/06 ,  C07D333/64 ,  C07D333/66 ,  C07D335/06 ,  C07D409/10 ,  C07D495/10 ,  C07D409/06

Abstract: Benzoyl derivatives according to formula (I), where substituents L, M, X, Y and n have the meaning given in claim 1 and Q stands for a 2-position cross-linked cyclohexane-1,3-dione ring according to formula (II), where R , R , R , and R indicate hydrogen or C1-C4-alkyl, R indicates hydrogen, C1-C4-alkyl or a -COOR group, R indicates hydrogen, C1-C4-alkyl or C3-C4-cycloalkyl where these groups may carry one to three of the following substituents: halogen, C1-C4-alkylthio or C1-C4 alkoxy, or R indicates tetrahydropyranyl-3, tetrahydropyranyl-4 or tetrahydrothiopyranyl-3, or R and R together form a bond or a three to six member carbocyclic ring, where in the case that Y = C=O, X is not equal to NR , and agriculturally usable salts, a process for the production thereof and their use as herbicides.

公开(公告)号：DE4438578A1

公开(公告)日：1996-05-02

申请号：DE4438578

申请日：1994-10-28

Applicant: BASF AG

Inventor： HEISTRACHER ELISABETH DR ,  PLATH PETER DR ,  BUSSCHE-HUENNEFELD CHRISTOPH V ,  HAMPRECHT GERHARD DR ,  KLINTZ RALF DR ,  SCHAEFER PETER DR ,  WESTPHALEN KARL-OTTO DR ,  WALTER HELMUT DR ,  GERBER MATTHIAS DR ,  MISLITZ ULF DR

IPC: C07D403/12 ,  A01N37/32 ,  A01N37/46 ,  A01N43/38 ,  C07C205/56 ,  C07C229/44 ,  C07D209/48 ,  C07D417/12 ,  C07F7/08 ,  C07D405/12 ,  C07D413/12 ,  A01N43/50 ,  A01N43/78 ,  A01N43/76 ,  A01N43/54

Abstract: Disclosed are substituted phthalimido-cinnamic acid derivatives of formula (I), wherein R is H, C1-C4-alkyl; R is H, halogen; R is CN, NO2, halogen, C1-C6-alkyl, C1-C6-alkyl halide, C1-C6-alkoxy, C1-C6-alkoxy halide; R is H, CN, NO2, halogen, C1-C6-alkyl; R is H, C1-C6-alkyl, C2-C6-alkenyl, C2-C6-alkinyl, substituted C1-C6-alkyl; R is one of the radicals indicated under R or CN, NO2, C1-C6-alkoxy, C1-C6-alkoxy halide, C1-C6-alkyl thio, C1-C6 alkyl thio halide, C3-C6-cycloalkyl, sustituted alkyl, C3-C6-alkenyl halide, (C1-C6-alkoxy)-carbonyl, COOH, (C1-C6-alkyl amino)carbonyl, di-(C1-C6-alkyl)amino carbonyl, (C1-C6-alkyl) carbonyl, (C1-C6-alkyl halide) carbonyl, optionally substituted aryl, hetaryl, aryl C1-C6 alkyl or hetaryl C1-C6 alkyl; or R and R together are an alkylene chain, in which a methylene unit can be substituted a C1-C4-alkyl imino group; R is H, C1-C6-alkyl, C3-C6-alkenyl, C3-C6 alkinyl, C2-C6 alkyl halide, C1-C6 cyanoalkyl, C1-C6 alkoxy C2-C6 alkyl, C1-C6-alkyl thio C2-C6 alkyl, (C1-C6-alkoxy)carbonyl-C1-C6-alkyl, optionally substituted phenyl or benzyl; X is O, S or N(R ), as well as the salts of formula (I). Disclose also is their use as herbicides and for desication/defoliation of plants.

公开(公告)号：DE59009528D1

公开(公告)日：1995-09-21

申请号：DE59009528

申请日：1990-09-07

Applicant: BASF AG

Inventor： MAYWALD VOLKER DR ,  FREUND WOLFGANG DR ,  HAMPRECHT GERHARD DR ,  KUEKENHOEHNER THOMAS DR ,  PLATH PETER DR ,  WUERZER BRUNO DR ,  WESTPHALEN KARL-OTTO DR

IPC: A01N43/80 ,  C07D261/18 ,  C07D275/02 ,  C07D275/03 ,  C07D413/04 ,  C07D413/12 ,  C07D413/14 ,  C07D417/04 ,  C07D417/12 ,  C07D417/14

Abstract: Carboxamides Ia, Ib, Ic and Id (X is O or S; R is H, halogen, optionally substituted alkyl, optionally substituted benzyl, alkoxy, alkylthio, haloalkoxy, haloalkylthio, optionally substituted phenyl, optionally substituted phenoxy or phenylthio, an optionally substituted 5- or 6-membered heterocycle having up to 2 hetero atoms, cycloalkylalkyl, optionally substituted alkenyl which can be epoxidised, optionally substituted alkynyl, optionally substituted cycloalkyl or cycloalkenyl; R is cycloalkylalkyl, optionally substituted alkenyl which can be epoxidised, optionally substituted cycloalkenyl; R is CHO, 4,5-dihydrooxazol-2-yl, COYR , CONR R ; Y is O or S; R is H, optionally substituted alkyl, cycloalkyl, optionally substituted alkenyl, optionally substituted cycloalkenyl, optionally substituted alkynyl, optionally substituted phenyl, a 5- or 6-membered heterocycle having up to 3 hetero atoms, benzotriazole, N-phthalimido, tetrahydrophthalimido, succinimido, maleimido, 2,2-di-methyl- 1,3-dioxolan-4-ylmethyl, 1,3-dioxolan-2-on-4-ylmethyl, in the case where Y = O: an equivalent of a cation from the group of the alkali metals or alkaline earth metals, Mn, Cu, Fe, ammonium and substituted ammonium, a radical -N = CR R or -W-Z; R and R are H, optionally substituted alkyl, optionally substituted haloalkyl, cycloalkyl, alkoxy, furanyl, optionally substituted phenyl; R + R are a 4- to 7-membered methylene chain; W is an alkylene chain, ethoxyethylene chain, butenylene or butynylene chain; Z is a moiety bonded to W in the omega -position which represents the same moiety which is linked to W in the alpha -position of W; R is H, alkyl, cycloalkyl; R is H; alkyl; -C(O-alkyl)=N-H or -C(O-alkyl)=N-alkyl; R + R are a 4- to 5-membered methylene chain; R is H, optionally substituted alkyl, optionally substituted cycloalkyl; R is H, OH, alkoxy, optionally substituted alkyl, optionally substituted cycloalkyl, optionally substituted alkenyl, optionally substituted alkynyl, di-(C1-C4)-alkylamino, an optionally substituted 5- to 6-membered heterocycle having up to 2 hetero atoms, optionally substituted phenyl, optionally substituted naphthyl; R3 + R4 are a 4- to 7-membered methylene chain which can be interrupted by O, S or N-CH3, or are -(CH2)3-CO-> and their environmentally compatible salts are suitable as herbicides.