公开(公告)号：JPH06312951A

公开(公告)日：1994-11-08

申请号：JP10332093

申请日：1993-04-28

Applicant: MITSUI PETROCHEMICAL IND

Inventor： FUJITA TERUNORI ,  NITAHARA MASATOSHI ,  KAWAI KOJI ,  KISO YOSHIHISA

IPC: C07C46/00 ,  C07C50/32 ,  C07C69/017 ,  C07C69/16 ,  C07C69/28 ,  C07C69/614 ,  C07C69/773 ,  C07C69/96 ,  C07C271/44 ,  C07C271/58 ,  C07C309/65 ,  C07C309/66 ,  C07C309/73 ,  C07F7/18 ,  G03G5/06

Abstract: PURPOSE:To provide a new quinone compound stable against heat, not having sublimating property and an irritating smell, and useful as a functional chemical. CONSTITUTION:A quinone compound of formula I [A, B are hydrocarbon group, R -CO, R -O-CO, R R N-CO, R -SO2, R R R Si (R to R are H, hydrocarbon group). The compound of formula I is produced by thermally dimerizing 1,2- naphthoquinone into dinaphthyldiquinhydrone in the presence of an acid, and subsequently reacting the produced compound with a reagent containing a suitable nucleating agent such as a compound of formula II [X is C, SO; Y is hydrocarbon group, OR, NRR (R is hydrocarbon group)] (e.g. tosyl chloride), a compound of formula III (e.g. acetic anhydride), a compound of formula IV (e.g. diphenyl carbonate), etc. The compound of formula I is useful as a color- developing agent, an intermediate for dyestuffs, pigments, medicines, agricultural chemicals, rubber chemicals, etc., an oxidizing agent, etc.

公开(公告)号：JPH06186732A

公开(公告)日：1994-07-08

申请号：JP34284092

申请日：1992-12-22

Applicant: MITSUI PETROCHEMICAL IND

Inventor： MATSUOKA HIDETO ,  FUKUOKA ONORI ,  KISO YOSHIHISA ,  FUJITA MINORU

IPC: B32B27/30 ,  C09J7/02 ,  C09J133/04 ,  C09J133/14 ,  G03F1/62 ,  H01L21/027 ,  G03F1/14

Abstract: PURPOSE:To provide an adhesive pellicle film excellent in adhesiveness and light transmissivity and having excellent light resistance even to light having such short wavelength as 360-450nm. CONSTITUTION:An adhesive material layer made of fluorine-contg. poly-(meth) acrylate is formed on one side of a transparent thin film of fatty acid ester of cellulose. The poly(meth)acrylate is a copolymer of 20-80mol% monomer (A) represented by a formula CH2=C(R )-COOR (where R is H or methyl and R is straight chain fluoroalkyl) with 80-20mol% monomer (B) represented by a formula CH2=C(R )-COOR (where R is H or methyl and R is branched fluoroalkyl) and has 0.10-0.35dl/g intrinsic viscosity (eta) measured in m-xylene hexafluoride at 60 deg.C. The objective adhesive pellicle film for exposure with light having such short wavelength as 360-450nm is obtd.

公开(公告)号：JPH06179287A

公开(公告)日：1994-06-28

申请号：JP33274992

申请日：1992-12-14

Applicant: MITSUI PETROCHEMICAL IND

Inventor： NITAHARA MASATOSHI ,  FUJITA TERUNORI ,  KAWAI KOJI ,  KISO YOSHIHISA

IPC: B41M5/132 ,  B41M5/155 ,  B41M5/26 ,  B41M5/30 ,  B41M5/323 ,  B41M5/333

Abstract: PURPOSE:To provide a color forming recording material having high absorption within the range from a visible region to a near infrared region and having a high light resistance by providing a recording layer containing a azo compd. represented by a specific general formula and an acidic substance on a support. CONSTITUTION:A predetermined amt. of an azo compd. represented by formula I (wherein X is H, an amino group, an alkyl group or an acyl group, Y is H, halogen, an alkyl group or an aryl group, m is a natural number of 4 or less and A and B are H, an alkyl group or an aralkyl group) and a predetermined amt. of an acidic substance are mixed. The obtained mixture is compounded with an aqueous soln. of a binder such as polyvinyl alcohol and ground to prepare a coating soln. This coating soln. is applied to a support such as fine paper and dried to form a recording layer, thus obtaining a color forming recording material. As a concrete example of the azo compd., there is 4-aminoazobenzene or 4-(N-methylamino)azobenzene and, as examples of the acidic substance, there are phenol, naphthol, acid clay, kaolin and the like.

公开(公告)号：JPH0517402A

公开(公告)日：1993-01-26

申请号：JP19607091

申请日：1991-07-11

Applicant: MITSUI PETROCHEMICAL IND

Inventor： KISO YOSHIHISA ,  IWASAKI HIROSHI

IPC: B01J31/02 ,  B01J31/20 ,  C07B61/00 ,  C07C67/38 ,  C07C69/533

Abstract: PURPOSE:To produce pentenoic acid esters from 1,3-butadiene, an aliphatic alcohol and carbon monoxide with industrial advantage by using a new catalyst system composed of a cobalt complex prepared by addition of a small amount of an aminopyridine. CONSTITUTION:A new catalyst system composed of a cobalt complex such as cobalt diacetylacetonate, cobalt bromide or a cobalt carbonyl complex and a small amount of an aminopyridine is used. Carbon monoxide, 1,3-butadiene of formula CH2=CH-CH=CH2 and an aliphatic alcohol of formula ROH (R is aliphatic) are brought into contact with the catalyst system to synthesize the objective pentenoic acid ester of formula CH3CH=CHCH2COOR, CH3CH2CH: CHCOOR or CH2=CHCH2CH2CO0R. As the aliphatic alcohol, a 1-10C aliphatic alcohol is preferable. The aminopyridine is used preferably in an amount of 0.005-0.3mol based on 1mol 1,3-butadiene. By using the new catalyst system, pentenoic acid esters can be produced with industrial advantage.

公开(公告)号：JPH0311048A

公开(公告)日：1991-01-18

申请号：JP14331889

申请日：1989-06-06

Applicant: MITSUI PETROCHEMICAL IND

Inventor： KISO YOSHIHISA ,  HAYASHI TETSUO

IPC: C07B61/00 ,  C07C271/26

Abstract: PURPOSE:To selectively prepare a compound useful as a raw material for preparing agricultural chemicals by reacting a hydroxyaniline with an alkylcarbonate compound. CONSTITUTION:A hydroxyaniline (e.g. m-aminoaniline) is reacted with an alkylcarbonate compound (e.g. dimethylcarbonate) in the presence of a catalyst such as a basic compound or metal compound in the absence of a solvent or in a solvent such as methanol at room temperature-250 deg.C under ordinary pressure-50 atmospheres for 0.1-50hrs to provide the objective compound. The catalyst is preferably an alkali metal compound, especially the metal itself, alkoxy compound, hydroxide, hydride or amide thereof. The hydroxyaniline and the alkylcarbonate compound are used in a molar ratio of 0.2-20, and the catalyst and the hydroxyaniline are also used in a molar ratio of 0.005-10.

公开(公告)号：JPH02284919A

公开(公告)日：1990-11-22

申请号：JP10894489

申请日：1989-04-27

Applicant: MITSUI PETROCHEMICAL IND

Inventor： KISO YOSHIHISA ,  SHIMAMOTO KENJI

IPC: C08G64/30 ,  C08G64/20

Abstract: PURPOSE:To obtain the subject compound in high efficient, using a nearly neutral catalyst to eliminate the post-treatment such as neutralization process by carrying out the ester-interchange reaction of an aliphatic alcohol and dimethyl carbonate using a specific compound as a catalyst. CONSTITUTION:The objective carbonate can be produced by the esterinterchange reaction of (A) a monohydric aliphatic alcohol (e.g. ethanol) or a dihydric aliphatic alcohol (e.g. ethylene glycol) and (B) dimethyl carbonate in the presence of (C) a catalyst consisting of one or more kinds of compounds selected from manganese compounds [e.g. Mn(CH3COCHCOCH3)3 or MnO2] and molybdenum compounds [e.g. Mo(CH3COCHCOCH3)3].

公开(公告)号：JPH02284918A

公开(公告)日：1990-11-22

申请号：JP10894389

申请日：1989-04-27

Applicant: MITSUI PETROCHEMICAL IND

Inventor： KISO YOSHIHISA ,  SHIMAMOTO KENJI

IPC: C08G64/30 ,  C08G64/20

Abstract: PURPOSE:To obtain the subject polymer from an inexpensive raw material with a simple process in a short time in high efficiency by reacting an aliphatic diol compound with dimethyl carbonate in two steps under respective specific conditions. CONSTITUTION:The objective polymer can be produced by reacting an aliphatic diol compound (e.g. 1,4-butanediol) with dimethyl carbonate in the presence of a catalyst (preferably an alkali metal compound, etc.) in a closed reaction system at a reaction temperature of 130-250 deg.C while keeping the molar ratio of dimethyl carbonate/aliphatic diol compound in the reaction system to 0.5-1.7, removing the methanol produced by the above reaction from the system and heating the reaction mixture under reduced pressure to perform the 2nd-stage reaction while removing the produced methanol from the reaction system. The 2nd stage reaction is carried out preferably at 150-250 deg.C under a pressure of

公开(公告)号：JPH02251523A

公开(公告)日：1990-10-09

申请号：JP7439089

申请日：1989-03-27

Applicant: MITSUI PETROCHEMICAL IND

Inventor： KISO YOSHIHISA ,  MATSUNAGA YUICHI

IPC: C08G64/30 ,  C08G64/20

Abstract: PURPOSE:To obtain the subject diol at low cost in high efficiency by reaction between dimethyl carbonate and an aromatic diol compound at specified molar ratio and carrying out reaction again while removing the dimethyl carbonate as by-produce through heating under reduced pressure. CONSTITUTION:(A) Dimethyl carbonate and (B) an aromatic diol compound are made to react at the molar ratio 0.2 to 3 in the presence of (C) 1X10 to 2X10 mol per mol of the component B of a catalyst under normal pressure - 50kg/cm . Thence, the dimethyl carbonate unreacted is put to reduced pressure at 0.1 to 20mmHg at 150 to 300 deg.C and the dimethyl carbonate as by-product is removed through e.g. distillation, thus obtaining the objective diol.

公开(公告)号：JPH02207074A

公开(公告)日：1990-08-16

申请号：JP2718989

申请日：1989-02-06

Applicant: MITSUI PETROCHEMICAL IND

Inventor： KISO YOSHIHISA ,  HAYASHI TETSUO

IPC: C07D233/60 ,  C07D233/68 ,  C07D235/02 ,  C07D235/20 ,  C07F7/20

Abstract: PURPOSE:To obtain the title compound useful as a substitute for phosgene in carbonylation reaction or a dehydrating agent safely and in high yield without using phosgene by reacting an N-silylated imidazole derivative with a carbonate compound as raw materials. CONSTITUTION:An N-silylated imidazole derivative such as 1- trimethylsilylimidazole shown by formula I (R -R are H, halogen, alkyl or aryl and R and R are bonded to form a ring; Ra to Rc are alkyl or aryl) is reacted with a carbonate such as diphenyl carbonate shown by formula II (R and R are alkyl or are bonded to form ring) in the molar ratio of usually (100:1)(0.1:1) optionally using a solvent such as tetrahydrofuran at -20-250 deg.C under 1mmHg-10kg/cm for 0.1-40 hours and the aimed compound shown by formula III useful for production of isocyanates is separated from the prepared reaction mixture by distillation under reduced pressure, etc.

公开(公告)号：JPH02124852A

公开(公告)日：1990-05-14

申请号：JP15390389

申请日：1989-06-16

Applicant: MITSUI PETROCHEMICAL IND

Inventor： KISO YOSHIHISA ,  ISHIBASHI MASAYASU ,  MATSUNAGA YUICHI

IPC: B01J31/12 ,  C07B61/00 ,  C07C67/08 ,  C07C69/773

Abstract: PURPOSE:To obtain compounds useful as an intermediate for dyes, high polymers, ultraviolet absorbers, synthetic resin stabilizers, color formers, medicines, etc., by reacting phenols with aromatic carboxylic acids in the presence of a catalyst of a tin compound. CONSTITUTION:Phenols are reacted with aromatic carboxylic acids in the presence of a tin compound expressed by the formula (R to R are alkyl or aryl; X and X are hydroxy, alkoxy or aryloxy) used as a catalyst in or without a solvent, such as benzene, at 100-400 deg.C for 10min-40hr to afford aryl aromatic carboxylates. The tin compound catalyst is used in an amount of 1X10 to 1X10 molar ratio based on the aromatic carboxylic acids and the phenols are used in an amount of 0.1-100 molar ratio based on the aromatic carboxylic acids. Side reactions due to high temperatures can be suppressed and selectively and reaction rate can be improved by the afore-mentioned method to afford the objective high-purity compounds excellent in hue.