公开(公告)号：JPH03193776A

公开(公告)日：1991-08-23

申请号：JP33421389

申请日：1989-12-22

Applicant: MITSUI PETROCHEMICAL IND

Inventor： FUKUOKA ONORI ,  TAKEI MITSUSACHI ,  KIHARA NORIAKI

IPC: C07D311/20

Abstract: NEW MATERIAL:A compound of formula I (R is lower alkyl; R -R are each H or lower alkyl). EXAMPLE:1-Hydroxy-3-[4-(2-methoxyl-2,4,4-trimethyl-2,3-dihydro-7- benzopyranyloxy)phenyl]urea. USE:An intermediate for synthesizing urea compounds useful as herbicides. PREPARATION:The objective compound of the formula I can be obtained by reaction at 0-50 deg.C for 0.1-20hr between a phenyl isocyanate derivative of formula II and hydroxylamine in a solvent such as water-toluene. The amounts of the hydroxylamine and solvent to be used are such as to be 0.5-10 molar times and 1-50 weight times, each based on the compound of the formula II, respectively.

公开(公告)号：JPH03193775A

公开(公告)日：1991-08-23

申请号：JP33421289

申请日：1989-12-22

Applicant: MITSUI PETROCHEMICAL IND

Inventor： FUKUOKA ONORI ,  ISHITOKU TAKESHI ,  HASHIMOTO ISAO ,  KIHARA NORIAKI

IPC: C07D311/20 ,  C07D311/74

Abstract: PURPOSE:To obtain in an economically advantageous manner the title compound useful as a herbicide using reaction agents with no problems in terms of handling by lower alkylation of a 1-hydroxy-3-phenylurea derivative. CONSTITUTION:The objective 1-alkoxy-1-alkyl-3-[4-(2-alkoxy-2,3-dihydro-7- benzopyranyloxy)phenyl]urea derivative of formula II can be obtained by reaction of a compound of formula I (R is lower alkyl; R to R are each H or lower alkyl) at -10 to 100 deg.C in the presence of a base (e.g. NaOH) using a sulfuric ester of formula R OSO2OR (R is lower alkyl) or a haloalkyl of formula R -X (X is halogen) in a solvent such as toluene pref. in the presence of a phase-transfer catalyst (e.g. benzyltriethyl ammonium chloride).

公开(公告)号：JPH0232048A

公开(公告)日：1990-02-01

申请号：JP17875088

申请日：1988-07-18

Applicant: MITSUI PETROCHEMICAL IND

Inventor： ISHIDA TATSUKAZU ,  FUKUOKA ONORI ,  NAGAI SUNAO ,  HASHIMOTO ISAO

IPC: C07C239/20

Abstract: PURPOSE:To obtain the subject compound useful as an intermediate raw material for the production of pharmaceuticals, agricultural chemicals, etc., in high yield by using sodium salt of a halophenol which is one of the most inexpensive industrial raw material and reacting the salt with hydroxylamine-O-sulfonic acid under specific condition. CONSTITUTION:The objective halophenoxyamine of formula II (e.g., 3,5- dichlorophenoxyamine) can be produced in high yield at a low cost by adding 0.5-10mol/l aqueous solution of hydroxylamine-O-sulfonic acid to 2-8mol/l aqueous solution of a halophenol sodium slat of formula I (X is halogen; n is 1-3) under heating and reacting the components with each other. The amount of the hydroxylamine-O-sulfonic acid is 0.1-0.4mol per 1mol of the halophenol sodium salt.

公开(公告)号：JPH03193777A

公开(公告)日：1991-08-23

申请号：JP33421489

申请日：1989-12-22

Applicant: MITSUI PETROCHEMICAL IND

Inventor： FUKUOKA ONORI ,  KIHARA NORIAKI

IPC: C07D311/20

Abstract: NEW MATERIAL:A compound of formula I (R is lower alkyl; R to R are each H or lower alkyl). EXAMPLE:4-(2-Methoxy-2,4,4-trimethyl-2,3-dihydro-7-benzopyranyloxy)phenyl isocyanate. USE:An intermediate for synthesizing urea compounds useful as herbicides. PREPARATION:The objective compound of the formula I can be obtained by reaction at -10-100 deg.C between a 4-(2-alkoxy-2,3-dihydro7-benzopyranyloxy)aniline derivative of formula II and phosgene in the presence of a base (e.g. sodium carbonate) in a solvent such as toluene. The amounts of the phosgene, base and solvent to be used are such as to be 1-2 molar times, 0.75-5 molar times and 1-50 weight times, each based on the compound of the formula II, respectively.

公开(公告)号：JPS63203677A

公开(公告)日：1988-08-23

申请号：JP3530887

申请日：1987-02-18

Applicant: MITSUI PETROCHEMICAL IND

Inventor： TAKAHASHI KATSUYA ,  FUKUOKA ONORI

IPC: C07D311/20 ,  C07B61/00 ,  C07D311/78

Abstract: NEW MATERIAL:2,3-Dihydrobenzopyrans of formula I (R -R are H or lower alkyl; R is lower alkyl; R and R may be bonded with alkylene chain together with bonded C to form a 5-6-membered ring). EXAMPLE:2,3-Dihydro-7-hydroxy-2-methoxy-2-methylbenzopyran. USE:Intermediate for producing a urea derivative useful as a herbicide. PREPARATION:The compound of formula IV which is one of the compound of formula I can be produced e.g. by reacting 1,3-dihydroxybenzenes of formula II with alpha,beta-unsaturated ketones of formula III (R is alkyl; R and R may form a ring in the same manner as R and R ) in the presence of orthoesters of formula R3 CH and an acidic catalyst.

公开(公告)号：JPS63192744A

公开(公告)日：1988-08-10

申请号：JP2448187

申请日：1987-02-06

Applicant: MITSUI PETROCHEMICAL IND

Inventor： ORI AIICHIRO ,  YOKOYAMA KEIICHI ,  FUKUOKA ONORI ,  FURUYA YOSHIRO

IPC: C07C225/16 ,  C07C67/00 ,  C07C213/00 ,  C07C221/00

Abstract: PURPOSE:To suppress side reaction and obtain aminoketones useful as medicines, etc., in good yield in a short time, by reacting alpha-halogenated ketones with amines under specific condition. CONSTITUTION:alpha-Halogenated ketones expressed by formula I (X is Cl, Br or I; Y is H, halogen, nitro or OH; R is H or lower alkyl) are dissolved in a mixed solvent of water-alcohol at a volume ratio of the water to alcohol within the range of 0.1-4:1 to provide a solution (A) in 0.1-2mol./l concentration. Amines expressed by the formula R -NH2 (R is lower alkyl) are dissolved in a mixed solvent of water-alcohol to afford a solution (B) in 0.5-10mol./l concentration. The solution (A) is then added to the solution (B) so as to provide 2.5-15 molar ratio of the amines to the alpha-halogenated ketones and the solution mixture is reacted for 5-240min to afford the aimed substance expressed by formula II. The reaction solvent is preferably a mixed solvent at a volume ratio of the water to the alcohol within the range of 0.1-4:1.

公开(公告)号：JPS63192743A

公开(公告)日：1988-08-10

申请号：JP2447987

申请日：1987-02-06

Applicant: MITSUI PETROCHEMICAL IND

Inventor： FUKUOKA ONORI ,  YOKOYAMA KEIICHI ,  ORI AIICHIRO

IPC: C07C225/16 ,  C07C67/00 ,  C07C213/00 ,  C07C221/00

Abstract: PURPOSE:To obtain aminoketones useful for producing medicines as succinates in a relatively high recovery ratio and high purity by simple operation, by neutralizing the aminoketones with a mineral acid in the presence of water from a mixed system of the aminoketones and amines. CONSTITUTION:Aminoketones expressed by the formula (Y is H, halogen, nitro or OH; R is H or lower alkyl; R is lower alkyl) are isolated as succinates from a mixed system of existing 1mol. aminoketones and 1-15mol., preferably 3-9mol. amines expressed by the formula R -NH2. In this process, 40-100%, preferably 70-95% free amines present in the mixed system is neutralized in the presence of water using a mineral acid (e.g. hydrochloric acid or hydrobomic acid).

公开(公告)号：JPH1087716A

公开(公告)日：1998-04-07

申请号：JP25035396

申请日：1996-09-20

Applicant: MITSUI PETROCHEMICAL IND

Inventor： FUKUOKA ONORI ,  KAWAI KOJI ,  NITAHARA MASATOSHI

IPC: C08F4/642 ,  C08F4/645 ,  C08F4/6592 ,  C08F10/00

Abstract: PROBLEM TO BE SOLVED: To obtain a catalyst, comprising a specific transition metallic compound and a specified compound, having excellent polymerizing activities agent an olefin and capable of providing a polyolefin having a high molecular weight. SOLUTION: This catalyst for polymerizing an olefin comprises (A) a transition metallic compound represented by the formula [M is a group IV to VI transition metallic atom of the periodic table; R and R are each a 1-4C alkyl; R and R are each a C1-16 aryl; R is H or a C4 alkyl; X and X are each H, a halogen a C1-20 (halogenated)hydrocarbon, etc.; Y is a C1-20 bivalent (halogenated)hydrocarbon, a bivalent silicon-containing group, a bivalent germanium-containing group, etc.] [e.g. dimethylsilanediyl(2-ethyl-4-(9-phenanthryl) indenyl) (2-methyl-4-(9-phenanthryl)z indenyl)zirconium dichloride], (B) an organoaluminum compound and/or (C) a compound reactive with the component A and capable of forming ion pairs.

公开(公告)号：JPH08188610A

公开(公告)日：1996-07-23

申请号：JP351095

申请日：1995-01-12

Applicant: MITSUI PETROCHEMICAL IND

Inventor： MATSUI NARIKAZU ,  FUKUOKA ONORI ,  IMUDA JUNICHI

IPC: C07F7/00 ,  C07F17/00 ,  C08F4/60 ,  C08F4/642 ,  C08F4/6592 ,  C08F10/00

Abstract: PURPOSE: To obtain a transition metal compound having a structure represented by a specified formula, and therefore serving as a catalyst component which can give an olefin polymer in high polymerization activity. CONSTITUTION: This compound is represented by the formula (wherein M is a transition metal atom of IVb, Vb or VIb group; R to R are each H, a halogen, a 1-20 C hydrocarbon group, a 1-20 C halohydrocarbon group, an Si- containing group, an O-containing group, as S-containing group, an N-containing group or a P-containing group, provided that, among R to R , any two groups on the adjoining carbon atoms may be combined with each other to form a fused ring; X and X are each H, a halogen, a 1-20 C hydrocarbon group, 1-20 C halohydrocarbon group, an O-containing group or an S-containing group). The compound can be used as a component of an olefin polymerization catalyst, and this catalyst is prepared by combining the compound with an organoaluminumoxy compound and/or a compound which reacts with this compound to form an ionic pair and optionally an organoaluminum compound.

公开(公告)号：JPH07149833A

公开(公告)日：1995-06-13

申请号：JP14641594

申请日：1994-06-28

Applicant: MITSUI PETROCHEMICAL IND

Inventor： KAWASAKI MASAAKI ,  ITO MASAAKI ,  UEDA TAKASHI ,  FUKUOKA ONORI ,  KISO YOSHIHISA ,  TASHIRO KOJI ,  HASHIMOTO MIKIO

IPC: C08F210/06 ,  C08F4/60 ,  C08F4/642 ,  C08F4/6592 ,  C08F10/00 ,  C08F10/06

Abstract: PURPOSE:To obtain the elastomer excellent in heat and blocking resistances, shock absorptivity, transparency and heat-sealability. CONSTITUTION:This propylene-based elastomer contains (a) 50-95mol% propylene unit and 5-50mol% ethylene unit and has (b) >=90.0% triad tacticity determined by C-NMR in a propylene unit chain part composed of head-tail bonds, (c) 0.05-0.5% ratio of positional irregular units, determined by the C-NMR and based on the 2,1-insert of propylene monomer in the whole propylene inserts and (d) an intrinsic viscosity [eta] measured at 135 deg.C in decalin within the range of 0.1-12dl/g.