-
公开(公告)号:HU0402363A2
公开(公告)日:2005-02-28
申请号:HU0402363
申请日:2002-11-05
Applicant: BASF AG
Inventor: STROEFER ECKHARD , SOHN MARTIN , HASSE HANS , SCHILLING KLEMENS
Abstract: In an aqueous formaldehyde solution comprising formaldehyde in the form of monomeric formaldehyde, methylene glycol and polyoxymethylene glycols in a total concentration x of >=65% by weight, the mean molar mass {overscore (M of the polyoxymethylene glycols is, as a function of the formaldehyde concentration, equal to or less than the values given by equation I: ( M _ g / mol ) = 48 + 6.589 . 10 - 1 . ( x % by weight ) + 4.725 . 10 2 . ( x % by weight ) 2 - 3.434 . 10 - 3 . ( x % by weight ) 3 + 9.625 . 10 - 5 . ( x % by weight ) 4 - 1.172 . 10 6 . ( x % by weight ) 5 + 5.357 . 10 - 9 . ( x % by weight ) 6 ( I ) where: {overscore (M is the mean molar mass, and x is the total concentration of formaldehyde in the form of monomeric formaldehyde, methylene glycol and polyoxymethylene glycols in % by weight (total formaldehyde concentration).
-
公开(公告)号:DE10309288A1
公开(公告)日:2004-09-16
申请号:DE10309288
申请日:2003-03-04
Applicant: BASF AG
Inventor: STROEFER ECKHARD , LANG NEVEN , STEINBRENNER ULRICH , HASSE HANS , OTT MICHAEL , GRUETZNER THOMAS
IPC: C07C45/00 , C07C45/82 , C07C47/058 , C02F1/08
Abstract: Process for preparing high-concentration gaseous formaldehyde having a molar CH 2 O:H 2 O ratio of >=0.6 from an aqueous formaldehyde solution by evaporation of at least part of the solution, in which the aqueous formaldehyde solution is heated to a vaporization temperature T and the gas phase formed is taken off, wherein the evaporation temperature T obeys the relationship: T[° C.]>=T' min [° C.] where T' min (c)=A+Bx(c/100)+Cx(c/100) 2 +Dx(c/100) 3 and A=+68.759, B=+124.77, C=-12.851, D=-10.095, where c is the instantaneous CH 2 O content of the aqueous formaldehyde solution during the evaporation in percent by weight and is from 20 to 99% by weight.
-
公开(公告)号:CA2517564A1
公开(公告)日:2004-09-16
申请号:CA2517564
申请日:2004-03-04
Applicant: BASF AG
Inventor: HASSE HANS , GRUETZNER THOMAS , STROEFER ECKHARD
IPC: C07C45/78 , C07C45/82 , C07C47/058
Abstract: A method for stabilization of highly concentrated formaldehyde solutions containing >70 wt. % CH2O with respect to solid precipitation, wherein th e highly concentrated formaldehyde solution is heated directly after productio n at a heating rate of at least 5~ C/min to a temperature of at least 80 ~C to 200 ~C maximum and is stored at a temperature within said range.
-
公开(公告)号:AT273265T
公开(公告)日:2004-08-15
申请号:AT01915134
申请日:2001-01-12
Applicant: BASF AG
Inventor: AUER HEINZ , BESSLING BERND , HAMMER HANS , HASSE HANS , SAUER FRIEDRICH , VICARI MAXIMILIAN , ADRIAN TILL
Abstract: The invention relates to a process for obtaining anhydrous or substantially anhydrous formic acid, in which firstly aqueous formic acid is produced by hydrolysis of methyl formate, with the methanol content in the methyl formate having been reduced in advance. The process according to the invention has the special feature that-before the hydrolysis of the methyl formate-the methanol content of the methanol-containing methyl formate is reduced in a distillation column, this distillation column simultaneously being employed for other separation functions during work-up of the formic acid.
-
公开(公告)号:NO20023513L
公开(公告)日:2002-08-26
申请号:NO20023513
申请日:2002-07-23
Applicant: BASF AG
Inventor: AUER HEINZ , BESSLING BERND , HAMMER HANS , HASSE HANS , SAUER FRIEDRICH , VICARI MAXIMILIAN , WAGNER GERHARD , ADRIAN TILL
Abstract: The invention relates to a process for obtaining anhydrous or substantially anhydrous formic acid in which, during the work-up, a compound of the general formula Iwhere the radicals R1 and R2 are alkyl, cycloalkyl, aryl or aralkyl groups, or R1 and R2 jointly, together with the N atom, form a heterocyclic 5- or 6-membered ring, and only one of the radicals is an aryl group, and where R3 is hydrogen or a C1-C4-alkyl group,is employed simultaneously as extractant for formic acid and as antifoam for a distillation process.
-
公开(公告)号:NO20023480A
公开(公告)日:2002-08-22
申请号:NO20023480
申请日:2002-07-22
Applicant: BASF AG
Inventor: AUER HEINZ , BESSLING BERND , HAMMER HANS , HASSE HANS , SAUER FRIEDRICH , VICARI MAXIMILIAN , WAGNER GERHARD , ADRIAN TILL
CPC classification number: C07C51/445 , B01J14/00 , B01J2219/00006 , C07C51/09 , C07C51/44 , C07C51/48 , C07C53/02
-
公开(公告)号:NO20023481A
公开(公告)日:2002-08-21
申请号:NO20023481
申请日:2002-07-22
Applicant: BASF AG
Inventor: AUER HEINZ , BESSLING BERND , HAMMER HANS , HASSE HANS , SAUER FRIEDRICH , VICARI MAXIMILIAN , ADRIAN TILL
CPC classification number: C07C51/445 , B01J14/00 , B01J2219/00006 , C07C51/09 , C07C51/44 , C07C51/48 , C07C53/02
-
公开(公告)号:NO20023514D0
公开(公告)日:2002-07-23
申请号:NO20023514
申请日:2002-07-23
Applicant: BASF AG
Inventor: AUER HEINZ , BESSLING BERND , HAMMER HANS , HASSE HANS , SAUER FRIEDRICH , VICARI MAXIMILIAN , ADRIAN TILL
Abstract: The invention relates to a process for obtaining anhydrous or substantially anhydrous formic acid, in which firstly aqueous formic acid is produced by hydrolysis of methyl formate, with the methanol content in the methyl formate having been reduced in advance. The process according to the invention has the special feature that-before the hydrolysis of the methyl formate-the methanol content of the methanol-containing methyl formate is reduced in a distillation column, this distillation column simultaneously being employed for other separation functions during work-up of the formic acid.
-
公开(公告)号:NO20023480D0
公开(公告)日:2002-07-22
申请号:NO20023480
申请日:2002-07-22
Applicant: BASF AG
Inventor: AUER HEINZ , BESSLING BERND , HAMMER HANS , HASSE HANS , SAUER FRIEDRICH , VICARI MAXIMILIAN , WAGNER GERHARD , ADRIAN TILL
Abstract: The invention relates to a process for the preparation of anhydrous or substantially anhydrous formic acid. The process has the special feature that a liquid of the general formula Iwhere the radicals R and R are alkyl, cycloalkyl, aryl or aralkyl groups, or R and R jointly, together with the N atom, form a heterocyclic 5- or 6-membered ring, and only one of the radicals is an aryl group, and where R is hydrogen or a C1-C4-alkyl group, employed as extractant is also employed as washing liquid for the offgases produced in the process.
-
公开(公告)号:AR020655A1
公开(公告)日:2002-05-22
申请号:ARP990104764
申请日:1999-09-22
Applicant: BASF AG
Inventor: BESSLING BERND , HASSE HANS , THEIS GERHARD , ADRIAN TILL , VANSANT FRANS
-
-
-
-
-
-
-
-
-