公开(公告)号：CA2280889A1

公开(公告)日：1998-08-13

申请号：CA2280889

申请日：1998-01-30

Applicant: BASF AG

Inventor： VOIT GUIDO ,  REHFINGER ALWIN ,  FISCHER ROLF ,  LUYKEN HERMANN ,  BASSLER PETER

IPC: C07C209/84 ,  C07C209/86 ,  C07C211/12

Abstract: The invention relates to a method for obtaining hexamethylene diamine (I) from a mixture (II) containing (I) hexamethylene diamine, (III) hexamethylenimine, (IV) a compound selected from the group consisting of 2-aminomethyl cyclopentylamine and 1,2-diaminocyclohexane, (V) an imine, and (VI) adipodinitrile and 6-aminocaproic acid nitrile. According to said method, (a) a mixture (II) is subjected to distillation, yielding (a1) a low-boiling fraction which essentially contains (III), (a2) a medium-boiling fraction (VII) containing (I), (IV) and (V), and (a3) a high-boiling fraction containing (V) and (VI); (b) a mixture (VII) is subjected to distillation, yielding (b1) an overhead which essentially contains (IV) and (b2) a mixture (VIII) containing (I) and (V) as bottom residue; and (c) a mixture (VIII) is subjected to distillation, yielding (c1) (I) as overhead and (c2) a bottom residue which contains the essential part of (V).

公开(公告)号：CA2279172A1

公开(公告)日：1998-08-13

申请号：CA2279172

申请日：1998-01-17

Applicant: BASF AG

Inventor： LUYKEN HERMANN ,  BASSLER PETER ,  RUST HARALD ,  REHFINGER ALWIN

IPC: C07C255/24 ,  C07C253/34

Abstract: The invention relates to a method for separating 6-aminocapronitrile from mixtures (I) containing 6-aminocapronitrile and an imine (II) by distillation. Said method is characterized in that distillation occurs in the presence of carbon dioxide.

公开(公告)号：CA2265488A1

公开(公告)日：1998-03-19

申请号：CA2265488

申请日：1997-08-21

Applicant: BASF AG

Inventor： REHFINGER ALWIN ,  LUYKEN HERMANN ,  FLICK KLEMENS ,  VOIT GUIDO ,  BASSLER PETER

IPC: B01J23/78 ,  C07B61/00 ,  C07C209/48 ,  C07C211/12 ,  C07C253/30 ,  C07C255/24

Abstract: The invention concerns a process for simultaneously preparing 6aminocapronitrile and hexamethylene diamine proceeding from a mixture which contains a phosphorated compound and substantially adipodinitrile and is obtained by reacting butadiene with hydrocyanic acid in the presence of a catalyst containing a phosphorated compound. The process is characterized in that: (1) the portion by weight of a phosphorated compound, calculated as phosphorus, in the mixture is reduced; (2) the resultant mixture is partially hydrogenated in the presence of a catalyst in order to form an alpha-, omega aminonitrile; and (3) 6-aminocapronitrile and hexamethylene diamine are separated from the mixture.

公开(公告)号：CA2265436A1

公开(公告)日：1998-03-19

申请号：CA2265436

申请日：1997-08-28

Applicant: BASF AG

Inventor： BASSLER PETER ,  RUST HARALD ,  FISCHER ROLF ,  VOIT GUIDO ,  LUYKEN HERMANN ,  REHFINGER ALWIN ,  MERGER MARTIN

IPC: C07C209/86 ,  C07C211/12 ,  C07C211/36

Abstract: Process for the separation of 2-aminomethylcyclopentylamine from a mixture containing hexamethyldiamine and 2-aminomethylcyclopentylamine, characterized by the fact that the separation is carried out by means of distillation at a pressure of 1-300 mbars.

公开(公告)号：SA1473B1

公开(公告)日：2006-10-29

申请号：SA2230226

申请日：2002-07-29

Applicant: BASF AG

Inventor： HENRIQUE JOAQUIM ,  REHFINGER ALWIN ,  BERG ANNE ,  RUDOLF PETER ,  REBR NORBERT ,  BABLER PETER

IPC: C08L67/00 ,  C08L67/02 ,  C08L77/00 ,  C08L77/02 ,  C08L77/06 ,  C08L77/12

Abstract: الملخص: يتعلقالإختراعالحالىبعملية (process)منأجلتحضيرأكسيدبروبيلين(propylene oxide) تشتعلعلىالأقلعلىالخطواتالتالية:(أ) يتفاعلالبروبين (propene) معبيروكسيدهيدروجين (hydrogen peroxide) فىمذيب (solvent) فىوجودمحفز (catalyst) مناسبلإعطاءخليط (MO) يشتملعلىالأقلعلىأكسيدبروبيلين،مذيب،بروبينغيرمتفاعل،بيروكسيدهيدروجينغيرمتفاعلوأكسجين (oxygen)، (ب) ينفصلأكسيدبروبيلينعنالخليط (MO) لإعطاءخليط (Ml) الذىيشتعلعلىالأقلعلىبروبينغيرمتفاعلوأكسجين،و (ج) يستخدمالخليط (Ml).

公开(公告)号：CA2265436C

公开(公告)日：2006-03-28

申请号：CA2265436

申请日：1997-08-28

Applicant: BASF AG

Inventor： RUST HARALD ,  MERGER MARTIN ,  BASSLER PETER ,  FISCHER ROLF ,  VOIT GUIDO ,  REHFINGER ALWIN ,  LUYKEN HERMANN

IPC: C07C209/86 ,  C07C211/12 ,  C07C211/36

Abstract: Process for the separation of 2-aminomethylcyclopentylamine from a mixture containing hexamethyldiamine and 2-aminomethylcyclopentylamine, characterized by the fact that the separation is carried out by means of distillation at a pressure of 1-300 mbars.

公开(公告)号：CA2280889C

公开(公告)日：2005-07-19

申请号：CA2280889

申请日：1998-01-30

Applicant: BASF AG

Inventor： LUYKEN HERMANN ,  BASSLER PETER ,  FISCHER ROLF ,  REHFINGER ALWIN ,  VOIT GUIDO

IPC: C07C209/84 ,  C07C209/86 ,  C07C211/12

Abstract: The invention relates to a method for obtaining hexamethylene diamine (I) fr om a mixture (II) containing (I) hexamethylene diamine, (III) hexamethylenimine, (IV) a compound selected from the group consisting of 2-aminomethyl cyclopentylamine and 1,2-diaminocyclohexane, (V) an imine, and (VI) adipodinitrile and 6- aminocaproic acid nitrile. According to said method, (a) a mixture (II) is subjected to distillation, yielding (a1) a low-boiling fraction whic h essentially contains (III), (a2) a medium-boiling fraction (VII) containing (I), (IV) and (V), and (a3) a high-boiling fraction containing (V ) and (VI); (b) a mixture (VII) is subjected to distillation, yielding (b1) an overhead which essentially contains (IV) and (b2) a mixture (VIII) containing (I) and (V) as bottom residue; and (c) a mixture (VIII) is subjected to distillation, yielding (c1) (I) as overhead and (c2) a bottom residue which contains the essential part of (V).

公开(公告)号：MX223544B

公开(公告)日：2004-10-19

申请号：MXPA02001115

申请日：2000-07-31

Applicant: BASF AG

Inventor： TELES JOAQUIM HENRIQUE ,  REHFINGER ALWIN ,  BASSLER PETER ,  RIEBER NORBERT ,  WENZEL ANNE ,  WALCH ANDREAS ,  HARDER WOLFGANG

IPC: C07B61/00 ,  C07D301/12 ,  C07D303/04

公开(公告)号：MY116969A

公开(公告)日：2004-04-30

申请号：MYPI9704195

申请日：1997-09-10

Applicant: BASF AG

Inventor： REHFINGER ALWIN ,  VOIT GUIDO ,  LUYKEN HERMANN ,  FISCHER ROLF ,  BABLER PETER

IPC: B01J27/187 ,  C07C253/34 ,  C07B61/00 ,  C07C209/48 ,  C07C209/84 ,  C07C211/12 ,  C07C253/30 ,  C07C255/24

Abstract: A PROCESS FOR COPRODUCTION OF 6-AMINOCAPRONITRILE AND HEXAMETHYLENEDIAMINE STARTING FROM ADIPONITRILE COMPRISES (1) PARTIALLY HYDROGENATING ADIPONITRILE IN THE PRESENCE OF A CATALYST TO OBTAIN A MIXTURE COMPRISING 6-AMINOCAPRONITRILE, HEXAMETHYLENEDIAMINE AND ADIPONITRILE, (2) REMOVING 6-AMINOCAPRONITRILE AND HEXAMETHYLENEDIAMINE FROM THE MIXTURE, (3) ADDING TO THE PORTION COMPRISING ESSENTIALLY ADIPONITRILE FROM 0.01 TO 10BY WEIGHT OF AN ACID, BASED ON ADIPONITRILE, OR AN ACIDIC ION EXCHANGER AND REMOVING THE ADIPONITRILE FROM THE MIXTURE, AND (4) RECYCLING THE ADIPONITRILE INTO STEP(1).

公开(公告)号：MY116967A

公开(公告)日：2004-04-30

申请号：MYPI9704170

申请日：1997-09-09

Applicant: BASF AG

Inventor： REHFINGER ALWIN ,  VOIT GUIDO ,  LUYKEN HERMANN ,  FLICK KLEMENS ,  BABLER PETER

IPC: B01J23/78 ,  C07B61/00 ,  C07C209/48 ,  C07C211/12 ,  C07C253/30 ,  C07C255/24

Abstract: A PROCESS FOR COPRODUCTION OF 6-AMINOCAPRONITRILE AND HEXAMETHYLENEDIAMINE STARTING FROM A MIXTURE COMPRISING A PHOSPHORUS-CONTAINING COMPOUND AND ESSENTIALLY ADIPONITRILE AND OBTAINED BY REACTION OF BUTADIENE WITH HYDROCYANIC ACID IN THE PRESENCE OF A CATALYST COMPRISING A PHOSPHORUS-CONTAINING COMPOUND COMPRISES (1)REDUCING THE WEIGHT PROPORTION OF PHOSPHORUS-CONTAINING COMPOUND, CALCULATED AS PHOSPHORUS, IN THE MIXTURE, (2)PARTIALLY HYDROGENATING THE RESULTING MIXTURE IN THE PRESENCE OF A CATALYST TO FORM AN (ALPHA),( )-AMINONITRILE, AND (3)REMOVING 6-AMINOCAPRONITRILE AND HEXAMETHYLENEDIAMINE FROM THE MIXTURE.