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公开(公告)号:GB2110684B
公开(公告)日:1985-11-06
申请号:GB8233499
申请日:1982-11-24
Applicant: CIBA GEIGY AG
Inventor: NYFELER ROBERT , MEYER ALFRED , STURM ELMAR
IPC: A01N43/50 , A01N43/64 , A01N43/653 , C07D233/60 , C07D249/08 , C07D521/00 , C07D233/56 , C07D249/10
Abstract: Novel substituted azolyl-ethyl ethers of the general formula I wherein R1 is phenyl, phenyl mono- to trisubstituted by halogen, C1-C3- haloalkyl, nitro, C1-C3-alkoxy, C1-C8-alkyl and/or cyano, or phenyl substituted by phenyl or phenoxy, naphthyl, or naphthyl mono- or -disubstituted by halogen, nitro and/or C1-C3-alkyl, benzyl, or benzyl mono- or disubstituted by halogen, nitro and/or C1-C3-alkyl; R2 is phenyl, phenyl mono- to trisubstituted by halogen, C1-C3-haloalkyl, nitro, C1-C3-alkoxy, C1-C8-alkyl and/or cyano, or phenyl substituted by phenyl or phenoxy, or it is C1-C10-alkyl, C3-C8-cycloalkyl or C3-C8- cycloalkyl-(C1-C4-alkyl); R3 is C1-C12-alkyl, C2-C4-alkenyl, C3-C4-alkynyl, benzyl, or benzyl mono- or disubstituted by halogen, nitro and/or C1-C3-alkyl; and R4 is an azolyl group; including acid addition salts thereof, quaternary azolium salts and metal complexes, are used in agrochemical compositions for the preventive and curative combating of harmful microorganisms.
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公开(公告)号:CA1189341A
公开(公告)日:1985-06-25
申请号:CA400724
申请日:1982-04-08
Applicant: CIBA GEIGY AG
Inventor: FANKHAUSER ERNST , STURM ELMAR
IPC: A01H3/04 , A01N33/22 , A01N41/10 , A01N43/08 , A01N47/06 , A01N53/00 , A01N53/10 , C07C317/14 , C07C317/22 , C07C317/36 , C07D307/16 , C07D307/24 , C07D307/38 , C07D307/68
Abstract: The invention describes gametocidal and microbicidal compositions which contain, as active ingredient, a nitroarylalkylsulfone derivative of the formula I (I) wherein Rl is alkyl, R2 and R3 are each hydrogen, alkyl, alkoxy, haloalkyl, halogen, cyano, nitro or amino or together they complete a naphthalene ring; R4 is hydrogen, a metal cation, or -COR5, wherein R5 is alkyl, alkoxy, haloalkoxy, alkenyl, haloalkenyl, alkynyl, cycloalkyl, phenyl, benzyl, furyl or tetrahydrofuryl. The invention relates also to the use of these compositions and compounds for stimulating generative plant growth and for obtaining hybrid seeds, as well as to a method of preparing the hydrazinium and ammonium salts within the scope of the formula I, and to a process for preparing agrochemical compositions which contain compounds of the formula I as active ingredient.
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公开(公告)号:GB2134114B
公开(公告)日:1985-03-27
申请号:GB8404737
申请日:1984-02-23
Applicant: CIBA GEIGY AG
Inventor: FANKHAUSER ERNST , STURM ELMAR
IPC: A01H3/04 , A01N33/22 , A01N41/10 , A01N43/08 , A01N47/06 , A01N53/00 , A01N53/10 , C07C317/14 , C07C317/22 , C07C317/36 , C07D307/16 , C07D307/24 , C07D307/38 , C07D307/68 , C07C147/06
Abstract: The invention describes gametocidal and microbicidal compositions which contain, as active ingredient, a nitroarylalkylsulfone derivative of the formula I (I) wherein R1 is alkyl, R2 and R3 are each hydrogen, alkyl, alkoxy, haloalkyl, halogen, cyano, nitro or amino or together they complete a naphthalene ring; R4 is hydrogen or -COR5, wherein R5 is alkyl, alkoxy, haloalkoxy, alkenyl, haloalkenyl, alkynyl, cycloalkyl, phenyl, benzyl, furyl or tetrahydrofuryl. The invention relates also to the use of these compositions and compounds for stimulating generative plant growth and for obtaining hybrid seeds, as well as to a method of preparing the hydrazinium and ammonium salts within the scope of the formula I, and to a process for preparing agrochemical compositions which contain compounds of the formula I as active ingredient.
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公开(公告)号:DK410384A
公开(公告)日:1985-03-01
申请号:DK410384
申请日:1984-08-28
Applicant: CIBA GEIGY AG
Inventor: HUBELE ADOLF , ECKHARDT WOLFGANG , STURM ELMAR , ZONDLER HELMUT
IPC: A01N43/54 , C07D239/42 , C07D239/46 , C07D239/47 , C07D239/48 , C07D239/50 , C07D239/52 , C07D239/56 , C07D401/12 , C07D405/12 , C07D , A01N
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公开(公告)号:AU2835884A
公开(公告)日:1984-11-22
申请号:AU2835884
申请日:1984-05-18
Applicant: CIBA GEIGY AG
Inventor: NYFELER ROBERT , ZONDLER HELMUT , STURM ELMAR
IPC: C07D249/08 , A01N31/04 , A01N31/14 , A01N43/64 , A01N43/653 , B01J27/10 , B01J31/10 , B01J31/22 , C07B61/00 , C07C20060101 , C07C33/20 , C07C41/00 , C07C41/03 , C07C43/13 , C07C43/178 , C07C43/23 , C07C43/295 , C07C43/315 , C07C67/00 , C07C201/00 , C07C201/12 , C07C205/34 , C07C253/00 , C07C253/30 , C07C255/54 , C07D253/00 , C07D521/00
Abstract: Essentially, a process is described for the preparation of the 1-triazolylethyl ether derivatives, defined in claim 1, of the general formula I (I) which consists in (a) reacting an oxirane of the formula II (II) at temperatures of -20 DEG to +100 DEG C., in the presence of an acid catalyst or an acid condensation agent, with an alcohol of the formula III R3-OH (III) to give a glycol monoether of the formula IV (IV) and (b) subsequently reacting the glycol monoether of the formula IV or one of its esters, in the presence of an acid-binding agent or condensation agent, at temperatures of 0 DEG to 150 DEG C., with a triazole of the formula V (V) the substituents R1, R2 ; amd R3 in the formula II to IV being as defined under formula I and M in formula V being hydrogen or a metal atom. The novel compounds within the scope of formula I and their use are also described.
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公开(公告)号:GB2102782B
公开(公告)日:1984-10-17
申请号:GB8210563
申请日:1982-04-08
Applicant: CIBA GEIGY AG
Inventor: STURM ELMAR , FRANKHAUSER ERNST
IPC: A01H3/04 , A01N33/22 , A01N41/10 , A01N43/08 , A01N47/06 , A01N53/00 , A01N53/10 , C07C317/14 , C07C317/22 , C07C317/36 , C07D307/16 , C07D307/24 , C07D307/38 , C07D307/68 , A01N5/00 , C07C147/06
Abstract: The invention describes gametocidal and microbicidal compositions which contain, as active ingredient, a nitroarylalkylsulfone derivative of the formula I (I) wherein R1 is alkyl, R2 and R3 are each hydrogen, alkyl, alkoxy, haloalkyl, halogen, cyano, nitro or amino or together they complete a naphthalene ring; R4 is hydrogen or -COR5, wherein R5 is alkyl, alkoxy, haloalkoxy, alkenyl, haloalkenyl, alkynyl, cycloalkyl, phenyl, benzyl, furyl or tetrahydrofuryl. The invention relates also to the use of these compositions and compounds for stimulating generative plant growth and for obtaining hybrid seeds, as well as to a method of preparing the hydrazinium and ammonium salts within the scope of the formula I, and to a process for preparing agrochemical compositions which contain compounds of the formula I as active ingredient.
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公开(公告)号:ZA839261B
公开(公告)日:1984-08-29
申请号:ZA839261
申请日:1983-12-13
Applicant: CIBA GEIGY AG
Inventor: STURM ELMAR , MUELLER URS , TOBLER HANS
IPC: A01N43/50 , A01N43/64 , A01N43/653 , C07D233/60 , C07D249/08 , C07D303/22 , C07D303/34 , C07D521/00 , C07D , A01N
Abstract: The compounds described are those of the general formula I (I) in which R1 is an azolyl group; R2 is C1-C12-alkyl; R3 is hydrogen, C1-C12-alkyl, C2-C4-alkenyl or C2-C4-alkinyl, or benzyl which is unsubstituted or substituted by C1-C6-alkyl, C1-C6-alkoxy, C1-C6-haloalkyl, halogen and/or cyano; R4 is hydrogen, fluorine or C1-C6-alkyl; R5 is an unsubstituted or substituted radical chosen from the series comprising phenyl, naphthyl, biphenyl, benzylphenyl and benzyloxyphenyl, the substituents being chosen from the series comprising halogen, cyano, C1-C6-alkyl, C1-C6-alkoxy C1-C6-haloalkyl, C1-C6-alkylthio, C1-C6-haloalkoxy, C1-C3-haloalkylthio, nitro and/or thiocyano; and X is oxygen or sulfur; including the acid addition salts, quaternary azolium salts and metal complexes. Methods for the preparation of these products are also disclosed, as well as agrochemical compositions containing one of these compounds as the active substance. A method of controlling phytopathogenic microorganisms and/or of regulating plant growth with the aid of these substances is furthermore described.
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公开(公告)号:ZA8308695B
公开(公告)日:1984-07-25
申请号:ZA8308695
申请日:1983-11-22
Applicant: CIBA GEIGY AG
Inventor: KUNZ WALTER , STURM ELMAR
IPC: A01N43/50 , A01N43/653 , A61K31/4164 , A61K31/4196 , A61P31/10 , C07C45/61 , C07C45/68 , C07C45/71 , C07D233/60 , C07D249/08 , C07D303/22 , C07D303/32 , C07D405/06 , C07D407/04 , C07D407/06 , C07D521/00 , C07D , A01N
CPC classification number: C07D231/12 , A01N43/50 , A01N43/653 , C07C45/61 , C07C45/68 , C07C45/71 , C07D233/56 , C07D249/08 , C07D303/32 , C07D407/06 , C07C49/84 , C07C49/235
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公开(公告)号:GB2130584A
公开(公告)日:1984-06-06
申请号:GB8330970
申请日:1983-11-21
Applicant: CIBA GEIGY AG
Inventor: STURM ELMAR , KUNZ WALTER
IPC: A01N43/50 , A01N43/653 , A61K31/4164 , A61K31/4196 , A61P31/10 , C07C45/61 , C07C45/68 , C07C45/71 , C07D233/60 , C07D249/08 , C07D303/22 , C07D303/32 , C07D405/06 , C07D407/04 , C07D407/06 , C07D521/00
Abstract: Novel 1-carbonyl-1-phenoxyphenyl-2-azolylethanol derivatives of the general formula I wherein R1 and R2 are each independently hydrogen, halogen C1-C4 alkyl or CF3, and Rn denotes one to three alkyl, alkoxy, haloalkoxy, haloalkyl, halogen and/or cyano groups, R4 is hydrogen, C1-C10 alkyl, C3-C6 cycloalkyl or unsubstituted or substituted phenyl, X is -CH= or -N=, R5 is hydrogen, C1-C12 alkyl, C2-C4 alkenyl, C2-C4 alkynyl, or unsubstituted or substituted benzyl; and A is the radical wherein R6 and R7 are each independently C1-C12 alkyl, unsubstituted or substituted phenyl, or both together form a C2-C4 alkylene bridge which is unsubstituted or substituted by one or more identical or different members selected from the group consisting of C1-C4 alkyl, C2-C4 alkenyloxymethyl or C1-C3 alkoxymethyl; and to the acid addition salts, quaternary azolium salts and metal complexes thereof, are useful for controlling phytopathogenic microorganisms and/or regulating plant growth.
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公开(公告)号:DK248184D0
公开(公告)日:1984-05-17
申请号:DK248184
申请日:1984-05-17
Applicant: CIBA GEIGY AG
Inventor: NYFELER ROBERT , ZONDLER HELMUT , STURM ELMAR
IPC: A01N31/04 , C07D249/08 , A01N31/14 , A01N43/64 , A01N43/653 , B01J27/10 , B01J31/10 , B01J31/22 , C07B61/00 , C07C20060101 , C07C33/20 , C07C41/00 , C07C41/03 , C07C43/13 , C07C43/178 , C07C43/23 , C07C43/295 , C07C43/315 , C07C67/00 , C07C201/00 , C07C201/12 , C07C205/34 , C07C253/00 , C07C253/30 , C07C255/54 , C07D253/00 , C07D521/00 , C07D249
Abstract: Essentially, a process is described for the preparation of the 1-triazolylethyl ether derivatives, defined in claim 1, of the general formula I (I) which consists in (a) reacting an oxirane of the formula II (II) at temperatures of -20 DEG to +100 DEG C., in the presence of an acid catalyst or an acid condensation agent, with an alcohol of the formula III R3-OH (III) to give a glycol monoether of the formula IV (IV) and (b) subsequently reacting the glycol monoether of the formula IV or one of its esters, in the presence of an acid-binding agent or condensation agent, at temperatures of 0 DEG to 150 DEG C., with a triazole of the formula V (V) the substituents R1, R2 ; amd R3 in the formula II to IV being as defined under formula I and M in formula V being hydrogen or a metal atom. The novel compounds within the scope of formula I and their use are also described.
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