公开(公告)号：JPH1046034A

公开(公告)日：1998-02-17

申请号：JP10485197

申请日：1997-04-22

Applicant: TORAY INDUSTRIES

Inventor： MATSUOKA HIDEO ,  YAMAUCHI KOJI ,  INOUE SHUNEI

IPC: C08K3/32 ,  C08K5/3492 ,  C08L67/00 ,  C08L101/00

Abstract: PROBLEM TO BE SOLVED: To obtain a flame-retardant resin composition capable of imparting high flame retardance to a thermoplastic resin by using a non-halogen-based flame retardant and having good moldability and mechanical properties and obtain a molding by molding the resin composition. SOLUTION: This resin composition is obtained by blending 100 pts.wt. thermoplastic resin with 0.1-100 pts.wt. red phosphorus and 0.5-100 pts.wt. salt of triazine-based compound with cyanuric acid or isocyanuric acid. Number- average dispersed particle diameter of red phosphorus in the resin composition is 50-0.01μm and number-average dispersed particle diameter of the salt of the triazine-based compound with a cyanuric acid or isocyanuric acid is 100-0.01μm.

公开(公告)号：JPH1046009A

公开(公告)日：1998-02-17

申请号：JP10324397

申请日：1997-04-21

Applicant: TORAY INDUSTRIES

Inventor： KAYABA KEIJI ,  OKAMOTO MASARU ,  INOUE SHUNEI

IPC: C08K7/00 ,  C08L67/00

Abstract: PROBLEM TO BE SOLVED: To obtain a thermoplastic resin composition which is excellent in resistance to heat, moldability, fluidity, resistance to hydrolysis and mechanical properties by formulating a specific liquid crystal polyester and a polyphenylene sulfide treated with an acid or boiling water. SOLUTION: This thermoplastic resin composition comprises 50-99wt.% of a liquid polyester which contains the structural units of formulas I-III and the formula: -(O-X-O)- (X is formula IV, -CH2 CH2 -), has a heat distortion temperature of 190-280 deg.C, the liquid crystal-starting temperature of

公开(公告)号：JPH1030052A

公开(公告)日：1998-02-03

申请号：JP33344696

申请日：1996-12-13

Applicant: TORAY INDUSTRIES

Inventor： UMETSU HIDEYUKI ,  NAKAMURA SEIICHI ,  INOUE SHUNEI ,  SAKAI YOSHINORI ,  KUREMATSU TOSHIO

IPC: C08J5/00 ,  C08K3/00 ,  C08K7/04 ,  C08K7/14 ,  C08K9/06 ,  C08L25/00 ,  C08L25/18 ,  C08L67/00

Abstract: PROBLEM TO BE SOLVED: To obtain a liquid crystal resin composition which is excellent in flowability and mechanical characteristics, particularly improved in stiffness, anisotropy and abrasion. SOLUTION: This liquid crystal resin composition contains 100 pts.wt. of a liquid crystal resin comprising 99.5-50wt.% of a semi-aromatic liquid crystal polyester resin and 0.5-50wt.% of a wholly aromatic liquid crystal polyester resin and 5-200 pts.wt. of an inorganic filler where the average aspect ratio of the filler is 25-100 in the composition. The objective molded products are produced by molding this liquid crystal resin composition.

公开(公告)号：JPH1025338A

公开(公告)日：1998-01-27

申请号：JP18092396

申请日：1996-07-10

Applicant: TORAY INDUSTRIES

Inventor： YAMAUCHI KOJI ,  MATSUOKA HIDEO ,  INOUE SHUNEI

IPC: C08K5/3492 ,  C08G63/692 ,  C08L67/00 ,  C08L67/02

Abstract: PROBLEM TO BE SOLVED: To obtain a phosphorus-containing polyester polymer which can impart excellent flame retardancy, mechanical properties and resistance against hydrolysis and is useful as fiber, film or the like by copolymerizing a polyester with a specific phosphorus compound. SOLUTION: This polymer is a polyester polymer containing the recurring units of formulae I and II (Ar1 is a halogen-free divalent aromatic residue; R1 is a halogen-free divalent aliphatic residue; (x) and (y) are each a mole % of the recurring unit in the recurring units) and a phosphorus-containing units. The phosphorus-containing unit is at least one kind among the recurring units of formula III and formula IV (R2 -R5 are each a halogen-free monovalent organic residue; z1 and z2 are each defined to be identical with (x) and (y) and, if the total of the components, (x), (y), z1 and z2 is defined as 100mol%, (x)+z1 is substantially equal to (y)+z2 and the number-average molecular weight is >=500. In addition, (x), (y), z1 and z2 preferably satisfy the formula, 0

公开(公告)号：JPH09302203A

公开(公告)日：1997-11-25

申请号：JP33344596

申请日：1996-12-13

Applicant: TORAY INDUSTRIES

Inventor： UMETSU HIDEYUKI ,  NAKAMURA SEIICHI ,  INOUE SHUNEI ,  SAKAI YOSHINORI ,  KUREMATSU TOSHIO

IPC: C08J5/00 ,  C08K3/00 ,  C08K7/04 ,  C08K7/14 ,  C08K9/06 ,  C08L67/00

Abstract: PROBLEM TO BE SOLVED: To obtain a liquid crystal resin composition excellent in flowability and mechanical properties and improved in the balance especially between toughness and rigidity. SOLUTION: This composition comprises 100 pts.wt. liquid crystal resin consisting of 99.5-50wt.% particlly aromatic liquid crystal polyester resin and 0.5-50wt.% wholly aromatic liquid crystal polyester resin and 5-200 pts.wt. inorganic filler having an average aspect ratio of 3-25, exclusive of 25. The molded article is obtained by molding this composition.

公开(公告)号：JPH09183891A

公开(公告)日：1997-07-15

申请号：JP27967696

申请日：1996-10-22

Applicant: TORAY INDUSTRIES

Inventor： KUREMATSU TOSHIO ,  NAKAMURA SEIICHI ,  INOUE SHUNEI

IPC: C08L67/02 ,  C08L67/00 ,  C08L69/00 ,  C08L77/00 ,  C08L77/12 ,  C08L101/00

Abstract: PROBLEM TO BE SOLVED: To obtain a thermoplastic resin composition excellent in mechanical characteristics, flowability during molding and impact strength and useful for housing parts, etc., by adding a predetermined filler to a resin composition containing a liquid crystalline resin, etc. SOLUTION: This thermoplastic composition is obtained by adding (D) 0-200 pts.wt. filler such as glass fiber to 100 pts.wt. resin composition comprising (A) 1-50wt.% liquid crystalline resin such as a liquid crystalline polyester, etc., consisting of structural units of formula I-IV (R1 is 4,4'-biphenylene, p-phenylene, etc.; R2 is p-phenylene, 2,6-naphthalene, etc.), (B) 99-25wt.% copolyester comprising condensation units of ethylene glycol, 1,4-cyclohexanedimethanol and terephthalic acid and having a molar ratio of ethylene glycol unit/ cyclohexanedimethanol unit in (20/80)-(80/20) and (C) 0-74wt.% thermoplastic resin except the components A and B such as polycarbonate, etc., each based on 100wt.% resin composition.

公开(公告)号：JPH08183910A

公开(公告)日：1996-07-16

申请号：JP32755294

申请日：1994-12-28

Applicant: TORAY INDUSTRIES

Inventor： KUREMATSU TOSHIO ,  NAKAMURA SEIICHI ,  INOUE SHUNEI

IPC: G02F1/13 ,  C08L67/00 ,  C08L69/00 ,  C08L71/00 ,  C08L71/12 ,  C08L77/00 ,  C08L77/12 ,  C08L101/00 ,  C09K19/38

Abstract: PURPOSE: To obtain the composition useful as electric/electronic parts, having excellent mechanical strength and moldability by adding a specific epoxy- modified vinyl-based copolymer in a specific ratio to a thermoplastic resin composition. CONSTITUTION: This composition is obtained by blending 100 pts.wt. of a resin composition composed of (i) 1-99wt.% of a liquid crystal resin and (ii) 99-1wt% of one or more thermoplastic resins of a styrenic resin, a polycarbonate resin and a polyphenylene ether-based resin with (B) (iii) 0.01-30 pts.wt. of an epoxy- modified vinyl-based copolymer (e.g., glycidyl methacrylate/styrenic copolymer) copolymerized with 0.01-15wt.% of a glycidyl group-containing vinyl monomer and (D) 0-200 pts.wt. of a filler (e.g., glass fibers). The component A is preferably a liquid polyester comprising structural units of formula I to formula IV in the ratios of the sum of the components of the formula IV formula II to that of the components of formula I to formula III of 60-95mol%, the amount of the formula III to the sum of the components of formula I to formula III of 40-5mol% and the ratio of formula I/formula II of 75/25-95/5 molar ratio.

公开(公告)号：JPH08165411A

公开(公告)日：1996-06-25

申请号：JP26127495

申请日：1995-10-09

Applicant: TORAY INDUSTRIES

Inventor： KUREMATSU TOSHIO ,  NAKAMURA SEIICHI ,  INOUE SHUNEI

IPC: C08K3/24 ,  C08K3/16 ,  C08K3/28 ,  C08K3/30 ,  C08K3/32 ,  C08K3/38 ,  C08K5/02 ,  C08K5/09 ,  C08K5/42 ,  C08L67/00 ,  C08L77/00 ,  C08L77/12

Abstract: PURPOSE: To obtain a resin composition, excellent in retention stability, having good mechanical properties and appearance of moldings, excellent in heat resistance and useful for mechanical parts, etc., by adding a specific nonfibrous metallic salt to a liquid crystal polyester (amide) after completing the polymerization. CONSTITUTION: This compound is obtained by adding (B) 0.001-5 pts.wt. nonfibrous metallic salt which is a metallic salt of at least one or more acids selected from sulfuric acid, hydrogen halides, hitric, boric, phosphoric, pyrophosphoric, formic, 1-10C alkylcarboxylic acids, oxalic, 1-10C alkylenedicarboxylic, benzoic, benzenesulfonic and 1-20C alkylbenzenesulfonic acids to (A) 100 pts.wt. liquid crystal polyester and/or liquid crystal polyester amide (containing ethylenedioxy unit as an essential component and having a structural unit of formulas I to IV) after completing the polymerization. Furthermore, (C) 0.001-5 pts.wt. any one or more compounds of (hypo)phosphorous acid and metallic salts thereof is preferably contained therein.

公开(公告)号：JPH0853605A

公开(公告)日：1996-02-27

申请号：JP18970594

申请日：1994-08-11

Applicant: TORAY INDUSTRIES

Inventor： KUREMATSU TOSHIO ,  NAKAMURA SEIICHI ,  INOUE SHUNEI

IPC: C08K3/32 ,  C08L67/00 ,  C08L77/12

Abstract: PURPOSE:To obtain a resin composition excellent in color tone residence stability, and heat resistance and satisfactory in mechanical properties and molding appearance by incorporating a specific phosphoric acid compound into a liquid- crystal polyester or liquid-crystal polyester-amide. CONSTITUTION:The composition comprises 100 pts.wt. liquid-crystal polyester and/or liquid-crystal polyester-amide and 0.001-5 pts.wt. at least one compound selected from among phosphorous acid, hydrophosphorous acid, and metal salts of these. For further improving residence stability, another metal salt (e.g., potassium sulfate, potassium acetate, or barium acetate) may be incorporated in an amount of about 0.001-5 pts.wt. For imparting flame retardancy to the composition, an organobromine compound can be incorporated in an amount of about 0.5-30 pts.wt.

公开(公告)号：JPH0853543A

公开(公告)日：1996-02-27

申请号：JP18970494

申请日：1994-08-11

Applicant: TORAY INDUSTRIES

Inventor： TANAKA YOSHINORI ,  AKIYAMA FUMIO ,  INOUE SHUNEI

IPC: C08L67/03 ,  C08G63/60 ,  C08G63/688 ,  C08L67/00

Abstract: PURPOSE:To obtain a liquid crystal polyester useful for machine parts, etc., having a structural unit expressed by a specific formula, excellent in a weld strength, suppressing acetic acid generated on heating or melting and capable of giving molded products having nice color tones. CONSTITUTION:This objective polyester comprises unit I;-X-Y-SO3M and/or unit II;-X-Y-COOM (X is O or CO; Y is a bivalent organic group having no carboxylic group as a substituent; M is an alkali metal) and has 0.5-5dl/g logarithmic viscosity measured in pentafluorophenol at expressed by formula I and formula II. The polyester contains 0.01-2mol% of the unit I and II based on the sum total of carboxylic groups (residues) in the polyester when X is 0 and 0.001-2mol% based on the total sum of hydroxyl groups (residues) in the polyester when X is CO. Further, the polyester preferably contains a unit structure of formula III, etc.