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公开(公告)号:DE59603866D1
公开(公告)日:2000-01-13
申请号:DE59603866
申请日:1996-04-23
Applicant: BASF AG
Inventor: GRAMMENOS WASSILIOS , GOETZ NORBERT , SAUTER HUBERT , OBERDORF KLAUS
IPC: C07C67/327 , C07C67/333 , C07C67/343 , C07C69/734
Abstract: PCT No. PCT/EP96/01689 Sec. 371 Date Oct. 9, 1997 Sec. 102(e) Date Oct. 9, 1997 PCT Filed Apr. 23, 1996 PCT Pub. No. WO96/34847 PCT Pub. Date Nov. 7, 1996A process for the preparation of essentially isomerically pure methyl E-2-(2-aryloxymethylenephenyl)crotonates of the formula Ia Ia where R is an aromatic radical and R' is a C1-C3-alkyl group, which comprises first converting a suitable methyl 2-(2-aryloxymethylenephenyl)- alpha -ketoacetate with an alkyl metal compound of the formula IIIM-CH2-R'IIIwhere M is a metal ion equivalent into the corresponding methyl 2-(2-aryloxymethylenephenyl)- alpha -hydroxybutyrate of the formula IV, subsequently dehydrating IV in the presence of an acid to give a mixture of methyl E- and Z-2-(2-aryloxymethylenephenyl)crotonates and, subsequently, converting this mixture in the presence of a base in an inert polar solvent into the essentially isomerically pure methyl E-2-(2-aryloxymethylenephenyl)crotonate Ia.
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142.
公开(公告)号:NZ325256A
公开(公告)日:1999-11-29
申请号:NZ32525696
申请日:1996-12-16
Applicant: BASF AG
Inventor: GROTE THOMAS , SAUTER HUBERT , KIRSTGEN REINHARD , BAYER HERBERT , MULLER RUTH , MULLER BERND , OBERDORF KLAUS , GRAMMENOS WASSILIOS , GOTZ NORBERT , RACK MICHAEL , HARREUS ALBRECHT , ROHL FRANZ , AMMERMAN EBERHARD , HARRIES VOLKER , LORENZ GISELA , STRATHMANN SIEGFRIED
IPC: C07C249/04 , A01N37/50 , A01N43/40 , A01P3/00 , A01P7/00 , C07C251/50 , C07C251/56 , C07C251/58 , C07C251/60 , C07C255/40
Abstract: The present relates to 2-iminooxyphenylacetic acid derivatives of the formula 1 where the substitutents are defined in the specification, and method of treating fungi and animal pests, and process for the preparation of the compound.
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143.
公开(公告)号:CA2332019A1
公开(公告)日:1999-11-25
申请号:CA2332019
申请日:1999-05-04
Applicant: BASF AG
Inventor: LORENZ GISELA , GROTE THOMAS , AMMERMANN EBERHARD , PTOCK ARNE , BAYER HERBERT , HARRIES VOLKER , KEIL MICHAEL , SAUTER HUBERT , GOTZ ROLAND , CULLMANN OLIVER , MULLER BERND , STRATHMANN SIEGFRIED , GEWEHR MARKUS , GYPSER ANDREAS , GRAMMENOS WASSILIOS
IPC: C07C251/38 , A01N37/40 , C07C49/303 , C07C251/42 , C07C251/50 , C07C251/52 , C07C251/60 , C07C49/35 , A01N37/50
Abstract: The invention relates to bisoximether derivatives of formula (I) in which th e variables have the following meanings: R1 represents halogen, C1-C4 alkyl, C 1- C4 alkyl halide, C1-C4 alkoxy or C1-C4 alkoxy halide; n is 1 to 5, whereby t he radicals R1 can be different if n is not equal to 1; R2 represents C1-C4 alkyl, C3-C6 alkenyl or C3-C6 alkynyl, whereby these groups can be partially or completely halogenated; Q represents C(=CHOCH3)-COOCH3, C(=CHCH3)-COOCH3, C(=NOCH3)-COOCH3 or C(=NOCH3)-CONHCH3. The invention also relates to the sal ts of the bisoximether derivatives, to methods and intermediate products for th e production of these compounds and to their use for combating animal pests an d fungicidal pests.
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公开(公告)号:CZ285824B6
公开(公告)日:1999-11-17
申请号:CZ215495
申请日:1994-02-12
Applicant: BASF AG
Inventor: KIRSTGEN REINHARD , GRAMMENOS WASSILIOS , BAYER HERBERT , DOETZER REINHARD , KOENIG HARTMANN , OBERDORF KLAUS , SAUTER HUBERT , WINGERT HORST , LORENZ GISELA , AMMERMANN EBERHARD
IPC: C07C251/48 , A01N37/50 , A01N43/50 , A01N43/56 , A01N43/647 , A01N43/653 , A01N43/74 , A01N43/76 , A01N43/78 , A01N43/80 , A01N43/82 , A01N43/824 , A01N43/828 , A01N43/836 , A01P3/00 , A01P7/02 , A01P7/04 , C07D207/00 , C07D231/18 , C07D231/20 , C07D231/22 , C07D233/70 , C07D233/84 , C07D249/04 , C07D249/08 , C07D249/12 , C07D261/12 , C07D263/20 , C07D263/38 , C07D263/40 , C07D263/46 , C07D271/06 , C07D271/07 , C07D271/10 , C07D271/113 , C07D277/20 , C07D277/28 , C07D277/34 , C07D277/36 , C07D285/08 , C07D285/125 , C07D401/04 , C07D403/04 , C07D405/04 , C07D409/04 , C07D413/04 , C07D417/04 , C07D417/14
Abstract: Ortho-substd. 2-methoxyiminophenyl ethanoic acid methyl amide derivs. of formula (I) are new. In (I), n = 0-4, X = O or S, Y = 5-membered heteroaromatic ring, which in addn. to R2 can also contain up to 3 gps. chosen from Cl, Me, CF3 or OMe, each R1 is NO2, CN, halogen, 1-4C alkyl, 1-4C haloalkyl, 1-4C alkoxy, 1-4C haloalkoxy, 1-4C alkylthio opt. substd. Ph or PhO. R2 = H, opt. substd. alkyl, alkenyl or alkynyl, on opt. substd. satd. or mono- or di-unsatd. ring contg. in addn. to C, 1-3 heteroatoms as ring members chosen from O, S and N or an opt. substd. mono- or di-nuclear aromatic ring contg. in addn. to C, 1-4 N or 1-2 N and 1 O or S heteroatoms as ring members.
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公开(公告)号:AU2718899A
公开(公告)日:1999-08-23
申请号:AU2718899
申请日:1999-01-26
Applicant: BASF AG
Inventor: PTOCK ARNE , SAUTER HUBERT , KIRSTGEN REINHARD , GRAMMENOS WASSILIOS , GROTE THOMAS , GYPSER ANDREAS , BAYER HERBERT , GEWEHR MARKUS , CULLMANN OLIVER , MULLER BERND , GOTZ ROLAND , ROHL FRANZ , AMMERMANN EBERHARD , LORENZ GISELA , HARRIES VOLKER , STRATHMANN SIEGFRIED
IPC: A01N43/48 , A01N43/56 , C07D401/12 , C07D401/14
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公开(公告)号:HU216269B
公开(公告)日:1999-05-28
申请号:HU9801604
申请日:1996-04-23
Applicant: BASF AG
Inventor: GRAMMENOS WASSILIOS , GOETZ NORBERT , OBERDORF KLAUS , SAUTER HUBERT
IPC: C07C67/327 , C07C67/333 , C07C67/343 , C07C69/734
Abstract: PCT No. PCT/EP96/01689 Sec. 371 Date Oct. 9, 1997 Sec. 102(e) Date Oct. 9, 1997 PCT Filed Apr. 23, 1996 PCT Pub. No. WO96/34847 PCT Pub. Date Nov. 7, 1996A process for the preparation of essentially isomerically pure methyl E-2-(2-aryloxymethylenephenyl)crotonates of the formula Ia Ia where R is an aromatic radical and R' is a C1-C3-alkyl group, which comprises first converting a suitable methyl 2-(2-aryloxymethylenephenyl)- alpha -ketoacetate with an alkyl metal compound of the formula IIIM-CH2-R'IIIwhere M is a metal ion equivalent into the corresponding methyl 2-(2-aryloxymethylenephenyl)- alpha -hydroxybutyrate of the formula IV, subsequently dehydrating IV in the presence of an acid to give a mixture of methyl E- and Z-2-(2-aryloxymethylenephenyl)crotonates and, subsequently, converting this mixture in the presence of a base in an inert polar solvent into the essentially isomerically pure methyl E-2-(2-aryloxymethylenephenyl)crotonate Ia.
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公开(公告)号:AU1335399A
公开(公告)日:1999-05-17
申请号:AU1335399
申请日:1998-10-21
Applicant: BASF AG
Inventor: GRAMMENOS WASSILIOS , OBERDORF KLAUS , SAUTER HUBERT , GYPSER ANDREAS , BAYER HERBERT , GEWEHR MARKUS , GROTE THOMAS , MULLER BERND , PTOCK ARNE , ROHL FRANZ , HAMPRECHT GERHARD , GOTZ NORBERT , AMMERMANN EBERHARD , LORENZ GISELA , STRATHMANN SIEGFRIED
IPC: A01N43/40 , C07D213/64
Abstract: Substituted 2-(2'-pyridyloxy)phenylacetamides I,whereR1 is fluorine, chlorine, CH3 or halomethyl;R2 is fluorine, bromine, alkyl or halomethyl;R3 is hydrogen or one of the radicals mentioned under R2; andR2 is 6-chloro if R3 is hydrogen,R3 is 5-chloro if R2 is fluorineand the compound in which R1, R2 and R3 are each chlorinewith the proviso that R1 may not be chlorine if R2 is 5-trifluoromethyl and R3 is hydrogen,and processes for their preparation and their use for controlling harmful fungi and animal pests are described.
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148.
公开(公告)号:CO4770924A1
公开(公告)日:1999-04-30
申请号:CO96064306
申请日:1996-12-06
Applicant: BASF AG
Inventor: MULLER BERND , SAUTER HUBERT , BAYER HERBERT , GRAMMENOS WASSILIOS , GROTE THOMAS
IPC: C07D213/75 , A01N43/40 , A01N47/08 , A01N47/18 , C07D213/74 , C07D213/76 , C07D213/79 , C07D213/81 , C07D401/12 , C07D401/14 , C07D405/12 , C07D405/14 , C07D409/12 , C07D409/14 , C07D413/12 , C07D413/14 , C07D417/12 , C07D417/14
Abstract: Carbamatos de piridilo de la fórmula Ien la que el índice y los sustituyentes tienen lossignificados siguientes: R´ hidrógeno, alquilo eventualmente sustituido, alquenilo, alquinilo, cicloalquilo, cicloalquenilo, alquilcarbonilo y alcoxicarbonilo; R" alquilo eventualmente sustituido, alquenilo, alquinilo, cicloalquilo cicloalquenilo, o cuando V significa un grupo amino, adicionalmente hidrógeno; V oxígeno (-O-), azufre (-S-) o un grupo amino, que puede llevar uno de los siguientes radicales: alquilo, alquenilo, alquinilo o cicloalquilo; X ciano, nitro, halógeno, Alquilo eventualmente sustituido, alquenilo, alquinilo, alcoxi, alqueniloxi, alquiloxi, o cuando n ANDgt; 1, un puente eventualmente sustituido unido a dos átomos de carbono vecinos del anillo piridilo, que contiene 3 a 4 miembros del grupo: 3 ó 4 átomos de carbono, 2 hasta 3 átomos de carbono y uno o dos átomos de nitrógeno, de oxígeno y/o de azufre, pudiendo este puente formar junto con el anillo al que está ligado, un radical parcialmente insaturado o aromático; n 0, 1, 2 o 3, pudiendo los radicales Y ser diferentes cuando n ANDgt; 1; R halógeno, hidroxi, mercapto, amino, formilo, carboxilo, carbonilamino o un radical orgánico que está ligado directamente o por vía de un grupo oxi, mercapto, amino carboxilo o carbonilamino, o forman junto con un grupo X y el anillo piridilo al que están ligados, un sistema bicíclico parcial o totalmente insaturado, eventualmente sustituido, que además de miembros anulares de carbono puede contener heteroátomos del grupo oxígeno, azufre y nitrógeno.
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公开(公告)号:CO4770922A1
公开(公告)日:1999-04-30
申请号:CO96057858
申请日:1996-11-01
Applicant: BASF AG
Inventor: MULLER BERND , SAUTER HUBERT , BAYER HERBERT , GRAMMENOS WASSILIOS , GROTE THOMAS , OBERDORF KLAUS , ROHL FRANZ , GOTZ NORBERT , RACK MICHAEL
IPC: C07D213/30 , A01N37/10 , A01N37/50 , A01N43/40 , C07D213/53 , C07D213/54 , A01N41/34
Abstract: Derivados del ácido piridilacético de la fórmula Ien la que los sustituyentes y el índice tienen los significados siguientes: X NOCH3 , CHOCH3 , CHCH3 y CHCH2 CH3 ; Y oxígeno o NR´;R´ hidrógeno o C1 -C4 -alquilo;m 0, 1 ó 2, pudiendo los radicales R ser diferentes cuando m es 2; R ciano, nitro, trifluorometilo, halógeno, C1-C4-alquilo y C1-C4-alcoxi; R1 hidrógeno y C1 -C4 -alquilo; R2 hidrógeno, ciano, nitro, hidroxi, amino, halógeno, C1 -C4 -alquilo, C1 -C4 -halogenoalquilo, C1 -C4 -alcoxi, C1 -C4 -halogenoalcoxi, C1 -C4 -alquiltio, C1 -C4 -alquilamino o di-C1 -C4 -alquilamino; R3 hidrógeno, ciano nitro, hidroxi, amino, halógeno, C1 -C6 -alquilo, C1 -C6 -alcoxi, C1 -C6 -alquiltio, C1 -C6 -alquilamino, di-C1 -C6 -alquilamino, C2 -C6 -alquenilo, C2 -C6 -alqueniloxi, C2 -C6 -alqueniltio, C2 -C6 -alquenilamino, N-C2 -C6 -alquenil-N-C1 -C6 -alquilamino, C2 -C6 -alquinilo, C2 -C6 -alquiniloxi, C2 -C6 -alquiniltio, C2 -C6 -alquinilamino, N-C2 -C6 -alquinil -N-C1 -C6 -alquilamino, donde los radicales hidrocarburo de estos grupos pueden estar parcial o totalmente halogenados o llevar de uno a tres de los...
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公开(公告)号:AU704131B2
公开(公告)日:1999-04-15
申请号:AU5691896
申请日:1996-04-23
Applicant: BASF AG
Inventor: GRAMMENOS WASSILIOS , GOTZ NORBERT , SAUTER HUBERT , OBERDORF KLAUS
IPC: C07C67/327 , C07C67/333 , C07C67/343 , C07C69/734
Abstract: PCT No. PCT/EP96/01689 Sec. 371 Date Oct. 9, 1997 Sec. 102(e) Date Oct. 9, 1997 PCT Filed Apr. 23, 1996 PCT Pub. No. WO96/34847 PCT Pub. Date Nov. 7, 1996A process for the preparation of essentially isomerically pure methyl E-2-(2-aryloxymethylenephenyl)crotonates of the formula Ia Ia where R is an aromatic radical and R' is a C1-C3-alkyl group, which comprises first converting a suitable methyl 2-(2-aryloxymethylenephenyl)- alpha -ketoacetate with an alkyl metal compound of the formula IIIM-CH2-R'IIIwhere M is a metal ion equivalent into the corresponding methyl 2-(2-aryloxymethylenephenyl)- alpha -hydroxybutyrate of the formula IV, subsequently dehydrating IV in the presence of an acid to give a mixture of methyl E- and Z-2-(2-aryloxymethylenephenyl)crotonates and, subsequently, converting this mixture in the presence of a base in an inert polar solvent into the essentially isomerically pure methyl E-2-(2-aryloxymethylenephenyl)crotonate Ia.
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