PYRAZOL-4-YL-BENZOYL DERIVATIVES AND THEIR USE AS HERBICIDES

    公开(公告)号:BG101825A

    公开(公告)日:1998-04-30

    申请号:BG10182597

    申请日:1997-08-08

    Applicant: BASF AG

    Abstract: Pyrazol-4-yl-benzoyl derivatives have the formulain which the substituents have the following meanings: L, M arehydrogen, C1-C6 alkyl, C2-C6 alkenyl, C2-C6 alkinyl, C1-C4 alkoxy,these groups being optionally substituted by 1 to 5 halogen atomsor C1-C4 alkoxy, halogen, cyano, nitro, a group -(Y)n-S(O)mR7 or agroup -(Y)n,-CO-R8; Z is a 5 or 6-membered saturated orunsaturated heterocyclic rest, that contains 1 to 3 heteroatomsselected from the group that includes oxygen, sulphur or nitrogen,optionally substituted by halogen, cyano, nitro, a group -CO-R8,C1-C4 alkyl, C1-C4 halogen alkyl, C3-C8 cycloalkyl, C1-C4 alkoxy,C1-C4 halogen alkoxy, C1-C4 alkylthio, C1-C4 halogen alkylthio,di-C1-C4-alkylamino, a phenyl optionally substituted by halogen,cyano, nitro C1-C4 alkyl or C1-C4 halogen alkyl or a twice boundoxygen that optionally in the tautomer form may also be a hydroxygroup, or that forms a bicyclic system together with a condensedphenyl ring optionally substituted by halogen, cyano, nitro, C1-C4alkyl or C1-C4 halogen alkyl, with a condensed carbon cycle orwith a second condensed heterocycle optionally substituted byhalogen, cyano, nitro, C1-C4 alkyl, di-C1-C4-alkylamino, C1-C4alkoxy, C1-C4 halogen alkoxy or C1-C4 halogen alkyl; Y is 0, NR9;n equals 0 or 1; m equals 0, 1 or 2; R7 is C1-C4 alkyl, C1-C4halogen alkyl or NR9R10; R8 is C1-C4 alkyl, C1-C4 halogen alkyl,C1-C4 alkoxy or NR9R10; R9 is hydrogen or C1-C4 alkyl; R10 isC1-C4 alkyl; Q is a pyrazol ring linked at position 4 having theformulain which R1 is C1-C4 alkyl; R2 is hydrogen or C1-C4 alkyl; and R3is hydrogen, C1-C4 alkyl sulphonyl, phenyl sulphonyl or alkylphenyl sulphonyl. Also disclosed are the salts of compounds (I)usually utilized in agriculture.8 claims

    DERIVADOS DEL ACIDO 5-PIRAZOLILBENZOICO.

    公开(公告)号:MX9709955A

    公开(公告)日:1998-03-29

    申请号:MX9709955

    申请日:1996-06-27

    Applicant: BASF AG

    Abstract: Derivados I del ácido 5-pirazolilbenzoico: donde: R1 es H, alquilo-C1-C4, ciano-alquilo-C1-C4, halo-alquilo-C1-C4; R2 es alcoxi-C1-C4, alquil-C1-C4-tio, haloalcoxi-C1-C4, o haloalquil-C1-C4-tio; R3 es H, CN, NO2, halogeno; R4 es halogeno; R5 es CN, halogeno, alquilo-C1-C4, haloalquilo-C1-C4, alcoxi-C1-C4, o haloalcoxi-C1-C4; R6 es -O-R7, -S-R7, -N(R8)-R7 o -N(R8)-O-R7; R7 es -X-C(R9)=N-OR10, -X-C(R9)=N-O-Z-R10; -X-O-N=C(R11, R12), -X-SO2-R13 o heterciclilo, insubstituido o substituido, de 3 a 7 miembros, o heterociclilo-alquilo-C1-C4; el heterocíclo contiene, además de miembros de metileno, uno a tres miembros de anillo, seleccionados del grupo que consta de tres puentes aza y dos átomos de oxígeno o de azufre, y, si se desea, es posible, que uno o dos gruspo de metileno del heterociclo sean reemplazados por -CO-, -CS- y/o -SO2-; R8 es H, alquilo-C1-C4, haloalquilo-C1-C4, alquenilo-C3-C5, haloalquenilo-C3-C5, alquinilo-C3-C5, alquil-C1-C4-sulfonilo; R9 es H, CN, alquilo-C1-C4, alcoxi-C1-C4 o alquil-C1-C4-tio; R10 es H, alquilo-C1-C4, haloalquilo-C1-C4, cianoalquilo-C1-C4, di(alquil-C1-C4)amino-alquilo-C1-C4, alcoxi-C1-C4-alquilo-C1-C4, alquil-C1-C4-tio-alquilo-C1-C4, (alquil-C1-C4)carbonilo, (alcoxi-C1-C4)carbonilo, di(alquil-C1-C4)-aminocarbonilo, haloalquil-C1-C4)carbonilo, alquenilo-C3-C5, haloaquenilo-C3-C5, di(alquil-C1-C4)amino-alquenilo-C3-C5, alcoxi-C1-C4-alquenilo-C3-C5, alquil-C1-C4-tio-alquenilo-C3-C5, alquinilo-C3-C5, haloalquinilo-C3-C5, cicloalquilo-C3-C7, insubstituido o substituido, fenilo, benzoílo o un heteroarilo de 5 o 6 miembros, que tiene 1 a 3 heteroátomos; R11, R12, son H, alquilo-C1-C4, haloalquilo-C1-C4, alcoxi-C1-C4-alquilo-C1-C4, alquenilo-C3-C5, haloalquenilo-C3-C5, alquinilo-C3-C5, haloalquinilo-C3-C5, cicloalquilo-C3-C7, insubstituido o substituido, o fenilo, o R11 + R12 juntos con el átomo de carbono al cual ellos se unen, forman un anillo saturado de 3 a 8 miembros, el cual, si se desea, puede contener además miembros de metileno, uno o dos oxígenos, azufres y/o miembros de anillo aza; R13 es alquilo-C1-C4, haloalquilo-C1-C4, cianoalquilo-C1-C4, di(alqiulo-C1-C4)amino-(alquilo-C1-C4), alcoxi-C1-C4-alquilo-C1-C4), alquiltio-C1-C4-alquilo-C1-C4, alquenilo-C3-C5, haloalquenilo-C3-C5, di(alquil-C1-C4)-amino-alquenilo-C3-C5, alcoxi-C1-C4-alquenilo-C3-C5, alquiltio-C1-C4-alquenilo-C3-C5), alquinilo-C3-C5, haloalquinilo-C3-C5, cicloalquilo-C3-C7, insubstituido o substituido, fenilo o un heteroarilo de 5 o 6 miembros, que tiene 1-3 heteroátomos; X, Z es una cadena de alquileno C1-C4, insubstituida o substituida; y sus sales; se usan como herbicidas; para desecar/defoliar plantas.

    1-SULFONYL-3-PHENYLPYRAZOLES AND THEIR USE AS HERBICIDES AND FOR DESICCATING OR DEFOLIATING PLANTS

    公开(公告)号:CA2266392A1

    公开(公告)日:1998-03-26

    申请号:CA2266392

    申请日:1997-09-09

    Applicant: BASF AG

    Abstract: 1-sulfonyl-3-phenylpyrazoles having the formula (I) and their salts are disclosed. In the formula, R1 is C1-C4-alkyl, C1-C4-alkyl halide; R2 is C1-C4-alkyl, C1-C4-alkyl halide; R3 is H, CN, halogen, C1-C4-alkyl; R4 is H, halogen; R5 is H, CN, NO2, halogen, C1-C4-alkyl, C1-C4-alkyl halide, C1-C4-alkoxy, C1-C4-alkoxy halide; X is a chemical bond, an optionally substituted methylene, ethylene, propan-1,3-diyl, ethen-1,2-diyl chain or an oxymethylene or thiamethylene chain bound to the phenyl ring by the heteroatom; R6 is H, NO2, CN, halogen, SO2-halogen, -O-Y-R8, -O-CO-Y-R8, -N(Y-R8)(Z-R9), -N(Y-R8)-SO2-Z-R9, -N(SO2-Y-R8)(SO2-Z-R9), -N(Y-R8)-CO-Z-R9, -N(Y-R8)(O-Z-R9), -S-Y-R8, -SO-Z-R8, -SO2-Y-R8, -SO2-O-Y-R8, -SO2-N(Y-R8)(Z-R9), -CO-Y-R8, -C(=NOR10)-Y-R8, -(=NOR10)-O-Y-R8, -CO-O-Y-R8, -CO-S-Y-R8, -CO-N(Y-R8)(Z-R9), -CO-N(Y-R8)(O-Z-R9), -PO(O-Y-R8)2; R7 is H, or R5 + XR6 or XR6 + R7 form, together with the C atoms of the phenyl ring which interconnect them, an annulated, optionally substituted carbocyclic or 5-/6-membered heterocyclic ring with 1-3 heteroatoms, whereas the cycle may also contain 1 or 2 CO-, CS- or SO2 ring members. These compounds are useful as herbicides, and for desiccating/defoliating plants.

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