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公开(公告)号:DE59108832D1
公开(公告)日:1997-09-25
申请号:DE59108832
申请日:1991-12-10
Applicant: BASF AG
Inventor: WINGERT HORST DR , WOLF BERND DR , BENOIT REMY DR , SAUTER HUBERT DR , HEPP MICHAEL DR , GRAMMENOS WASSILIOS DR , KUEKENHOEHNER THOMAS DR
IPC: C07C69/736 , C07C20060101 , C07C51/09 , C07C51/367 , C07C59/68 , C07C65/21 , C07C65/24 , C07C67/22 , C07C69/738 , C07C69/76 , C07C235/34 , C07C235/78 , C07C249/08 , C07C251/48 , C07C253/14 , C07C255/17 , C07C255/40 , C07C317/24
Abstract: Prepn. of 2-phenoxymethyl benzoic acid derivs. of formula (I) comprises (a) converting a phenol of formula (II) to the phenolate in the presence of a basic diluent; (b) mixing the mixt. with a lactone of formula (III); (c) distilling off the diluent; (d) reacting the mixt. at 50-250 degrees C in the melt; and (e) dissolving the liq. melt with water and acidifying. X, Y = halogen, 1-4C alkyl, 1-4C alkoxy or CF3; m = 0-4; n = 0-3.
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公开(公告)号:DK0621264T3
公开(公告)日:1997-09-15
申请号:DK94105661
申请日:1994-04-13
Applicant: BASF AG
Inventor: SIEGEL WOLFGANG DR , SAUTER HUBERT DR , OBERDORF KLAUS DR , MUELLER BERND DR , GRAMMENOS WASSILIOS DR , DOETZER REINHARD DR
IPC: C07B61/00 , C07C45/46 , C07C45/48 , C07C49/84 , C07C65/40 , C07C67/313 , C07C69/734 , C07C69/736 , C07C235/34 , C07C235/80 , C07C251/48 , C07C255/54 , C07D213/50
Abstract: The process is characterised in that 4-alkanoylaryl benzyl ethers of the general formula I where the variables have the following meaning: R is hydrogen, halogen, cyano; alkyl, alkoxy; X is CH2, CH-CH3, CH-CH2-CH3, CH-OCH3, N-OCH3; Y is oxygen, sulphur, a direct bond or nitrogen; m is 0, 1, 2 or 3; R is hydrogen; alkyl, alkenyl, alkynyl, alkoxy; R is cyano, halogen, alkyl, alkoxy, haloalkyl; R is alkyl, haloalkyl; cycloalkyl; or an optionally substituted mono- to trinuclear aromatic system, are prepared by reacting an aryl benzyl ether of the general formula II where X, Y, R, R , R and m have the abovementioned meaning, with a carboxylic acid halide or with a carboxylic anhydride or with a carboxylic - sulphonic anhydride in the presence of an acid and optionally in the presence of a diluent.
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公开(公告)号:DE59108820D1
公开(公告)日:1997-09-11
申请号:DE59108820
申请日:1991-09-07
Applicant: BASF AG
Inventor: BRAND SIEGBERT DR , AMMERMANN EBERHARD DR , LORENZ GISELA DR , SAUTER HUBERT DR , OBERDORF KLAUS DR , KARDORFF UWE DR , KUENAST CHRISTOPH DR
IPC: A01N35/10 , A01N37/18 , A01N37/50 , A01N43/08 , A01N43/40 , A01N43/60 , A01N43/78 , A01N53/10 , C07C235/06 , C07C235/34 , C07C235/46 , C07C235/78 , C07C245/08 , C07C251/48 , C07C255/57 , C07C255/61 , C07C255/62 , C07C255/64 , C07C309/66 , C07C309/73 , C07C309/76 , C07C323/18 , C07C323/20 , C07C323/47 , C07C323/56 , C07C323/60 , C07C323/62 , C07C323/63 , C07D213/30 , C07D213/53 , C07D213/56 , C07D213/61 , C07D213/64 , C07D213/643 , C07D213/70 , C07D215/14 , C07D215/22 , C07D215/227 , C07D277/64 , C07D277/68 , C07D277/74 , C07D307/42 , C07D307/52
Abstract: Ortho-substd. phenyl acetamides of formula (I) are new. R1 = H, (cyclo)alkyl, alkenyl, (phenyl)alkynyl, alkoxyalkyl, alkoxycarbonyl, phenyl(alkyl), phenylalkenyl or phenoxyalkyl, 5- or 6-membered heterocycle with 1-3 hetero atoms to which a benzene ring or a 5- or 6-membered heterocycle may be fused; R2 and R3 = H, CN, halogen, alkyl, alkoxy; R4 and R5 = H, alkyl and R4 or R5 = alkoxy; Y = O, S, SO, SO2, N = N, O-CO, CO-O, CO-O-CH2, or (halo)alkylene, alkenylene, alkynylene, oxy- alkylene, thioalkylene, alkyleneoxy, carbonylalkylene or alkylenecarbonyl, W = alkoxyimino, alkoxymethylene or alkylthiomethylene), excepting cpds. where R1 is hydrogen, phenyl or 2,2-dimethyl-3-(2,2-dichlorovinyl) cyclopropyl, R2-R5 are each hydrogen, Y is carbonyloxy methylene and W is methoxy- or methylthio methylene. -
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公开(公告)号:DE59208733D1
公开(公告)日:1997-08-28
申请号:DE59208733
申请日:1992-01-24
Applicant: BASF AG
Inventor: GRAMMENOS WASSILIOS DR , HARREUS ALBRECHT DR , SAUTER HUBERT DR , HELLENDAHL BEATE DR , DOETZER REINHARD DR , AMMERMANN EBERHARD DR , LORENZ GISELA DR
IPC: A01N37/50 , A01N43/54 , A01N43/58 , A01N43/76 , A01N43/836 , C07C69/65 , C07C69/653 , C07C69/734 , C07C69/738 , C07C251/48 , C07C251/50 , C07C251/52 , C07C251/54 , C07C251/56 , C07C251/58 , C07C251/60 , C07C251/86 , C07C255/15 , C07C255/57 , C07C255/58 , C07C255/62 , C07D213/77 , C07D239/42 , C07D241/20 , C07D263/32 , C07D333/28
Abstract: Iminoalkyl-phenylacrylic acid derivs. (I) ar new: R = H or 1-6C alkyl; R = H; 1-4C alkyl opt. substd. by halo; or opt. substd. aryl; Z ,Z = H; halo; CN; NO2;etc.;Y = O; NH; or NR ; and R = H; 1-4C alkoxycarbonyl-1-4C alkyl; or opt. substd. alkyl, cycloalkyl, etc.; or Y+R form a ring which is opt. substd. when Y = NH or NR ; R = 1-6C alkyl; X = CH-1-4C alkoxy or CH-1-4C alkylthio (also 1-4C alkylidene and 1-4C alkoxyimino in the description).
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公开(公告)号:AT156478T
公开(公告)日:1997-08-15
申请号:AT95106286
申请日:1991-09-07
Applicant: BASF AG
Inventor: BRAND SIEGBERT DR , AMMERMANN EBERHARD DR , LORENZ GISELA DR , SAUTER HUBERT DR , OBERDORF KLAUS DR , KARDORFF UWE DR , KUENAST CHRISTOPH DR
IPC: A01N35/10 , A01N37/18 , A01N37/50 , A01N43/08 , A01N43/40 , A01N43/60 , A01N43/78 , A01N53/10 , C07C235/06 , C07C235/34 , C07C235/46 , C07C235/78 , C07C245/08 , C07C251/48 , C07C255/57 , C07C255/61 , C07C255/62 , C07C255/64 , C07C309/66 , C07C309/73 , C07C309/76 , C07C323/18 , C07C323/20 , C07C323/47 , C07C323/56 , C07C323/60 , C07C323/62 , C07C323/63 , C07D213/30 , C07D213/53 , C07D213/56 , C07D213/61 , C07D213/64 , C07D213/643 , C07D213/70 , C07D215/14 , C07D215/22 , C07D215/227 , C07D277/64 , C07D277/68 , C07D277/74 , C07D307/42 , C07D307/52
Abstract: Ortho-substd. phenyl acetamides of formula (I) are new. R1 = H, (cyclo)alkyl, alkenyl, (phenyl)alkynyl, alkoxyalkyl, alkoxycarbonyl, phenyl(alkyl), phenylalkenyl or phenoxyalkyl, 5- or 6-membered heterocycle with 1-3 hetero atoms to which a benzene ring or a 5- or 6-membered heterocycle may be fused; R2 and R3 = H, CN, halogen, alkyl, alkoxy; R4 and R5 = H, alkyl and R4 or R5 = alkoxy; Y = O, S, SO, SO2, N = N, O-CO, CO-O, CO-O-CH2, or (halo)alkylene, alkenylene, alkynylene, oxy- alkylene, thioalkylene, alkyleneoxy, carbonylalkylene or alkylenecarbonyl, W = alkoxyimino, alkoxymethylene or alkylthiomethylene), excepting cpds. where R1 is hydrogen, phenyl or 2,2-dimethyl-3-(2,2-dichlorovinyl) cyclopropyl, R2-R5 are each hydrogen, Y is carbonyloxy methylene and W is methoxy- or methylthio methylene. -
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公开(公告)号:DE19604732A1
公开(公告)日:1997-08-14
申请号:DE19604732
申请日:1996-02-09
Applicant: BASF AG
Inventor: GROTE THOMAS DR , SAUTER HUBERT DR , KIRSTGEN REINHARD DR , BAYER HERBERT DR , MUELLER RUTH DR , MUELLER BERND DR , OBERDORF KLAUS DR , GRAMMENOS WASSILIOS DR , GOETZ NORBERT DR , RACK MICHAEL DR , HARREUS ALBRECHT DR , ROEHL FRANZ DR , AMMERMANN EBERHARD DR , HARRIES VOLKER DR , LORENZ GISELA DR , STRATHMANN SIEGFRIED DR
IPC: C07C251/60 , A01N37/34 , A01N37/50 , A01N43/00 , C07C69/757 , C07C255/62 , C07C255/64 , C07C323/24
Abstract: 2-Iminooxyphenylacetic acid derivatives of formula (I) and their salts are new. R = C(CO2Me)=NOMe, C(CONHMe)=NOMe, C(CONH2)=NOMe, C(CO2Me)=COMe or C(CO2Me)=CHMe; R2 = CN, NO2, halo, 1-4C alkyl, 1-4C haloalkyl or 1-4C alkoxy; m = 0-2; R3 = H, CN, OH, halo, 1-6C alkyl (optionally substituted by halo or 1-6C alkoxy) 1-6C alkoxy, 1-6C haloalkoxy, 1-6C alkylthio, cyclopropyl, 2-6C alkenyl, or aryloxy-1-6C alkyl, benzyl or benzyloxy (all optionally ring-substituted by 1-3 CN, NO2, halo, 1-6C alkyl, 1-6C alkoxy, 1-6C haloalkyl or 1-6C haloalkoxy) or C(Me)=N-Y-Ra; Ra = 1-6C alkyl; Y = O, NH or NRa; R4 = H, CN, -Qp-C(R5)=N-Y'-R6 or -Q-O-N=CR7R8; or alkyl, alkenyl, alkynyl, cycloalkyl, heterocyclyl, aryl, heteroaryl, alkoxy, alkenyloxy, alkynyloxy, cycloalkoxy, heterocyclyloxy, aryloxy, heteroaryloxy, arylthio or heteroarylthio (all optionally substituted); or CR3R4 = 4-8 membered ring containing C atoms an optionally 1 or 2 of O, S, NH and/or N(1-4C alkyl) (optionally substituted on C by halo, 1-6C alkyl or 1-4C alkoxyimino), provided R3 and R4 are not both bonded to C via hetero atoms; Q = bond, CH2, CH(Me), CH(Et) or 1,1-cyclopropyl; p = 0 or 1; Y' = O, NH or N(1-4C alkyl); R5 = as for R3 or optionally substituted cycloalkoxy, heterocyclyloxy, aryloxy, heteroaryloxy, arylthio or heteroarylthio; R6 = optionally substituted 1-10C alkyl, 3-6C cycloalkyl, 2-10C alkenyl, 2-10C alkynyl, 1-10C alkylcarbonyl, 2-10C alkenylcarbonyl, 2-10C alkynylcarbonyl, 1-10C alkylsulphonyl, aryl, heteroaryl, arylcarbonyl, heteroarylcarbonyl, arylsulphonyl or heteroarylsulphonyl; R7, R8 = Me, Et, Ar or CH2Ar; Ar = phenyl (optionally mono-, di- or trisubstituted by CN, NO2, halo, 1-6C alkyl, 1-6C alkoxy, 1-6C haloalkyl or 1-6C haloalkoxy.
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公开(公告)号:ES2102111T3
公开(公告)日:1997-07-16
申请号:ES94113852
申请日:1994-09-03
Applicant: BASF AG
Inventor: EICKEN KARL DR , MULLER BERND DR , SAUTER HUBERT DR , LORENZ GISELA DR , AMMERMANN EBERHARD DR , SCHELBERGER KLAUS
Abstract: Fungicidal, synergistic mixture comprising a) a compound of the formula I in which the substituents have the following meanings: R is a phenyl radical which can have attached to it one to three of the following groups: cyano, halogen, C1-C4-alkyl, C1-C2-haloalkyl and C1-C4-alkoxy, or a pyrimidyl radical which can have attached to it a C1-C3-alkyl group and/or a phenoxy group, it being possible for the phenoxy group, in turn, to have attached to it one to three of the following radicals: cyano, halogen, C1-C4-alkyl, C1-C2-haloalkyl and C1-C4-alkoxy, A is oxygen or oxymethylene (-OCH2-); X is CH or N, Y is oxygen or NR , R representing hydrogen, C1-C3-alkyl and C1-C3-alkoxy, and b) a pyrimidine derivative of the formula II in which R represents methyl, propyn-1-yl or cyclopropyl, in a synergistically effective amount.
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公开(公告)号:DE59208596D1
公开(公告)日:1997-07-10
申请号:DE59208596
申请日:1992-01-17
Applicant: BASF AG
Inventor: BENOIT REMY DR , SAUTER HUBERT DR , KIRSTGEN REINHARD DR , LORENZ GISELA DR , AMMERMANN EBERHARD DR
IPC: A01N35/10 , A01N37/12 , A01N37/34 , A01N37/50 , A01N43/10 , A01N53/10 , C07C251/48 , C07C251/50 , C07C251/58 , C07C251/60 , C07C251/80 , C07C255/61 , C07C255/62 , C07D239/52
Abstract: alpha -Imino oxime cpds, described as oxime ethers, of formula (I) are new: R = CR2R3R4 or opt. substd. 3-8C cycloalkyl, 2-8C alkenyl, 2-8C alkynyl, phenyl or heteroaryl; R1 = H or 1-8C alkyl; R2 = H, 1-8C alkyl, aralkyl, heteroarylalkyl, alkoxyalkyl, aryloxyalkyl, aryl or heteroaryl; R3 = H, Me, CN, COOH or 2-9C alkoxycarbonyl; R4 = a gp. as defined for R2; or CR2R3 is a 5- to 8-membered lactone ring or CR2R4 is a 3-8C cycloalkane ring; R5 = H, 1-8C alkyl, aralkyl, 3-6C cycloalkyl, OH, 1-4C alkoxy, NH2, 1-4C alkylamino or dialkylamino; Y = a gp. stated to be an opt. substd. 1-8C alkyl, opt. substd. 2-8C alkenyl, 2-8C alkynyl, O, S(O)m (m = 0-2), N substd. by opt. substd. 1-8C alkyl, oxycarbonyl, carbonyloxy, oxycarbonyl (1-8C) alkyl, carbonyloxy (1-8C) alkyl, 2-8C oxyalkyloxy, 2-8C oxyalkenyl, 1-8C alkoxy, 1-4C oxyalkyl, 1-8C thioalkyl, azo, opt. 1-8C alkyl-substd. -carbonylamino, -aminocarbonyl or -aminocarbonyloxy, oxyimino or opt. substd. imino oxyalkyl; Z = (a) 1-18C alkyl, 2-18C alkenyl, 3-18C alkynyl, aryl, aryl (1-10C) alkyl, aryl (2-10C) alkenyl, aryloxy (1-10C) alkyl, (1-4C) alkoxy (1-10C) alkyl, 1-10C haloalkyl, 2-5C alkoxycarbonyl or heteroaryl; (b) aryloxy, aryloxy (1-10C) alkoxy, aryl (1-10C) alkoxy, 1-10C alkoxy or heteroaryloxy when Y is not oxyalkyl, oxyalkyloxy, thialkyl (sic), -O-N=C- (sic), -N=N-, oxycarbonyl, oxycarbonyloxy, O or S; or (c) 1-18C alkylthio or arylthio when Y is not oxyalkyl, oxyalkyloxy, -O-N=C- (sic), -N=N-, oxycarbonyl, oxycarbonyloxy or O, and Z is opt. substd. by halogen, CN, NO2, 1-4C alkyl, 2-4C alkenyl, 1-4C alkoxy, 1-4C haloalkyl, (1-4C) alkoxy (1-4C) alkyl, di(1-4C) alkoxy (1-4C) alkyl, opt. substd. 1-10C alkoxyimino, opt. substd. 2-10C alkenyloxyimino, opt. substd. aralkoxyimino, opt. substd. 2-10C alkanoyl, opt. substd. formyl, 2-4C haloalkenyl, 2-5C alkoxycarbonyl, opt. substd. phenyl, or opt. substd. 5-membered heterocyclyl which contains 1-4 heteroatoms (N, O and/or S) and is opt. fused with an opt. substd. aromatic or heteroaromatic ring; X = H, halogen, NO2 and/or opt. substd. 1-4C alkyl, 1-4C alkoxy and/or 1-4C haloalkyl; m = 1-4.
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公开(公告)号:DE19548783A1
公开(公告)日:1997-07-03
申请号:DE19548783
申请日:1995-12-27
Applicant: BASF AG
Inventor: BAYER HERBERT DR , MUELLER RUTH DR , SAUTER HUBERT DR , GRAMMENOS WASSILIO DR , GROTE THOMAS DR , KIRSTGEN REINHARD DR , MUELLER BERND DR , OBERDORF KLAUS DR , ROEHL FRANZ DR , AMMERMANN EBERHARD DR , HARRIES VOLKER DR , LORENZ GISELA DR , STRATHMANN SIEGFRIED DR
IPC: A01N37/34 , A01N47/40 , C07C255/61 , C07C261/04 , A01N37/42 , A01N37/50 , A01N43/08 , A01N43/26 , A01N43/28 , A01N43/36 , A01N43/38 , A01N43/40 , A01N43/54 , A01N43/653
Abstract: The invention relates to cyanimino oxime ethers of formula (I), in which X is NOCH3, CHOCH3, CHCH3; Y is O, NZ, where Z is H, alkyl; R is H, alkyl; R is cyano, nitro, trifluoromethyl, halogen, alkyl, alcoxy; m is 0, 1, 2, the radicals R possibly being different when m is 2; R is H, cyano, alkyl, alkylhalide, alkoxy or cycloalkyl; R is H, optionally substituted alkyl, alkenyl, alkinyl, cycloalkyl, cycloalkenyl, heterocyclyl. The invention also relates to salts of said ethers, and the process and intermediates for the preparation and use thereof for the control of noxious fungi and animal pests.
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公开(公告)号:DK0678505T3
公开(公告)日:1997-06-23
申请号:DK95110519
申请日:1992-01-17
Applicant: BASF AG
Inventor: SAUTER HUBERT DR , LORENZ GISELA DR , BENOIT REMY DR , KIRSTGEN REINHARD DR , AMMERMANN EBERHARD DR
IPC: A01N35/10 , A01N37/12 , A01N37/34 , A01N37/50 , A01N43/10 , A01N53/10 , C07C251/48 , C07C251/50 , C07C251/58 , C07C251/60 , C07C251/80 , C07C255/61 , C07C255/62 , C07D239/52
Abstract: alpha -Imino oxime cpds, described as oxime ethers, of formula (I) are new: R = CR2R3R4 or opt. substd. 3-8C cycloalkyl, 2-8C alkenyl, 2-8C alkynyl, phenyl or heteroaryl; R1 = H or 1-8C alkyl; R2 = H, 1-8C alkyl, aralkyl, heteroarylalkyl, alkoxyalkyl, aryloxyalkyl, aryl or heteroaryl; R3 = H, Me, CN, COOH or 2-9C alkoxycarbonyl; R4 = a gp. as defined for R2; or CR2R3 is a 5- to 8-membered lactone ring or CR2R4 is a 3-8C cycloalkane ring; R5 = H, 1-8C alkyl, aralkyl, 3-6C cycloalkyl, OH, 1-4C alkoxy, NH2, 1-4C alkylamino or dialkylamino; Y = a gp. stated to be an opt. substd. 1-8C alkyl, opt. substd. 2-8C alkenyl, 2-8C alkynyl, O, S(O)m (m = 0-2), N substd. by opt. substd. 1-8C alkyl, oxycarbonyl, carbonyloxy, oxycarbonyl (1-8C) alkyl, carbonyloxy (1-8C) alkyl, 2-8C oxyalkyloxy, 2-8C oxyalkenyl, 1-8C alkoxy, 1-4C oxyalkyl, 1-8C thioalkyl, azo, opt. 1-8C alkyl-substd. -carbonylamino, -aminocarbonyl or -aminocarbonyloxy, oxyimino or opt. substd. imino oxyalkyl; Z = (a) 1-18C alkyl, 2-18C alkenyl, 3-18C alkynyl, aryl, aryl (1-10C) alkyl, aryl (2-10C) alkenyl, aryloxy (1-10C) alkyl, (1-4C) alkoxy (1-10C) alkyl, 1-10C haloalkyl, 2-5C alkoxycarbonyl or heteroaryl; (b) aryloxy, aryloxy (1-10C) alkoxy, aryl (1-10C) alkoxy, 1-10C alkoxy or heteroaryloxy when Y is not oxyalkyl, oxyalkyloxy, thialkyl (sic), -O-N=C- (sic), -N=N-, oxycarbonyl, oxycarbonyloxy, O or S; or (c) 1-18C alkylthio or arylthio when Y is not oxyalkyl, oxyalkyloxy, -O-N=C- (sic), -N=N-, oxycarbonyl, oxycarbonyloxy or O, and Z is opt. substd. by halogen, CN, NO2, 1-4C alkyl, 2-4C alkenyl, 1-4C alkoxy, 1-4C haloalkyl, (1-4C) alkoxy (1-4C) alkyl, di(1-4C) alkoxy (1-4C) alkyl, opt. substd. 1-10C alkoxyimino, opt. substd. 2-10C alkenyloxyimino, opt. substd. aralkoxyimino, opt. substd. 2-10C alkanoyl, opt. substd. formyl, 2-4C haloalkenyl, 2-5C alkoxycarbonyl, opt. substd. phenyl, or opt. substd. 5-membered heterocyclyl which contains 1-4 heteroatoms (N, O and/or S) and is opt. fused with an opt. substd. aromatic or heteroaromatic ring; X = H, halogen, NO2 and/or opt. substd. 1-4C alkyl, 1-4C alkoxy and/or 1-4C haloalkyl; m = 1-4.
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