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公开(公告)号：KR101914236B1
公开(公告)日：2018-12-28
申请号：KR1020170004186
申请日：2017-01-11
Applicant: 한국과학기술연구원
IPC: C07C17/25 , C07C21/18 , C07C17/354 , C07C19/08 , B01J8/02
Abstract: 본 발명에서는 헥사플루오로프로필렌(HFP)으로부터 1,2,3,3,3-펜타플루오로프로펜(HFO-1225ye)을 제조하는 방법을 제공한다. 1,2,3,3,3-펜타플루오로프로펜은 온난화 지수가 매우 낮으며 오존층 파괴능이 없는 냉매인 2,3,3,3-테트라플루오로프로펜(HFO-1234yf)의 중간생성물로서 HFP와 수소를 수소화 촉매 상에서 수소화 반응시켜 1,1,2,3,3,3-헥사플루오로프로판(HFC-236ea)을 생성하는 단계; 상기 HFC-236ea를 탈불화수소 촉매 상에서 탈불화수소 반응시켜 HFO-1225ye 제조하는 단계를 거쳐 제조한다. HFP를 수소와 기상에서 반응시켜 HFC-236ea를 제조할 때, 반응에 소비되는 수소만을 적절하게 투입함으로써 미반응 수소를 분리 및 순환시키는 공정을 없앨 수 있고, 과량의 수소에 의한 부반응을 억제시킨다. 수소화 반응에서 생성된 기체상태의 생성물(HFC-236ea)을 별도의 분리단계 없이 기상의 탈불화수소화 반응에 직접 투입하여 HFO-1225ye를 제조한다. 또한 본 발명에서는 HFP 수소화 반응의 반응열을 효율적으로 제거하고 반응온도를 제어하기 위해 HFC-236ea 탈불화수소화 반응에서 미반응한 HFC-236ea를 적정량 수소화 반응기로 순환시키는 방법을 사용한다.
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154.发明公开헥사플루오로프로필렌으로부터 2,3,3,3-테트라플루오로프로펜과 1,3,3,3-테트라플루오로프로펜의 제조방법 审中-实审共同制备2,3,3,3-四氯丙烯和1,3,3,3-四氢呋喃的方法从十六烷基
公开(公告)号：KR1020160017661A
公开(公告)日：2016-02-16
申请号：KR1020160011642
申请日：2016-01-29
Applicant: 한국과학기술연구원
IPC: C07C17/25 , C07C17/383 , C07C21/18
Abstract: 헥사플루오로프로필렌으로(HFP)부터 2,3,3,3-테트라플루오로프로펜(HFO-1234yf)과 1,3,3,3-테트라플루오로프로펜(HFO-1234ze, E-form)의동시제조방법이제공된다.
Abstract translation: 本发明提供了从六氟丙烯同时制备2,3,3,3-四氟丙烯（HFO-1234yf）和1,3,3,3-四氟丙烯（HFO-1234ze，E型）的制造方法（ HFP）。 该方法能有效收集氟化氢，有效分离可影响HFO-1234yf纯度的其他中间产物。 该方法包括以下步骤：（a）制备1,1,2,3,3,3-六氟丙烷（HFC-236ea）; （b）制备1,2,3,3,3-五氟丙烯（HFO-1225ye）; （c）以高浓度的氢氟酸收集氟化氢; （d）精制1,2,3,3,3-五氟丙烯（HFO-1225ye）; （e）制备1,2,3,3,3-五氟丙烷（HFC-245eb）; （f）精制1,2,3,3,3-五氟丙烷（HFC-245eb）; （g）制备2,3,3,3-四氟丙烯（HFO-1234yf）和1,3,3,3-四氟丙烯（HFO-1234ze，E-型）; （h）以高浓度的氢氟酸收集氟化氢; （i）精制2,3,3,3-四氟丙烯（HFO-1234yf）和1,3,3,3-四氟丙烯（HFO-1234ze，E-型）的混合物; 和（j）从精制混合物中分离2,3,3,3-四氟丙烯（HFO-1234yf）和1,3,3,3-四氟丙烯（HFO-1234ze，E型），并精制。
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公开(公告)号：KR1020150034420A
公开(公告)日：2015-04-03
申请号：KR1020130114476
申请日：2013-09-26
Applicant: 코오롱인더스트리 주식회사 , 한국과학기술연구원
IPC: C07C253/28 , C07C255/51 , B01J23/22 , B01J23/26
Abstract: 본발명은프탈로니트릴의제조방법에관한것으로, 보다상세하게는, 상기반응원료가최초로투입되는제1 주입부온도를 200 ~ 400℃로유지하면서, 상기제1 주입부에서투입된반응원료의반응이발생되는제1 반응구역의열점온도와상기제1 주입부온도의온도차가 70 ~ 80℃가되도록조절하여안정적으로원료의손실율을감소시켜고수율저손실로프탈로니트릴을제조하는방법에관한것이다.
Abstract translation: 本发明涉及邻苯二甲腈的制造方法，更具体地说，涉及通过调节第一反应区域的热点温度之间的温度差而产生高收率和低损耗的邻苯二甲腈的方法，其中反应 发生从第一注射单元引入的原料，并且第一注射单元的温度为70-80℃，以便稳定地降低反应原料的损失率，同时保持第一注射单元的温度， 反应原料最初在200-400℃下引入。
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Patent Agency Ranking
公开(公告)号：KR101500655B1
公开(公告)日：2015-03-12
申请号：KR1020130111959
申请日：2013-09-17
Applicant: 한국과학기술연구원
CPC classification number: B01J27/132 , B01J27/12 , B01J37/26 , C07C17/25 , C07C21/18
Abstract: 본 발명은 유독성·부식성의 특징을 갖는 불산(HF)기체의 사용 없이, 트리플루오로아세트산 용액을 이용한 온화한 조건에서 고활성을 가진 탈불산화 촉매인 금속불소화물 촉매를 제조하는 금속불소화물 촉매 제조방법에 관한 것이며, 또한 상기 제조된 촉매를 이용하여 HFP-236ea로부터 HFO-1225ye를 고효율로 제조하기 위한 탈불산화 방법에 관한 것이다.
Abstract translation: 本发明涉及一种在不使用具有毒性和腐蚀特性的氢氟酸（HF）的情况下，使用三氟乙酸溶液在温和条件下具有高活性的脱氟化氢催化剂的制备方法和脱氟化氢方法制造方法 HFO-1225ye通过使用制造的催化剂高效率地从HFP-236ea得到。
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157.发明授权이온성 액체를 이용하여 제조된 탄소에 담지된 팔라듐 촉매 및 이것의 제조방법과, 이를 이용한 수소불화탄소의 수소화 반응 有权碳基钯催化剂及其使用离子液体制备方法及其催化剂应用于氢化氢化
公开(公告)号：KR101492871B1
公开(公告)日：2015-02-13
申请号：KR1020130093520
申请日：2013-08-07
Applicant: 한국과학기술연구원
CPC classification number: B01J23/44 , B01J21/18 , B01J31/0284 , B01J35/0013 , B01J35/0053 , B01J35/006 , B01J37/035 , B82Y30/00 , C07C17/354 , C07C19/08
Abstract: The invention relates to a palladium catalyst (Pd/C) dipped in carbon that is manufactured by using an ionic liquid and a manufacturing method thereof; and to a hydrogenation reaction of hydrofluorocarbon using the same. More specifically, as a method that dips a palladium particle in the carbon granule using the ionic liquid, after which the same is used in the hydrogenation of the hydrofluorocarbon, the size of the palladium particle is small in comparison with the existing palladium-dipped catalyst, and the shape thereof is uniformly molded so as to present high catalytic activity.
Abstract translation: 本发明涉及通过使用离子液体制造的浸渍在碳中的钯催化剂（Pd / C）及其制造方法; 以及使用其的氢氟烃的氢化反应。 更具体地说，作为使用离子液体浸渍碳粒子中的钯粒子的方法，其后与氢氟烃的氢化相同，钯粒子的大小与现有的钯浸渍催化剂相比较小 并且其形状被均匀地模制以呈现高催化活性。
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公开(公告)号：KR1020140077615A
公开(公告)日：2014-06-24
申请号：KR1020120146619
申请日：2012-12-14
Applicant: 코오롱인더스트리 주식회사 , 한국과학기술연구원
IPC: C07C209/48 , C07C209/82 , C07C211/27
Abstract: The present invention relates to a method for manufacturing xylenediamine using an organic solvent of amides and, more specifically, to a method for manufacturing xylenediamine via hydrogenation of phthalonitrile in an atmosphere of ammonia. High-purity xylenediamine can be manufactured in high yields even under a low temperature and low pressure reaction conditions by selectively using the organic solvent of amides which is chemically stabler than the existing reaction solvents and is economical while having excellent dissolvability of phthalonitrile.
Abstract translation: 本发明涉及一种使用酰胺的有机溶剂制备二甲苯胺的方法，更具体地说，涉及在氨气氛中通过邻苯二甲腈的氢化制备二甲苯胺的方法。 通过选择性地使用比现有的反应溶剂化学稳定的酰胺的有机溶剂，并且经济且具有优异的邻苯二甲腈溶解性，可以以高产率甚至在低温和低压反应条件下制备高纯度二甲苯二胺。
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公开(公告)号：KR1020140067675A
公开(公告)日：2014-06-05
申请号：KR1020120135227
申请日：2012-11-27
Applicant: 한국과학기술연구원
CPC classification number: Y02P20/52 , B01J23/80 , B01J23/002 , B01J35/1014 , B01J37/00 , B01J2523/00 , B01J2523/17 , B01J2523/22 , B01J2523/27 , B01J2523/31 , C07C1/044
Abstract: The present invention relates to a method for using Cu-Zn-Mg-Al-based oxide that contains CuO, ZnO, MgO, and Al_2O_3 at a particular ratio as a reactive catalyst for synthesizing methanol from a synthetic gas and to a method for synthesizing methanol from a synthetic gas by using the catalyst.
Abstract translation: 本发明涉及以特定比例含有CuO，ZnO，MgO和Al_2O_3的Cu-Zn-Mg-Al系氧化物作为合成气体合成甲醇的反应催化剂的方法，以及合成方法 使用催化剂从合成气中提取甲醇。
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公开(公告)号：KR1020130005888A
公开(公告)日：2013-01-16
申请号：KR1020110067549
申请日：2011-07-07
Applicant: 한국과학기술연구원
IPC: C07C17/354 , C07C17/23 , C07C19/08 , B01J23/44
CPC classification number: Y02P20/544
Abstract: PURPOSE: A manufacturing method of chlorodifluoromethane is provided to increase the yield of chlorodifluoromethane, to production amount by using a reaction at high temperature and high pressure and to prevent the caulking phenomenon of a catalyst. CONSTITUTION: A manufacturing method of chlorodifluoromethane comprises: a step of removing oxygen from a reactor containing a metal support catalyst which Pd is supported by a porous catalyst support; a step of injecting a mixture which comprises hydrogen and liquefied chlorodifluoromethane into the reactor; and a step of obtaining a reactant with chlorodifluoromethane from a supercritical fluid phase with the inner temperature of 50-300 bar and the temperature of 300-500 deg. C by a hydrodechlorination reaction; a step of cooling the reactant; and a step of collecting difluoromethane from the reactant. [Reference numerals] (AA) Yield, conversion rate(%); (BB) HCFC-22 conversion rate; (CC) HFC-23 yield; (DD) HFC-32 yield; (EE) Methane yield; (FF) Reaction time(hr)
Abstract translation: 目的：提供氯二氟甲烷的制造方法，以通过在高温高压下进行反应来提高氯二氟甲烷的产率，提高生产量，防止催化剂的堵塞现象。 构成：一氯二氟甲烷的制造方法包括：从含有金属载体催化剂的反应器除去氧的步骤，Pd由多孔催化剂载体负载; 将包含氢气和液化氯二氟甲烷的混合物注入反应器的步骤; 以及从内部温度为50-300巴，温度为300-500度的超临界流体相用氯二氟甲烷获得反应物的步骤。 C通过加氢脱氯反应; 冷却反应物的步骤; 以及从反应物中收集二氟甲烷的步骤。 （AA）产率，转化率（％）; （BB）HCFC-22转化率; （CC）HFC-23产量; （DD）HFC-32产率; （EE）甲烷产率; （FF）反应时间（hr）
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