公开(公告)号：DE4204203A1

公开(公告)日：1993-08-19

申请号：DE4204203

申请日：1992-02-13

Applicant: BASF AG

Inventor： MISSLITZ ULF DR ,  MEYER NORBERT DR ,  KAST JUERGEN DR ,  RANG HARALD DR ,  WALTER HELMUT DR ,  WESTPHALEN KARL-OTTO DR ,  GERBER MATTHIAS DR ,  KARDORFF UWE DR

IPC: A01N35/10 ,  A01N43/16 ,  A01N43/18 ,  A01N43/80 ,  C07C251/54 ,  C07C323/47 ,  C07D261/06 ,  C07D309/06 ,  C07D335/02

Abstract: The invention concerns cyclohexenone oxime ethers of formula (I), in which R = alkyl; W = an optionally substituted alkylene chain; X = NO2, CN, halogen, alkyl or haloalkyl; n = 2 to 3, or 2 to 5 if all the X substituents are halogens; R = alkoxyalkyl, alkylthioalkyl, optionally substituted cycloalkyl, optionally substituted cycloalkenyl, an optionally substituted saturated 5-membered heterocyclic ring, an optionally substituted 6 or 7-membered heterocyclic ring, an optionally substituted aromatic 5-membered heterocyclic ring or an optionally substituted phenyl or pyridyl group. The invention also concerns methods for the preparation of such ethers and their use.

公开(公告)号：DE4201875A1

公开(公告)日：1993-07-29

申请号：DE4201875

申请日：1992-01-24

Applicant: BASF AG

Inventor： BAUMANN ERNST DR ,  SAUPE THOMAS DR ,  RHEINHEIMER JOACHIM DR ,  VOGELBACHER UWE JOSEF DR ,  BRATZ MATTHIAS DR ,  MEYER NORBERT DR ,  GERBER MATTHIAS DR ,  WESTPHALEN KARL-OTTO DR ,  KARDORFF UWE DR ,  LANDES ANDREAS DR ,  WALTER HELMUT DR

IPC: A01N43/54 ,  A01N43/66 ,  C07D239/46 ,  C07D239/60 ,  C07D251/30 ,  C07D401/12 ,  C07D403/12 ,  C07D405/12 ,  C07D409/12 ,  C07D413/12 ,  C07D417/12 ,  C07D491/048

Abstract: Thiocarboxylic acid derivatives of the general formula I in which the substituents have the following meanings: R is optionally substituted alkyl, optionally substituted cycloalkyl or cycloalkenyl, optionally substituted alkenyl or alkynyl, optionally substituted phenyl; R is halogen, alkyl, haloalkyl, alkoxy, haloalkoxy or alkylthio; X is nitrogen or CR , where R denotes hydrogen or together with R forms a C3-C4-alkylene chain or C3-C4-alkenylene chain, in which one methylene group is replaced by oxygen; R is halogen, alkyl, haloalkyl, alkoxy, haloalkoxy, alkylthio or R is linked to R as indicated above to form a 5- or 6-membered ring; R is optionally substituted alkyl, optionally substituted alkenyl or alkynyl, an optionally substituted five- or six-membered heteroaromatic ring containing one to three nitrogen atoms and/or one sulphur or oxygen atom; optionally substituted phenyl or naphthyl; R and R together with the adjacent carbon atom form a 3- to 6-membered ring which can contain an oxygen or sulphur atom and which is optionally substituted; R is hydrogen, alkyl, haloalkyl, alkoxy, haloalkoxy or alkylthio; Y and Z are oxygen or sulphur. The thiocarboxylic acid derivatives I are suitable as herbicides or plant growth regulators.

公开(公告)号：DE4142570A1

公开(公告)日：1993-06-24

申请号：DE4142570

申请日：1991-12-21

Applicant: BASF AG

Inventor： RHEINHEIMER JOACHIM DR ,  BAUMANN ERNST DR ,  VOGELBACHER UWE JOSEF DR ,  SAUPE THOMAS DR ,  BRATZ MATTHIAS DR ,  MEYER NORBERT DR ,  GERBER MATTHIAS DR ,  WESTPHALEN KARL-OTTO DR ,  WALTER HELMUT DR ,  KARDORFF UWE DR

IPC: A01N43/90 ,  C07D491/04 ,  C07D491/044 ,  C07D491/048 ,  C07D491/052

Abstract: Glycolaldehyde and lactic acid derivatives, and their sulphur analogues of the formula I in which R to R have the meaning given in the description, X represents oxygen, sulphur or a single bond and Y denotes an optionally substituted C2-C4-alkylene or C2-C4-alkylene chain or C2-C4-alkenylene chain, and environmentally compatible salts of the compounds I, the preparation of the compounds I and their use as herbicides.

公开(公告)号：DE4126935A1

公开(公告)日：1993-02-11

申请号：DE4126935

申请日：1991-08-10

Applicant: BASF AG

Inventor： VOGELBACHER UWE JOSEF DR ,  EICKEN KARL DR ,  MEYER NORBERT DR ,  RHEINHEIMER JOACHIM DR ,  SAUPE THOMAS DR ,  GERBER MATTHIAS DR ,  WESTPHALEN KARL-OTTO DR ,  WALTER HELMUT DR

IPC: A01N43/90 ,  C07D231/12 ,  C07D233/60 ,  C07D491/04 ,  C07D491/048

Abstract: Pyrimidinyl-substd. (thio)salicylaldehyde and (thio)salicylic acid derivs. (I) and their salts are new. In (I), R1 = H; succinylimidooxy; 5-membered heteroaryl contg. 1-3 N atoms and opt. 1-4 halo and/or 1-2 1-4C alkyl, 1-4C haloalkyl, 1-4C alkoxy, 1-4C haloalkoxy and/or 1-4C alkylthio substits.; OR5; -N=CR6R7; -(O)mNR14R15, -(CH2)l-CO-NR16NR17, -(CH2)l-S(O)kR18; -O-(CH2)l-P(O)(OR18)2 or -NHSO2R19, R2 = 1-4C alkyl, 1-4C alkoxy, 1-4C haloalkoxy or halogen; R3 = H; and R4 = H; halogen; 1-4C alkoxy; 1-4C haloalkoxy; aryloxy; 1-4C haloalkyl; formyl; 1-8C alkoxycarbonyl; R3+R4 = -Z=CH-CH=CH- where Z = CH or N; R5 = H; alkali metal, alkaline earth metal or organic ammonium cation; 3-12C cycloalkyl opt. contg. 1-3 1-4C alkyl substits; 1-10C alkyl opt. contg. 1-5 halo and/or 1 1-4C alkoxy, 1-4C alkylthio, cyano, 1-8C alkylcarbonyl, 1-8C alkoxycarbonyl, 3-12C cycloalkyl or phenyl, phenoxy or phenylcarbonyl substits. R6, R7 = 1-20C alkyl opt. substd. by phenyl, 1-4C alkoxy and/or 1-4C alkylthio; phenyl; or R6+R7 = 3-12C alkylene opt. contg. 1-3 1-3C alkyl substits.; R14, R15 = H; 1-6C alkyl, 3-6C alkenyl or 3-6C alkynyl opt. contg. 1-5 halo and/or 1-2 1-6C alkoxy, 3-6C alkenyloxy, 3-6C alkynyloxy, 1-6C alkylthio, 3-6C alkenylthio, 3-6C alkynylthio, 1-6C haloalkoxy, cyano, 1-6C alkylcarbonyl, 3-6C alkenylcarbonyl, 3-6C alkynylcarbonyl, 1-6C alkoxycarbonyl, 3-6C alkenyloxycarbonyl; R16, R17 = H; 1-6C alkyl; 3-6C alkenyl or 3-6C alkynyl; R18 = 1-6C alkyl; 3-6C alkenyl or 3-6C alkynyl; R19 = 1-6C alkyl or phenyl opt. contg. 1-4 halo, nitro, cyano or 1-6C alkyl substits; X = O or S; Y = N when R3 = H and n = 0 or when R4 = O and n = 1; or C when R3+R4 form a ring or when R3 = H and k = 0-2; n = 1; l = 1-4; m = 0 or 1; and n = 1 when Y = C or when Y = N and R4 = O or 0 when Y = N and R4 is other than O.

公开(公告)号：DE4108183A1

公开(公告)日：1992-09-17

申请号：DE4108183

申请日：1991-03-14

Applicant: BASF AG

Inventor： MAYWALD VOLKER DR ,  MUENSTER PETER DR ,  KOENIG HARTMANN DR ,  HAMPRECHT GERHARD DR ,  KUEKENHOEHNER THOMAS DR ,  ROHR WOLFGANG DR ,  WALTER HELMUT DR ,  WESTPHALEN KARL-OTTO DR ,  GERBER MATTHIAS DR

IPC: A01N43/80 ,  C07D261/18 ,  C07D275/02 ,  C07D275/03 ,  C07D413/04 ,  C07D417/12

Abstract: Isoxazol- and isothiazol-5-carboxylic acid amides have formula (I), in which X stands for oxygen or sulphur, R stands for hydrogen, if necessary substituted alkyl, cycloalkyl, cycloalkenyl, alkenyl, (if necessary epoxydized at the double bond), alkinyl, alkoxy, a heterocyclic residue or phenyl; R stands for a derived carboxylic function; and R , R have the meaning given in the description. Also disclosed are herbicides containing the compounds (I).

公开(公告)号：DE4108181A1

公开(公告)日：1992-09-17

申请号：DE4108181

申请日：1991-03-14

Applicant: BASF AG

Inventor： MAYWALD VOLKER DR ,  MUENSTER PETER DR ,  KOENIG HARTMANN DR ,  HAMPRECHT GERHARD DR ,  KUEKENHOEHNER THOMAS DR ,  WALTER HELMUT DR ,  WESTPHALEN KARL-OTTO DR ,  GERBER MATTHIAS DR

IPC: A01N43/80 ,  C07D261/18 ,  C07D275/02 ,  C07D275/03 ,  C07D413/04 ,  C07D413/12 ,  C07D417/04 ,  C07F7/08 ,  C07F9/653 ,  C07F9/6539

Abstract: Isoxazole- and isothiazole-5-carboxamides of the formula I I where X is oxygen or sulfur, R1 is halogen, alkylthio, haloalkoxy, haloalkylthio, cyano, formyl, alkanoyl, alkoxycarbonyl, alkylaminocarbonyl, di-(C1-C3)-alkylaminocarbonyl, cyclopropylaminocarbonyl, methylsulfonyl, trifluoromethylsulfonyl, unsubstituted or substituted phenoxy or phenylthio; R2 is formyl, haloformyl, 4,5-dihydro-2-oxazolyl, COOR5, COSR5 or CONR6R7, and R3 to R7 have the meanings specified in the description, are suitable as herbicides.

公开(公告)号：DE4039940A1

公开(公告)日：1992-06-17

申请号：DE4039940

申请日：1990-12-14

Applicant: BASF AG

Inventor： EICKEN KARL DR ,  RHEINHEIMER JOACHIM DR ,  VOGELBACHER UWE JOSEF DR ,  WESTPHALEN KARL-OTTO DR ,  GERBER MATTHIAS DR ,  WALTER HELMUT DR

IPC: A01N43/90 ,  C07D491/04 ,  C07D491/048

Abstract: Pyrimidinyl-substd. (thio)salicylaldehyde and (thio)salicylic acid derivs. (I) and their salts are new. In (I), R1 = H; succinylimidooxy; 5-membered heteroaryl contg. 1-3 N atoms and opt. 1-4 halo and/or 1-2 1-4C alkyl, 1-4C haloalkyl, 1-4C alkoxy, 1-4C haloalkoxy and/or 1-4C alkylthio substits.; OR5; -N=CR6R7; -(O)mNR14R15, -(CH2)l-CO-NR16NR17, -(CH2)l-S(O)kR18; -O-(CH2)l-P(O)(OR18)2 or -NHSO2R19, R2 = 1-4C alkyl, 1-4C alkoxy, 1-4C haloalkoxy or halogen; R3 = H; and R4 = H; halogen; 1-4C alkoxy; 1-4C haloalkoxy; aryloxy; 1-4C haloalkyl; formyl; 1-8C alkoxycarbonyl; R3+R4 = -Z=CH-CH=CH- where Z = CH or N; R5 = H; alkali metal, alkaline earth metal or organic ammonium cation; 3-12C cycloalkyl opt. contg. 1-3 1-4C alkyl substits; 1-10C alkyl opt. contg. 1-5 halo and/or 1 1-4C alkoxy, 1-4C alkylthio, cyano, 1-8C alkylcarbonyl, 1-8C alkoxycarbonyl, 3-12C cycloalkyl or phenyl, phenoxy or phenylcarbonyl substits. R6, R7 = 1-20C alkyl opt. substd. by phenyl, 1-4C alkoxy and/or 1-4C alkylthio; phenyl; or R6+R7 = 3-12C alkylene opt. contg. 1-3 1-3C alkyl substits.; R14, R15 = H; 1-6C alkyl, 3-6C alkenyl or 3-6C alkynyl opt. contg. 1-5 halo and/or 1-2 1-6C alkoxy, 3-6C alkenyloxy, 3-6C alkynyloxy, 1-6C alkylthio, 3-6C alkenylthio, 3-6C alkynylthio, 1-6C haloalkoxy, cyano, 1-6C alkylcarbonyl, 3-6C alkenylcarbonyl, 3-6C alkynylcarbonyl, 1-6C alkoxycarbonyl, 3-6C alkenyloxycarbonyl; R16, R17 = H; 1-6C alkyl; 3-6C alkenyl or 3-6C alkynyl; R18 = 1-6C alkyl; 3-6C alkenyl or 3-6C alkynyl; R19 = 1-6C alkyl or phenyl opt. contg. 1-4 halo, nitro, cyano or 1-6C alkyl substits; X = O or S; Y = N when R3 = H and n = 0 or when R4 = O and n = 1; or C when R3+R4 form a ring or when R3 = H and k = 0-2; n = 1; l = 1-4; m = 0 or 1; and n = 1 when Y = C or when Y = N and R4 = O or 0 when Y = N and R4 is other than O.

公开(公告)号：DE4020072A1

公开(公告)日：1992-01-02

申请号：DE4020072

申请日：1990-06-23

Applicant: BASF AG

Inventor： MAYWALD VOLKER DR ,  DITRICH KLAUS DR ,  KUEKENHOEHNER THOMAS DR ,  HAMPRECHT GERHARD DR ,  FREUND WOLFGANG DR ,  WESTPHALEN KARL-OTTO DR ,  GERBER MATTHIAS DR ,  WALTER HELMUT DR

IPC: A01N43/90 ,  C07D498/04 ,  C07D513/04

Abstract: Dicarboximides of formulae (Ia) and (Ib) and their salts are new. In the formulae, X = O or S; R1 = H; halo; 1-6C alkyl opt. mono- to penta-substd. by halogen and/or mono- or disubstd. by cyclopropyl, 1-4C alkoxy, etc or cyano; phenyl or phenyl-1-4C alkyl opt. mono-, di- or trisubstd. in the ring by 1-6C alkyl, 1-6C haloalkyl, etc 3-8C cycloalkyl opt. mono-, di- or trisubstd. by 1-4C alkyl or halogen; 2-6C alkenyl or 2-6C alkynyl opt. mono-, di- or trisubstd. by halogen or 1-3C alkoxy and/or monosubstd. by A; opt. halo-substd. 1-4C alkoxy or 1-4C alkylthio; OA; SA; or a 5-or 6- membered satd. or aromatic heterocyclic gp. contg. 1 or 2 N, S and/or O atoms and opt. mono- or disubstd. by 1-3C alkyl, halogen 1-3C alkoxy or 1-3C alkoxycarbonyl; R2 = H; OH; 1-4C alkoxy; 1-6C alkyl opt. mono-, di- or trisubstd. by cyano, 1-4C alkoxy-1-4C alkoxy, 1-4C alkoxy, 3-8C or A; 3-8C cycloalkyl opt. mono- di- or trisubstd. by 1-6C alkyl, 1-6C haloalkyl, 1-4C alkoxy etc; 3-6C alkenyl or 3-6C alkynyl opt. mono-, di- or trisubstd. by halogen and/or monosubstd. by A; di(1-4C alkyl)amino; or a 5- or 6-membered satd. or aromatic heterocyclic gp. contg. 1 or 2 N, S and/or O atoms and opt. mono-, di- or trisubstd. by 1-4C alkyl or halogen; or 1-4C alkoxycarbonyl; or naphthyl opt. mono-, di- or trisubstd. by 1-4C alkyl or halogen; A = phenyl opt. mono-, di- or trisubstd. by 1-4C alkyl, 1-4C haloalkyl, 1-4C alkoxy, 1-4C haloalkoxy, 1-4C alkylthio, 1-4C haloalkylthio, halogen, cyano or nitor; except 3-methylisoxazole-4,5-dicarboximide (Ic). USE - Cpds (Ia) and (Ib) are pre- and post-emergence herbicides and plant growth regulators. (Ia) and (Ib) are applied e.g. at a rate of 0.01-3 kg/ha.

公开(公告)号：DE4014986A1

公开(公告)日：1991-11-14

申请号：DE4014986

申请日：1990-05-09

Applicant: BASF AG

Inventor： MISSLITZ ULF DR ,  MEYER NORBERT DR ,  KAST JUERGEN DR ,  GOETZ NORBERT DR ,  HARREUS ALBRECHT DR ,  WUERZER BRUNO DR ,  WALTER HELMUT DR ,  WESTPHALEN KARL-OTTO DR ,  GERBER MATTHIAS DR

IPC: A01N35/10 ,  A01N43/14 ,  C07C239/20 ,  C07D309/06 ,  C07D335/02

Abstract: Cyclohexenone oxime ether derivs. of formula (I) and their agriculturally useful salts and esters of 1-10C carboxylic acids and inorganic acids are new. R1 = 1-6C alkyl; A = oot. 1-3C alkyl-substd. 3-6C alkylene or 4-6C alkenyl in which one CH2 gp. is replaced by O, S, SO, SO2 or N(Ra); Ra = H, 1-4C alkyl, 3-6C alkenyl or 3-6C alkynyl; Z = Ph, 5-membered heteroaromatic contg. 1-3 heteroatoms chosen from 3N, O or S or 4-membered heteroaromatic contg. 1-4N; X = NRaRb, NO2 CN, halogen, 1-4C alkyl, partially or completely halogenated 1-4C alkyl, 1-4C alkoxy, 1-4C alkylthio, partially or completely halogenated 1-4C alkoxv, carboxyl, 1-4C alkoxy carbonyl, benzyloxycarbonyl or KPh; n= 0-3 or 1-5 if Z = halogen; Rb = as Ra or is 1-6C aryl or R2 = 1-4C alkoxy(1-6C)alkyl, 1-4Calkylthio(1-6C)alkyl, 3-7C cycloalkyl, 5-7C cycloalkenyl, a 5-membered heterocycle (contg. 1 or 2 heteroatoms chosen from O and S), a 6- or 7-membered satd., singly or double unsatd. heterocycle (contg. or 2 heteroatoms chosen from O and S and opt. mono-, di or tri-substd. by O, halogen, 1-4C alkyl, 1-4C alkoxy, 1-4C di or tri-substd. by OH, halogen, 1-4C alkyl, 1-4C alkoxy, 1-4C alkylthio or partially or completely halogenated 1-4C alkyl), a 5-membered heteroaromatic (contg. 1-3 heteroatoms chosen from O and S and opt. mono-, di or tri-substd. by halogen, CN, 1-4C alkyl, 1-4C alkoxy, 1-4C alkylthio, oartially or completely halogenated 1-4C alkyl, 2-6C alkenyl, 2-6C alkenyloxy, partially or completely halogenated 2-6C alkenyl or 1-4Calkoxy(1-4C)alkyll, Ph or pyridyl.

公开(公告)号：DE4014983A1

公开(公告)日：1991-11-14

申请号：DE4014983

申请日：1990-05-09

Applicant: BASF AG

Inventor： MEYER NORBERT DR ,  KAST JUERGEN DR ,  MISSLITZ ULF DR ,  HARREUS ALBRECHT DR ,  GOETZ NORBERT DR ,  WUERZER BRUNO DR ,  WALTER HELMUT DR ,  WESTPHALEN KARL-OTTO DR ,  GERBER MATTHIAS DR

IPC: A01N35/10 ,  A01N43/08 ,  A01N43/10 ,  A01N43/14 ,  A01N43/16 ,  A01N43/18 ,  A01N43/30 ,  A01N43/32 ,  A01N43/36 ,  A01N43/80 ,  A01P13/00 ,  C07C239/08 ,  C07C239/20 ,  C07C251/34 ,  C07C251/36 ,  C07C251/42 ,  C07C251/50 ,  C07C251/52 ,  C07C251/54 ,  C07C251/60 ,  C07C255/62 ,  C07C323/47 ,  C07D207/32 ,  C07D207/335 ,  C07D257/02 ,  C07D261/02 ,  C07D261/04 ,  C07D261/08 ,  C07D275/02 ,  C07D307/14 ,  C07D309/04 ,  C07D309/06 ,  C07D309/20 ,  C07D317/26 ,  C07D317/28 ,  C07D319/06 ,  C07D333/04 ,  C07D333/16 ,  C07D333/22 ,  C07D333/58 ,  C07D335/02 ,  C07D339/06

Abstract: Cyclohexenone oxime ethers of the general formula I in which the substituents have the following meanings: R is alkyl; A is optionally substituted C3-, C5- or C6-alkylene or C3-, C5- or C6-alkenylene, X is NO2, CM, halogen, alkyl, alkoxy, phenoxy, alkylthio, haloalkyl, haloalkoxy, carboxyl, alkoxycarbonyl, optionally substituted benzyloxycarbonyl, optionally substituted phenyl, n is 0 - 3 or 1 - 5 if X is halogen; R is alkoxyalkyl or alkylthioalkyl; optionally substituted cycloalkyl or cycloalkenyl, an optionally substituted 5-membered saturated heterocycle having one or two oxygen and/or sulphur atoms as hetero atoms, an optionally substituted 6- or 7-membered heterocycle having up to two oxygen and/or sulphur atoms and up to two double bonds, an optionally substituted 5-membered hetaryl having up to two nitrogen atoms and one oxygen atom or one sulphur atom, optionally substituted phenyl or pyridyl, and their agriculturally utilisable salts and esters of C1-C10-carboxylic acids and inorganic acids, methods and intermediates for their preparation, and their use as herbicides.