公开(公告)号：DE10017222A1

公开(公告)日：2001-10-11

申请号：DE10017222

申请日：2000-04-06

Applicant: BASF AG

Inventor： BOETTCHER ARND ,  PINKOS ROLF ,  LORENZ RUDOLF ERICH

IPC: C07B61/00 ,  C07C41/08 ,  C07C43/16 ,  C07C43/176 ,  C07C43/14 ,  B01J31/02

Abstract: The invention relates to a method for producing alkenyl ethers by reacting the corresponding alcohols or phenols with acetylenes in the liquid phase in the presence of basic alkali metal compounds and a cocatalyst. The inventive method is further characterized by using as the cocatalyst the compounds of the general formulae (Ia) and/or (Ib), wherein R , R independently represent C1 to C6 alkyl or C2 to C6 alkenyl, or R and R together represent a butenyl unit, and n is 1, 2, 3, 4 or 5.

公开(公告)号：DE19962405A1

公开(公告)日：2001-06-28

申请号：DE19962405

申请日：1999-12-22

Applicant: BASF AG

Inventor： BOETTCHER ARND ,  PINKOS ROLF ,  PREISS THOMAS ,  LORENZ RUDOLF ERICH

IPC: C07B61/00 ,  C07D207/26 ,  C07D207/267 ,  C07D211/76 ,  C07D223/10 ,  C07B43/06 ,  C07D227/087

Abstract: A process for the production of N-alkenyl amides comprises reaction of the corresponding NH-amide with acetylene in the liquid phase in the presence of a basic alkali metal compound and an alkoxy cocatalyst. A process for the production of N-alkenyl amides comprises reaction of the corresponding NH-amide with acetylene in the liquid phase in the presence of a basic alkali metal compound and a cocatalyst, whereby the cocatalyst is of formula (1) or (2). R O-(CH2CH2CH2CH2O)n-H (1) R O-(CH2CH2CH2CH2O)n-R (2) R ,R = 1-6C alkyl or 2-6C alkenyl or R and R together are both a butenyl unit; n = 1-3.

公开(公告)号：DE19962138A1

公开(公告)日：2001-06-28

申请号：DE19962138

申请日：1999-12-22

Applicant: BASF AG

Inventor： PREISS THOMAS ,  BOETTCHER ARND ,  PINKOS ROLF ,  LORENZ RUDOLF ERICH

IPC: C07D223/12 ,  C07B61/00 ,  C07C231/08 ,  C07D207/26 ,  C07D207/267 ,  C07D211/76 ,  C07D223/10 ,  C07B43/06 ,  C07D211/74 ,  C07D227/087

Abstract: A process for the production of N-alkenyl amides comprises reaction of the corresponding NH-amide with acetylene in the liquid phase in the presence of a basic alkali metal compound and a diol cocatalyst. A process for the production of N-alkenyl amides comprises reaction of the corresponding NH-amide with acetylene in the liquid phase in the presence of a basic alkali metal compound and a cocatalyst, whereby the cocatalyst is a diol of formula (1). HO-X-OH (1) C(R )(R )-C(R )(R ) (2) C(R )(R )-C(R )(R )-C(R )(R ) (3) X = formula (2) or (3); R -R = H, 1-4C alkyl or 3-14C alkylene of which 3-12C are ring atoms and/or their mono- and/or di-alkenylethers.

公开(公告)号：BR9813786A

公开(公告)日：2000-10-03

申请号：BR9813786

申请日：1998-12-18

Applicant: BASF AG

Inventor： BRUNNER MELANIE ,  BOETTCHER ARND ,  BREITSCHEIDEL BORIS ,  HALBRITTER KLAUS ,  HENKELMANN JOCHEM ,  THIL LUCIEN ,  PINKOS ROLF

IPC: B01J23/46 ,  C07B61/00 ,  C07C51/36 ,  C07C61/08 ,  C07C61/09 ,  C07C67/303 ,  C07C69/75 ,  C08K5/12

Abstract: The hydrogenation of esters of benzene-dicarboxylic acids is carried out on supported catalysts containing a Sub-Group VIIII metal on a macroporous support. A process for the hydrogenation of benzene-dicarboxylic acid ester(s) with hydrogen in presence of a supported catalyst containing Sub-Group VIII metal(s) on a macroporous support. If the ester is dimethyl terephthalate, this excludes hydrogenation on a catalyst containing ruthenium, with or without Sub-Group I, VII or VIII metal(s), on a support with an average pore diameter (APD) of at least 50 nm and a BET surface of not more than 30 m /g, with an active metal content of 0.01-30 wt.% and a ratio of (active metal surface):(support surface) of less than 0.05, and/or on a catalyst containing 0.01-30 wt.% active metal(s) as above on a support in which 10-50 vol.% of the pores consist of macropores with a diameter of 50-10,000 nm and 50-90 vol.% consist of mesopores with a diameter of 2-50 nm.

公开(公告)号：DE19832088A1

公开(公告)日：2000-01-20

申请号：DE19832088

申请日：1998-07-16

Applicant: BASF AG

Inventor： BRUNNER MELANIE ,  BOETTCHER ARND ,  BREITSCHEIDEL BORIS ,  HALBRITTER KLAUS ,  HENKELMANN JOCHEM ,  THIL LUCIEN ,  PINKOS ROLF

IPC: C07C51/36 ,  C07C67/303 ,  C07C69/75 ,  C08K5/12 ,  B01J23/46 ,  C07B35/02 ,  C08K5/10

Abstract: Hydrogenation of benzene polycarboxylic acid(s) (or derivative(s)) with an H2-containing gas uses a catalyst which has a sub-Group VIII metal as active metal, alone or together with a sub-Group I or VII metal, on a carrier which is characterized by having macropores, there being provisos relating to the catalyst when dimethyl terephthalate is being hydrogenated. Hydrogenation of benzene polycarboxylic acid(s) (or derivative(s)) with an H2-containing gas uses a catalyst which has a sub-Group VIII metal as active metal, alone or together with a sub-Group I or VII metal, on a carrier which is characterized by having macropores, there being provisos when dimethyl terephthalate is being hydrogenated such that the following two types of catalysts are excluded : (i) a catalyst with Ru as the active metal, alone or together with a sub-Group I, VII or VIII metal, and which has (a) a carrier of average pore diameter at least 50nm and BET surface area at most 30m /g; (b) an active metal content of 0.01-30 wt.% of total catalyst wt.; and (c) a ratio active metal surface to carrier surface of below 0.05; and/or (ii) a catalyst with Ru as the active metal, alone or together with a sub-Group I, VII or VIII metal in an amount of 0.01-30 wt.% based on total catalyst wt., on a carrier having 10-50% of its pore volume of macropores of diameter 50-10,000nm and 50-90% of mesopores of diameter 2-50nm, the fractions of each type of pore adding up to 100%. An Independent claim is included for 9 novel cyclohexane-1,2-dicarboxylic acid esters.

公开(公告)号：DE59603422D1

公开(公告)日：1999-11-25

申请号：DE59603422

申请日：1996-03-21

Applicant: BASF AG

Inventor： FISCHER ROLF ,  PINKOS ROLF

IPC: B01J23/46 ,  B01J23/656 ,  B01J23/755 ,  B01J23/889 ,  B01J23/89 ,  C07B61/00 ,  C07C29/10 ,  C07C29/132 ,  C07C29/141 ,  C07C29/17 ,  C07C31/20 ,  C07D307/08

Abstract: PCT No. PCT/EP96/01247 Sec. 371 Date Sep. 16, 1997 Sec. 102(e) Date Sep. 16, 1997 PCT Filed Mar. 21, 1996 PCT Pub. No. WO96/29322 PCT Pub. Date Sep. 26, 19961,4-butanediol and THF are prepared from furan by a process which comprises converting furan in the presence of water and hydrogen but in the absence of a water-soluble acid in a single stage over a hydrogenation catalyst, the hydrogenation catalyst containing at least one element of subgroup I, V, VI, VII or VIII in the form of a compound or in elemental form and the restriction that the catalyst does not contain nickel alone being applicable.

公开(公告)号：DE19806038A1

公开(公告)日：1999-08-19

申请号：DE19806038

申请日：1998-02-13

Applicant: BASF AG

Inventor： PINKOS ROLF ,  RAHN RALF-THOMAS

IPC: C07C29/149 ,  C07C29/17 ,  C07C31/20 ,  C07C51/573 ,  C07C57/145 ,  C07C67/08 ,  C07C69/60 ,  C07D307/08 ,  C07D307/33 ,  C07D307/60 ,  C07D207/26 ,  B01D3/38

Abstract: The invention relates to a method for separating maleic anhydride from the maleic anhydride-containing reactor waste gases resulting from maleic anhydride production by hydrocarbon oxidation. According to said method the gas stream is placed into contact with a high-boiling inert absorption agent for maleic anhydride and maleic anhydride is separated from the resulting liquid absorbate phase by steam stripping. An alcohol is used as desorption agent and maleic anhydride at least partly reacts with the alcohol to yield an ester.

公开(公告)号：AT176908T

公开(公告)日：1999-03-15

申请号：AT95900684

申请日：1994-11-09

Applicant: BASF AG

Inventor： PINKOS ROLF ,  FISCHER ROLF

IPC: C07D307/33 ,  B01J23/36 ,  B01J23/656 ,  B01J23/72 ,  B01J23/86 ,  C07B61/00 ,  C07D307/32 ,  C07D315/00

Abstract: PCT No. PCT/EP94/03683 Sec. 371 Date May 16, 1996 Sec. 102(e) Date May 16, 1996 PCT Filed Nov. 9, 1994 PCT Pub. No. WO95/14010 PCT Pub. Date May 26, 1995A process for the preparation of gamma -butyrolactone, in which 2,5-dihydrofuran or 2,3-dihydrofuran or a mixture of these two dihydrofurans is caused to react in the gas phase in the presence of water and in the presence or absence of additional hydrogen at elevated temperature over a hydrogenating catalyst.

公开(公告)号：MX9700123A

公开(公告)日：1998-01-31

申请号：MX9700123

申请日：1995-06-16

Applicant: BASF AG

Inventor： PINKOS ROLF ,  FISCHER ROLF ,  BREITSCHEIDEL BORIS ,  POLANEK PETER

IPC: C07C31/20 ,  C07C45/59 ,  C07C47/19 ,  C07D307/20

Abstract: Se presenta un procedimiento para la preparacion de 1,4-butadiol, en donde se hace reaccionar 2,3-dihidroofurano en un catalizador de hidrogenacion, en una etapa unica, en presencia de agua e hidrogeno a una temperatura comprendida entre 20 degree C y 300 degree C, y bajo una presion de 1 a 300 bar en un entorno neutro o bien ácido.

公开(公告)号：FI965228A0

公开(公告)日：1996-12-27

申请号：FI965228

申请日：1996-12-27

Applicant: BASF AG

Inventor： PINKOS ROLF ,  FISCHER ROLF ,  BREITSCHEIDEL BORIS ,  POLANEK PETER

IPC: B01J23/36 ,  B01J23/46 ,  B01J23/72 ,  C07B61/00 ,  C07C29/10 ,  C07C29/132 ,  C07C29/14 ,  C07C29/141 ,  C07C31/20 ,  C07C45/59 ,  C07C47/19 ,  C07D307/20 ,  C07C

Abstract: PCT No. PCT/EP95/02335 Sec. 371 Date Dec. 27, 1996 Sec. 102(e) Date Dec. 27, 1996 PCT Filed Jun. 16, 1995 PCT Pub. No. WO96/00203 PCT Pub. Date Jan. 4, 1996Described is a method of producing 1,4-butanediol, the method calling for 2,3-dihydrofuran to be decomposed in a single stage over a hydrogenation catalyst in the presence of water and hydrogen at a temperature of 20 to 300 DEG C. and a pressure of 1 to 300 bar and in neutral or acid conditions.