ELECTROSTATIC CHARGE DEVELOPING TONER

    公开(公告)号:JPS61221757A

    公开(公告)日:1986-10-02

    申请号:JP6254185

    申请日:1985-03-27

    Applicant: KAO CORP

    Abstract: PURPOSE:To form an electrostatic charge developing toner sufficiently and uniformly chargeable to positive or negative polarity by incorporating a specified compd. to improve compatibility of dispersible components, such as colorant and charge controller, with a binder resin. CONSTITUTION:The compd. to be incorporated is represented by formula 1 in which R1 is a 1-32C straight chain or branched alkyl, alkenyl, or aryl group, such as methyl, and M is a divalent metal, such as Mg of alkaline earth metals or Zn of divalent transition metals. This compd. is embodied by formula 1-1, and this compd. is contained, preferably, in an amt. of 0.01-10pts.wt. per 100pts. wt. of a binder resin, and its preferable softening point is 90-160 deg.C measured by the KOKASHIKI flow tester, and its preferable glass transition point is >=50 deg.C.

    MAGNETIC RECORDING MEDIUM
    182.
    发明专利

    公开(公告)号:JPS61198418A

    公开(公告)日:1986-09-02

    申请号:JP3850585

    申请日:1985-02-27

    Applicant: KAO CORP

    Abstract: PURPOSE:To improve magnetic powder dispersibility, durability and surface smoothness by using a specific polyurethane resin as a binder. CONSTITUTION:The polyurethane resin having at least >=1 of an ammonium salt and/or amine salt of a COOH group in the molecular chain is used. A magnetic recording medium is produced by coating a magnetic paint for which the polyurethane resin is used as the binder and to which pulverous ferromagnetic powder and additive, etc. are added together with an org. solvent, on a non- magnetic substrate and drying the coating. The ratio of the binder and the pulverous ferromagnetic powder is 10-100pts.wt., more preferably 20-50pts.wt. by 100pts.wt. pulverous ferromagnetic powder. The mechanical strength and wear resistance are not enough if the ratio of the binder is below 10pts.wt. The magnetic powder density in the magnetic layer decreases and the satisfactory performance (reproduced output, etc.) as the magnetic recording medium is not obtainable if the ratio of the binder is increased to 100pts.wt. or above.

    DISPERSION STABILIZER FOR OILY SUSPENSION POLYMERIZATION

    公开(公告)号:JPS61157506A

    公开(公告)日:1986-07-17

    申请号:JP27641784

    申请日:1984-12-28

    Applicant: KAO CORP

    Abstract: PURPOSE:The titled dispersion stabilizer capable of producing effectively a granular polymer, consisting of a polymer comprising three of lipophilic ethylenic unsaturated monomer unit, a cationic and an anionic ethylenic unsaturated monomer units as essential constituent components. CONSTITUTION:The aimed dispersion stabilizer consisting of a polymer having preferably 1,000-1,000,000 number-average molecular weight, comprising (A) 70-99mol% lipophilic ethylenic unsaturated monomer unit [e.g., unit such as styrene, (meth)acrylic acid alkyl ester, etc.], (B) 0.5-29.5wt% cationic ethylenic unsaturated monomer unit (e.g., unit such as vinylpyridine, N,N- dimethylaminostyrene, etc.), and (C) 0.5-29.5wt% anionic ethylenic unsaturated monomer unit (e.g., unit such as acrylic acid, vinylbenzoic acid, etc.) as essential constituent components. A molar ratio of the component B to component C is preferably 5-0.2.

    COSMETIC
    184.
    发明专利
    COSMETIC 失效

    公开(公告)号:JPS6094904A

    公开(公告)日:1985-05-28

    申请号:JP20227383

    申请日:1983-10-28

    Applicant: KAO CORP

    Abstract: PURPOSE:To provide a film-forming cosmetic, especially film-forming pack, resistant to hydrolysis with time, and having substituted storage stability, by using a copolymer of vinyl alcohol and an alkyl vinyl ether as a component. CONSTITUTION:The objective cosmetic contains the copolymer (especially having an average molecular weight of 30,000-200,000) composed of 98-80mol% (especially 95-85mol%) vinyl alcohol monomer and 2-20mol% (especially 5- 15mol%) 1-6C straight or branched chain alkyl vinyl ether monomer unit, as a main component. The content of the copolymer is preferably 1-40wt%. The cosmetic is a homogeneous paste or liquid having low viscosity, and accordingly, is can be spread easily and uniformly on the skin, and dried in a short time. USE:Film-forming agent for nail enamel, eyeliner, mascara, hair-dressing, etc., and thickener, emulsifier, binder, etc. for various cosmetics such as milky lotion, foundation, cream, face powder, shampoo, etc.

    BIOCIDAL AQUEOUS SUSPENSION COMPOSITION

    公开(公告)号:JPS6032701A

    公开(公告)日:1985-02-19

    申请号:JP13921583

    申请日:1983-07-29

    Applicant: KAO CORP

    Abstract: PURPOSE:To provide the titled composition having excellent storage stability, suspension stability in dilution, and resistance to agglomeration in the combined use with other emulsifiable concentrate, wettable powder, etc., by using a thickening and dispersing agent comprising a water-soluble polymer compound having a specific chemical structure. CONSTITUTION:A biocide storable stably for a long period at a viscosity of 100-500cps is prepared by compounding (A) 1-70(wt)% biocide insoluble in water and solid or pasty at normal temperature, (B) 0.1-40%, especially 1-20% water-soluble polymer compound having an average molecular weight of 1,000- 10,000,000 and containing one or more basic or cationic N-atom in the recurring unit, and (C) 0.1-20%, especially 1-10% nonionic and/or anionic surface active agent. The component B is a homopolymer or copolymer of the salt or quaternary ammonium salt of the nitrogen-containing monomer of formula I -formula V(A is O or NH; n1 is 1-3; R1 is H or CH3; R2 and R3 are H, CH3 or C2H5).

    Magnetic recording medium
    188.
    发明专利
    Magnetic recording medium 失效
    磁记录介质

    公开(公告)号:JPS59129938A

    公开(公告)日:1984-07-26

    申请号:JP545483

    申请日:1983-01-17

    Applicant: Kao Corp

    CPC classification number: G11B5/7023

    Abstract: PURPOSE:To obtain a magnetic recording medium having a magnetic layer having good dispersibility of magnetic powder, excellent durability, etc. by incorporating magnetic powder coated with the resulted reaction product of a silane coupling agent contg. an isocyanate group with a copolymer of specific vinyl monomers. CONSTITUTION:An organosilicone polymer soln. obtd. by the reaction of a silane coupling agent contg. an isocyanate group such as the one expressed by the formula for example, with >=1 kind copolymer from the group of copolymers of either 5-70mol% vinyl monomer contg. OH or 5-70mol% vinyl monomer contg. COOH and 30-95mol% hydrophobic vinyl monomer is prepd. A magnetic medium having a magnetic layer dispersed with the magnetic powder coated with the organosilicon polymer by dipping the magnetic powder into such soln. in a binder resin is manufactured. The magnetic layer having uniform dispersion of the magnetic powder, a smooth surface and an excellent electromagnetic conversion characteristic is thus obtd.

    Abstract translation: 目的:为了获得具有磁性粉末分散性好的磁性层,优异的耐久性等的磁记录介质,其中包含用所得到的硅烷偶联剂反应产物所涂覆的磁性粉末。 具有特定乙烯基单体的共聚物的异氰酸酯基团。 构成:有机硅聚合物溶胶。 obtd。 通过硅烷偶联剂的反应 异氰酸酯基团,例如由式表示的异氰酸酯基团,其具有来自5-70mol%乙烯基单体的共聚物的> = 1种共聚物。 OH或5-70mol%乙烯基单体 COOH和30-95mol%疏水乙烯基单体制备。 一种磁性介质,其磁性层通过将磁性粉末浸渍在这样的溶液中而被涂有有机硅聚合物的磁性粉末分散。 在粘合剂树脂中制造。 因此,具有磁粉均匀分散的磁性层,光滑表面和优异的电磁转换特性。

    Surfactant for use in emulsion polymerization
    189.
    发明专利
    Surfactant for use in emulsion polymerization 失效
    用于乳液聚合的表面活性剂

    公开(公告)号:JPS5938207A

    公开(公告)日:1984-03-02

    申请号:JP15041382

    申请日:1982-08-30

    Applicant: Kao Corp

    Abstract: PURPOSE: The titled surfactant capable of providng stable, low-foaming emulsions, consisting mainly of a salt of a copolymer consisting of a carboxyl group or sulfonic acid group-containing unsaturated monomer and an acrylate ester monomer in a specified weight ratio.
    CONSTITUTION: 85W99wt% carboxyl group or sulfonic acid group-containing unsaturated monomer (e.g., acrylic acid or vinylsulfonic acid) is mixed with 15W 1wt% ester of an 8W20C aliphatic alcohol with (meth)acrylic acid (e.g., lauryl acrylate or stearyl acrylate). Then, above 60wt% resulting monomer mixture as an essential component is copolymerized with below 40wt% different nonionic unsaturated monomer (e.g., ethyl acrylate or acrylamide). Then, the produced copolymer is neutralized into a salt, which is the purpose surfactant for use in emuosion copolymerization.
    COPYRIGHT: (C)1984,JPO&Japio

    Abstract translation: 目的:能够提供稳定的低发泡乳液的标题表面活性剂,主要由含羧基或含磺酸基的不饱和单体和丙烯酸酯单体的共聚物的盐组成,其特定重量比。 构成:将85-99重量%的羧基或含磺酸基的不饱和单体(例如丙烯酸或乙烯基磺酸)与15重量%的8-20重量%脂肪醇酯与(甲基)丙烯酸(例如月桂基 丙烯酸酯或硬脂基丙烯酸酯)。 然后,以60重量%以下得到的单体混合物作为必要组分,与40重量%以下的不同的非离子不饱和单体(例如丙烯酸乙酯或丙烯酰胺)共聚。 然后,将生成的共聚物中和成为用于乳化共聚的目的表面活性剂的盐。

    PREPARATION OF LOW-MOLECULAR WEIGHT KERATINOUS SUBSTANCE

    公开(公告)号:JPS57109797A

    公开(公告)日:1982-07-08

    申请号:JP18719080

    申请日:1980-12-26

    Applicant: KAO CORP

    Abstract: PURPOSE:To obtain an oligokeratin useful as a cosmetic base material for hair, etc. at a low cost without requiring the purifying step, by treating a fibrous reduced keratin reduced without collapsing the orginal fibrous shape with a proteolytic hydrolase. CONSTITUTION:A fibrous keratin, e.g. wool, feather or hair, is reduced in a reaction medium, e.g. water and/or an alcohol, with the original fibrous shape retained. The reduced fibrous keratin is then hydrolyzed with a proteolytic hydrolase, preferably an acidic enzyme, e.g. pepsin, in water at 35-40 deg.C at a pH

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