Abstract:
PURPOSE: A polycarbonate resin is provided to prevent the degradation of mechanical properties while excellent fluidity and to ensure excellent productivity and workability due to an injection molding temperature is low than a general carbonate resin. CONSTITUTION: A polycarbonate resin comprises a terminal capping group which is a 4-alkoxyphenyl group represented by chemical formula 1, wherein the R1 shows respectively C1~20 alkoxy radical. The average molecular weight of the polycarbonate resin is 14,000-20,000. A method for preparing the polycarbonate resin comprises a step of reacting divalent phenol, carbonate precursor, and a terminal capping agent which is a 4-alkoxyphenyl group represented by chemical formula 3 for capping a carbonate molecule chain terminal.
Abstract:
A flame resistant scratch-resistant thermoplastic resin composition is provided to improve compatability and to enhance coloring property and appearance. A flame resistant scratch-resistant thermoplastic resin composition comprises 100 parts by weight of which comprises 50 ~ 90 parts by weight of a polycarbonate resin, 1 ~ 50 parts by weight of a methacryl-based copolymer resin having a refractive index of 1.495 ~ 1.590, and 0 ~ 49 parts by weight of a (meth)acryl-based resin; and 5 ~ 40 parts by weight of a flame retardant.
Abstract:
A flame retardant thermoplastic resin composition, and a plastic molded product using the composition are provided to minimize the deterioration of transparency and coloration and to improve flame retardancy and scratch resistance. A flame retardant thermoplastic resin composition comprises 100 parts by weight of a base resin which comprises 50-90 wt% of a polycarbonate-based resin, and 10-50 wt% of a (meth)acrylate resin; 0.5-10 parts by weight of a superhigh molecular weight aromatic vinyl-cyanovinyl copolymer having a weight average molecular weight of 1,000,000-7,000,000; 1-50 parts by weight of a flame retardant; and 1-30 parts by weight of an impact modifier.
Abstract:
A flame retardant copolymer, and a flame retardant thermoplastic resin composition are provided to improve flame retardancy, transparency, scratch resistance and the balance of physical properties. A flame retardant copolymer comprises 80-99 wt% of an acrylic monomer; and 1-20 wt% of a vinyl group-containing phosphorus-based monomer. Preferably the vinyl group-containing phosphorus-based monomer is represented by the formula 1, 2, 3 or 4, wherein R1 is H or a methyl group; R2 and R3 are independently a methyl group or an ethyl group; and n is 0 or 1. A flame retardant thermoplastic resin composition comprises 100 parts by weight of the flame retardant copolymer; and 30 parts by weight or less of an impact modifier.
Abstract:
A phosphorous-containing cyclic compound is provided to improve flameproof effects when the compound is applied to thermoplastic resin by increasing phosphorous content and inhibit environment pollution by burning through suppression of halogenized gas release. A phosphorous-containing cyclic compound represented by the formula(1), in which R is hydrogen atom or C1-C6 alkyl, phenyl or phenoxy; and n is 1 or 2, is prepared by reacting 2-(6-oxid-6H-dibezoxa-phosphorin-6-yl)methanol with compounds represented by the formula(3) in organic solvent at 90-120 deg. C, wherein the organic solvent is selected from benzene, toluene, xylene, 1,4-dioxane, dichloromethane and dichloroethane. A flameproof thermoplastic resin composition comprises 0.1-50 parts by weight of the phosphorous-containing cyclic compound represented by the formula(1), and 100 parts by weight of thermoplastic resin.
Abstract:
A flame retardant thermoplastic resin composition is provided to improve scratch resistance and to obtain satisfactory mechanical strength and flame retardancy. A flame retardant thermoplastic resin composition comprises 100 parts by weight of a base resin which comprises 30-90 parts by weight of a polycarbonate-based resin, 20-50 parts by weight of a poly(methyl methacrylate) resin, and 5-50 parts by weight of a polyethylene terephthalate-based resin; and 5-30 parts by weight of a phosphorus-based flame retardant. Preferably the phosphorus-based flame retardant is represented by the formula 1, wherein R1, R2, R4 and R5 are independently a C6-C20 aryl group or alkyl-substituted aryl group; R3 is a group derived from resorcinol, hydroquinol, bisphenol A and bisphenol S; and n is 0-5.
Abstract:
PURPOSE: Provided is a thermoplastic resin composition excellent in heat-resistance and impact-resistance, which contains a styrene-acrylonitrile copolymer as a compatibilizer and can be recycled. CONSTITUTION: The thermoplastic resin composition comprises: 50-90wt% of an acrylonitrile-butadiene-styrene(ABS) copolymer resin produced by graft-copolymerizing 10-60wt% of a butadiene rubber with an average particle size of 0.1-4 micrometer and 40-90wt% of a monomer mixture comprising 50-82wt% of an aromatic vinyl monomer and 50-18wt% of an unsaturated nitrile monomer, wherein the aromatic vinyl monomer is styrene, alpha-methyl styrene, or p-methyl styrene and the unsaturated nitrile monomer is acrylonitrile or methacrylonitrile; 5-45wt% of a polyphenylene ether resin such as poly(2,6-dimethyl-1,4-phenylene)ether; 5-20wt% of the styrene-acrylonitrile copolymer resin containing 5-18wt% of acrylonitrile.
Abstract:
PURPOSE: Provided is a thermoplastic and fire retardant resin composition which has excellent injection releasability, impact resistance, fire retardancy, and fluidity. CONSTITUTION: The composition comprises 100 parts by weight of base resin consisting of the following (A) and (B): (A) 40-95 parts by weight of rubber modified styrene-acrylonitrile copolymer resin consisting of (a1) 20-90 parts by weight of styrene-acrylonitrile graft copolymer resin containing 10-60 wt% of rubber component and 18-50 wt% of acrylonitrile(in components except for the rubber component), (a2) 0-80 parts by weight of styrene-acrylonitrile copolymer resin containing 18-50 wt% of acrylonitrile, and (a3) 5-40 parts by weight of styrene-based resin containing 0-20 wt% of rubber, (B) 60-5 parts by weight of polyphenylene ether resin; (C) 2-30 parts by weight of styrene-acrylonitrile copolymer containing 5-18 wt% of acrylonitrile; (D) 5-30 parts by weight of aromatic phosphate ester compound(formula 1); and (E) 0.05-3 parts by weight of montan wax.