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公开(公告)号：KR1020060122576A
公开(公告)日：2006-11-30
申请号：KR1020050045153
申请日：2005-05-27
Applicant: 한국화학연구원
Abstract: Provided is a method for preparing a porous organic-inorganic hybrid material which has a nano-sized micropore and is used to encapsulate a small guest molecule or to separate a large molecule. The method comprises the steps of stirring a metal material and an organic material in the presence of a solvent with a velocity of 50-2,000 rpm for 1-600 min or irradiating an ultrasonic wave of 15,000 Hz to 30 MHz to the mixture for 1-600 min, to prepare a reaction solution where a crystal nucleus is formed; and irradiating a microwave of 1-30 GHz to the obtained reaction solution containing a crystal nucleus at a temperature of 100-250 deg.C. Preferably the organic material is an organic compound capable of coordinating with the metal material.
Abstract translation: 提供一种制备具有纳米尺寸微孔并用于包封小客体分子或分离大分子的多孔有机 - 无机混合材料的方法。 该方法包括在溶剂存在下，以50-2,000rpm的速度搅拌1-600分钟或将15,000Hz至30MHz的超声波照射到混合物中的金属材料和有机材料的步骤， 600分钟，制备形成晶核的反应溶液; 并在100-250℃的温度下，将得到的含有晶核的反应溶液照射1-30GHz的微波。 优选地，有机材料是能够与金属材料配位的有机化合物。
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公开(公告)号：KR100571053B1
公开(公告)日：2006-04-14
申请号：KR1020040012393
申请日：2004-02-24
Applicant: 한국화학연구원
Abstract: 본 발명은 텅스텐산화물이 치환된 티타늄산화물 친수성 박막의 제조방법에 관한 것으로, 구체적으로 10 중량% 이하의 텅스텐 할로겐화물과 티타늄 알콕사이드로 이루어진 혼합물을 킬레이팅제에 용해시켜 졸 상태의 텅스텐-티타늄 전구체 용액을 제조하는 단계(단계 1), 상기 졸 용액을 기질의 표면 위에 코팅하는 단계(단계 2), 상기 코팅된 기질을 350∼500℃에서 열처리하여 무정형 WO
3 -TiO
2 복합산화물을 형성시키는 단계(단계 3)를 포함하는 것으로 이루어진 친수성 박막의 제조방법에 관한 것이다.
본 발명의 제조방법은 킬레이팅제를 이용함으로써 가수분해 속도를 조절하고, 열처리 온도를 낮추어 수십 나노미터의 입자 크기를 갖는 균일한 복합산화물 박막을 제조할 수 있으며, 낮은 온도에서 소결함으로써 유리 또는 세라믹 등 다양한 기질 표면에 코팅할 수 있을 뿐만 아니라 저렴한 가격으로 제조할 수 있다. 또한 상기 제조방법의 의해 제조된 박막은 자외선 조사 후 장시간 동안 친수성을 유지할 수 있다.
친수성, 초친수성, WO3, TiO2, 복합산화물, 안티포깅Abstract translation: 另外，本发明的氧化钨被制造的亲水性薄膜中，特别是由钨的卤化物与通过所述螯合剂溶解在溶胶 - 钨 - 钛前体溶液的混合物的至多10重量％的钛的醇盐的方法取代用氧化钛 （步骤1），将溶胶溶液涂布在基材表面上（步骤2），在350-500℃下热处理涂布的基材以形成无定形的WO
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13.发明授权
公开(公告)号：KR100392202B1
公开(公告)日：2003-08-19
申请号：KR1020000056495
申请日：2000-09-26
Applicant: 한국화학연구원 , 세우엔지니어링 주식회사
IPC: B01J21/06 , B01J23/755 , B01J23/58
Abstract: PURPOSE: Provided are a selective hydrogenation catalyst and a selective hydrogenation process of diolefin compound using the catalyst. The above catalyst is tetragonal Ni/Zr type and is used in the selective hydrogenation of diolefin compounds that are contained in the carbohydrate mixtures into mono-olefin compounds. CONSTITUTION: The preparation method of the above catalyst comprises: 0.1-5wt.% (based on the hydrate) of Ni alone or having 0.1-5mol.% (based on Zr carrier) of a cocatalyst selected from Pd, Pt, Ag, Cu, Mo and B and its carrier of Zr alone or modified by one metal chosen from Ca, lanthanide metals such as Se and La, IIIB group metal(silicone) or IVB group metal(Al). The above selective hydrogenation is conducted in the temperature range of 80 to 250°C at a pressure of 1 to 12 atm. and at space velocity of 4 to 12/h (based on the volume of liquid reactant).
Abstract translation: 目的：提供使用该催化剂的选择性加氢催化剂和二烯烃化合物的选择性加氢方法。 上述催化剂是四方型Ni / Zr型，用于将碳水化合物混合物中所含的二烯烃化合物选择性加氢成单烯烃化合物。 构成：上述催化剂的制备方法包括：0.1-5重量％（基于水合物）单独的Ni或0.1-5摩尔％（基于Zr载体）助催化剂，选自Pd，Pt，Ag，Cu ，Mo和B及其单独的Zr或其载体，或由选自Ca，镧系金属如Se和La，IIIB族金属（硅氧烷）或IVB族金属（Al）的一种金属改性的载体。 上述选择性加氢在80至250℃的温度范围和1至12大气压的压力下进行。 并且空速为4至12 / h（基于液体反应物的体积）。
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公开(公告)号：KR100383218B1
公开(公告)日：2003-05-12
申请号：KR1020000063272
申请日：2000-10-26
Applicant: 한국화학연구원
IPC: C01B15/01
Abstract: PURPOSE: Provided is a direct preparation method of hydrogen peroxide, which is characterized in that the hydrogen carrier quinone and its derivatives are fixed to the channels of zeolite by anchoring and grafting method and the product is made in aqueous solution. Usual process uses solvent dissolving quinone and hydroquinone and in the above process the quinones are fixed to the zeolite more than 2 times than the usual process, making the method improved in the stability and reactivity of the catalyst. CONSTITUTION: The method includes the steps of: making the catalyst by anchoring or grafting quinone or its derivatives into the zeolite which is ion-exchanged with VIII group transition metals and carries them; and directly synthesizing hydrogen peroxide at 0-90deg.C by introducing reducing agent and oxygen gas. The above anchoring and grafting is conducted by using as anchoring agent tetrahydrofuran and dicyclohexylcarbodiimide and pre-grafting to zeolite with 3-aminopropyltrimethoxysilane and trimethoxysilylpropyldiethylenetriamine. The above zeolite is selected from Y, Beta, L or MCM-41 structure and Si/Al ratio is 1-160. The cationic form of zeolite is selected from Na, K and H while VIII group transition metal is chosen from Rd, Pt, Rh, Ir, Fe, Cu and Ni. The reducing agent is selected from hydrogen, ammonia and alcohol. The catalyst is washed with benzene, alcohol and acetone, and the acid is added to the above aqueous solution, the acid being chosen from 0.001-1N sulfuric acid, acetic acid and hydrochloric acid.
Abstract translation: 用途：提供了一种过氧化氢的直接制备方法，其特征在于氢载体醌及其衍生物通过锚定和接枝方法固定在沸石的通道上，并将产物制成水溶液。 通常的方法使用溶解醌和氢醌的溶剂，并且在上述方法中醌固定在沸石上比常规方法多2倍以上，使得该方法提高了催化剂的稳定性和反应性。 组成：该方法包括以下步骤：通过将醌或其衍生物锚定或接枝到与VIII族过渡金属离子交换并携带它们的沸石中制备催化剂; 并通过引入还原剂和氧气直接在0-90℃下合成过氧化氢。 上述锚定和接枝通过使用四氢呋喃和二环己基碳二亚胺作为锚定剂并用3-氨丙基三甲氧基硅烷和三甲氧基甲硅烷基丙基二亚乙基三胺预接枝到沸石上来进行。 上述沸石选自Y，Beta，L或MCM-41结构，Si / Al比为1-160。 阳离子形式的沸石选自Na，K和H，而VIII族过渡金属选自Rd，Pt，Rh，Ir，Fe，Cu和Ni。 还原剂选自氢气，氨和酒精。 催化剂用苯，乙醇和丙酮洗涤，将酸加入上述水溶液中，酸选自0.001-1N硫酸，乙酸和盐酸。
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公开(公告)号：KR1020020061434A
公开(公告)日：2002-07-24
申请号：KR1020010002734
申请日：2001-01-17
Applicant: 한국화학연구원
IPC: B01J23/755 , B01J21/04 , B01J21/06
CPC classification number: B01J23/755 , B01J23/83 , B01J23/835 , B01J37/0201 , B01J37/0205 , B01J37/035 , C07C5/05
Abstract: PURPOSE: The modified nickel-alumina catalyst for selective hydrogenation of diolefins of the present invention is manufactured by surface modifying gamma-alumina support with one element selected from zirconium, lanthanum and tin, and then it is further supported by nickel. CONSTITUTION: In a modified nickel-alumina catalyst for selective hydrogenation of diolefins that is manufactured by surface modifying gamma-alumina support with one element selected from zirconium, lanthanum and tin, and then it is further supported by nickel, the present invention is characterized in that gamma-alumina support is supported by one element selected from zirconium, lanthanum and tin in an amount of 0.2 to 10 wt.% and nickel in an amount of 0.5 to 10 wt.%, based on the weight of the gamma-alumina support. Before the modified nickel-alumina catalyst is used to convert diolefins to corresponding mono olefins through selective hydrogenation reaction, the modified nickel-alumina catalyst should undergo reduction stage at 400-500deg.C and pretreatment at 300-450deg.C in H2S gas atmosphere.
Abstract translation: 目的：本发明二烯烃选择性氢化的改性镍 - 氧化铝催化剂是通过用选自锆，镧和锡的一种元素表面改性γ-氧化铝载体，然后进一步由镍负载制备的。 构成：在通过用选自锆，镧和锡的一种元素表面改性γ-氧化铝载体制备的二烯烃选择性氢化的改性镍 - 氧化铝催化剂中，然后进一步由镍负载，本发明的特征在于 该γ-氧化铝载体由选自锆，镧和锡的一种元素以0.2至10重量％的量负载，镍的量为0.5至10重量％，基于γ-氧化铝载体的重量 。 在通过选择性氢化反应将改性镍 - 氧化铝催化剂用于将二烯烃转化为相应的单烯烃之前，改性镍 - 氧化铝催化剂应在400-500℃下进行还原阶段，并在H 2 S气体气氛中在300-450℃下进行预处理。
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Patent Agency Ranking
公开(公告)号：KR1019960007835A
公开(公告)日：1996-03-22
申请号：KR1019940020711
申请日：1994-08-22
Applicant: 한국화학연구원
IPC: C30B25/02
Abstract: 본 발명은 질화칼륨(Gallium Nitride, GaN)을 집광성 레이저광 여기(coherent laser aided vapour phase epitaxy, LVPE)방법에 의해 육방정계의 부루자이트(Wurtzite) 단결정 격자구조로 피복성장시키는 방법에 관한 것으로서 더욱 상세하게는 기판위에 질화알루미늄(Aluminum nitride, AIN)완충막을 인시츄(in-situ)방법에 의해 도입하고 갈륨 함유 반응물과 질소함유 반응물을 약 800℃의 낮은 온도와 0.1~3.8torr의 낮은 증기압하에서 공명적 에너지 광분해 증착법에 의해 단결정 두께 2~20μm를 갖는 청색 발광성 질화갈륨 적층막(epitaxial film)을 제조하는 방법에 관한 것이다.
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公开(公告)号：KR101462035B1
公开(公告)日：2014-12-04
申请号：KR1020120129447
申请日：2012-11-15
Applicant: 한국화학연구원
IPC: C07D493/04 , C07D307/20 , C07H1/00 , C07B35/04
Abstract: 본발명은솔비톨, 만니톨, 자이리톨및 아라비니톨같은폴리올의탈수방법에관한것으로, 보다상세하게황산화된고체촉매를사용하여높은탈수전환율, 높은선택성및 높은수율을얻을수 있는폴리올의탈수방법을제공한다.
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公开(公告)号：KR101359446B1
公开(公告)日：2014-02-11
申请号：KR1020120028318
申请日：2012-03-20
Applicant: 한국화학연구원
IPC: B01J23/46 , B01J21/08 , C07C29/151 , C07C31/26
Abstract: 본 발명은 알루미나, 티타니아, 실리카 등의 담체에 산화니켈 피막을 입히고 그 위에 루테늄을 나노입자로 담지한 촉매 및 이의 제조방법에 관한 것으로, 보다 상세하게는 알루미나, 티타니아, 실리카 등의 담체에 니켈의 양을 0.5~15 중량％이 되도록 담지하고 그 위에 루테늄의 양이 0.2~15 중량％가 되도록 담지한 담지촉매 및 이의 제조방법에 관한 것이다.
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公开(公告)号：KR1020120123189A
公开(公告)日：2012-11-08
申请号：KR1020120028423
申请日：2012-03-20
Applicant: 한국화학연구원
CPC classification number: Y02P20/584
Abstract: PURPOSE: A manufacturing method of sugar alcohols is provided to continuously manufacture sugar alcohols with high yield through a repeated catalytic hydrogenation of sugars without regeneration of a catalyst. CONSTITUTION: A manufacturing method of sugar alcohols comprises a step of preparing sugar alcohols through a hydrogenation of sugars by using a supported catalyst. The supported catalyst is that ruthenium is supported into a single support or a mixture support selected from silica, alumina, and titania. The support has a coating consisting of nickel metal oxide. The hydrogenation is conducted at the reaction temperature 60-200 °C and reaction pressure of 2-200 MPa. The comprised amount of the ruthenium is 0.2-15 weight% based on the total weight.
Abstract translation: 目的：提供糖醇的制造方法，通过反复催化氢化糖而不再催化剂连续制备高产率的糖醇。 构成：糖醇的制造方法包括通过使用负载型催化剂通过糖的氢化制备糖醇的步骤。 负载催化剂是将钌负载到单个载体或选自二氧化硅，氧化铝和二氧化钛的混合物载体中。 载体具有由镍金属氧化物组成的涂层。 氢化反应温度为60-200℃，反应压力为2-200MPa。 钌的含量相对于总重量为0.2-15重量％。
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