SILSESQUIOXANE POLYMERS, COMPOSITIONS, METHODS, AND ARTICLES

    公开(公告)号:WO2019058228A1

    公开(公告)日:2019-03-28

    申请号:PCT/IB2018/057022

    申请日:2018-09-13

    Abstract: A silsesquioxane polymer, composition, method, and article including such polymer, wherein the polymer includes a three-dimensional network of Formula (I): wherein: each R 1 and R 2 is independently a (C1-C4)alkyl; each L 1 and L 2 is independently a single bond, an alkylene, or an alkylene bonded to a group selected from oxy, thio, carbonyl, -NH-, and combinations thereof; each R 3 is independently a linear (C14-C100)alkyl; each R 4 is independently a (C1-C30)alkyl, a (C2-C30)heteroalkyl having at least one oxygen, sulfur, or -NH- group, or a (C1-C30)alkyl substituted with a fluoro, thiol, isocyanato, cyanato, hydroxyl, glycidoxy, or epoxy group; with the proviso that L 1 , L 2 , and R 4 are selected such that each Si atom is directly bonded to an alkylene or an alkyl; m is an integer of at least 2; n is an integer of 0 or above; m + n is an integer of at least 3; each oxygen atom at an asterisk (*) is bonded to another Si atom within the three- dimensional network; and the silsesquioxane polymer is a solid at 25°C.

    GEL ADHESIVE COMPRISING CROSSLINKED BLEND OF POLYDIORGANOSILOXANE AND ACRYLIC POLYMER

    公开(公告)号:WO2019193514A1

    公开(公告)日:2019-10-10

    申请号:PCT/IB2019/052727

    申请日:2019-04-03

    Abstract: A method of making a silicone gel adhesive is described comprising providing an acrylic polymer, the acrylic polymer comprising at least 50 wt.-% of polymerized units of C1-C32 (meth)acrylate ester monomer; providing at least one non-functional polydiorganosiloxane, hydroxy-functional polydiorganosiloxane, or a mixture thereof; combining the acrylic polymer and polydiorganosiloxane into a mixture; coating the mixture onto a substrate, and subjecting the mixture to radiation thereby crosslinking the mixture. Also described is a silicone gel adhesive comprising a crosslinked material at least one non-functional polydiorganosiloxane, hydroxy-functional polydiorganosiloxane, or a mixture thereof; and an acrylic polymer comprising at least 50 wt.-% of polymerized units of alkyl (meth)acrylate monomers and a gel content of at least 20 wt.-%. Also described is a medical article or intermediate thereof, comprising a layer of the silicone gel adhesive described herein adhered to a substrate; and methods of adhering a medical article.

    SILSESQUIOXANE POLYMERS, COMPOSITIONS, AND ARTICLES

    公开(公告)号:WO2019058232A1

    公开(公告)日:2019-03-28

    申请号:PCT/IB2018/057027

    申请日:2018-09-13

    Abstract: A silsesquixane polymer, a composition including such silsesquixane polymer, and an article including such polymer or composition, wherein the composition includes a silsesquioxane polymer and a free siloxane; wherein the silsesquioxane polymer includes a three-dimensional network of Formula (I): wherein: each R 1 and R 2 is independently a (C1-C4)alkyl; each L 1 is independently a single bond, an alkylene, or an alkylene bonded to a group selected from oxy, thio, carbonyl, -NH-, and combinations thereof; each R 3 is independently a linear (C14-C100)alkyl; with the proviso that L 1 is selected such that each Si atom is directly bonded to an alkylene or an alkyl; m is an integer of at least 2; n is an integer of at least 1; m + n is an integer of at least 10; each oxygen atom at an asterisk (*) is bonded to another Si atom within the three-dimensional network; and the silsesquioxane polymer is a solid at 25°C.

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