公开(公告)号：US20170183448A1

公开(公告)日：2017-06-29

申请号：US15313253

申请日：2015-06-12

Applicant: 3M INNOVATIVE PROPERTIES COMPANY

Inventor： Yu Yang ,  Miguel A. Guerra ,  Suresh S. Iyer

IPC: C08G65/26 ,  C09D171/02 ,  C09D151/08 ,  C08F283/06

CPC classification number: C08G65/2639 ,  C08F2/02 ,  C08F30/08 ,  C08F230/08 ,  C08F283/002 ,  C08F283/06 ,  C08F2230/085 ,  C08G65/007 ,  C08G65/323 ,  C08G65/336 ,  C08G65/48 ,  C08G2261/12 ,  C09D5/1637 ,  C09D5/1668 ,  C09D143/04 ,  C09D151/08 ,  C09D171/02 ,  C08F230/02

Abstract: A silicon-containing polymer is represented by the general formula: (I) wherein A, Q, Z, x, and y are as defined in the specification, and I is iodine. Group Q includes a hydrolyzable silane group and group A is fluorinated. A method of making the silicon-containing polymer is also disclosed.

公开(公告)号：US20160376391A1

公开(公告)日：2016-12-29

申请号：US14901261

申请日：2014-06-06

Applicant: 3M INNOVATIVE PROPERTIES COMPANY

Inventor： Yu Yang ,  Suresh S. Iyer ,  Miguel A. Guerra ,  Kui Chen-Ho ,  Daniel R. Vitcak

IPC: C08F230/08 ,  C09D143/04

CPC classification number: C08F230/08 ,  C09D143/04 ,  C08F2230/085 ,  C08F214/182 ,  C08F220/36 ,  C08F2220/325 ,  C08F214/08 ,  C08F220/44 ,  C08F226/02 ,  C08F220/06 ,  C08F210/14 ,  C08F216/1416

Abstract: A moisture-curable composition includes a polymer preparable by free-radical copolymerization of monomers comprising at least one monomer A and at least one monomer B. Monomer(s) A comprise free-radically polymerizable hydrolyzable silane. Monomer(s) B include a divalent group selected from the group consisting of —(CF2O)a—, —(CF2CF2O)b—, —(CF2CF2CF2O)c—, —(CF2CF2CF2CF2O)d—, —(CF2CF(CF3)O)e—, and combinations thereof, wherein a, b, c, d, and e represent integers in the range of from 0 to 130, and wherein 1≦

Abstract translation: 可湿气固化的组合物包括通过使包含至少一种单体A和至少一种单体B的单体的自由基共聚制备的聚合物。单体A包含可自由基聚合的可水解硅烷。 单体B包括选自 - （CF 2 O）a - ， - （CF 2 CF 2 O）b - ， - （CF 2 CF 2 CF 2 CF 2 O）c - ， - （CF 2 CF 2 CF 2 CF 2 O）d - ， - （CF 2 CF（CF 3）O ）e-及其组合，其中a，b，c，d和e表示0至130的整数，并且其中1≤a+ b + c + d +e≤130。 复合制品包括在基底上的组合物层。 组合物包含包含可湿固化组合物的组分的交联反应产物。 还公开了制备复合制品的方法。

公开(公告)号：US20160318287A1

公开(公告)日：2016-11-03

申请号：US15105913

申请日：2014-12-16

Applicant: 3M INNOVATIVE PROPERTIES COMPANY

Inventor： Kui Chen-Ho ,  Caroline M. Ylitalo ,  Yu Yang ,  Yongshang Lu ,  Alan L. Levin ,  Hyacinth L. Lechuga ,  Steven H. Kong ,  Suresh I. Iyer ,  Ingrid N. Haugan ,  Mahfuza B. Ali

IPC: B32B27/08 ,  B32B7/02 ,  C09D133/10 ,  B32B27/30 ,  C09D7/12 ,  C09D143/04 ,  B32B37/14 ,  B32B27/28

CPC classification number: B32B27/08 ,  B32B1/00 ,  B32B7/02 ,  B32B27/28 ,  B32B27/308 ,  B32B27/365 ,  B32B37/14 ,  B32B2255/10 ,  B32B2255/20 ,  B32B2255/24 ,  B32B2255/28 ,  B32B2264/102 ,  B32B2307/554 ,  B32B2457/20 ,  B32B2551/00 ,  C08K3/22 ,  C09D7/61 ,  C09D127/12 ,  C09D133/10 ,  C09D143/04

Abstract: Described herein is composite article comprising a substrate; and on at least one face of the substrate a multilayered coating disposed thereon. The multilayered coating comprises (i) an abrasion-resistant layer adjacent to the substrate, wherein the abrasion-resistant layer comprises inorganic oxide nanoparticles and a polymer binder; and (ii) an antireflection layer adjacent to the abrasion-resistant layer opposite the substrate, wherein the antireflection layer comprises a fluorosilane polymer, wherein the fluorosilane polymer comprises: at least one monomeric unit A represented by the formula (I) wherein R1 represents H or methyl, L1 represents a covalent bond or a divalent aliphatic group having from 1 to 10 carbon atoms, each Y1 independently represents a hydrocarbyl group having from 1 to 6 carbon atoms, each Y2 independently represents a hydrolyzable group, g is 0, 1, or 2; and at least one divalent monomeric unit B represented by the formula (I) wherein R2, R3, and R4 represent H, methyl, trifluoromethyl, or F, wherein at least one of R2, R3, and R4 is F, Rf1 represents a covalent bond or a divalent group selected from the group consisting of —(CF2O)a—, —(CF2CF2O)b—, —(CF2CF2CF2O)c—, —(CF2CF2CF2CF2O)d—, —(CF2CF(CF3)O)e—, and combinations thereof, wherein a, b, c, d, and e represent integers in the range of from 0 to 130, and wherein 1≦a+b+c+d+e≦130, and Rf2 is a perfluoroalkyl group.

公开(公告)号：US09382441B2

公开(公告)日：2016-07-05

申请号：US14411199

申请日：2013-06-27

Applicant: 3M INNOVATIVE PROPERTIES COMPANY

Inventor： Xinyu Liang ,  Lifei Hao ,  Yu Yang ,  Minhao Song ,  KeFeng Xia

IPC: C09D133/02 ,  C03C17/30 ,  C09D133/08 ,  C09D183/08 ,  C08K3/16 ,  C08K5/09 ,  C08K5/092 ,  C08G77/24

CPC classification number: C09D133/02 ,  C03C17/30 ,  C03C2217/76 ,  C08G77/24 ,  C08K3/16 ,  C08K5/09 ,  C08K5/092 ,  C09D133/08 ,  C09D183/08 ,  C08L83/08

Abstract: The present disclosure provides a hydrophobic and oleophobic coating composition, which comprises the following components based on weight percentage: 0.1-15% of a fluorosiloxane, 1-30% of a polyacrylic resin, 0.1-15% of a silane coupler, 33-98% of an organic solvent, and 0.05-15% of an acid. By combining the polyacrylic resin and the fluorosiloxane which exhibits hydrophobic property, the present composition not only provides good hydrophobic property but also ensures durable hydrophobic property of the coating with the help of good adhesion of polyacrylic resin. The coating composition can form hard coating which has high glossiness and high transparency under relatively low temperatures and has a contact angle of 115-120°. This coating composition can be used on surfaces of substrates, such as automotive paints, metal, plastic and glass, and it can retain long lasting hydrophobic and oleophobic property even placed outdoors for several months, and it can also prevent the surface of the substrate from being scratched.

Abstract translation: 本公开内容提供疏水和疏油涂料组合物，其包含基于重量百分比的以下组分：0.1-15％的氟硅氧烷，1-30％的聚丙烯酸树脂，0.1-15％的硅烷偶联剂，33-98 ％的有机溶剂和0.05-15％的酸。 通过组合聚丙烯酸树脂和显示疏水性的氟硅氧烷，本发明的组合物不仅提供了良好的疏水性，而且借助于聚丙烯酸树脂的良好粘附性，确保了涂层的耐久的疏水性。 涂料组合物可以形成硬涂层，其在相对低的温度下具有高光泽度和高透明度，并具有115-120°的接触角。 该涂料组合物可以用于汽车涂料，金属，塑料和玻璃等基材的表面，并且可以保持长时间的疏水性和疏油性，甚至可以在室外放置数月，并且还可以防止基材的表面 被划伤

公开(公告)号：US20140329012A1

公开(公告)日：2014-11-06

申请号：US14368359

申请日：2012-12-28

Applicant: 3M INNOVATIVE PROPERTIES COMPANY

Inventor： David M. Mahli ,  Robert A. Yapel ,  Justin A. Riddle ,  Mitchell A.F. Johnson ,  Moses M. David ,  Frederick J. Gustafson ,  Lan H. Liu ,  Yu Yang ,  Naiyong Jing ,  Caleb T. Nelson

IPC: B43L1/00 ,  C09D183/04

CPC classification number: B43L1/002 ,  B43L1/00 ,  C09D183/04 ,  Y10T428/31663

Abstract: Cleanable articles having overcoats with hydrophilic front surfaces and which are siloxane-bonded to an underlying body member. Also, methods of making and using such articles.

Abstract translation: 具有具有亲水前表面的外涂层并且与硅氧烷键合到下面的主体构件上的可清洁制品。 另外，制作和使用这些物品的方法。

公开(公告)号：US20130264061A1

公开(公告)日：2013-10-10

申请号：US13996863

申请日：2011-12-21

Applicant: 3M INNOVATIVE PROPERTIES COMPANY

Inventor： Jimmie R. Baran, JR. ,  George G.I. Moore ,  Nathan E. Schultz ,  Dean M. Moren ,  Yu Yang ,  Rudolf J. Dams

IPC: C09K8/60 ,  E21B43/26

CPC classification number: C09K8/602 ,  C07C303/40 ,  C07C311/08 ,  C09K8/68 ,  C09K8/88 ,  E21B43/26

Abstract: A method of modifying a surface of a hydrocarbon-bearing formation is disclosed. The method includes contacting the surface of the hydrocarbon-bearing formation with a fluorinated amine, and the surface of the hydrocarbon-bearing formation includes a carbonate. The method can typically include introducing a treatment composition comprising solvent and at least one of the fluorinated amine or a salt thereof into the carbonate hydrocarbon-bearing formation. Hydrocarbon-bearing formations treated according to the method are also disclosed. Certain fluorinated amines useful for treating carbonate hydrocarbon-bearing formations and methods of making them are also disclosed.

Abstract translation: 公开了一种改变含烃地层表面的方法。 该方法包括使含烃地层的表面与氟化胺接触，并且含烃地层的表面包括碳酸盐。 该方法通常可以包括将包含溶剂和至少一种氟化胺或其盐的处理组合物引入含碳酸盐烃的地层中。 还公开了根据该方法处理的含烃地层。 还公开了可用于处理碳酸盐含烃地层的某些氟化胺及其制备方法。

公开(公告)号：US20220081556A1

公开(公告)日：2022-03-17

申请号：US17415934

申请日：2019-12-18

Applicant: 3M INNOVATIVE PROPERTIES COMPANY

Inventor： Yu Yang ,  Mark F. Schulz ,  Andrew D. Norlander ,  Ruijian Xu ,  Richard J. Pokorny

IPC: C08L67/06 ,  C08L31/04 ,  C08F222/10 ,  C08F220/28 ,  C08F283/01 ,  C08F290/06 ,  C08K5/14 ,  C08K5/18 ,  C08K5/098 ,  C08K3/34 ,  C09D5/34

Abstract: The composition includes a polyester resin comprising at least one α,β-unsaturated ester group, an acrylate or methacrylate, a vinyl ester represented by formula R—[C(O)—O—CH—CH2]n, wherein R is alkyl, aryl, or a combination thereof and n is 1 or 2, and a metal salt of a carboxylic acid. A method of repairing a damaged surface using the composition is also described.

公开(公告)号：US09994676B2

公开(公告)日：2018-06-12

申请号：US15313253

申请日：2015-06-12

Applicant: 3M INNOVATIVE PROPERTIES COMPANY

Inventor： Yu Yang ,  Miguel A. Guerra ,  Suresh S. Iyer

IPC: C07F9/02 ,  C08G65/26 ,  C08F283/06 ,  C09D171/02 ,  C09D151/08

CPC classification number: C08G65/2639 ,  C08F2/02 ,  C08F30/08 ,  C08F230/08 ,  C08F283/002 ,  C08F283/06 ,  C08F2230/085 ,  C08G65/007 ,  C08G65/323 ,  C08G65/336 ,  C08G65/48 ,  C08G2261/12 ,  C09D5/1637 ,  C09D5/1668 ,  C09D143/04 ,  C09D151/08 ,  C09D171/02 ,  C08F230/02

Abstract: A silicon-containing polymer is represented by the general formula: (I) wherein A, Q, Z, x, and y are as defined in the specification, and I is iodine. Group Q includes a hydrolyzable silane group and group A is fluorinated. A method of making the silicon-containing polymer is also disclosed.

公开(公告)号：US20180037767A1

公开(公告)日：2018-02-08

申请号：US15555128

申请日：2016-03-02

Applicant: 3M INNOVATIVE PROPERTIES COMPANY

Inventor： Yifan Zhang ,  Alexandra L. Sevenich ,  Lylien Tan ,  Yu Yang

IPC: C09D133/26 ,  C09D7/02 ,  C09D5/14 ,  C11D3/16 ,  C11D3/00 ,  C11D3/48 ,  C11D3/37 ,  C09D7/12 ,  C09D5/00

CPC classification number: C09D133/26 ,  C09D5/00 ,  C09D5/14 ,  C09D7/45 ,  C09D7/63 ,  C09D7/65 ,  C11D3/0036 ,  C11D3/162 ,  C11D3/3773 ,  C11D3/48

Abstract: Compositions include a water-soluble copolymer, a hydrophilic silane compound, and in some embodiments surfactant dispersed in a liquid phase. Methods of using the compositions to coat and optionally clean a substrate are also disclosed.

公开(公告)号：US20170355805A1

公开(公告)日：2017-12-14

申请号：US15532881

申请日：2015-12-08

Applicant: 3M INNOVATIVE PROPERTIES COMPANY

Inventor： Yu Yang ,  Jason M. Kehren ,  Yongshang Lu ,  Suresh S. Iyer ,  William M. Lamanna ,  Thomas P. Klun ,  Jeffrey A. Peterson

IPC: C08G18/08 ,  C08G18/44 ,  C07C229/30 ,  C07C307/06 ,  C08G18/75 ,  C08G18/32 ,  C08G18/38

CPC classification number: C08G18/0814 ,  C07C219/06 ,  C07C229/30 ,  C07C307/06 ,  C07C311/48 ,  C08G18/3206 ,  C08G18/3819 ,  C08G18/3861 ,  C08G18/4018 ,  C08G18/44 ,  C08G18/4833 ,  C08G18/758 ,  C08K5/0075 ,  C08K5/19 ,  C09D175/04 ,  D06M15/576

Abstract: An ionic diol has formula wherein R1 represents an alkyl group having from 6 to 18 carbon atoms; R2 and R3 independently represent alkyl groups having from 1 to 4 carbon atoms; R4 represents an alkylene group having from 2 to 8 carbon atoms; and R5 represents an alkylene group having from 1 to 8 carbon atoms. Antistatic polymers are formed by copolymerization of monomers including a diisocyanate, an ionic diol, a polyether diol, and at least one non-ionic diols. Methods of making the antistatic polyurethanes are also disclosed.