公开(公告)号：WO2017182211A1

公开(公告)日：2017-10-26

申请号：PCT/EP2017/056515

申请日：2017-03-20

Applicant: BASELL POLIOLEFINE ITALIA S.R.L.

Inventor： DE PALO, Roberto ,  CAVALIERI, Claudio

IPC: C08F210/06 ,  D01F6/30 ,  B33Y70/00

Abstract: A consumable filament for use in an extrusion-based additive manufacturing system comprising a propylene terpolymer containing ethylene and 1-butene or 1-hexene as comonomers having: -MFR L (Melt Flow Rate according to ISO 1133, condition L, i.e. 230°C and 2.16 kg load) ranging from 1 to 20 g/10 min; - xylene solubles measured at 25°C comprised between 3 wt% and 30 wt%.

Abstract translation: 用于基于挤出的添加剂制造系统的可消耗长丝，其包含含有乙烯和1-丁烯或1-己烯作为共聚单体的丙烯三元共聚物，其具有：-MFR L（根据ISO 1133的熔体流动速率 ，条件L，即230℃和2.16kg负载）范围为1至20g / 10min; - 在25℃下测量的二甲苯可溶物为3重量％至30重量％。

公开(公告)号：WO2017097579A1

公开(公告)日：2017-06-15

申请号：PCT/EP2016/078417

申请日：2016-11-22

Applicant: BASELL POLIOLEFINE ITALIA S.R.L.

Inventor： COVEZZI, Massimo ,  MASSARI, Paola ,  CAVALIERI, Claudio ,  MARZOLLA, Roberta

IPC: C08L23/12 ,  C08F110/06

CPC classification number: C08L23/12 ,  C08F210/06 ,  C08L2203/162 ,  C08L2205/02 ,  C08L2207/02 ,  C08L23/16 ,  C08F2/001 ,  C08F210/14 ,  C08F2500/12

Abstract: A propylene polymer composition comprising: a) from 40 wt% to 80 wt% of a propylene 1-hexene copolymer containing from 5.5 to 9.0% by weight, of 1-hexene derived units having a Melt Flow Rate (MFR, measured according to ASTM D 1238, 230°C/2.16 kg, i.e. at 230°C, with a load of 2.16 kg) from 3.5 to 12.0 g/10 min; b) from 20 wt% to 60 wt% of a propylene ethylene copolymer containing from 1.5 wt% to 6.5 wt% of ethylene derived units, a having a Melt Flow Rate (MFR, measured according to ASTM D 1238, 230°C/2.16 kg, i.e. at 230°C, with a load of 2.16 kg) from 3.5 to 12.0 g/10 min.

Abstract translation: 丙烯聚合物组合物，其包含：a）40重量％至80重量％的含5.5至9.0重量％的1-己烯衍生单元的丙烯1-己烯共聚物，所述单元具有熔体流动 速率（MFR，根据ASTM D 1238,230℃/ 2.16kg，即在230℃，2.16kg的负荷下测量）为3.5-12.0g / 10min; b）20重量％至60重量％的含有1.5重量％至6.5重量％的乙烯衍生单元的丙烯乙烯共聚物，其熔体流动速率（MFR，根据ASTM D 1238,230℃/ 2.16 kg，即在230℃，2.16kg的负载下）为3.5-12.0g / 10min。

公开(公告)号：WO2017021136A1

公开(公告)日：2017-02-09

申请号：PCT/EP2016/067141

申请日：2016-07-19

Applicant: BASELL POLIOLEFINE ITALIA S.R.L.

Inventor： MASSARI, Paola ,  PIEMONTESI, Fabrizio ,  VITALE, Gianni ,  CATHELIN, Caroline ,  MORINI, Giampiero ,  CAVALIERI, Claudio ,  CIARAFONI, Marco ,  PANTALEONI, Roberto

IPC: C08J5/18 ,  C08L23/14

CPC classification number: C08L23/142 ,  C08J5/18 ,  C08J2323/16 ,  C08J2423/16 ,  C08L23/14 ,  C08L2201/10 ,  C08L2203/162 ,  C08L2205/025 ,  C08F210/06 ,  C08F4/6574 ,  C08F4/6492 ,  C08F2/001 ,  C08F4/6465 ,  C08F210/16 ,  C08F2500/12 ,  C08F2500/26

Abstract: A polyolefin composition comprising: A) from 19 wt% to 50 wt% of a propylene ethylene copolymer having an ethylene derived units content ranging from 1.5 wt% to 6.0 wt% B) from 50 wt% to 81 wt% of a propylene ethylene 1-butene terpolymer having an ethylene derived units content ranging from 1.5 wt% and 6.0 wt% and 1-butene derived units content of between 4.8 wt% and 12.4 wt%; the sum of the amount of component A) and B) being 100; the composition being characterized by the following features: - molecular weight distribution (MWD), expressed in terms of Mw/Mn, greater than 4.0; - the creep and recovery curve measured on the polymer fuse at 200°C measured accordingto the procedure reported in the characterizing section shows a maximum value between 600 and 200 seconds lower than 53x10 -4 1/Pa.

Abstract translation: 一种聚烯烃组合物，其包含：A）19重量％至50重量％的乙烯衍生单元含量范围为1.5重量％至6.0重量％的丙烯乙烯共聚物B）50重量％至81重量％的丙烯乙烯1 乙烯衍生单元含量为1.5重量％至6.0重量％，1-丁烯衍生单元含量为4.8重量％至12.4重量％的丁烯三元共聚物; 组分A）和B）的量的总和为100; 该组合物的特征在于以下特征： - 以Mw / Mn表示的分子量分布（MWD）大于4.0; - 根据在特征部分中报道的程序测量的在200℃下聚合物保险丝上测得的蠕变和恢复曲线显示出低于53×10 -4 1 / Pa的600至200秒的最大值。

公开(公告)号：WO2016207235A1

公开(公告)日：2016-12-29

申请号：PCT/EP2016/064450

申请日：2016-06-22

Applicant: BASELL POLIOLEFINE ITALIA S.R.L.

Inventor： CAVALIERI, Claudio ,  GRAZZI, Michele ,  PANTALEONI, Roberto

IPC: C08L23/12 ,  C08L23/16

CPC classification number: C08L23/16 ,  C08F210/16 ,  C08L23/12 ,  C08L2205/02 ,  C08L2205/025 ,  C08L2205/03 ,  C08L2205/035 ,  C08L2308/00 ,  C08L2310/00 ,  C08L2314/02 ,  C08L23/06 ,  C08F110/06 ,  C08F4/6492 ,  C08F2/001 ,  C08F210/06 ,  C08F2500/08 ,  C08F2500/12 ,  C08F2500/17

Abstract: Polyolefin compositions comprising: (A) 5-35% by weight of a propylene-based polymer containing 90% by weight or more of propylene units and containing 10% by weight or less of a fraction soluble in xylene at 25°C (XS A ); (B) 25-50% by weight, of an ethylene homopolymer containing 5% by weight or less of a fraction soluble in xylene at 25°C (XS B ) referred to the weight of (B); and (C) 30-60% by weight, of a copolymer of ethylene and propylene containing from 25% to 75% by weight of ethylene units and containing from 55% to 95% by weight, of a fraction soluble in xylene at 25°C (XS C ). The composition has 20% by weight or less of a fraction obtained in the second fractionation step in a preparative fractionation method.

Abstract translation: 聚烯烃组合物，其包含：（A）5-35重量％的含有90重量％以上丙烯单元并含有10重量％以下的在25℃下可溶于二甲苯的馏分（XSA）的丙烯类聚合物， ; （B）25-50重量％的以25重量％（XSB）表示的可溶于二甲苯的馏分的5重量％以下的乙烯均聚物（B）的重量; 和（C）30-60重量％的乙烯和丙烯的共聚物，其含有25重量％至75重量％的乙烯单元，并且含有55重量％至95重量％的在25℃下可溶于二甲苯的馏分 C（XSC）。 该组合物在制备分馏方法中，在第二分馏步骤中得到的馏分的重量比为20重量％以下。

公开(公告)号：WO2010072841A1

公开(公告)日：2010-07-01

申请号：PCT/EP2009/067925

申请日：2009-12-24

Applicant: BASELL POLIOLEFINE ITALIA S.R.L. ,  CAVALIERI, Claudio ,  GALVAN, Monica ,  BECCARINI, Enrico

Inventor： CAVALIERI, Claudio ,  GALVAN, Monica ,  BECCARINI, Enrico

IPC: B29C47/00 ,  C08L23/14

CPC classification number: C08L23/14 ,  B29C47/0004 ,  B29C47/0023 ,  B29K2023/06 ,  B29K2023/12 ,  C08L23/0815 ,  C08L23/142 ,  C08L23/16 ,  C08L2203/18 ,  C08L2207/02 ,  C08L2666/06

Abstract: Articles, particularly pressure pipes, having high strength as well as high stiffness and very good impact resistance even at low temperatures can be obtained by using a heterophasic polyolefϊn composition comprising (percent by weight) 70-90% of a random copolymer of propylene with 0.5-6% of 1-hexene, and 10-30% of a polymer of ethylene with a C 3 -C 10 α- olefϊn and optionally a diene, wherein the polymer of ethylene has an ethylene content higher than 45% and an intrinsic viscosity [η] value from 3 to 5 dl/g. A particular advantage of the present invention is that articles comprising the above heterophasic polyolefϊn composition show a low ductile to brittle transition temperature (DBTT).

Abstract translation: 可以通过使用包含（重量％）70-90％的丙烯无规共聚物的异相聚烯烃组合物来获得具有高强度以及高刚度以及高耐冲击性的制品，特别是压力管， 具有0.5-6％的1-己烯和10-30％的乙烯与C 3 -C 10α-烯烃和任选的二烯的聚合物，其中乙烯的聚合物具有高于45％的乙烯含量和 特性粘度[η]值为3〜5dl / g。 本发明的一个特别的优点是包含上述多相聚烯烃组合物的制品显示出较低的延性至脆性转变温度（DBTT）。

公开(公告)号：WO2009077293A1

公开(公告)日：2009-06-25

申请号：PCT/EP2008/066103

申请日：2008-11-25

Applicant: BASELL POLIOLEFINE ITALIA S.R.L. ,  CAVALIERI, Claudio ,  GALVAN, Monica

Inventor： CAVALIERI, Claudio ,  GALVAN, Monica

IPC: C08L23/10

CPC classification number: C08L23/10 ,  C08K5/005 ,  C08K5/0083 ,  C08K5/14 ,  C08L23/20 ,  C08L23/22 ,  Y10T428/1352 ,  C08L2666/06 ,  C08L2666/08

Abstract: A polyolefin composition having good transparency and mechanical properties comprising, all percent amounts being by weight: A) from 70 to 98% of a propylene homopolymer or copolymer having haze of 25% or less and melting temperature of 130°C or higher; and B) from 2 to 30% of a butene-1 copolymer containing from 0.5 to 30% of one or more comonomer(s).

Abstract translation: 具有良好的透明性和机械性能的聚烯烃组合物，其全部百分数为重量百分比：A）70-98％的雾度为25％或更低，熔点为130℃或更高的丙烯均聚物或共聚物; 和B）2至30％的含有0.5至30％的一种或多种共聚单体的丁烯-1共聚物。

公开(公告)号：WO2008142019A1

公开(公告)日：2008-11-27

申请号：PCT/EP2008/056042

申请日：2008-05-16

Applicant: BASELL POLIOLEFINE ITALIA S.R.L. ,  CAGNANI, Camillo ,  BECCARINI, Enrico ,  CAVALIERI, Claudio

Inventor： CAGNANI, Camillo ,  BECCARINI, Enrico ,  CAVALIERI, Claudio

IPC: C08F210/06

CPC classification number: C08F210/06 ,  C08F210/16 ,  C08F2500/11 ,  C08F2500/20

Abstract: A propylene polymer composition having a Flexural modulus lower than 500MPa, a total ethylene content from 9 to 30% by weight, a xylene soluble fraction at room temperature higher than 25% by weight, a melting temperature measured by DSC (Tm°C) from 130 to 150°C and a ratio between the weight of xylene soluble fraction at 25°C and the hexane soluble fraction determined on plaque (100μm) of higher than 4.

Abstract translation: 弯曲模量低于500MPa，总乙烯含量为9〜30重量％，室温下二甲苯可溶成分高于25重量％的丙烯聚合物组合物，DSC测定的熔融温度（Tm℃） 130℃〜150℃，二甲苯可溶成分在25℃下的重量与在斑块（100μm）上测定的己烷可溶成分之比高于4。

公开(公告)号：WO2006114357A1

公开(公告)日：2006-11-02

申请号：PCT/EP2006/060976

申请日：2006-03-23

Applicant: BASELL POLIOLEFINE ITALIA S.R.L. ,  CAGNANI, Camillo ,  CAVALIERI, Claudio ,  MARZOLLA, Roberta

Inventor： CAGNANI, Camillo ,  CAVALIERI, Claudio ,  MARZOLLA, Roberta

IPC: C08F297/08 ,  C08L23/14 ,  C08F2/34 ,  C08F2/00 ,  C08F210/06

CPC classification number: C08F297/08 ,  C08F210/06 ,  C08F297/083 ,  C08L23/14 ,  C08L23/142 ,  C08L2205/02 ,  C08L2205/025 ,  C08F2/001 ,  C08F2/34 ,  C08L2666/06 ,  C08F210/16 ,  C08F2500/12

Abstract: A propylene polymer composition comprising (weight percentages being referred to the sum of A+B): A propylene polymer composition comprising (weight percentages being referred to the sum of A+B): (A) 60-90% by weight of a copolymer of propylene with ethylene containing less than 2.5%wt of ethylene units; and (B) 10-40% by weight of a copolymer of propylene comprising from 15 to 35%wt of ethylene units, said polymer composition having a melt flow rate value according to ISO 1133 (230°C, 2.16 Kg) of less than 10 g/10min.

Abstract translation: 丙烯聚合物组合物，其包含（重量百分比指A + B之和）：丙烯聚合物组合物，其包含（重量百分比指A + B之和）：（A）60-90重量％的共聚物 的丙烯与含有小于2.5重量％乙烯单元的乙烯; 和（B）10-40重量％的包含15至35重量％乙烯单元的丙烯共聚物，所述聚合物组合物具有根据ISO 1133（230℃，2.16Kg）的熔体流动速率值小于 10g / 10min。

公开(公告)号：WO2022090105A1

公开(公告)日：2022-05-05

申请号：PCT/EP2021/079447

申请日：2021-10-25

Applicant: BASELL POLIOLEFINE ITALIA S.R.L.

Inventor： CAVALIERI, Claudio ,  TREOSSI, Mauro ,  CONSALVI, Marco

IPC: C08L23/10 ,  C08L23/14 ,  C08L23/04 ,  C08L53/00

Abstract: The present disclosure relates to polyolefin compositions, in particular polypropylene compositions containing (a) recycled polypropylene, (b) recycled polyethylene (c) a polyolefin elastomer (POE) and (d) a specific polypropylene heterophasic composition that can be used in injection molded articles. The polyolefin compositions according to the present disclosure find application in automotive field, and houseware such as suitcase and containers.

公开(公告)号：WO2022017758A1

公开(公告)日：2022-01-27

申请号：PCT/EP2021/068172

申请日：2021-07-01

Applicant: BASELL POLIOLEFINE ITALIA S.R.L.

Inventor： GRAZZI, Michele ,  CAVALIERI, Claudio

IPC: B32B27/08 ,  B32B27/32 ,  B32B5/02 ,  C08J5/18 ,  C08L23/16 ,  E04D5/10

Abstract: A soft polyolefin composition comprising for producing sheets or membranes, the polyolefin composition comprising: (A) 18-35% by weight of a copolymer of propylene with at least one alpha-olefin, wherein the copolymer contains 2.0-4.0% by weight of alpha-olefin, the amount of alpha-olefin is based on the weight of (A) and has melt flow rate (MFRA) ranging from 30 to 60 g/10min; and (B) 65-82% by weight of a copolymer of propylene with at least one alpha-olefin, and optionally a diene, the copolymer comprising 20-35% by weight of alpha-olefin, the amount of alpha olefin being based on the weight of (B), wherein - the polyolefin composition comprises a fraction that is soluble in xylene at 25°C (XS(tot)) in an amount higher than 70% by weight; - the amounts of (A), (B) and of the fraction soluble in xylene at 25°C (XS(tot)) are based on the total weight of the polyolefin composition; and - the melt flow rate (MFR) of the polyolefin composition ranges from 0.2 to 2.0 g/10 min.