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    PROPYLENE BASED POLYMER COMPOSITION
    1.
    发明申请
    PROPYLENE BASED POLYMER COMPOSITION 审中-公开
    丙烯基聚合物组合物

    公开(公告)号：WO2017097579A1

    公开(公告)日：2017-06-15

    申请号：PCT/EP2016/078417

    申请日：2016-11-22

    Applicant: BASELL POLIOLEFINE ITALIA S.R.L.

    Inventor： COVEZZI, Massimo ,  MASSARI, Paola ,  CAVALIERI, Claudio ,  MARZOLLA, Roberta

    IPC: C08L23/12 ,  C08F110/06

    CPC classification number: C08L23/12 ,  C08F210/06 ,  C08L2203/162 ,  C08L2205/02 ,  C08L2207/02 ,  C08L23/16 ,  C08F2/001 ,  C08F210/14 ,  C08F2500/12

    Abstract: A propylene polymer composition comprising: a) from 40 wt% to 80 wt% of a propylene 1-hexene copolymer containing from 5.5 to 9.0% by weight, of 1-hexene derived units having a Melt Flow Rate (MFR, measured according to ASTM D 1238, 230°C/2.16 kg, i.e. at 230°C, with a load of 2.16 kg) from 3.5 to 12.0 g/10 min; b) from 20 wt% to 60 wt% of a propylene ethylene copolymer containing from 1.5 wt% to 6.5 wt% of ethylene derived units, a having a Melt Flow Rate (MFR, measured according to ASTM D 1238, 230°C/2.16 kg, i.e. at 230°C, with a load of 2.16 kg) from 3.5 to 12.0 g/10 min.

    Abstract translation: 丙烯聚合物组合物，其包含：a）40重量％至80重量％的含5.5至9.0重量％的1-己烯衍生单元的丙烯1-己烯共聚物，所述单元具有熔体流动 速率（MFR，根据ASTM D 1238,230℃/ 2.16kg，即在230℃，2.16kg的负荷下测量）为3.5-12.0g / 10min; b）20重量％至60重量％的含有1.5重量％至6.5重量％的乙烯衍生单元的丙烯乙烯共聚物，其熔体流动速率（MFR，根据ASTM D 1238,230℃/ 2.16 kg，即在230℃，2.16kg的负载下）为3.5-12.0g / 10min。

    GAS-PHASE PROCESS FOR THE POLYMERIZATION OF PROPYLENE
    2.
    发明申请
    GAS-PHASE PROCESS FOR THE POLYMERIZATION OF PROPYLENE 审中-公开
    丙烯聚合的气相工艺

    公开(公告)号：WO2017021454A1

    公开(公告)日：2017-02-09

    申请号：PCT/EP2016/068555

    申请日：2016-08-03

    Applicant: BASELL POLIOLEFINE ITALIA S.R.L.

    Inventor： MORINI, Giampiero ,  COVEZZI, Massimo ,  DALL'OCCO, Tiziano ,  LIGUORI, Dario ,  PIEMONTESI, Fabrizio ,  VITALE, Gianni

    IPC: C08F2/34 ,  C08F110/06 ,  C08F4/651 ,  C08F4/649

    CPC classification number: C08F110/06 ,  C08F4/651 ,  C08F4/6543 ,  C08F2/34 ,  C08F2500/15 ,  C08F2500/18 ,  C08F2500/12 ,  C08F110/02 ,  C08F4/6492

    Abstract: A gas-phase process for the homo or copolymerization of propylene with other olefins, carried out in the presence of a catalyst system comprising: (a) a solid catalyst component comprising Mg, Ti, halogen, an electron donor selected from 1.3-diethers and an olefin polymer in a specific amount; (b) an aluminum alkyl compound and (c) an external electron donor compound selected from specific classes; said components (a) and (c) being employed in amounts such that the Al/(ED) molar ratio ranges from 2 to 200. The process is capable to give polypropylene product having good morphological properties, high stereoregularity, and capable to show self- extinguishing properties such that the negative effects caused by the fine catalyst particle polymerization can be selectively solved or mitigated.

    Abstract translation: 丙烯与其它烯烃同时或共聚的气相方法，在催化剂体系存在下进行，该催化剂体系包含：（a）包含Mg，Ti，卤素的固体催化剂组分，选自1,3-二醚的电子给体和 特定量的烯烃聚合物; （b）烷基铝化合物和（c）选自特定类别的外部电子给体化合物; 所述组分（a）和（c）的用量使得Al /（ED）的摩尔比范围为2-200。该方法能够得到具有良好形态特性，高立构规整性并能显示自身的聚丙烯产物 - 可以选择性地解决或减轻由催化剂微粒聚合引起的负面影响的灭火性能。

    PROCESS FOR THE PREPARATION OF ETHYLENE POLYMERS
    4.
    发明申请
    PROCESS FOR THE PREPARATION OF ETHYLENE POLYMERS 审中-公开
    制备乙烯聚合物的方法

    公开(公告)号：WO2014108283A1

    公开(公告)日：2014-07-17

    申请号：PCT/EP2013/077051

    申请日：2013-12-18

    Applicant: BASELL POLIOLEFINE ITALIA S.R.L.

    Inventor： COVEZZI, Massimo ,  MEI, Gabriele ,  Baita, Pietro ,  Marturano, Lorella

    IPC: C08F10/02 ,  C08F2/00 ,  C08F4/64

    CPC classification number: C08F10/02 ,  C08F2/005 ,  C08F2410/02 ,  C08F110/02 ,  C08F2500/12 ,  C08F2500/18 ,  C08F2500/24

    Abstract: A process for the preparation of ethylene polymers comprising polymerizing ethylene, optionally with one or more α-olefin comonomers, in the presence of: (i) a solid catalyst component comprising titanium, magnesium, halogen and optionally an internal electron-donor compound, (ii) an aluminum alkyl compound, and (iii) an antistatic compound selected among the hydroxyesters with at least two free hydroxyl groups, wherein the weight ratio of aluminum alkyl compound to solid catalyst component is higher than 0.80 and the weight ratio of antistatic compound to aluminum alkyl compound is higher than 0.10.

    Abstract translation: 一种用于制备乙烯聚合物的方法，包括在以下存在下聚合乙烯，任选与一种或多种α-烯烃共聚单体：（i）包含钛，镁，卤素和任选的内电子给体化合物的固体催化剂组分（ ii）铝烷基化合物，和（iii）选自具有至少两个游离羟基的羟基酯中​​的抗静电化合物，其中烷基铝化合物与固体催化剂组分的重量比高于0.80，抗静电化合物与 铝烷基化合物高于0.10。

    GAS-PHASE PROCESS FOR PREPARING HETEROPHASIC PROPYLENE COPOLYMERS
    5.
    发明申请
    GAS-PHASE PROCESS FOR PREPARING HETEROPHASIC PROPYLENE COPOLYMERS 审中-公开
    制备亲水性丙烯共聚物的气相法

    公开(公告)号：WO2008015113A2

    公开(公告)日：2008-02-07

    申请号：PCT/EP2007/057539

    申请日：2007-07-20

    Applicant: BASELL POLIOLEFINE ITALIA S.R.L.

    Inventor： GOVONI, Gabriele ,  COVEZZI, Massimo ,  PENZO, Giuseppe ,  CIARROCCHI, Antonio ,  DE LUCIA, Antonio

    IPC: C08F210/06

    CPC classification number: C08F297/08 ,  C08F210/06 ,  C08F297/083 ,  C08L23/10 ,  C08L23/142 ,  C08L2205/02 ,  C08L2205/025 ,  C08L2207/02 ,  C08L2308/00 ,  C08F2/001 ,  C08F2/34 ,  C08L2666/02 ,  C08L2666/06 ,  C08F210/16 ,  C08F2500/18 ,  C08F2500/17 ,  C08F2500/26

    Abstract: A polymerization process for preparing heterophasic propylene copolymers in two or more gas-phase reactors connected in series, in the presence of a polymerization catalyst comprising a catalytic component based on a titanium compound supported on magnesium halide, the process comprising the following steps: - contacting said catalytic component with an organo-Aluminum compound at a temperature from 5°C to 30°C and a weight ratio propylene/(catalytic component) ranging from 0 to 2.0; - prepolymerizing the catalyst from A) with propylene, optionally in the presence of an inert hydrocarbon solvent; - polymerizing propylene, optionally with an another -olefin comonomer in an amount lower than 15% by weight, to prepare a semicrystalline polymer component; - successively copolymerizing two or more alpha-olefin comonomers C 2 -C 10 to prepare one or more olefin copolymers having a solubility in xylene higher than 15% by weight; the process being characterized in that the bulk density of the semi-crystalline component of step C) is adjusted at a value lower than 0.40 g/cm 3 .

    Abstract translation: 在包含基于负载在卤化镁上的钛化合物的催化组分的聚合催化剂存在下，在两个或更多个串联连接的气相反应器中制备多相丙烯共聚物的聚合方法， 所述方法包括以下步骤： - 使所述催化组分与有机铝化合物在5℃至30℃的温度下接触，丙烯/（催化组分）的重量比为0至2.0; - 任选在惰性烃溶剂存在下，使来自A）的催化剂与丙烯预聚合; - 使丙烯，任选与低于15重量％的另一种α-烯烃共聚单体聚合，以制备半结晶聚合物组分; - 连续共聚两种或更多种α-烯烃共聚单体C 2 -C 10以制备一种或多种在二甲苯中的溶解度高于15重量％的烯烃共聚物; 该方法的特征在于，将步骤C）的半晶体组分的体积密度调节为低于0.40g / cm 3的值。

    PROCESS FOR THE POLYMERIZATION OF OLEFINS
    7.
    发明申请
    PROCESS FOR THE POLYMERIZATION OF OLEFINS 审中-公开
    烯烃聚合的方法

    公开(公告)号：WO2018083161A1

    公开(公告)日：2018-05-11

    申请号：PCT/EP2017/078033

    申请日：2017-11-02

    Applicant: BASELL POLIOLEFINE ITALIA S.R.L.

    Inventor： BAITA, Pietro ,  COVEZZI, Massimo ,  DI DIEGO, Maria ,  MARTURANO, Lorella ,  MAZZUCCO, Antonio ,  MEI, Gabriele ,  PICA, Roberta

    IPC: C08F110/02 ,  C08F2/34 ,  C08F4/654 ,  C08F4/649

    Abstract: A gas-phase process for the homo or copolymerization of olefins carried out in the presence of a catalyst system formed by a contacting in a liquid hydrocarbon and in the presence of hydrogen (a) a solid catalyst component comprising a Ti, Mg and C1, and optionally an internal electron donor compound, (b) an aluminum alkyl compound and optionally (c) an external donor compound.

    Abstract translation: 在催化剂体系存在下进行烯烃的均相或共聚的气相方法，所述催化剂体系通过在液态烃中和在氢存在下接触而形成（a）固体催化剂组分 （b）烷基铝化合物和任选的（c）外部给体化合物，其中所述化合物包含Ti，Mg和C1以及任选的内部电子给体化合物。

    PROCESS FOR THE GAS-PHASE POLYMERIZATION OF OLEFINS
    8.
    发明申请
    PROCESS FOR THE GAS-PHASE POLYMERIZATION OF OLEFINS 审中-公开
    油相的气相聚合方法

    公开(公告)号：WO2006040240A1

    公开(公告)日：2006-04-20

    申请号：PCT/EP2005/054645

    申请日：2005-09-19

    Applicant: Basell Poliolefine Italia s.r.l. ,  MEI, Gabriele ,  COVEZZI, Massimo ,  BERTOLINI, Stefano

    Inventor： MEI, Gabriele ,  COVEZZI, Massimo ,  BERTOLINI, Stefano

    IPC: C08F10/00 ,  C08F2/34 ,  C08F2/01

    CPC classification number: C08F10/00 ,  C08F110/06 ,  C08F210/06 ,  Y10S526/904 ,  Y10S526/919 ,  C08F2/01 ,  C08F4/651 ,  C08F4/6492 ,  C08F2/001 ,  C08F2/34 ,  C08F2500/24 ,  C08F210/16

    Abstract: Process for the gas-phase polymerization of one or more alpha-olefins in the presence of a catalyst system, the process comprising: contacting in a continuous way one or more of said alpha-olefins with said catalyst system in a prepolymerization reactor, wherein the reaction is carried out in a liquid medium at a temperature ranging from 23° to 500C; feeding in continuous the prepolymer obtained in step a) into a gas-phase reactor having interconnected polymerization zones, where the growing polymer particles flow upward through a first polymerization zone (riser) under fast fluidization or transport conditions, leave said riser and enter a second polymerization zone (downcomer) through which they flow downward under the action of gravity, leave said downcomer and are reintroduced into said riser; wherein the prepolymer obtained from step a) is continuously fed at a section of said riser characterized by an upwardly gas velocity higher than 3.0 m/s.

    Abstract translation: 在催化剂体系存在下，一种或多种α-烯烃的气相聚合方法，该方法包括：在预聚合反应器中以连续方式使一种或多种所述α-烯烃与所述催化剂体系接触，其中 反应在液体介质中在23℃至50℃的温度下进行; 在步骤a）中获得的预聚物连续进料到具有互连聚合区的气相反应器中，其中生长的聚合物颗粒在快速流化或运输条件下通过第一聚合区（提升管）向上流动，离开所述提升管并进入第二个 聚合区（降液管）通过它们在重力作用下向下流动，离开所述降液管并重新引入所述提升管中; 其中从步骤a）获得的预聚物在所述提升管的部分连续进料，其特征在于高于3.0m / s的向上气体速度。

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