POLYMER MIXTURE HAVING IMPROVED RHEOLOGICAL PROPERTIES AND IMPROVED SHRINKING BEHAVIOUR

    公开(公告)号:BG108522A

    公开(公告)日:2004-12-30

    申请号:BG10852204

    申请日:2004-01-12

    Applicant: BASF AG

    Abstract: The thermoplastic mixture contains m polymers Pn, m representing a natural number higher than 1, and n is a natural number bigger than 1, and n is a natural number from 1 to m, and each of the polymers has: a) one or more functional groups with structure -(R1)x-C(O)-(R2)y- found as a recurring unit in the polymer chain of Pn, wherein x and y represent 0 or 1 and x + y = 1, R1 and R2 independent ly represent oxygen or nitrogen linked in the main polymer chain; b) numerical value - mean molecular weight Mn(Pn); c) average molecular weight Mw(Pn); d) z average molecular weight Mz(Pn); e) a heterogeneity index Mw(Pn)/Mn(Pn); and f) molecular weight Mp(Pn) and polymers Pn differ for each other by 1, 2, 3, 4, 5 and 6 of the properties of a), b), c), d), e) and f), and wherein the polymer mixturehas numerical value - mean molecular weight Mn(P)1, weight average molecular weight Mw(P)1, z - a weight average molecular weight Mz(P)1, heterogeneity index Mw(P)1/Mn(P)1 and molecular weight Mp(P)1, and after ageing of the polymer mixture at its melting point, it has numerical value - average molecular weight Mn(P)2, weight average molecular weight Mw(P)2, z - mean molecular weight Mz(P)2, heterogeneity index Mw(P)2, and molecular weight Mp(P)2 and these values Mn(P)2, Mw(P)2/Mn(P), Mz(P)2, Mw(P)2/Mn(P)2 lie within the triple replication standard deviation sigma (r) in relation to Mn(P)1, Mw(P)1, Mz(P)1, Mw(P)1/Mn(P)1 and Mp(P)1.

    12.
    发明专利
    未知

    公开(公告)号:CZ20033513A3

    公开(公告)日:2004-05-12

    申请号:CZ20033513

    申请日:2002-06-13

    Applicant: BASF AG

    Abstract: A thermoplastic polymer mixture comprising m polymers Pn, where m is a natural number greater than 1 and n is a natural number from 1 to m, where n is a natural number from 1 to m, where each of the polymers has one or more functional groups of the structure -(R )x-C(O)-(R )y- present as repeat units in the main chain of polymer Pn where x and y, independently of one another, are 0 or 1, and x+y=1 R and R , independently of one another, are oxygen or nitrogen bonded into the main polymer chain, where in the differential distribution curve W(M) determined to DIN 55672-2 in hexafluoroisopropanol as eluent the polymer mixture has at least two maxima of the relative frequency W, and after aging of the polymer mixture at the melting point of the polymer mixture determined to ISO 11357-1 and 11357-3 for 5 minutes, the polymer mixture has in the differential distribution curve W(M) determined to DIN 55672-2 in hexafluoroisopropanol as eluent at least 2 maxima of the relative frequency W, and the position of the maxima here after aging of the polymer mixture at the melting point of the polymer mixture is within three times the recurrent standard deviation sigma(r) of MP in percentage of the value measured to DIN 55672-2, based on the position of the maxima prior to aging of the polymer mixture at the melting point of the polymer mixture.

    Polymer mixture having improved rheological properties and improved shrinking behaviour

    公开(公告)号:SK15472003A3

    公开(公告)日:2004-04-06

    申请号:SK15472003

    申请日:2002-06-14

    Applicant: BASF AG

    Abstract: The invention relates to a thermoplastic polymer mixture containing m, m representing a natural number higher than 1, polymers Pn wherein n represents a natural number between 1 and m, and at least one recurring functional group contained in the Pn polymer chain, said group(s) having the structure -(R )x-C(O)-(R )y- wherein x and y independently represent 0 or 1, and x+y=1, and R , R independently represent oxygen or nitrogen linked into the main polymer chain. The polymers Pn differ in terms of at least one characteristic related to molecular weight. The polymer mixture has a number average molecular weight Mn(P)1, a weight average molecular weight Mw(P)1, a Z average molecular weight Mz(P)1, a heterogeneity index Mw(P)1/Mn(P)1, and a molecular weight Mp(P)1 defined according to DIN 55672-2 in hexafluoroisopropanol as an elution agent. After maintaining the polymer mixture at the melting point of the same, defined according to ISO 11357-1 and 11357-3, for five minutes, the polymer mixture has a number average molecular weight Mn(P)2, a weight average molecular weight Mw(P)2, a Z average molecular weight Mz(P)2, a heterogeneity index Mw(P)2/Mn(P)2, and a molecular weight Mp(P)2 defined according to DIN 55672-2 in hexafluoroisopropanol as an elution agent. The values Mn(P)2, Mw(P)2, Mz(P)2, Mw(P)2/Mn(P)2 and Mp(P)2 lie within the triple replication standard deviation sigma (r) in relation to Mn(P)1, Mw(P)1, Mz(P)1, Mw(P)1/Mn(P)1 and Mp(P

    MULTIMODAL POLYAMIDES, POLYESTERS AND POLYESTER AMIDES

    公开(公告)号:PL375040A1

    公开(公告)日:2005-11-14

    申请号:PL37504002

    申请日:2002-06-13

    Applicant: BASF AG

    Abstract: A thermoplastic polymer mixture comprising m polymers Pn, where m is a natural number greater than 1 and n is a natural number from 1 to m, where n is a natural number from 1 to m, where each of the polymers has one or more functional groups of the structure -(R )x-C(O)-(R )y- present as repeat units in the main chain of polymer Pn where x and y, independently of one another, are 0 or 1, and x+y=1 R and R , independently of one another, are oxygen or nitrogen bonded into the main polymer chain, where in the differential distribution curve W(M) determined to DIN 55672-2 in hexafluoroisopropanol as eluent the polymer mixture has at least two maxima of the relative frequency W, and after aging of the polymer mixture at the melting point of the polymer mixture determined to ISO 11357-1 and 11357-3 for 5 minutes, the polymer mixture has in the differential distribution curve W(M) determined to DIN 55672-2 in hexafluoroisopropanol as eluent at least 2 maxima of the relative frequency W, and the position of the maxima here after aging of the polymer mixture at the melting point of the polymer mixture is within three times the recurrent standard deviation sigma(r) of MP in percentage of the value measured to DIN 55672-2, based on the position of the maxima prior to aging of the polymer mixture at the melting point of the polymer mixture.

    17.
    发明专利
    未知

    公开(公告)号:BR0210567A

    公开(公告)日:2004-06-08

    申请号:BR0210567

    申请日:2002-06-14

    Applicant: BASF AG

    Abstract: The invention relates to a thermoplastic polymer mixture containing m, m representing a natural number higher than 1, polymers Pn wherein n represents a natural number between 1 and m, and at least one recurring functional group contained in the Pn polymer chain, said group(s) having the structure -(R )x-C(O)-(R )y- wherein x and y independently represent 0 or 1, and x+y=1, and R , R independently represent oxygen or nitrogen linked into the main polymer chain. The polymers Pn differ in terms of at least one characteristic related to molecular weight. The polymer mixture has a number average molecular weight Mn(P)1, a weight average molecular weight Mw(P)1, a Z average molecular weight Mz(P)1, a heterogeneity index Mw(P)1/Mn(P)1, and a molecular weight Mp(P)1 defined according to DIN 55672-2 in hexafluoroisopropanol as an elution agent. After maintaining the polymer mixture at the melting point of the same, defined according to ISO 11357-1 and 11357-3, for five minutes, the polymer mixture has a number average molecular weight Mn(P)2, a weight average molecular weight Mw(P)2, a Z average molecular weight Mz(P)2, a heterogeneity index Mw(P)2/Mn(P)2, and a molecular weight Mp(P)2 defined according to DIN 55672-2 in hexafluoroisopropanol as an elution agent. The values Mn(P)2, Mw(P)2, Mz(P)2, Mw(P)2/Mn(P)2 and Mp(P)2 lie within the triple replication standard deviation sigma (r) in relation to Mn(P)1, Mw(P)1, Mz(P)1, Mw(P)1/Mn(P)1 and Mp(P

    Multimodal polyamides, polyesters and polyester amides

    公开(公告)号:SK15482003A3

    公开(公告)日:2004-04-06

    申请号:SK15482003

    申请日:2002-06-13

    Applicant: BASF AG

    Abstract: A thermoplastic polymer mixture comprising m polymers Pn, where m is a natural number greater than 1 and n is a natural number from 1 to m, where n is a natural number from 1 to m, where each of the polymers has one or more functional groups of the structure -(R )x-C(O)-(R )y- present as repeat units in the main chain of polymer Pn where x and y, independently of one another, are 0 or 1, and x+y=1 R and R , independently of one another, are oxygen or nitrogen bonded into the main polymer chain, where in the differential distribution curve W(M) determined to DIN 55672-2 in hexafluoroisopropanol as eluent the polymer mixture has at least two maxima of the relative frequency W, and after aging of the polymer mixture at the melting point of the polymer mixture determined to ISO 11357-1 and 11357-3 for 5 minutes, the polymer mixture has in the differential distribution curve W(M) determined to DIN 55672-2 in hexafluoroisopropanol as eluent at least 2 maxima of the relative frequency W, and the position of the maxima here after aging of the polymer mixture at the melting point of the polymer mixture is within three times the recurrent standard deviation sigma(r) of MP in percentage of the value measured to DIN 55672-2, based on the position of the maxima prior to aging of the polymer mixture at the melting point of the polymer mixture.

    19.
    发明专利
    未知

    公开(公告)号:DE10129525A1

    公开(公告)日:2003-01-09

    申请号:DE10129525

    申请日:2001-06-21

    Applicant: BASF AG

    Abstract: A thermoplastic polymer mixture comprising m polymers Pn, where m is a natural number greater than 1 and n is a natural number from 1 to m, where n is a natural number from 1 to m, where each of the polymers has one or more functional groups of the structure -(R )x-C(O)-(R )y- present as repeat units in the main chain of polymer Pn where x and y, independently of one another, are 0 or 1, and x+y=1 R and R , independently of one another, are oxygen or nitrogen bonded into the main polymer chain, where in the differential distribution curve W(M) determined to DIN 55672-2 in hexafluoroisopropanol as eluent the polymer mixture has at least two maxima of the relative frequency W, and after aging of the polymer mixture at the melting point of the polymer mixture determined to ISO 11357-1 and 11357-3 for 5 minutes, the polymer mixture has in the differential distribution curve W(M) determined to DIN 55672-2 in hexafluoroisopropanol as eluent at least 2 maxima of the relative frequency W, and the position of the maxima here after aging of the polymer mixture at the melting point of the polymer mixture is within three times the recurrent standard deviation sigma(r) of MP in percentage of the value measured to DIN 55672-2, based on the position of the maxima prior to aging of the polymer mixture at the melting point of the polymer mixture.

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