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公开(公告)号:DE102005046263A1
公开(公告)日:2007-03-29
申请号:DE102005046263
申请日:2005-09-27
Applicant: BASF AG
Inventor: HIBST HARTMUT , RIEGER JENS , KISSEL JUTTA , ANDRE VALERIE , MC KEE GRAHAM EDMUND
IPC: B01J13/02 , C01F5/02 , C01F7/02 , C01G1/02 , C01G9/02 , C08K3/10 , C08K9/10 , C09C1/04 , C09C3/10
Abstract: Preparation of an aqueous suspension of surface-modified nano-particles of a metallic oxide, a metal hydroxide and/or a metallic oxide hydroxide, where the metal is aluminum, magnesium, cerium, iron, titanium, zinc and zirconium, comprises mixing an aqueous solution of a metal salt with an aqueous solution of a polymer at a pH of 3-13 and at a temperature (T1) of 0-50[deg]C and precipitating the surface-modified nanoparticles of the metallic oxide, metal hydroxide and/or the metallic oxide hydroxide by heating the mixture at a temperature (T2) of 60-300[deg]C. Independent claims are included for: (1) a method for the production of a powdered surface-modified nanoparticles of metallic oxide, metal hydroxide and/or metallic oxide hydroxide, comprising mixing an aqueous solution of a metal salt with an aqueous solution of a polymer at a pH value of 3-13 and at a temperature (T1) of 0-50[deg]C, precipitating the surface-modified nano-particle of the metallic oxide, metal hydroxide and/or the metallic oxide hydroxide by heating the mixture at 60-300[deg]C, isolating the precipitated nanoparticles from the aqueous reaction mixture, and drying the nanoparticles; and (2) a powdered surface-modified nanoparticles of a metallic oxide, metal hydroxide, and/or a metallic oxide hydroxide, having a coating with polyasparaginic acid, with a BET surface area of 25-500 m 2>/g.
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公开(公告)号:AU2006254151A1
公开(公告)日:2006-12-07
申请号:AU2006254151
申请日:2006-05-30
Applicant: BASF AG
Inventor: RIEGER JENS , KISSEL JUTTA , BOUILLO NATHALIE , ANDRE VALERIE
Abstract: The present invention relates to surface-modified nanoparticulate metal oxides where the metal is chosen from the group consisting of aluminum, cerium, iron, titanium, zinc and zirconium, wherein the surface modification comprises a coating with a copolymer P comprising, as monomers, A) 1 to 99 mol % of a N-vinylamide N-vinylpyrrolidone and B) 99 to 1 mol % of a monomer comprising, per molecule, a free-radically polymerizable α,&bgr;-ethylenically unsaturated double bond and an anionogenic and/or anionic group, with the proviso that the copolymer P must comprise no further monomers chosen from the group consisting of C8-C30-alkyl esters of monoethylenically unsaturated C3-C8-carboxylic acids, N-alkyl- or N,N-dialkyl-substituted amides of acrylic acid or of methacrylic acid with C8-C18-alkyl radicals, or vinyl esters of aliphatic C8-C30-carboxylic acids.
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公开(公告)号:BRPI0611064A2
公开(公告)日:2016-11-16
申请号:BRPI0611064
申请日:2006-05-30
Applicant: BASF AG
Inventor: KISSEL JUTTA , RIEGER JENS , BOUILLO NATHALIE , ANDRE VALERIE
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公开(公告)号:DE102005025972A1
公开(公告)日:2006-12-07
申请号:DE102005025972
申请日:2005-06-03
Applicant: BASF AG
Inventor: RIEGER JENS , KISSEL JUTTA , ANDRE VALERIE , BOUILLO NATHALIE
Abstract: The present invention relates to surface-modified nanoparticulate metal oxides where the metal is chosen from the group consisting of aluminum, cerium, iron, titanium, zinc and zirconium, wherein the surface modification comprises a coating with a copolymer P comprising, as monomers, A) 1 to 99 mol % of a N-vinylamide N-vinylpyrrolidone and B) 99 to 1 mol % of a monomer comprising, per molecule, a free-radically polymerizable α,&bgr;-ethylenically unsaturated double bond and an anionogenic and/or anionic group, with the proviso that the copolymer P must comprise no further monomers chosen from the group consisting of C8-C30-alkyl esters of monoethylenically unsaturated C3-C8-carboxylic acids, N-alkyl- or N,N-dialkyl-substituted amides of acrylic acid or of methacrylic acid with C8-C18-alkyl radicals, or vinyl esters of aliphatic C8-C30-carboxylic acids.
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公开(公告)号:DE10156293A1
公开(公告)日:2003-05-28
申请号:DE10156293
申请日:2001-11-19
Applicant: BASF AG
Inventor: RAUSCHENBERGER VOLKER , LAUN HANS-MARTIN , KISSEL JUTTA , HECKMANN WALTER , BERNSTORFF BERND-STEFFEN VON , HORN HANS CHRISTOPH
Abstract: A thermoplastic polymer mixture (I) containing a polyamide (II) and a polymer (III), where the melt viscosity, as measured at 280 deg C is 100-20,000 s-1 is at most 75% of the melt viscosity measured in accordance with ISO 1443 of polyamide (II) at 280 deg C, and the boundary surface tension between a melt of polyamide (II) and a melt of polyamide (III) at 280 deg C, measured in accordance with US patent 5,50,607 by the Spinning-Drop-Method is in the region of 0-10 mN/m. A thermoplastic polymer mixture (I) containing (wt.%): (a) a polyamide (II)(50-99.9), (b) a polymer (III)( 0.1-50), where the melt viscosity, as measured in accordance with ISO 1443 of polyamide (II) at 280 deg C over the whole Scherraten (sic) region is 100-20,000 s-1 is at most 75% of the melt viscosity measured in accordance with ISO 1443 of polyamide (II) at 280 deg C, and the boundary surface tension between a melt of polyamide (II) and a melt of polyamide (III) at 280 deg C, measured in accordance with US patent 5,50,607 by the Spinning-Drop-Method is in the region of 0-10 mN/m. Independent claims are included for: (1) a process for preparation of a fiber by spinning a melt of a thermoplastic polymer, using the above polymer mixture (I) as the thermoplastic polymer; (2) a fiber obtained by the above process; (3) a carpet containing the above fiber; and (4) flat structure textiles containing the above fiber.
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公开(公告)号:AU2002366216A1
公开(公告)日:2003-06-10
申请号:AU2002366216
申请日:2002-11-15
Applicant: BASF AG
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公开(公告)号:DE10129532A1
公开(公告)日:2003-01-09
申请号:DE10129532
申请日:2001-06-21
Applicant: BASF AG
Inventor: EMRI IGOR , BERNSTORFF BERND-STEFFEN VON , RAUSCHENBERGER VOLKER , HORN HANS CHRISTOPH , KISSEL JUTTA , MOLNAR FERENC
IPC: C08G63/16 , C08G63/20 , C08G69/02 , C08G69/26 , C08G69/44 , C08L77/00 , C08G69/28 , C08J5/02 , C08K7/16 , C08L51/06 , C08L101/02
Abstract: The invention relates to a thermoplastic polymer, whose parent chain contains one or more recurrent functional groups with the structure - (R )x - C(O) - (R )y -. In said structure x and y independently of one another represent 0 or 1, whereby x + y = 1 or 2 and R and R independently of one another represent oxygen or nitrogen that are bound into the polymer parent chain. Said polymer is characterised in that the number of at least one species of reactive terminal groups (EG) in the polymer parent chain, (in relation to the sum of all said species of reactive terminal groups in the polymer parent chain), satisfies the inequation EG
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公开(公告)号:CA2622363A1
公开(公告)日:2007-04-05
申请号:CA2622363
申请日:2006-09-21
Applicant: BASF AG
Inventor: RIEGER JENS , HIBST HARTMUT , MC KEE GRAHAM EDMUND , KISSEL JUTTA , ANDRE VALERIE
Abstract: Powdery preparations of surface-modified, nanoparticulate particles of at least one metal oxide, metal hydroxide and/or metal oxyhydroxide are disclosed, as well as a method for preparing the same and their use for cosmetic sunscreen preparations, as stabilisers in plastics and as active antimicrobial substances. Also disclosed is a method for producing aqueous suspensions of surface-modified, nanoparticulate particles of at least one metal oxide, metal hydroxide and/or metal oxyhydroxide.
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公开(公告)号:AU2002366216A8
公开(公告)日:2003-06-10
申请号:AU2002366216
申请日:2002-11-15
Applicant: BASF AG
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